A new polymorph of trans-carbonyl­chlorobis[tris­(4-fluoro­phenyl)phosphine]rhodium(I)

In the title compound, trans-[RhCl{P(4-FC₆H₄)₃}₂(CO)], where 4-FC₆H₄ is 4-fluoro­phenyl, the Rh—P bond distances are 2.3118 (5), 2.3220 (5), 2.3136 (5) and 2.3233 (5) Å, and the Rh—Cl bond distances are 2.3689 (5) and 2.3694 (5) Å. The effective cone angles (θ_E) for the phosphine ligands were calculated to be 155 and 156°.

Key indicators

• Single-crystal X-ray study
• T = 150 K
• Mean [sigma](C-C) = 0.003 Å
• R factor = 0.027
• wR factor = 0.067
• Data-to-parameter ratio = 19.4

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       2.51 Ratio
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Rh1    -   P1      ..       5.36 su
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Rh1    -   C01     ..       9.14 su
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X)  Rh2    -   C02     ..       9.56 su
PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........          4

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   5 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   4 ALERT type 2 Indicator that the structure model may be wrong or deficient
   0 ALERT type 3 Indicator that the structure quality may be low
   1 ALERT type 4 Improvement, methodology, query or suggestion

---

Computing details

Data collection: APEX2 (Bruker, 2005); cell refinement: SAINT-Plus (Bruker, 2004); data reduction: SAINT-Plus and XPREP (Bruker 2004); program(s) used to solve structure: SIR97 (Altomare et al., 1999); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: DIAMOND (Brandenburg & Putz, 2005); software used to prepare material for publication: WinGX (Farrugia, 1999).

trans-carbonylchlorobis[tris(4-fluorophenyl)phosphine]rhodium(I)

Crystal data

[RhCl(C18H12F3P)(CO)]	Z = 4
Mr = 798.86	F(000) = 1600
Triclinic, P1	Dx = 1.578 Mg m^−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 11.0530 (4) Å	Cell parameters from 7376 reflections
b = 12.0560 (4) Å	θ = 2.9–28.3°
c = 26.5140 (9) Å	µ = 0.75 mm^−1
α = 83.685 (2)°	T = 150 K
β = 84.150 (2)°	Cuboid, yellow
γ = 73.725 (2)°	0.30 × 0.11 × 0.06 mm
V = 3361.6 (2) Å^3

Data collection

Bruker X8 APEXII 4K KappaCCD area-detector diffractometer	16749 independent reflections
Radiation source: fine-focus sealed tube	14119 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.031
ω and φ scans	θmax = 28.3°, θmin = 0.8°
Absorption correction: multi-scan (SADABS; Bruker, 1998)	h = −14→14
Tmin = 0.807, Tmax = 0.957	k = −16→16
59610 measured reflections	l = −35→35

Refinement

Refinement on F^2	0 restraints
Least-squares matrix: full	H-atom parameters constrained
R[F^2 > 2σ(F^2)] = 0.027	w = 1/[σ^2(Fo^2) + (0.0273P)^2 + 2.075P] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.067	(Δ/σ)max = 0.001
S = 1.01	Δρmax = 0.52 e Å^−3
16749 reflections	Δρmin = −0.35 e Å^−3
865 parameters

