trans-Di­chloro­(di­cyclo­hexyl­amine)(tri­phenyl­phosphine)­palladium(II)

In the crystal structure of the title compound, [PdCl₂(C₁₂H₂₃N)(C₁₈H₁₅P)], the Pd atom is four-coordinate in a nearly square-planar environment, with Pd-Cl = 2.2974 (6) and 2.3055 (7) Å, Pd-N = 2.1573 (17) Å and Pd-P = 2.2504 (7) Å. Both cyclo­hexyl rings adopt chair conformations.

Key indicators

• Single-crystal X-ray study
• T = 173 K
• Mean [sigma](C-C) = 0.003 Å
• R factor = 0.029
• wR factor = 0.068
• Data-to-parameter ratio = 20.5

checkCIF/PLATON results

No syntax errors found


No errors found in this datablock

---

Computing details

Data collection: COLLECT (Hooft, 1998); cell refinement: HKL DENZO (Otwinowski & Minor, 1997); data reduction: SCALEPACK (Otwinowski & Minor, 1997); program(s) used to solve structure: SAPI91 (Fan, 1991); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97 (Sheldrick, 1997).

trans-Dichloro(dicyclohexylamine)(triphenylphosphine)palladium(II)

Crystal data

[PdCl2(C12H23N)(C18H15P)]	F(000) = 1280
Mr = 620.88	Dx = 1.452 Mg m^−3
Monoclinic, P21/n	Melting point: 483-485 (decomp) K
Hall symbol: -P 2yn	Mo Kα radiation, λ = 0.71073 Å
a = 10.326 (2) Å	Cell parameters from 12408 reflections
b = 24.760 (4) Å	θ = 3.7–27.5°
c = 11.178 (2) Å	µ = 0.92 mm^−1
β = 96.274 (7)°	T = 173 K
V = 2840.8 (9) Å^3	Prism, yellow
Z = 4	0.14 × 0.12 × 0.12 mm

Data collection

Nonius KappaCCD diffractometer	6483 independent reflections
Radiation source: fine-focus sealed tube	5185 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.035
ω and φ scans	θmax = 27.5°, θmin = 3.7°
Absorption correction: multi-scan (SORTAV; Blessing, 1997)	h = −13→13
Tmin = 0.882, Tmax = 0.898	k = −32→31
12408 measured reflections	l = −14→14

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.029	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.068	H-atom parameters constrained
S = 1.02	w = 1/[σ^2(Fo^2) + (0.0257P)^2 + 0.6275P] where P = (Fo^2 + 2Fc^2)/3
6483 reflections	(Δ/σ)max = 0.001
316 parameters	Δρmax = 0.49 e Å^−3
0 restraints	Δρmin = −0.72 e Å^−3

