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The title complex [{Li(C4H8O)3}Br{Pr(C9H13)3}] has a distorted pseudo-tetrahedral geometry around the ten-coordinate Pr atom. The (tBuCp)3Pr unit and Li(thf)3+ cation (where thf is tetrahydrofuran) are connected by a μ-Br atom. The Pr—Br and Li—Br distances are 2.995 (1) and 2.495 (15) Å, respectively, and the Pr—Br—Li angle is 137.3 (3)°.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, I

hkl

Structure factor file (CIF format)
Supplementary material

CCDC reference: 130102

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