Special details

Experimental. The intensity data were collected on a Bruker X8 Apex II 4 K Kappa CCD diffractometer using an exposure time of 10 s per frame. A total of 2216 frames were collected with a frame width of 0.5° covering up to θ = 28.34° with 99.7% completeness accomplished.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Rh1	0.982452 (13)	0.602025 (12)	0.132789 (5)	0.01665 (4)
P1	0.98366 (5)	0.41183 (4)	0.126869 (19)	0.01894 (10)
P2	0.98859 (5)	0.78457 (4)	0.150646 (18)	0.01777 (9)
Cl1	0.80794 (4)	0.61249 (4)	0.193616 (18)	0.02434 (10)
C01	1.11113 (19)	0.59185 (16)	0.08361 (8)	0.0237 (4)
O01	1.18989 (15)	0.58450 (14)	0.05152 (6)	0.0373 (4)
C1	1.10414 (18)	0.33698 (15)	0.08022 (7)	0.0197 (4)
C2	1.07659 (19)	0.35813 (16)	0.02928 (7)	0.0234 (4)
H2	0.9953	0.3988	0.0211	0.028*
C3	1.1680 (2)	0.31963 (17)	−0.00912 (8)	0.0250 (4)
H3	1.1497	0.3344	−0.0431	0.03*
C4	1.28690 (19)	0.25897 (17)	0.00420 (8)	0.0254 (4)
C5	1.31731 (19)	0.23326 (19)	0.05362 (8)	0.0285 (4)
H5	1.3981	0.1901	0.0614	0.034*
C6	1.22469 (19)	0.27311 (17)	0.09210 (8)	0.0254 (4)
H6	1.2438	0.2568	0.1259	0.031*
C7	1.02247 (18)	0.33193 (16)	0.18791 (7)	0.0227 (4)
C8	0.9577 (2)	0.25592 (18)	0.21324 (9)	0.0317 (5)
H8	0.8911	0.2423	0.1984	0.038*
C9	0.9916 (2)	0.2002 (2)	0.26043 (9)	0.0390 (6)
H9	0.9483	0.1495	0.2774	0.047*
C10	1.0904 (2)	0.2216 (2)	0.28138 (8)	0.0363 (5)
C11	1.1567 (2)	0.29657 (19)	0.25811 (8)	0.0327 (5)
H11	1.2234	0.3092	0.2733	0.039*
C12	1.1207 (2)	0.35285 (18)	0.21122 (8)	0.0273 (4)
H12	1.1628	0.4054	0.1951	0.033*
C13	0.84346 (19)	0.38228 (17)	0.10730 (8)	0.0245 (4)
C14	0.8480 (2)	0.27148 (19)	0.09472 (9)	0.0353 (5)
H14	0.9184	0.2101	0.1017	0.042*
C15	0.7499 (3)	0.2517 (2)	0.07222 (10)	0.0460 (6)
H15	0.7531	0.1778	0.0641	0.055*
C16	0.6479 (3)	0.3436 (3)	0.06210 (11)	0.0493 (7)
C17	0.6375 (2)	0.4534 (2)	0.07465 (10)	0.0428 (6)
H17	0.566	0.5137	0.0678	0.051*
C18	0.7364 (2)	0.47234 (19)	0.09783 (8)	0.0300 (5)
H18	0.7306	0.546	0.1071	0.036*
C19	1.09004 (18)	0.85556 (16)	0.10779 (7)	0.0205 (4)
C20	1.0448 (2)	0.95735 (18)	0.07755 (8)	0.0310 (5)
H20	0.9587	0.9946	0.0794	0.037*
C21	1.1272 (2)	1.0042 (2)	0.04443 (9)	0.0396 (6)
H21	1.0971	1.0728	0.0243	0.047*
C22	1.2527 (2)	0.94756 (19)	0.04210 (8)	0.0322 (5)
C23	1.3019 (2)	0.84748 (19)	0.07119 (8)	0.0312 (5)
H23	1.3882	0.8112	0.0689	0.037*
C24	1.2197 (2)	0.80126 (18)	0.10431 (8)	0.0273 (4)
H24	1.2513	0.7331	0.1245	0.033*
C25	1.04585 (18)	0.78423 (16)	0.21283 (7)	0.0208 (4)
C26	1.0397 (2)	0.69491 (19)	0.24960 (8)	0.0344 (5)
H26	1.0114	0.6337	0.2416	0.041*
C27	1.0752 (3)	0.6953 (2)	0.29811 (9)	0.0432 (6)
H27	1.0716	0.6348	0.3227	0.052*
C28	1.1157 (2)	0.7866 (2)	0.30926 (8)	0.0362 (5)
C29	1.1270 (2)	0.8751 (2)	0.27343 (9)	0.0354 (5)
H29	1.1573	0.9349	0.2816	0.042*
C30	1.0922 (2)	0.87332 (18)	0.22497 (8)	0.0297 (5)
H30	1.0998	0.9324	0.2002	0.036*
C31	0.83479 (18)	0.89138 (15)	0.15184 (7)	0.0198 (4)
C32	0.7923 (2)	0.96825 (18)	0.18928 (8)	0.0283 (4)
H32	0.8426	0.9656	0.2157	0.034*
C33	0.6752 (2)	1.04890 (19)	0.18756 (8)	0.0339 (5)
H33	0.6464	1.1008	0.2125	0.041*
C34	0.60302 (19)	1.05055 (17)	0.14847 (8)	0.0270 (4)
C35	0.6394 (2)	0.97496 (18)	0.11142 (8)	0.0277 (4)
H35	0.5873	0.9773	0.0857	0.033*
C36	0.75685 (19)	0.89456 (17)	0.11356 (8)	0.0272 (4)
H36	0.7838	0.8419	0.0889	0.033*
F1	1.37785 (12)	0.22313 (12)	−0.03358 (5)	0.0362 (3)
F2	1.12383 (14)	0.16714 (14)	0.32750 (5)	0.0523 (4)
F3	0.55360 (17)	0.32539 (18)	0.03804 (8)	0.0788 (6)
F4	1.33317 (15)	0.99241 (13)	0.00941 (6)	0.0497 (4)
F5	1.14937 (18)	0.78836 (14)	0.35676 (5)	0.0580 (5)
