Buy article online - an online subscription or single-article purchase is required to access this article.
metal-organic compounds
In the title coordination polymer, [Mn(4-CPOA)(2,2′-bipy)(H2O)]n [where 4-CPOA2− is 4-carboxylatophenoxyacetate (C9H6O5) and 2,2′-bipy is 2,2′-bipyridine (C10H8N2)], each MnII ion displays a distorted octahedral coordination configuration, defined by three carboxyl O atoms from two different 4-CPOA2− groups, two N atoms from the 2,2′-bipyridine ligand and one water molecule. Adjacent MnII ions are linked by carboxylate groups into a one-dimensional chain structure with a shortest MnMn distance of 9.771 (3) Å. A two-dimensional supramolecular network is constructed through O—HO intermolecular hydrogen bonds and π–π stacking interactions.
Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536805012584/lh6411sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536805012584/lh6411Isup2.hkl |
CCDC reference: 224464
Key indicators
- Single-crystal X-ray study
- T = 296 K
- Mean (C-C) = 0.007 Å
- R factor = 0.066
- wR factor = 0.146
- Data-to-parameter ratio = 16.0
checkCIF/PLATON results
No syntax errors found
Alert level C PLAT341_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 7 PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........ 2
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 2 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 0 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 1 ALERT type 4 Improvement, methodology, query or suggestion
Computing details top
Data collection: RAPID-AUTO (Rigaku, 1998); cell refinement: RAPID-AUTO; data reduction: CrystalStructure (Rigaku/MSC, 2002); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.
catena-Poly[[aqua(2,2'-bipyridine-κ2N,N')manganese(II)]-µ- 4-carboxylatophenoxyacetato-κ3O,O':O''] top
Crystal data top
[Mn(C9H6O5)(C10H8N2)(H2O)] | F(000) = 1736 |
Mr = 423.28 | Dx = 1.545 Mg m−3 |
Monoclinic, C2/c | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -C 2yc | Cell parameters from 6068 reflections |
a = 14.379 (2) Å | θ = 3.0–27.4° |
b = 13.234 (2) Å | µ = 0.77 mm−1 |
c = 19.705 (3) Å | T = 296 K |
β = 104.00 (3)° | Prism, yellow |
V = 3638.3 (10) Å3 | 0.32 × 0.24 × 0.18 mm |
Z = 8 |
Data collection top
Rigaku R-AXIS RAPID diffractometer | 4139 independent reflections |
Radiation source: fine-focus sealed tube | 2578 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.057 |
