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The title compound, [Co(C4H7N2O2)2(C4H7O2)(C9H12N3P)], has been analyzed by X-ray diffraction to correlate the structure with the reactivity of the photoracemization on exposure to visible light. Although the crystal decomposed during the racemization, the size of the reaction cavity for the 1-methoxycarbonylethyl group explains the high reactivity.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks cobaloxime, global

hkl

Structure factor file (CIF format)
Contains datablock cobaloxime

CCDC reference: 130105

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