F6	0.48846 (12)	1.13076 (12)	0.14666 (5)	0.0398 (3)
Rh2	0.543138 (13)	0.156397 (11)	0.367911 (5)	0.01554 (4)
P3	0.53595 (4)	−0.03462 (4)	0.374217 (18)	0.01697 (9)
P4	0.54185 (4)	0.34987 (4)	0.350675 (18)	0.01673 (9)
Cl2	0.72729 (4)	0.10095 (4)	0.312189 (17)	0.02167 (9)
C02	0.40659 (19)	0.19151 (16)	0.41355 (8)	0.0241 (4)
O02	0.32293 (16)	0.21035 (13)	0.44356 (7)	0.0411 (4)
C37	0.40666 (17)	−0.06274 (15)	0.41794 (7)	0.0188 (4)
C38	0.28580 (18)	−0.04647 (17)	0.40281 (7)	0.0230 (4)
H38	0.2716	−0.0312	0.3684	0.028*
C39	0.18560 (19)	−0.05268 (18)	0.43833 (8)	0.0269 (4)
H39	0.1046	−0.0412	0.4282	0.032*
C40	0.20969 (19)	−0.07620 (17)	0.48860 (8)	0.0254 (4)
C41	0.32785 (19)	−0.09436 (17)	0.50532 (7)	0.0240 (4)
H41	0.3413	−0.1112	0.5397	0.029*
C42	0.42633 (19)	−0.08688 (16)	0.46962 (7)	0.0218 (4)
H42	0.5069	−0.0981	0.4802	0.026*
C43	0.50482 (18)	−0.06915 (16)	0.31259 (7)	0.0208 (4)
C44	0.5650 (2)	−0.17249 (19)	0.29097 (8)	0.0297 (5)
H44	0.6272	−0.2284	0.3079	0.036*
C45	0.5325 (2)	−0.1926 (2)	0.24414 (9)	0.0370 (5)
H45	0.5726	−0.2615	0.2295	0.044*
C46	0.4410 (2)	−0.1096 (2)	0.22013 (8)	0.0359 (5)
C47	0.3810 (2)	−0.0048 (2)	0.23936 (8)	0.0317 (5)
H47	0.3198	0.0507	0.2218	0.038*
C48	0.41489 (18)	0.01526 (17)	0.28572 (7)	0.0240 (4)
H48	0.3772	0.086	0.2991	0.029*
C49	0.66917 (17)	−0.14867 (15)	0.39767 (7)	0.0208 (4)
C50	0.6559 (2)	−0.26035 (17)	0.41063 (8)	0.0281 (4)
H50	0.585	−0.2788	0.4019	0.034*
C51	0.7470 (2)	−0.34359 (18)	0.43627 (9)	0.0333 (5)
H51	0.7385	−0.4181	0.4447	0.04*
C52	0.8504 (2)	−0.31370 (19)	0.44901 (9)	0.0324 (5)
C53	0.8691 (2)	−0.20618 (19)	0.43569 (9)	0.0321 (5)
H53	0.9415	−0.1893	0.4439	0.038*
C54	0.77706 (18)	−0.12310 (17)	0.40966 (8)	0.0250 (4)
H54	0.788	−0.0497	0.4002	0.03*
C55	0.43655 (18)	0.45220 (15)	0.39234 (7)	0.0191 (4)
C56	0.30749 (19)	0.46226 (17)	0.39461 (8)	0.0244 (4)
H56	0.278	0.4178	0.3748	0.029*
C57	0.2224 (2)	0.53727 (18)	0.42583 (8)	0.0272 (4)
H57	0.1363	0.5436	0.4274	0.033*
C58	0.2692 (2)	0.60222 (17)	0.45450 (8)	0.0262 (4)
C59	0.3944 (2)	0.59530 (18)	0.45347 (8)	0.0311 (5)
H59	0.4227	0.6407	0.4732	0.037*
C60	0.4792 (2)	0.51899 (17)	0.42222 (8)	0.0267 (4)
H60	0.5652	0.5127	0.4214	0.032*
C61	0.69468 (17)	0.37854 (15)	0.35186 (7)	0.0186 (4)
C62	0.73749 (19)	0.45517 (18)	0.31631 (8)	0.0260 (4)
H62	0.6881	0.4929	0.2899	0.031*
C63	0.8531 (2)	0.4758 (2)	0.31995 (9)	0.0327 (5)
H63	0.8822	0.5267	0.2961	0.039*
C64	0.92382 (19)	0.41980 (18)	0.35926 (8)	0.0271 (4)
C65	0.88675 (19)	0.34178 (18)	0.39497 (8)	0.0274 (4)
H65	0.9374	0.3039	0.421	0.033*
C66	0.77089 (19)	0.32177 (17)	0.39058 (8)	0.0265 (4)
H66	0.7435	0.2691	0.4141	0.032*
C67	0.48800 (17)	0.40944 (16)	0.28813 (7)	0.0198 (4)
C68	0.4292 (2)	0.52684 (18)	0.27741 (8)	0.0321 (5)
H68	0.4169	0.5774	0.3027	0.038*
C69	0.3889 (2)	0.56928 (19)	0.22936 (9)	0.0363 (5)
H69	0.3493	0.6476	0.2222	0.044*
C70	0.4089 (2)	0.4930 (2)	0.19280 (8)	0.0336 (5)
C71	0.4655 (3)	0.3775 (2)	0.20184 (9)	0.0463 (7)
H71	0.478	0.3277	0.1762	0.056*
C72	0.5040 (2)	0.33603 (19)	0.24990 (8)	0.0372 (5)
H72	0.5415	0.2572	0.2567	0.045*
F7	0.11315 (12)	−0.08361 (12)	0.52382 (5)	0.0364 (3)
F8	0.93552 (13)	−0.39382 (12)	0.47639 (6)	0.0505 (4)
F9	0.40806 (15)	−0.12999 (15)	0.17490 (5)	0.0548 (4)
F10	0.18585 (13)	0.67648 (11)	0.48493 (5)	0.0401 (3)
F11	1.03750 (12)	0.44014 (13)	0.36296 (5)	0.0413 (3)
F12	0.36870 (16)	0.53334 (13)	0.14593 (5)	0.0526 (4)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Rh1	0.01801 (7)	0.01439 (7)	0.01731 (7)	−0.00430 (5)	−0.00050 (5)	−0.00126 (5)
P1	0.0200 (2)	0.0158 (2)	0.0212 (2)	−0.00529 (18)	−0.00105 (18)	−0.00152 (18)