Detector resolution: 10 pixels mm-1 | θmax = 27.4°, θmin = 3.0° |
ω scans | h = −18→18 |
Absorption correction: multi-scan (ABSCOR; Higashi, 1995) | k = −17→16 |
Tmin = 0.792, Tmax = 0.874 | l = −25→25 |
6190 measured reflections |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.066 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.146 | H atoms treated by a mixture of independent and constrained refinement |
S = 1.04 | w = 1/[σ2(Fo2) + (0.055P)2] where P = (Fo2 + 2Fc2)/3 |
4139 reflections | (Δ/σ)max = 0.001 |
259 parameters | Δρmax = 0.45 e Å−3 |
2 restraints | Δρmin = −0.33 e Å−3 |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
x | y | z | Uiso*/Ueq | ||
Mn1 | 0.75561 (5) | 0.79563 (5) | 0.62120 (3) | 0.0465 (2) | |
N1 | 0.8419 (2) | 0.8701 (3) | 0.71681 (18) | 0.0471 (9) | |
N2 | 0.8265 (3) | 0.6716 (3) | 0.69679 (19) | 0.0493 (9) | |
O1 | 0.6192 (2) | 0.7915 (2) | 0.66021 (16) | 0.0588 (8) | |
O2 | 0.6315 (2) | 0.6948 (2) | 0.57219 (15) | 0.0543 (8) | |
O3 | 0.1895 (2) | 0.6410 (2) | 0.57211 (17) | 0.0603 (9) | |
O4 | 0.1079 (3) | 0.4223 (3) | 0.46691 (18) | 0.0758 (11) | |
O5 | 0.2164 (2) | 0.4350 (2) | 0.56862 (16) | 0.0607 (9) | |
O1W | 0.8585 (3) | 0.7647 (3) | 0.56178 (16) | 0.0578 (9) | |
C1 | 0.5818 (3) | 0.7334 (3) | 0.6107 (2) | 0.0485 (11) | |
C2 | 0.4786 (3) | 0.7077 (3) | 0.5983 (2) | 0.0444 (10) | |
C3 | 0.4256 (3) | 0.7396 (3) | 0.6450 (2) | 0.0518 (12) | |
C4 | 0.3301 (3) | 0.7160 (3) | 0.6352 (2) | 0.0551 (12) | |
C5 | 0.2847 (3) | 0.6593 (3) | 0.5773 (2) | 0.0473 (11) | |
C6 | 0.3347 (3) | 0.6283 (4) | 0.5291 (2) | 0.0526 (12) | |
C7 | 0.4314 (3) | 0.6519 (3) | 0.5407 (2) | 0.0491 (11) | |
C8 | 0.1368 (3) | 0.5830 (4) | 0.5150 (3) | 0.0591 (13) | |
C9 | 0.1569 (3) | 0.4688 (4) | 0.5179 (2) | 0.0534 (12) | |
C10 | 0.8480 (3) | 0.9708 (4) | 0.7231 (2) | 0.0591 (13) | |
C11 | 0.8960 (4) | 1.0178 (4) | 0.7839 (3) | 0.0707 (15) | |
C12 | 0.9379 (4) | 0.9576 (5) | 0.8394 (3) | 0.0840 (18) | |
C13 | 0.9337 (4) | 0.8555 (4) | 0.8336 (3) | 0.0762 (17) | |
C14 | 0.8846 (3) | 0.8119 (4) | 0.7713 (2) | 0.0504 (12) | |
C15 | 0.8776 (3) | 0.7006 (4) | 0.7601 (2) | 0.0468 (10) | |
C16 | 0.9221 (3) | 0.6323 (4) | 0.8107 (3) | 0.0626 (13) | |
C17 | 0.9124 (4) | 0.5317 (5) | 0.7971 (3) | 0.0744 (17) | |
C18 | 0.8599 (4) | 0.4996 (4) | 0.7325 (3) | 0.0741 (16) | |
C19 | 0.8193 (3) | 0.5724 (4) | 0.6841 (3) | 0.0607 (13) | |
