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In the title compound, trans-dichloro(1,5,9,13-tetrathiacyclohexadecane-κ4S)rhodium(III) pentaiodide diiodine, [RhCl2(C12H24S4)](I5).I2, the complex cations are embedded in a three-dimensional polyiodide matrix composed of cages of I5 ions and I2 molecules interacting via I...I contacts which range from 3.336 (2) to 4.133 (2) Å.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks ln1058, global

fcf

Structure factor file (CIF format)
Contains datablock ln1058

CCDC reference: 130497

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