P2	0.0204 (2)	0.0146 (2)	0.0181 (2)	−0.00446 (18)	−0.00158 (18)	−0.00095 (17)
Cl1	0.0236 (2)	0.0260 (2)	0.0226 (2)	−0.00713 (19)	0.00555 (18)	−0.00408 (18)
C01	0.0284 (10)	0.0201 (9)	0.0240 (10)	−0.0085 (8)	−0.0017 (8)	−0.0031 (7)
O01	0.0399 (9)	0.0400 (9)	0.0339 (9)	−0.0175 (8)	0.0151 (7)	−0.0108 (7)
C1	0.0228 (9)	0.0141 (8)	0.0229 (9)	−0.0063 (7)	−0.0003 (7)	−0.0021 (7)
C2	0.0253 (10)	0.0182 (9)	0.0247 (10)	−0.0018 (8)	−0.0053 (8)	−0.0017 (7)
C3	0.0321 (11)	0.0231 (9)	0.0204 (10)	−0.0081 (8)	−0.0040 (8)	−0.0012 (7)
C4	0.0256 (10)	0.0278 (10)	0.0238 (10)	−0.0094 (8)	0.0043 (8)	−0.0071 (8)
C5	0.0202 (10)	0.0344 (11)	0.0299 (11)	−0.0040 (8)	−0.0040 (8)	−0.0050 (9)
C6	0.0249 (10)	0.0279 (10)	0.0223 (10)	−0.0044 (8)	−0.0036 (8)	−0.0025 (8)
C7	0.0239 (10)	0.0184 (9)	0.0223 (10)	−0.0022 (8)	0.0017 (8)	0.0009 (7)
C8	0.0271 (11)	0.0272 (11)	0.0375 (12)	−0.0067 (9)	0.0009 (9)	0.0064 (9)
C9	0.0315 (12)	0.0334 (12)	0.0426 (14)	−0.0033 (10)	0.0065 (10)	0.0149 (10)
C10	0.0329 (12)	0.0354 (12)	0.0242 (11)	0.0096 (10)	0.0058 (9)	0.0106 (9)
C11	0.0322 (12)	0.0362 (12)	0.0247 (11)	−0.0017 (10)	−0.0035 (9)	0.0005 (9)
C12	0.0314 (11)	0.0257 (10)	0.0236 (10)	−0.0079 (9)	−0.0007 (8)	0.0017 (8)
C13	0.0255 (10)	0.0257 (10)	0.0255 (10)	−0.0129 (8)	0.0004 (8)	−0.0028 (8)
C14	0.0366 (12)	0.0283 (11)	0.0451 (14)	−0.0156 (10)	−0.0015 (10)	−0.0050 (10)
C15	0.0513 (16)	0.0462 (15)	0.0541 (16)	−0.0330 (13)	−0.0003 (13)	−0.0132 (12)
C16	0.0402 (15)	0.0705 (19)	0.0518 (16)	−0.0364 (14)	−0.0060 (12)	−0.0087 (14)
C17	0.0246 (12)	0.0549 (16)	0.0503 (15)	−0.0120 (11)	−0.0061 (11)	−0.0046 (12)
C18	0.0255 (11)	0.0345 (11)	0.0315 (11)	−0.0108 (9)	−0.0002 (9)	−0.0040 (9)
C19	0.0257 (10)	0.0183 (9)	0.0190 (9)	−0.0083 (8)	−0.0010 (7)	−0.0018 (7)
C20	0.0326 (12)	0.0224 (10)	0.0333 (12)	−0.0037 (9)	0.0000 (9)	0.0053 (8)
C21	0.0496 (15)	0.0276 (11)	0.0365 (13)	−0.0100 (11)	0.0022 (11)	0.0122 (10)
C22	0.0435 (13)	0.0318 (11)	0.0250 (11)	−0.0202 (10)	0.0098 (9)	−0.0031 (9)
C23	0.0273 (11)	0.0340 (11)	0.0334 (12)	−0.0116 (9)	0.0046 (9)	−0.0049 (9)
C24	0.0269 (10)	0.0258 (10)	0.0284 (11)	−0.0083 (8)	−0.0015 (8)	0.0038 (8)
C25	0.0223 (9)	0.0209 (9)	0.0192 (9)	−0.0058 (7)	−0.0032 (7)	−0.0008 (7)
C26	0.0522 (14)	0.0311 (11)	0.0279 (11)	−0.0239 (11)	−0.0121 (10)	0.0046 (9)
C27	0.0706 (18)	0.0418 (13)	0.0281 (12)	−0.0337 (13)	−0.0178 (12)	0.0118 (10)
C28	0.0501 (14)	0.0428 (13)	0.0231 (11)	−0.0221 (11)	−0.0126 (10)	−0.0001 (9)
C29	0.0468 (14)	0.0378 (12)	0.0312 (12)	−0.0257 (11)	−0.0065 (10)	−0.0041 (9)
C30	0.0387 (12)	0.0290 (11)	0.0266 (11)	−0.0185 (9)	−0.0046 (9)	0.0013 (8)
C31	0.0220 (9)	0.0160 (8)	0.0212 (9)	−0.0049 (7)	−0.0010 (7)	−0.0011 (7)
C32	0.0306 (11)	0.0290 (10)	0.0233 (10)	−0.0016 (9)	−0.0059 (8)	−0.0071 (8)
C33	0.0354 (12)	0.0317 (11)	0.0275 (11)	0.0067 (9)	−0.0040 (9)	−0.0125 (9)
C34	0.0252 (10)	0.0239 (10)	0.0249 (10)	0.0030 (8)	−0.0003 (8)	0.0008 (8)
C35	0.0272 (11)	0.0288 (10)	0.0261 (11)	−0.0038 (9)	−0.0065 (8)	−0.0045 (8)
C36	0.0273 (10)	0.0255 (10)	0.0280 (11)	−0.0021 (8)	−0.0041 (8)	−0.0108 (8)
F1	0.0285 (7)	0.0502 (8)	0.0289 (7)	−0.0093 (6)	0.0078 (5)	−0.0122 (6)
F2	0.0453 (9)	0.0595 (10)	0.0318 (8)	0.0073 (7)	0.0015 (6)	0.0226 (7)
F3	0.0533 (11)	0.1048 (15)	0.1012 (15)	−0.0470 (11)	−0.0242 (10)	−0.0237 (12)
F4	0.0591 (10)	0.0470 (8)	0.0433 (8)	−0.0266 (8)	0.0207 (7)	0.0040 (7)
F5	0.0975 (13)	0.0662 (10)	0.0290 (8)	−0.0487 (10)	−0.0275 (8)	0.0057 (7)
F6	0.0323 (7)	0.0390 (7)	0.0355 (7)	0.0132 (6)	−0.0061 (6)	−0.0062 (6)
Rh2	0.01657 (7)	0.01362 (7)	0.01662 (7)	−0.00497 (5)	−0.00043 (5)	−0.00052 (5)
