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An intramolecular oxygenation sequence leads to the hithero unknown C-17,C-18-bridged title estrane derivative, C20H24O3. The requisite assignment of its configuration was carried out by X-ray analysis.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, na1351

fcf

Structure factor file (CIF format)
Contains datablock na1351

CCDC reference: 130331

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