metal-organic compounds
The coordination around the Cu-metal centre in the title compound, [CuBr(C15H24N2S)(C18H15P)2], is distorted tetrahedral with bond lengths Cu—S 2.367 (1), Cu—Br 2.469 (1), Cu—P(1) 2.279 (2) and Cu—P(2) 2.284 (2) Å, and bond angles S—Cu—Br 111.86 (5), S—Cu—P(1) 111.28 (6), S—Cu—P(2) 98.01 (6), Br—Cu—P(1) 103.08 (5), Br—Cu—P(2) 108.60 (5) and P(1)—Cu—P(2) 124.11 (6)°. The H atom of the NH group is intramolecularly hydrogen bonded to the Br atom, with an NHBr distance of 2.411 Å.
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (CIF format) |
CCDC reference: 126463