H1W1 | 0.853 (4) | 0.793 (4) | 0.5225 (14) | 0.087* | |
H1W2 | 0.859 (4) | 0.7007 (10) | 0.556 (3) | 0.087* | |
H3 | 0.4556 | 0.7778 | 0.6837 | 0.062* | |
H4 | 0.2962 | 0.7379 | 0.6671 | 0.066* | |
H6 | 0.3040 | 0.5921 | 0.4896 | 0.063* | |
H7 | 0.4654 | 0.6296 | 0.5090 | 0.059* | |
H8A | 0.1499 | 0.6095 | 0.4724 | 0.071* | |
H8B | 0.0690 | 0.5929 | 0.5119 | 0.071* | |
H10 | 0.8187 | 1.0105 | 0.6850 | 0.071* | |
H11 | 0.8997 | 1.0878 | 0.7871 | 0.085* | |
H12 | 0.9696 | 0.9871 | 0.8815 | 0.101* | |
H13 | 0.9635 | 0.8150 | 0.8711 | 0.091* | |
H16 | 0.9584 | 0.6550 | 0.8536 | 0.075* | |
H17 | 0.9410 | 0.4849 | 0.8309 | 0.089* | |
H18 | 0.8521 | 0.4312 | 0.7219 | 0.089* | |
H19 | 0.7849 | 0.5511 | 0.6402 | 0.073* |
Atomic displacement parameters (Å2) top
U11 | U22 | U33 | U12 | U13 | U23 | |
Mn1 | 0.0497 (4) | 0.0463 (4) | 0.0413 (4) | −0.0042 (4) | 0.0067 (3) | −0.0005 (3) |
N1 | 0.055 (2) | 0.043 (2) | 0.043 (2) | −0.0043 (18) | 0.0114 (17) | 0.0001 (17) |
N2 | 0.054 (2) | 0.043 (2) | 0.053 (2) | 0.0013 (17) | 0.0169 (18) | 0.0034 (18) |
O1 | 0.0504 (18) | 0.062 (2) | 0.063 (2) | −0.0054 (17) | 0.0127 (15) | −0.0115 (18) |
O2 | 0.0546 (18) | 0.063 (2) | 0.0477 (17) | −0.0045 (16) | 0.0160 (15) | −0.0018 (17) |
O3 | 0.0475 (19) | 0.064 (2) | 0.072 (2) | −0.0036 (16) | 0.0192 (16) | 0.0016 (18) |
O4 | 0.078 (2) | 0.077 (3) | 0.061 (2) | 0.005 (2) | −0.0043 (19) | −0.0130 (19) |
O5 | 0.067 (2) | 0.051 (2) | 0.056 (2) | −0.0017 (17) | −0.0006 (17) | 0.0161 (16) |
O1W | 0.071 (2) | 0.060 (2) | 0.0437 (18) | 0.0004 (19) | 0.0178 (17) | −0.0045 (17) |
C1 | 0.053 (3) | 0.051 (3) | 0.044 (3) | 0.000 (2) | 0.016 (2) | 0.013 (2) |
C2 | 0.050 (3) | 0.040 (2) | 0.043 (2) | −0.002 (2) | 0.0119 (19) | 0.009 (2) |
C3 | 0.063 (3) | 0.046 (3) | 0.048 (3) | −0.008 (2) | 0.017 (2) | −0.004 (2) |
C4 | 0.056 (3) | 0.054 (3) | 0.058 (3) | −0.003 (2) | 0.020 (2) | −0.005 (2) |
C5 | 0.045 (3) | 0.043 (3) | 0.055 (3) | 0.001 (2) | 0.014 (2) | 0.010 (2) |
C6 | 0.059 (3) | 0.055 (3) | 0.042 (2) | −0.011 (2) | 0.007 (2) | −0.001 (2) |
C7 | 0.048 (3) | 0.058 (3) | 0.042 (2) | 0.004 (2) | 0.013 (2) | 0.008 (2) |
C8 | 0.043 (3) | 0.059 (3) | 0.073 (3) | 0.004 (2) | 0.009 (2) | 0.013 (3) |
C9 | 0.043 (3) | 0.070 (3) | 0.050 (3) | 0.001 (2) | 0.017 (2) | 0.009 (3) |
C10 | 0.068 (3) | 0.056 (3) | 0.052 (3) | 0.003 (3) | 0.013 (2) | −0.002 (2) |
C11 | 0.077 (4) | 0.065 (4) | 0.070 (4) | −0.007 (3) | 0.017 (3) | −0.019 (3) |