P3	0.0171 (2)	0.0146 (2)	0.0197 (2)	−0.00507 (17)	−0.00151 (18)	−0.00113 (17)
P4	0.0177 (2)	0.0144 (2)	0.0186 (2)	−0.00562 (17)	−0.00140 (18)	−0.00025 (17)
Cl2	0.0201 (2)	0.0223 (2)	0.0211 (2)	−0.00542 (17)	0.00395 (17)	−0.00117 (17)
C02	0.0287 (10)	0.0165 (9)	0.0265 (10)	−0.0070 (8)	0.0005 (8)	−0.0004 (7)
O02	0.0428 (10)	0.0305 (8)	0.0445 (10)	−0.0092 (7)	0.0233 (8)	−0.0059 (7)
C37	0.0204 (9)	0.0149 (8)	0.0218 (9)	−0.0069 (7)	−0.0008 (7)	−0.0002 (7)
C38	0.0229 (10)	0.0266 (10)	0.0197 (9)	−0.0081 (8)	−0.0028 (7)	0.0015 (7)
C39	0.0181 (9)	0.0348 (11)	0.0278 (11)	−0.0078 (8)	−0.0016 (8)	−0.0012 (9)
C40	0.0254 (10)	0.0237 (10)	0.0253 (10)	−0.0073 (8)	0.0068 (8)	−0.0010 (8)
C41	0.0298 (10)	0.0232 (9)	0.0185 (9)	−0.0075 (8)	−0.0011 (8)	0.0013 (7)
C42	0.0231 (10)	0.0195 (9)	0.0241 (10)	−0.0076 (8)	−0.0055 (8)	0.0011 (7)
C43	0.0204 (9)	0.0236 (9)	0.0207 (9)	−0.0102 (8)	0.0012 (7)	−0.0043 (7)
C44	0.0250 (10)	0.0291 (11)	0.0355 (12)	−0.0057 (9)	−0.0010 (9)	−0.0108 (9)
C45	0.0334 (12)	0.0428 (13)	0.0387 (13)	−0.0112 (10)	0.0049 (10)	−0.0249 (11)
C46	0.0326 (12)	0.0586 (15)	0.0244 (11)	−0.0217 (11)	0.0014 (9)	−0.0170 (10)
C47	0.0263 (11)	0.0460 (13)	0.0247 (11)	−0.0123 (10)	−0.0032 (8)	−0.0032 (9)
C48	0.0233 (10)	0.0271 (10)	0.0224 (10)	−0.0084 (8)	0.0004 (8)	−0.0034 (8)
C49	0.0185 (9)	0.0160 (8)	0.0255 (10)	−0.0015 (7)	−0.0008 (7)	−0.0006 (7)
C50	0.0263 (10)	0.0191 (9)	0.0388 (12)	−0.0058 (8)	−0.0038 (9)	−0.0012 (8)
C51	0.0298 (11)	0.0179 (9)	0.0463 (14)	−0.0015 (8)	0.0026 (10)	0.0044 (9)
C52	0.0203 (10)	0.0309 (11)	0.0354 (12)	0.0043 (9)	0.0026 (9)	0.0095 (9)
C53	0.0184 (10)	0.0340 (11)	0.0410 (13)	−0.0053 (9)	−0.0047 (9)	0.0065 (10)
C54	0.0206 (10)	0.0224 (9)	0.0306 (11)	−0.0061 (8)	0.0006 (8)	0.0022 (8)
C55	0.0223 (9)	0.0149 (8)	0.0203 (9)	−0.0061 (7)	−0.0011 (7)	−0.0002 (7)
C56	0.0235 (10)	0.0239 (10)	0.0271 (10)	−0.0073 (8)	−0.0022 (8)	−0.0052 (8)
C57	0.0223 (10)	0.0287 (10)	0.0293 (11)	−0.0054 (8)	0.0011 (8)	−0.0036 (8)
C58	0.0330 (11)	0.0210 (9)	0.0217 (10)	−0.0047 (8)	0.0065 (8)	−0.0037 (8)
C59	0.0383 (12)	0.0284 (11)	0.0310 (11)	−0.0137 (9)	0.0003 (9)	−0.0121 (9)
C60	0.0267 (10)	0.0263 (10)	0.0304 (11)	−0.0116 (8)	−0.0010 (8)	−0.0060 (8)
C61	0.0184 (9)	0.0168 (8)	0.0213 (9)	−0.0061 (7)	0.0003 (7)	−0.0028 (7)
C62	0.0265 (10)	0.0295 (10)	0.0238 (10)	−0.0128 (9)	−0.0035 (8)	0.0052 (8)
C63	0.0330 (12)	0.0383 (12)	0.0310 (12)	−0.0212 (10)	−0.0007 (9)	0.0081 (9)
C64	0.0205 (10)	0.0344 (11)	0.0310 (11)	−0.0151 (9)	0.0010 (8)	−0.0056 (9)
C65	0.0227 (10)	0.0349 (11)	0.0259 (11)	−0.0096 (9)	−0.0064 (8)	0.0010 (8)
C66	0.0272 (10)	0.0266 (10)	0.0264 (10)	−0.0119 (8)	−0.0031 (8)	0.0070 (8)
C67	0.0187 (9)	0.0198 (9)	0.0211 (9)	−0.0061 (7)	−0.0025 (7)	0.0012 (7)
C68	0.0433 (13)	0.0211 (10)	0.0271 (11)	0.0000 (9)	−0.0069 (9)	−0.0008 (8)
C69	0.0424 (13)	0.0249 (11)	0.0331 (12)	0.0040 (10)	−0.0084 (10)	0.0044 (9)
C70	0.0380 (12)	0.0340 (12)	0.0240 (11)	−0.0026 (10)	−0.0108 (9)	0.0060 (9)
C71	0.077 (2)	0.0293 (12)	0.0271 (12)	0.0003 (12)	−0.0156 (12)	−0.0053 (9)
C72	0.0574 (16)	0.0204 (10)	0.0273 (11)	0.0022 (10)	−0.0109 (11)	−0.0016 (8)
F7	0.0283 (7)	0.0466 (8)	0.0292 (7)	−0.0078 (6)	0.0090 (5)	0.0028 (6)
F8	0.0260 (7)	0.0423 (8)	0.0671 (10)	0.0058 (6)	−0.0058 (7)	0.0264 (7)
F9	0.0528 (9)	0.0872 (12)	0.0340 (8)	−0.0249 (9)	−0.0049 (7)	−0.0297 (8)
F10	0.0413 (8)	0.0381 (7)	0.0394 (8)	−0.0079 (6)	0.0143 (6)	−0.0203 (6)
F11	0.0281 (7)	0.0587 (9)	0.0457 (8)	−0.0275 (7)	−0.0060 (6)	0.0029 (7)
F12	0.0707 (11)	0.0475 (9)	0.0285 (7)	0.0042 (8)	−0.0210 (7)	0.0066 (6)

