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The first crystal structure of a dicyanamide nickel(II) complex [Ni(C2N3)2(C4H6N2)4], is reported. The central atom is octahedrally coordinated by four N atoms from four 4-methylimidazole ligands and by two nitrogen atoms from two terminally bonded dicyanamide anions. The Ni-N distances are in the range of 2.090 (2) to 2.210 (2) Å.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks KOZ3, global

fcf

Structure factor file (CIF format)
Contains datablock koz3

CCDC reference: 128309

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