C12 | 0.093 (4) | 0.087 (5) | 0.059 (4) | −0.012 (4) | −0.007 (3) | −0.026 (3) |
C13 | 0.093 (4) | 0.077 (4) | 0.049 (3) | 0.010 (3) | −0.001 (3) | −0.006 (3) |
C14 | 0.047 (3) | 0.065 (4) | 0.040 (2) | 0.003 (2) | 0.014 (2) | −0.001 (2) |
C15 | 0.047 (2) | 0.056 (3) | 0.041 (2) | 0.009 (2) | 0.0194 (19) | 0.008 (2) |
C16 | 0.060 (3) | 0.076 (4) | 0.056 (3) | 0.012 (3) | 0.022 (2) | 0.011 (3) |
C17 | 0.072 (4) | 0.083 (5) | 0.078 (4) | 0.023 (3) | 0.038 (3) | 0.034 (3) |
C18 | 0.084 (4) | 0.043 (3) | 0.108 (5) | 0.005 (3) | 0.048 (4) | 0.002 (3) |
C19 | 0.067 (3) | 0.051 (3) | 0.066 (3) | 0.001 (3) | 0.021 (3) | −0.005 (3) |
Geometric parameters (Å, º) top
Mn1—N1 | 2.220 (4) | C4—H4 | 0.9300 |
Mn1—N2 | 2.284 (4) | C5—C6 | 1.385 (6) |
Mn1—O1 | 2.274 (3) | C6—C7 | 1.389 (6) |
Mn1—O2 | 2.251 (3) | C6—H6 | 0.9300 |
Mn1—O5i | 2.124 (3) | C7—H7 | 0.9300 |
Mn1—O1W | 2.136 (4) | C8—C9 | 1.537 (6) |
O1—C1 | 1.257 (5) | C8—H8A | 0.9700 |
O2—C1 | 1.268 (5) | C8—H8B | 0.9700 |
O4—C9 | 1.242 (5) | C10—C11 | 1.377 (6) |
O5—C9 | 1.232 (5) | C10—H10 | 0.9300 |
Mn1—C1 | 2.591 (5) | C11—C12 | 1.369 (7) |
N1—C10 | 1.338 (5) | C11—H11 | 0.9300 |
N1—C14 | 1.343 (5) | C12—C13 | 1.357 (7) |
N2—C15 | 1.342 (5) | C12—H12 | 0.9300 |
N2—C19 | 1.335 (5) | C13—C14 | 1.384 (6) |
O3—C5 | 1.370 (5) | C13—H13 | 0.9300 |
O3—C8 | 1.419 (5) | C14—C15 | 1.489 (6) |
O5—Mn1ii | 2.124 (3) | C15—C16 | 1.383 (6) |
O1W—H1W1 | 0.85 (3) | C16—C17 | 1.358 (7) |
O1W—H1W2 | 0.85 (3) | C16—H16 | 0.9300 |
C1—C2 | 1.484 (6) | C17—C18 | 1.380 (7) |
C2—C7 | 1.386 (6) | C17—H17 | 0.9300 |
C2—C3 | 1.395 (6) | C18—C19 | 1.381 (7) |
C3—C4 | 1.375 (6) | C18—H18 | 0.9300 |
C3—H3 | 0.9300 | C19—H19 | 0.9300 |
C4—C5 | 1.389 (6) | ||
N1—Mn1—N2 | 72.33 (14) | C2—C7—H7 | 119.1 |
N1—Mn1—O1 | 94.28 (12) | C3—C2—C1 | 120.5 (4) |
N1—Mn1—O2 | 148.19 (12) | C3—C4—C5 | 119.4 (4) |
O1—Mn1—N2 | 92.72 (12) | C3—C4—H4 | 120.3 |
O5i—Mn1—N1 | 93.22 (13) | C4—C3—C2 | 121.7 (4) |
O5i—Mn1—N2 | 165.06 (13) | C4—C3—H3 | 119.1 |
O5i—Mn1—O1 | 92.11 (13) | C5—O3—C8 | 119.2 (4) |
O2—Mn1—N2 | 92.06 (13) | C5—C4—H4 | 120.3 |
O2—Mn1—O1 | 58.08 (11) | C5—C6—C7 | 119.0 (4) |
O5i—Mn1—O2 | 102.48 (12) | C5—C6—H6 | 120.5 |
O5i—Mn1—O1W | 92.08 (13) | C6—C5—C4 | 120.4 (4) |
O1W—Mn1—N1 | 103.37 (13) | C6—C7—H7 | 119.1 |
O1W—Mn1—N2 | 87.76 (13) | C7—C2—C1 | 121.9 (4) |
O1W—Mn1—O1 | 161.60 (12) | C7—C2—C3 | 117.6 (4) |