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Pd1	0.351510 (15)	0.390695 (6)	0.376312 (14)	0.01704 (6)
Cl1	0.29242 (5)	0.30318 (2)	0.41525 (5)	0.02685 (13)
Cl2	0.43463 (6)	0.47302 (2)	0.32846 (5)	0.03184 (14)
P1	0.26264 (5)	0.37534 (2)	0.18647 (5)	0.01856 (12)
N1	0.41235 (15)	0.40935 (7)	0.56251 (14)	0.0171 (4)
H1N	0.4602	0.4410	0.5591	0.020*
C1	0.50808 (19)	0.36995 (9)	0.62420 (18)	0.0191 (4)
H1	0.4686	0.3331	0.6167	0.023*
C2	0.5464 (2)	0.38149 (9)	0.7574 (2)	0.0237 (5)
H2A	0.4682	0.3795	0.8012	0.028*
H2B	0.5825	0.4185	0.7671	0.028*
C3	0.6478 (2)	0.34072 (10)	0.8109 (2)	0.0309 (6)
H3A	0.6725	0.3493	0.8969	0.037*
H3B	0.6094	0.3040	0.8059	0.037*
C4	0.7684 (2)	0.34162 (10)	0.7448 (2)	0.0339 (6)
H4A	0.8304	0.3137	0.7788	0.041*
H4B	0.8116	0.3772	0.7560	0.041*
C5	0.7328 (2)	0.33112 (10)	0.6116 (2)	0.0360 (6)
H5A	0.7000	0.2937	0.6002	0.043*
H5B	0.8118	0.3346	0.5694	0.043*
C6	0.6291 (2)	0.37042 (10)	0.5563 (2)	0.0279 (5)
H6A	0.6038	0.3605	0.4712	0.034*
H6B	0.6659	0.4074	0.5579	0.034*
C7	0.30186 (18)	0.42505 (8)	0.63238 (18)	0.0184 (4)
H7	0.3403	0.4393	0.7122	0.022*
C8	0.2146 (2)	0.37771 (9)	0.6556 (2)	0.0233 (5)
H8A	0.2669	0.3492	0.7003	0.028*
H8B	0.1763	0.3623	0.5780	0.028*
C9	0.1053 (2)	0.39604 (9)	0.7286 (2)	0.0291 (5)
H9A	0.0484	0.3649	0.7421	0.035*
H9B	0.1435	0.4095	0.8082	0.035*
C10	0.0246 (2)	0.44053 (9)	0.6630 (2)	0.0296 (5)
H10A	−0.0435	0.4527	0.7127	0.036*
H10B	−0.0191	0.4263	0.5861	0.036*
C11	0.1111 (2)	0.48800 (9)	0.6377 (2)	0.0265 (5)
H11A	0.1475	0.5044	0.7149	0.032*
H11B	0.0580	0.5157	0.5913	0.032*
C12	0.2229 (2)	0.47063 (9)	0.56693 (19)	0.0222 (5)
H12A	0.1872	0.4582	0.4858	0.027*
H12B	0.2806	0.5019	0.5571	0.027*
C13	0.0921 (2)	0.35599 (8)	0.18920 (19)	0.0213 (5)
C14	0.0238 (2)	0.37942 (9)	0.2769 (2)	0.0260 (5)
H14	0.0680	0.4029	0.3348	0.031*
C15	−0.1074 (2)	0.36902 (9)	0.2810 (2)	0.0300 (5)
H15	−0.1528	0.3858	0.3405	0.036*
C16	−0.1718 (2)	0.33437 (10)	0.1987 (2)	0.0350 (6)
H16	−0.2618	0.3271	0.2013	0.042*
C17	−0.1058 (2)	0.31015 (10)	0.1126 (3)	0.0407 (7)
H17	−0.1505	0.2861	0.0562	0.049*
C18	0.0259 (2)	0.32065 (9)	0.1074 (2)	0.0318 (6)
H18	0.0706	0.3036	0.0478	0.038*
C19	0.3431 (2)	0.32432 (9)	0.10398 (19)	0.0223 (5)
C20	0.4484 (2)	0.29556 (9)	0.1612 (2)	0.0256 (5)
H20	0.4756	0.3016	0.2440	0.031*
C21	0.5133 (2)	0.25815 (9)	0.0975 (2)	0.0314 (6)
H21	0.5858	0.2391	0.1368	0.038*
C22	0.4740 (2)	0.24825 (9)	−0.0223 (2)	0.0334 (6)
H22	0.5184	0.2222	−0.0651	0.040*
C23	0.3696 (3)	0.27645 (9)	−0.0798 (2)	0.0339 (6)
H23	0.3418	0.2695	−0.1622	0.041*
C24	0.3055 (2)	0.31475 (9)	−0.0180 (2)	0.0278 (5)
H24	0.2355	0.3347	−0.0589	0.033*
C25	0.2547 (2)	0.43476 (8)	0.08968 (19)	0.0214 (5)
C26	0.1609 (2)	0.47436 (10)	0.1014 (2)	0.0319 (6)
H26	0.0955	0.4684	0.1535	0.038*
C27	0.1622 (3)	0.52216 (10)	0.0379 (2)	0.0392 (6)
H27	0.0987	0.5491	0.0476	0.047*
C28	0.2558 (3)	0.53094 (10)	−0.0398 (2)	0.0392 (6)
H28	0.2561	0.5637	−0.0840	0.047*
