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Crystal structures of two symmetrically substituted thiourea derivatives, 1,3-dibenzylthiourea, C15H16N2S (DBTU) and 1,3-dicyclohexylthiourea, C13H24N2S (DCHTU) are reported. One of the cyclohexane rings in DCHTU is disordered adopting two orientations separated by an angle of 44.6 (2)°. In both structures centrosymmetrically related molecules are linked by N-H...S hydrogen bonds to form dimers and weak N-H...S bonds connecting glide-related molecules are also observed in both DBTU and DCHTU.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks DBTU, DCHTU, global

CCDC references: 126238; 126239

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