O1W—Mn1—O2 | 103.51 (12) | C7—C6—H6 | 120.5 |
Mn1—O1W—H1W1 | 120 (4) | C9—O5—Mn1ii | 139.6 (3) |
Mn1—O1W—H1W2 | 107 (4) | C9—C8—H8A | 108.2 |
N1—Mn1—C1 | 122.63 (15) | C9—C8—H8B | 108.2 |
N1—C10—C11 | 122.6 (5) | C10—N1—Mn1 | 122.1 (3) |
N1—C10—H10 | 118.7 | C10—N1—C14 | 119.3 (4) |
N1—C14—C13 | 120.4 (5) | C10—C11—H11 | 121.2 |
N1—C14—C15 | 116.5 (4) | C11—C10—H10 | 118.7 |
N2—Mn1—C1 | 95.33 (13) | C11—C12—H12 | 119.7 |
N2—C15—C14 | 115.1 (4) | C12—C11—C10 | 117.6 (5) |
N2—C15—C16 | 122.4 (5) | C12—C11—H11 | 121.2 |
N2—C19—C18 | 123.8 (5) | C12—C13—C14 | 119.5 (5) |
N2—C19—H19 | 118.1 | C12—C13—H13 | 120.3 |
O1—Mn1—C1 | 29.01 (12) | C13—C12—C11 | 120.7 (5) |
O1—C1—Mn1 | 61.3 (2) | C13—C12—H12 | 119.7 |
O1—C1—O2 | 121.0 (4) | C13—C14—C15 | 123.0 (4) |
O1—C1—C2 | 119.4 (4) | C14—N1—Mn1 | 118.5 (3) |
O2—Mn1—C1 | 29.28 (12) | C14—C13—H13 | 120.3 |
O2—C1—Mn1 | 60.3 (2) | C15—N2—Mn1 | 117.2 (3) |
O2—C1—C2 | 119.7 (4) | C15—C16—H16 | 120.3 |
O3—C5—C4 | 114.8 (4) | C16—C15—C14 | 122.5 (4) |
O3—C5—C6 | 124.8 (4) | C16—C17—C18 | 119.4 (5) |
O3—C8—C9 | 116.3 (4) | C16—C17—H17 | 120.3 |
O3—C8—H8A | 108.2 | C17—C16—C15 | 119.4 (5) |
O3—C8—H8B | 108.2 | C17—C16—H16 | 120.3 |
O4—C9—C8 | 113.2 (4) | C17—C18—C19 | 117.8 (5) |
O5i—Mn1—C1 | 95.74 (13) | C17—C18—H18 | 121.1 |
O5—C9—O4 | 128.5 (5) | C18—C17—H17 | 120.3 |
O5—C9—C8 | 118.4 (4) | C18—C19—H19 | 118.1 |
O1W—Mn1—C1 | 132.63 (14) | C19—N2—Mn1 | 125.6 (3) |
C1—O1—Mn1 | 89.6 (3) | C19—N2—C15 | 117.1 (4) |
C1—O2—Mn1 | 90.4 (3) | C19—C18—H18 | 121.1 |
C2—C1—Mn1 | 173.0 (3) | H1W1—O1W—H1W2 | 108 (5) |
C2—C3—H3 | 119.1 | H8A—C8—H8B | 107.4 |
C2—C7—C6 | 121.8 (4) | ||
O5i—Mn1—O1—C1 | 98.0 (3) | O1—C1—C2—C7 | 173.8 (4) |
O1W—Mn1—O1—C1 | −5.0 (5) | O2—C1—C2—C7 | −7.7 (6) |
N1—Mn1—O1—C1 | −168.6 (3) | O1—C1—C2—C3 | −6.2 (6) |
O2—Mn1—O1—C1 | −5.4 (2) | O2—C1—C2—C3 | 172.3 (4) |
N2—Mn1—O1—C1 | −96.1 (3) | C7—C2—C3—C4 | 0.7 (6) |
O5i—Mn1—O2—C1 | −79.3 (3) | C1—C2—C3—C4 | −179.3 (4) |
O1W—Mn1—O2—C1 | −174.6 (2) | C2—C3—C4—C5 | −0.2 (7) |
N1—Mn1—O2—C1 | 38.5 (4) | C8—O3—C5—C6 | 2.4 (6) |
O1—Mn1—O2—C1 | 5.3 (2) | C8—O3—C5—C4 | −179.5 (4) |
N2—Mn1—O2—C1 | 97.2 (3) | C3—C4—C5—O3 | −179.3 (4) |
O5i—Mn1—N1—C10 | 2.7 (4) | C3—C4—C5—C6 | −1.2 (7) |
O1W—Mn1—N1—C10 | 95.6 (4) | O3—C5—C6—C7 | −180.0 (4) |
O2—Mn1—N1—C10 | −117.4 (4) | C4—C5—C6—C7 | 2.0 (7) |
O1—Mn1—N1—C10 | −89.7 (4) | C3—C2—C7—C6 | 0.3 (6) |
N2—Mn1—N1—C10 | 178.8 (4) | C1—C2—C7—C6 | −179.8 (4) |
