(Thiocyanato-N)tris(triphenylphosphine)silver(I) Chloroform Solvate

Crystals of [Ag(NCS)(C₁₈H₁₅P)₃].CHCl₃ consist of discrete [Ag(PPh₃)₃(NCS)] molecules, in which the Ag atom is tetrahedrally surrounded by three P atoms of the PPh₃ groups and the N atom of the isothiocyanate ligand, and chloroform molecules. The coordination polyhedron around the Ag atom is distorted with angles at Ag ranging from 102.58 (10) to 114.73 (3)°. The Ag-N-C angle is 159.6 (3)°.

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