Geometric parameters (Å, º)

Rh1—C01	1.816 (2)	Rh2—C02	1.818 (2)
Rh1—P1	2.3118 (5)	Rh2—P3	2.3136 (5)
Rh1—P2	2.3220 (5)	Rh2—P4	2.3233 (5)
Rh1—Cl1	2.3689 (5)	Rh2—Cl2	2.3694 (5)
P1—C7	1.816 (2)	P3—C43	1.8183 (19)
P1—C13	1.820 (2)	P3—C49	1.8192 (19)
P1—C1	1.8314 (19)	P3—C37	1.8298 (19)
P2—C31	1.8221 (19)	P4—C61	1.8205 (18)
P2—C25	1.8244 (19)	P4—C67	1.8220 (19)
P2—C19	1.8290 (19)	P4—C55	1.8248 (19)
C01—O01	1.145 (2)	C02—O02	1.145 (2)
C1—C6	1.387 (3)	C37—C38	1.389 (3)
C1—C2	1.395 (3)	C37—C42	1.396 (3)
C2—C3	1.380 (3)	C38—C39	1.392 (3)
C2—H2	0.93	C38—H38	0.93
C3—C4	1.373 (3)	C39—C40	1.369 (3)
C3—H3	0.93	C39—H39	0.93
C4—F1	1.359 (2)	C40—F7	1.360 (2)
C4—C5	1.367 (3)	C40—C41	1.374 (3)
C5—C6	1.392 (3)	C41—C42	1.384 (3)
C5—H5	0.93	C41—H41	0.93
C6—H6	0.93	C42—H42	0.93
C7—C8	1.392 (3)	C43—C44	1.392 (3)
C7—C12	1.396 (3)	C43—C48	1.396 (3)
C8—C9	1.388 (3)	C44—C45	1.391 (3)
C8—H8	0.93	C44—H44	0.93
C9—C10	1.370 (4)	C45—C46	1.362 (3)
C9—H9	0.93	C45—H45	0.93
C10—F2	1.357 (2)	C46—F9	1.355 (2)
C10—C11	1.376 (3)	C46—C47	1.378 (3)
C11—C12	1.389 (3)	C47—C48	1.385 (3)
C11—H11	0.93	C47—H47	0.93
C12—H12	0.93	C48—H48	0.93
C13—C18	1.387 (3)	C49—C54	1.387 (3)
C13—C14	1.398 (3)	C49—C50	1.397 (3)
C14—C15	1.377 (3)	C50—C51	1.380 (3)
C14—H14	0.93	C50—H50	0.93
C15—C16	1.367 (4)	C51—C52	1.374 (3)
C15—H15	0.93	C51—H51	0.93
C16—F3	1.355 (3)	C52—F8	1.349 (2)
C16—C17	1.371 (4)	C52—C53	1.372 (3)
C17—C18	1.390 (3)	C53—C54	1.391 (3)
C17—H17	0.93	C53—H53	0.93
C18—H18	0.93	C54—H54	0.93
C19—C20	1.386 (3)	C55—C60	1.389 (3)
C19—C24	1.397 (3)	C55—C56	1.393 (3)
C20—C21	1.391 (3)	C56—C57	1.385 (3)
C20—H20	0.93	C56—H56	0.93
C21—C22	1.363 (3)	C57—C58	1.377 (3)
C21—H21	0.93	C57—H57	0.93
C22—F4	1.358 (2)	C58—F10	1.359 (2)
C22—C23	1.363 (3)	C58—C59	1.360 (3)
C23—C24	1.386 (3)	C59—C60	1.392 (3)
C23—H23	0.93	C59—H59	0.93
C24—H24	0.93	C60—H60	0.93
C25—C26	1.383 (3)	C61—C62	1.389 (3)
C25—C30	1.392 (3)	C61—C66	1.389 (3)
C26—C27	1.383 (3)	C62—C63	1.383 (3)
C26—H26	0.93	C62—H62	0.93
C27—C28	1.368 (3)	C63—C64	1.367 (3)
C27—H27	0.93	C63—H63	0.93
C28—F5	1.353 (2)	C64—F11	1.361 (2)
C28—C29	1.372 (3)	C64—C65	1.375 (3)
C29—C30	1.382 (3)	C65—C66	1.386 (3)
C29—H29	0.93	C65—H65	0.93
C30—H30	0.93	C66—H66	0.93
C31—C36	1.387 (3)	C67—C72	1.384 (3)
C31—C32	1.389 (3)	C67—C68	1.393 (3)
C32—C33	1.385 (3)	C68—C69	1.389 (3)
C32—H32	0.93	C68—H68	0.93
C33—C34	1.366 (3)	C69—C70	1.368 (3)
C33—H33	0.93	C69—H69	0.93
C34—F6	1.363 (2)	C70—F12	1.355 (2)
C34—C35	1.367 (3)	C70—C71	1.363 (3)
C35—C36	1.387 (3)	C71—C72	1.381 (3)
C35—H35	0.93	C71—H71	0.93
C36—H36	0.93	C72—H72	0.93
C01—Rh1—P1	91.41 (6)	C02—Rh2—P3	90.30 (6)
C01—Rh1—P2	92.43 (6)	C02—Rh2—P4	92.37 (6)
P1—Rh1—P2	171.800 (18)	P3—Rh2—P4	172.352 (18)
C01—Rh1—Cl1	176.78 (6)	C02—Rh2—Cl2	176.36 (6)
P1—Rh1—Cl1	86.902 (17)	P3—Rh2—Cl2	87.484 (16)
P2—Rh1—Cl1	89.601 (17)	P4—Rh2—Cl2	90.188 (17)
C7—P1—C13	108.94 (9)	C43—P3—C49	108.29 (9)
C7—P1—C1	105.58 (9)	C43—P3—C37	104.92 (8)
C13—P1—C1	100.66 (9)	C49—P3—C37	100.76 (9)
C7—P1—Rh1	107.82 (6)	C43—P3—Rh2	108.83 (6)
C13—P1—Rh1	118.90 (7)	C49—P3—Rh2	119.48 (6)
C1—P1—Rh1	114.07 (6)	C37—P3—Rh2	113.44 (6)
C31—P2—C25	104.79 (9)	C61—P4—C67	105.29 (8)
C31—P2—C19	103.90 (9)	C61—P4—C55	103.95 (8)
C25—P2—C19	102.91 (9)	C67—P4—C55	102.17 (9)
C31—P2—Rh1	113.73 (6)	C61—P4—Rh2	114.93 (6)
C25—P2—Rh1	112.86 (6)	C67—P4—Rh2	112.48 (6)
C19—P2—Rh1	117.26 (6)	C55—P4—Rh2	116.59 (6)
O01—C01—Rh1	177.75 (18)	O02—C02—Rh2	177.4 (2)
C6—C1—C2	118.94 (17)	C38—C37—C42	118.66 (17)
C6—C1—P1	123.54 (15)	C38—C37—P3	122.53 (15)
C2—C1—P1	117.04 (14)	C42—C37—P3	118.29 (14)
C3—C2—C1	121.06 (19)	C37—C38—C39	120.97 (18)
C3—C2—H2	119.5	C37—C38—H38	119.5
C1—C2—H2	119.5	C39—C38—H38	119.5
C4—C3—C2	118.14 (18)	C40—C39—C38	118.14 (19)
C4—C3—H3	120.9	C40—C39—H39	120.9
C2—C3—H3	120.9	C38—C39—H39	120.9
F1—C4—C5	118.87 (19)	F7—C40—C39	118.96 (18)
F1—C4—C3	118.26 (18)	F7—C40—C41	118.03 (18)
C5—C4—C3	122.86 (18)	C39—C40—C41	123.00 (18)
C4—C5—C6	118.59 (19)	C40—C41—C42	118.22 (18)
C4—C5—H5	120.7	C40—C41—H41	120.9
C6—C5—H5	120.7	C42—C41—H41	120.9
C1—C6—C5	120.36 (19)	C41—C42—C37	121.01 (18)
C1—C6—H6	119.8	C41—C42—H42	119.5
C5—C6—H6	119.8	C37—C42—H42	119.5
C8—C7—C12	118.83 (19)	C44—C43—C48	118.94 (18)
C8—C7—P1	124.25 (16)	C44—C43—P3	124.36 (16)
C12—C7—P1	116.86 (15)	C48—C43—P3	116.70 (14)
C9—C8—C7	120.7 (2)	C45—C44—C43	120.3 (2)
C9—C8—H8	119.7	C45—C44—H44	119.8
C7—C8—H8	119.7	C43—C44—H44	119.8
C10—C9—C8	118.5 (2)	C46—C45—C44	118.7 (2)
C10—C9—H9	120.8	C46—C45—H45	120.6
C8—C9—H9	120.8	C44—C45—H45	120.6