C1—Mn1—N1—C10 | −96.2 (4) | C5—C6—C7—C2 | −1.6 (7) |
O5i—Mn1—N1—C14 | 178.8 (3) | C5—O3—C8—C9 | 73.6 (5) |
O1W—Mn1—N1—C14 | −88.3 (3) | Mn1ii—O5—C9—O4 | −19.2 (9) |
O2—Mn1—N1—C14 | 58.7 (4) | Mn1ii—O5—C9—C8 | 159.9 (3) |
O1—Mn1—N1—C14 | 86.4 (3) | O3—C8—C9—O5 | 0.1 (6) |
N2—Mn1—N1—C14 | −5.1 (3) | O3—C8—C9—O4 | 179.3 (4) |
C1—Mn1—N1—C14 | 79.9 (3) | C14—N1—C10—C11 | −0.6 (7) |
O5i—Mn1—N2—C19 | −162.8 (5) | Mn1—N1—C10—C11 | 175.5 (4) |
O1W—Mn1—N2—C19 | −73.1 (4) | N1—C10—C11—C12 | −0.4 (8) |
N1—Mn1—N2—C19 | −177.9 (4) | C10—C11—C12—C13 | 1.4 (9) |
O2—Mn1—N2—C19 | 30.3 (4) | C11—C12—C13—C14 | −1.4 (9) |
O1—Mn1—N2—C19 | 88.4 (4) | C10—N1—C14—C13 | 0.6 (7) |
C1—Mn1—N2—C19 | 59.5 (4) | Mn1—N1—C14—C13 | −175.6 (4) |
O5i—Mn1—N2—C15 | 19.1 (7) | C10—N1—C14—C15 | −178.2 (4) |
O1W—Mn1—N2—C15 | 108.8 (3) | Mn1—N1—C14—C15 | 5.6 (5) |
N1—Mn1—N2—C15 | 4.0 (3) | C12—C13—C14—N1 | 0.4 (8) |
O2—Mn1—N2—C15 | −147.8 (3) | C12—C13—C14—C15 | 179.1 (5) |
O1—Mn1—N2—C15 | −89.6 (3) | C19—N2—C15—C16 | 0.5 (6) |
C1—Mn1—N2—C15 | −118.6 (3) | Mn1—N2—C15—C16 | 178.7 (3) |
Mn1—O1—C1—O2 | 9.5 (4) | C19—N2—C15—C14 | 179.2 (4) |
Mn1—O1—C1—C2 | −172.1 (3) | Mn1—N2—C15—C14 | −2.6 (5) |
Mn1—O2—C1—O1 | −9.6 (4) | N1—C14—C15—N2 | −1.9 (6) |
Mn1—O2—C1—C2 | 172.0 (3) | C13—C14—C15—N2 | 179.4 (4) |
O5i—Mn1—C1—O1 | −84.0 (3) | N1—C14—C15—C16 | 176.9 (4) |
O1W—Mn1—C1—O1 | 177.8 (2) | C13—C14—C15—C16 | −1.9 (7) |
N1—Mn1—C1—O1 | 13.6 (3) | N2—C15—C16—C17 | −1.6 (7) |
O2—Mn1—C1—O1 | 170.7 (4) | C14—C15—C16—C17 | 179.8 (4) |
N2—Mn1—C1—O1 | 86.0 (3) | C15—C16—C17—C18 | 1.3 (8) |
O5i—Mn1—C1—O2 | 105.4 (2) | C16—C17—C18—C19 | 0.1 (8) |
O1W—Mn1—C1—O2 | 7.2 (3) | C15—N2—C19—C18 | 1.0 (7) |
N1—Mn1—C1—O2 | −157.1 (2) | Mn1—N2—C19—C18 | −177.1 (4) |
O1—Mn1—C1—O2 | −170.7 (4) | C17—C18—C19—N2 | −1.3 (8) |
N2—Mn1—C1—O2 | −84.7 (2) |
Symmetry codes: (i) x+1/2, y+1/2, z; (ii) x−1/2, y−1/2, z. |
Hydrogen-bond geometry (Å, º) top
D—H···A | D—H | H···A | D···A | D—H···A |
O1W—H1W1···O2iii | 0.85 (3) | 1.94 (2) | 2.732 (4) | 155 (5) |
O1W—H1W2···O4iv | 0.85 (3) | 1.78 (2) | 2.609 (5) | 162 (6) |
Symmetry codes: (iii) −x+3/2, −y+3/2, −z+1; (iv) −x+1, −y+1, −z+1. |
Subscribe to Acta Crystallographica Section E: Crystallographic Communications
The full text of this article is available to subscribers to the journal.
- Information on subscribing
- Sample issue
- If you have already subscribed, you may need to register