N-Chloro(methyl)arsino-N,N'-dimethyl-N'-(p-tolylthio)urea

The title compound, C₁₁H₁₆AsClN₂OS, crystallizes with two independent but closely similar molecules. The pyramidal geometry at arsenic is supplemented by a 1,5 intramolecular interaction with the S atom [2.8682 (13) and 2.8101 (13) Å] and by further weaker intermolecular contacts to oxygen and chlorine.

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