C29	0.3482 (3)	0.49200 (10)	−0.0526 (2)	0.0358 (6)
H29	0.4118	0.4978	−0.1065	0.043*
C30	0.3492 (2)	0.44431 (9)	0.0124 (2)	0.0276 (5)
H30	0.4147	0.4180	0.0043	0.033*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Pd1	0.01936 (9)	0.01616 (9)	0.01542 (9)	−0.00214 (7)	0.00111 (6)	0.00054 (6)
Cl1	0.0363 (3)	0.0180 (3)	0.0259 (3)	−0.0055 (2)	0.0020 (2)	0.0023 (2)
Cl2	0.0465 (4)	0.0264 (3)	0.0216 (3)	−0.0170 (3)	−0.0011 (3)	0.0033 (2)
P1	0.0212 (3)	0.0177 (3)	0.0166 (3)	0.0001 (2)	0.0012 (2)	−0.0013 (2)
N1	0.0187 (8)	0.0178 (9)	0.0147 (9)	−0.0008 (7)	0.0014 (7)	0.0011 (7)
C1	0.0189 (10)	0.0186 (11)	0.0194 (11)	0.0017 (9)	0.0001 (9)	0.0036 (9)
C2	0.0195 (11)	0.0299 (13)	0.0213 (12)	0.0019 (9)	0.0012 (9)	0.0033 (10)
C3	0.0251 (12)	0.0361 (14)	0.0303 (14)	0.0033 (11)	−0.0022 (10)	0.0099 (11)
C4	0.0186 (11)	0.0380 (14)	0.0446 (16)	0.0060 (11)	0.0006 (11)	0.0125 (12)
C5	0.0268 (12)	0.0397 (15)	0.0430 (16)	0.0117 (11)	0.0099 (11)	0.0020 (12)
C6	0.0232 (11)	0.0356 (13)	0.0260 (13)	0.0043 (10)	0.0070 (10)	0.0000 (11)
C7	0.0169 (10)	0.0214 (11)	0.0166 (11)	0.0014 (9)	0.0007 (8)	−0.0007 (9)
C8	0.0197 (11)	0.0256 (12)	0.0248 (12)	0.0036 (9)	0.0042 (9)	0.0040 (10)
C9	0.0247 (12)	0.0338 (14)	0.0306 (14)	0.0009 (10)	0.0108 (10)	0.0048 (10)
C10	0.0210 (11)	0.0362 (14)	0.0323 (14)	0.0061 (10)	0.0060 (10)	−0.0012 (11)
C11	0.0277 (12)	0.0263 (13)	0.0246 (13)	0.0082 (10)	−0.0013 (10)	−0.0021 (10)
C12	0.0233 (11)	0.0206 (11)	0.0220 (12)	0.0009 (9)	−0.0012 (9)	−0.0003 (9)
C13	0.0241 (11)	0.0183 (11)	0.0211 (12)	0.0001 (9)	0.0004 (9)	0.0023 (9)
C14	0.0253 (12)	0.0282 (13)	0.0240 (13)	−0.0046 (10)	0.0007 (10)	−0.0037 (10)
C15	0.0269 (12)	0.0280 (13)	0.0356 (14)	−0.0005 (11)	0.0060 (11)	0.0026 (11)
C16	0.0228 (12)	0.0289 (14)	0.0522 (17)	−0.0034 (11)	−0.0013 (11)	0.0068 (12)
C17	0.0325 (14)	0.0343 (15)	0.0519 (18)	−0.0111 (12)	−0.0103 (12)	−0.0118 (13)
C18	0.0312 (13)	0.0277 (13)	0.0356 (15)	−0.0025 (11)	−0.0005 (11)	−0.0107 (11)
C19	0.0264 (11)	0.0198 (11)	0.0216 (12)	−0.0007 (9)	0.0063 (9)	0.0000 (9)
C20	0.0230 (11)	0.0252 (12)	0.0290 (13)	−0.0004 (10)	0.0043 (10)	−0.0021 (10)
C21	0.0225 (12)	0.0244 (13)	0.0486 (16)	0.0009 (10)	0.0098 (11)	−0.0010 (11)
C22	0.0386 (14)	0.0206 (12)	0.0455 (16)	−0.0024 (11)	0.0242 (13)	−0.0061 (11)
C23	0.0529 (16)	0.0246 (13)	0.0268 (13)	−0.0035 (12)	0.0167 (12)	−0.0049 (11)
C24	0.0377 (13)	0.0219 (12)	0.0239 (13)	0.0022 (10)	0.0043 (10)	0.0005 (10)
C25	0.0270 (11)	0.0198 (11)	0.0162 (11)	−0.0006 (9)	−0.0036 (9)	−0.0024 (9)
C26	0.0332 (13)	0.0261 (13)	0.0355 (15)	0.0036 (11)	0.0001 (11)	0.0051 (11)
C27	0.0429 (15)	0.0245 (13)	0.0473 (17)	0.0069 (11)	−0.0080 (13)	0.0070 (12)
C28	0.0573 (17)	0.0266 (14)	0.0298 (15)	−0.0105 (13)	−0.0132 (12)	0.0099 (11)
C29	0.0504 (16)	0.0334 (14)	0.0229 (14)	−0.0167 (13)	0.0005 (12)	0.0021 (11)
C30	0.0345 (13)	0.0251 (12)	0.0229 (12)	−0.0026 (10)	0.0015 (10)	−0.0003 (10)