F2—C10—C9	118.6 (2)	F9—C46—C45	118.7 (2)
F2—C10—C11	118.2 (2)	F9—C46—C47	118.2 (2)
C9—C10—C11	123.1 (2)	C45—C46—C47	123.1 (2)
C10—C11—C12	117.8 (2)	C46—C47—C48	117.9 (2)
C10—C11—H11	121.1	C46—C47—H47	121.1
C12—C11—H11	121.1	C48—C47—H47	121.1
C11—C12—C7	121.1 (2)	C47—C48—C43	120.98 (19)
C11—C12—H12	119.4	C47—C48—H48	119.5
C7—C12—H12	119.4	C43—C48—H48	119.5
C18—C13—C14	118.70 (19)	C54—C49—C50	119.09 (18)
C18—C13—P1	120.34 (15)	C54—C49—P3	120.85 (14)
C14—C13—P1	120.36 (17)	C50—C49—P3	119.43 (15)
C15—C14—C13	121.2 (2)	C51—C50—C49	120.73 (19)
C15—C14—H14	119.4	C51—C50—H50	119.6
C13—C14—H14	119.4	C49—C50—H50	119.6
C16—C15—C14	118.2 (2)	C52—C51—C50	118.41 (19)
C16—C15—H15	120.9	C52—C51—H51	120.8
C14—C15—H15	120.9	C50—C51—H51	120.8
F3—C16—C15	118.4 (2)	F8—C52—C53	119.3 (2)
F3—C16—C17	118.7 (3)	F8—C52—C51	117.9 (2)
C15—C16—C17	123.0 (2)	C53—C52—C51	122.8 (2)
C16—C17—C18	118.4 (2)	C52—C53—C54	118.3 (2)
C16—C17—H17	120.8	C52—C53—H53	120.9
C18—C17—H17	120.8	C54—C53—H53	120.9
C13—C18—C17	120.5 (2)	C49—C54—C53	120.62 (18)
C13—C18—H18	119.8	C49—C54—H54	119.7
C17—C18—H18	119.8	C53—C54—H54	119.7
C20—C19—C24	118.67 (18)	C60—C55—C56	118.74 (17)
C20—C19—P2	123.63 (16)	C60—C55—P4	123.12 (15)
C24—C19—P2	117.66 (15)	C56—C55—P4	118.14 (14)
C19—C20—C21	120.5 (2)	C57—C56—C55	121.19 (18)
C19—C20—H20	119.8	C57—C56—H56	119.4
C21—C20—H20	119.8	C55—C56—H56	119.4
C22—C21—C20	118.7 (2)	C58—C57—C56	117.93 (19)
C22—C21—H21	120.7	C58—C57—H57	121
C20—C21—H21	120.7	C56—C57—H57	121
F4—C22—C21	118.8 (2)	F10—C58—C59	119.00 (18)
F4—C22—C23	118.1 (2)	F10—C58—C57	118.10 (19)
C21—C22—C23	123.0 (2)	C59—C58—C57	122.90 (18)
C22—C23—C24	118.1 (2)	C58—C59—C60	118.71 (18)
C22—C23—H23	120.9	C58—C59—H59	120.6
C24—C23—H23	120.9	C60—C59—H59	120.6
C23—C24—C19	121.0 (2)	C55—C60—C59	120.53 (19)
C23—C24—H24	119.5	C55—C60—H60	119.7
C19—C24—H24	119.5	C59—C60—H60	119.7
C26—C25—C30	118.78 (18)	C62—C61—C66	118.82 (17)
C26—C25—P2	119.29 (15)	C62—C61—P4	123.06 (15)
C30—C25—P2	121.89 (15)	C66—C61—P4	118.12 (14)
C25—C26—C27	120.91 (19)	C63—C62—C61	120.44 (19)
C25—C26—H26	119.5	C63—C62—H62	119.8
C27—C26—H26	119.5	C61—C62—H62	119.8
C28—C27—C26	118.7 (2)	C64—C63—C62	118.77 (19)
C28—C27—H27	120.7	C64—C63—H63	120.6
C26—C27—H27	120.7	C62—C63—H63	120.6
F5—C28—C27	119.1 (2)	F11—C64—C63	118.84 (18)
F5—C28—C29	118.62 (19)	F11—C64—C65	118.04 (19)
C27—C28—C29	122.2 (2)	C63—C64—C65	123.10 (18)
C28—C29—C30	118.56 (19)	C64—C65—C66	117.32 (19)
C28—C29—H29	120.7	C64—C65—H65	121.3
C30—C29—H29	120.7	C66—C65—H65	121.3
C29—C30—C25	120.8 (2)	C65—C66—C61	121.53 (18)
C29—C30—H30	119.6	C65—C66—H66	119.2
C25—C30—H30	119.6	C61—C66—H66	119.2
C36—C31—C32	118.98 (18)	C72—C67—C68	118.40 (19)
C36—C31—P2	117.87 (14)	C72—C67—P4	119.35 (15)
C32—C31—P2	123.15 (15)	C68—C67—P4	122.25 (15)
C33—C32—C31	120.39 (19)	C69—C68—C67	120.7 (2)
C33—C32—H32	119.8	C69—C68—H68	119.6
C31—C32—H32	119.8	C67—C68—H68	119.6
C34—C33—C32	118.53 (19)	C70—C69—C68	118.4 (2)
C34—C33—H33	120.7	C70—C69—H69	120.8
C32—C33—H33	120.7	C68—C69—H69	120.8
F6—C34—C33	118.34 (18)	F12—C70—C71	118.5 (2)
F6—C34—C35	118.41 (19)	F12—C70—C69	118.8 (2)
C33—C34—C35	123.25 (19)	C71—C70—C69	122.7 (2)
C34—C35—C36	117.67 (19)	C70—C71—C72	118.5 (2)
C34—C35—H35	121.2	C70—C71—H71	120.8
C36—C35—H35	121.2	C72—C71—H71	120.8
C35—C36—C31	121.15 (18)	C71—C72—C67	121.3 (2)
C35—C36—H36	119.4	C71—C72—H72	119.3
C31—C36—H36	119.4	C67—C72—H72	119.3
C01—Rh1—P1—C7	117.76 (9)	Cl2—Rh2—P3—C43	−65.98 (7)
Cl1—Rh1—P1—C7	−64.98 (7)	C02—Rh2—P3—C49	−118.08 (10)
C01—Rh1—P1—C13	−117.70 (10)	Cl2—Rh2—P3—C49	59.03 (7)
Cl1—Rh1—P1—C13	59.55 (8)	C02—Rh2—P3—C37	0.53 (9)
Cl1—Rh1—P1—C1	178.11 (7)	Cl2—Rh2—P3—C37	177.64 (7)
C01—Rh1—P2—C31	129.96 (9)	C02—Rh2—P4—C61	131.90 (9)
Cl1—Rh1—P2—C31	−47.54 (7)	Cl2—Rh2—P4—C61	−45.51 (7)
C01—Rh1—P2—C25	−110.83 (9)	C02—Rh2—P4—C67	−107.64 (9)
Cl1—Rh1—P2—C25	71.67 (7)	Cl2—Rh2—P4—C67	74.95 (7)
C01—Rh1—P2—C19	8.51 (10)	C02—Rh2—P4—C55	9.90 (10)
Cl1—Rh1—P2—C19	−168.99 (7)	Cl2—Rh2—P4—C55	−167.51 (7)
C7—P1—C1—C6	−26.67 (18)	C43—P3—C37—C38	−32.27 (18)
C13—P1—C1—C6	−139.96 (17)	C49—P3—C37—C38	−144.68 (16)
Rh1—P1—C1—C6	91.53 (16)	Rh2—P3—C37—C38	86.39 (16)
C7—P1—C1—C2	161.44 (14)	C43—P3—C37—C42	156.19 (14)
C13—P1—C1—C2	48.15 (16)	C49—P3—C37—C42	43.77 (16)
Rh1—P1—C1—C2	−80.37 (15)	Rh2—P3—C37—C42	−85.16 (15)
C6—C1—C2—C3	−2.0 (3)	C42—C37—C38—C39	0.7 (3)
P1—C1—C2—C3	170.33 (15)	P3—C37—C38—C39	−170.79 (15)
C1—C2—C3—C4	0.5 (3)	C37—C38—C39—C40	−0.5 (3)
C2—C3—C4—F1	−178.60 (17)	C38—C39—C40—F7	−179.42 (17)
C2—C3—C4—C5	1.4 (3)	C38—C39—C40—C41	−0.3 (3)
F1—C4—C5—C6	178.16 (18)	F7—C40—C41—C42	−179.99 (16)
C3—C4—C5—C6	−1.9 (3)	C39—C40—C41—C42	0.9 (3)
C2—C1—C6—C5	1.5 (3)	C40—C41—C42—C37	−0.7 (3)
P1—C1—C6—C5	−170.24 (15)	C38—C37—C42—C41	−0.1 (3)
C4—C5—C6—C1	0.3 (3)	P3—C37—C42—C41	171.74 (14)
C13—P1—C7—C8	3.3 (2)	C49—P3—C43—C44	6.7 (2)
C1—P1—C7—C8	−104.06 (18)	C37—P3—C43—C44	−100.26 (18)
Rh1—P1—C7—C8	133.65 (16)	Rh2—P3—C43—C44	138.02 (16)
C13—P1—C7—C12	−174.05 (15)	C49—P3—C43—C48	−172.83 (14)
C1—P1—C7—C12	78.57 (16)	C37—P3—C43—C48	80.22 (16)
Rh1—P1—C7—C12	−43.73 (16)	Rh2—P3—C43—C48	−41.51 (16)
C12—C7—C8—C9	−1.2 (3)	C48—C43—C44—C45	−2.2 (3)
P1—C7—C8—C9	−178.49 (17)	P3—C43—C44—C45	178.27 (17)
C7—C8—C9—C10	−0.2 (3)	C43—C44—C45—C46	−0.1 (3)
C8—C9—C10—F2	−180.0 (2)	C44—C45—C46—F9	−179.0 (2)
C8—C9—C10—C11	0.7 (4)	C44—C45—C46—C47	1.8 (4)
F2—C10—C11—C12	−179.24 (19)	F9—C46—C47—C48	179.75 (19)
C9—C10—C11—C12	0.1 (3)	C45—C46—C47—C48	−1.0 (3)
C10—C11—C12—C7	−1.5 (3)	C46—C47—C48—C43	−1.4 (3)
C8—C7—C12—C11	2.0 (3)	C44—C43—C48—C47	3.0 (3)
P1—C7—C12—C11	179.52 (16)	P3—C43—C48—C47	−177.42 (16)
C7—P1—C13—C18	121.80 (17)	C43—P3—C49—C54	122.38 (17)
C1—P1—C13—C18	−127.50 (17)	C37—P3—C49—C54	−127.82 (17)
Rh1—P1—C13—C18	−2.2 (2)	Rh2—P3—C49—C54	−2.88 (19)
C7—P1—C13—C14	−67.24 (19)	C43—P3—C49—C50	−66.82 (18)
C1—P1—C13—C14	43.46 (19)	C37—P3—C49—C50	42.99 (18)
Rh1—P1—C13—C14	168.77 (15)	Rh2—P3—C49—C50	167.92 (14)
C18—C13—C14—C15	1.6 (3)	C54—C49—C50—C51	1.8 (3)
P1—C13—C14—C15	−169.53 (19)	P3—C49—C50—C51	−169.18 (17)
C13—C14—C15—C16	0.4 (4)	C49—C50—C51—C52	0.4 (3)
C14—C15—C16—F3	177.3 (2)	C50—C51—C52—F8	176.6 (2)
C14—C15—C16—C17	−1.9 (4)	C50—C51—C52—C53	−2.5 (4)
F3—C16—C17—C18	−177.9 (2)	F8—C52—C53—C54	−176.9 (2)
C15—C16—C17—C18	1.3 (4)	C51—C52—C53—C54	2.2 (4)
C14—C13—C18—C17	−2.2 (3)	C50—C49—C54—C53	−2.1 (3)
P1—C13—C18—C17	168.89 (18)	P3—C49—C54—C53	168.75 (16)
C16—C17—C18—C13	0.9 (4)	C52—C53—C54—C49	0.2 (3)
C31—P2—C19—C20	−10.92 (19)	C61—P4—C55—C60	−8.77 (19)
C25—P2—C19—C20	−119.98 (17)	C67—P4—C55—C60	−118.13 (17)
Rh1—P2—C19—C20	115.52 (16)	Rh2—P4—C55—C60	118.82 (16)
C31—P2—C19—C24	171.42 (15)	C61—P4—C55—C56	172.12 (15)
C25—P2—C19—C24	62.37 (17)	C67—P4—C55—C56	62.76 (17)
Rh1—P2—C19—C24	−62.14 (16)	Rh2—P4—C55—C56	−60.29 (17)
C24—C19—C20—C21	0.0 (3)	C60—C55—C56—C57	0.1 (3)
P2—C19—C20—C21	−177.61 (18)	P4—C55—C56—C57	179.29 (16)
C19—C20—C21—C22	0.5 (4)	C55—C56—C57—C58	0.3 (3)
C20—C21—C22—F4	179.3 (2)	C56—C57—C58—F10	179.58 (18)
C20—C21—C22—C23	−0.7 (4)	C56—C57—C58—C59	−0.2 (3)
F4—C22—C23—C24	−179.56 (19)	F10—C58—C59—C60	179.96 (19)
C21—C22—C23—C24	0.5 (3)	C57—C58—C59—C60	−0.2 (3)
C22—C23—C24—C19	0.1 (3)	C56—C55—C60—C59	−0.6 (3)
C20—C19—C24—C23	−0.3 (3)	P4—C55—C60—C59	−179.72 (16)
P2—C19—C24—C23	177.48 (16)	C58—C59—C60—C55	0.7 (3)
C31—P2—C25—C26	102.85 (18)	C67—P4—C61—C62	14.08 (18)
C19—P2—C25—C26	−148.76 (18)	C55—P4—C61—C62	−92.97 (17)
Rh1—P2—C25—C26	−21.42 (19)	Rh2—P4—C61—C62	138.41 (15)
C31—P2—C25—C30	−75.15 (19)	C67—P4—C61—C66	−166.68 (15)
C19—P2—C25—C30	33.24 (19)	C55—P4—C61—C66	86.27 (16)
Rh1—P2—C25—C30	160.58 (15)	Rh2—P4—C61—C66	−42.34 (17)
C30—C25—C26—C27	1.9 (4)	C66—C61—C62—C63	−1.0 (3)
P2—C25—C26—C27	−176.1 (2)	P4—C61—C62—C63	178.27 (16)
C25—C26—C27—C28	0.5 (4)	C61—C62—C63—C64	−0.3 (3)
C26—C27—C28—F5	179.3 (2)	C62—C63—C64—F11	−179.87 (19)
C26—C27—C28—C29	−2.7 (4)	C62—C63—C64—C65	1.4 (3)
F5—C28—C29—C30	−179.8 (2)	F11—C64—C65—C66	−179.80 (18)
C27—C28—C29—C30	2.2 (4)	C63—C64—C65—C66	−1.1 (3)
C28—C29—C30—C25	0.4 (4)	C64—C65—C66—C61	−0.3 (3)
C26—C25—C30—C29	−2.4 (3)	C62—C61—C66—C65	1.3 (3)
P2—C25—C30—C29	175.57 (18)	P4—C61—C66—C65	−177.95 (16)
C25—P2—C31—C36	−167.45 (16)	C61—P4—C67—C72	98.96 (18)
C19—P2—C31—C36	84.89 (17)	C55—P4—C67—C72	−152.70 (18)
Rh1—P2—C31—C36	−43.74 (17)	Rh2—P4—C67—C72	−26.91 (19)
C25—P2—C31—C32	11.99 (19)	C61—P4—C67—C68	−81.94 (18)
C19—P2—C31—C32	−95.68 (18)	C55—P4—C67—C68	26.40 (19)
Rh1—P2—C31—C32	135.69 (16)	Rh2—P4—C67—C68	152.19 (16)
C36—C31—C32—C33	−1.8 (3)	C72—C67—C68—C69	−0.6 (3)
P2—C31—C32—C33	178.81 (17)	P4—C67—C68—C69	−179.75 (18)
C31—C32—C33—C34	0.3 (3)	C67—C68—C69—C70	−0.3 (4)
C32—C33—C34—F6	−179.4 (2)	C68—C69—C70—F12	179.3 (2)
C32—C33—C34—C35	1.3 (4)	C68—C69—C70—C71	0.6 (4)
F6—C34—C35—C36	179.41 (19)	F12—C70—C71—C72	−178.6 (2)
C33—C34—C35—C36	−1.3 (3)	C69—C70—C71—C72	0.1 (4)
C34—C35—C36—C31	−0.3 (3)	C70—C71—C72—C67	−1.1 (4)
C32—C31—C36—C35	1.8 (3)	C68—C67—C72—C71	1.3 (4)
P2—C31—C36—C35	−178.76 (16)	P4—C67—C72—C71	−179.5 (2)
C02—Rh2—P3—C43	116.91 (9)