Geometric parameters (Å, º)

Pd1—N1	2.1573 (17)	C10—H10B	0.9900
Pd1—P1	2.2504 (7)	C11—C12	1.531 (3)
Pd1—Cl2	2.2974 (6)	C11—H11A	0.9900
Pd1—Cl1	2.3055 (6)	C11—H11B	0.9900
Cl2—H1N	2.68	C12—H12A	0.9900
P1—C19	1.818 (2)	C12—H12B	0.9900
P1—C25	1.823 (2)	C13—C18	1.390 (3)
P1—C13	1.828 (2)	C13—C14	1.395 (3)
N1—C1	1.502 (2)	C14—C15	1.385 (3)
N1—C7	1.503 (2)	C14—H14	0.9500
N1—H1N	0.9300	C15—C16	1.375 (3)
C1—C2	1.525 (3)	C15—H15	0.9500
C1—C6	1.531 (3)	C16—C17	1.376 (4)
C1—H1	1.0000	C16—H16	0.9500
C2—C3	1.528 (3)	C17—C18	1.392 (3)
C2—H2A	0.9900	C17—H17	0.9500
C2—H2B	0.9900	C18—H18	0.9500
C3—C4	1.516 (3)	C19—C20	1.395 (3)
C3—H3A	0.9900	C19—C24	1.397 (3)
C3—H3B	0.9900	C20—C21	1.385 (3)
C4—C5	1.516 (3)	C20—H20	0.9500
C4—H4A	0.9900	C21—C22	1.378 (3)
C4—H4B	0.9900	C21—H21	0.9500
C5—C6	1.527 (3)	C22—C23	1.383 (3)
C5—H5A	0.9900	C22—H22	0.9500
C5—H5B	0.9900	C23—C24	1.384 (3)
C6—H6A	0.9900	C23—H23	0.9500
C6—H6B	0.9900	C24—H24	0.9500
C7—C8	1.518 (3)	C25—C30	1.392 (3)
C7—C12	1.530 (3)	C25—C26	1.395 (3)
C7—H7	1.0000	C26—C27	1.381 (3)
C8—C9	1.532 (3)	C26—H26	0.9500
C8—H8A	0.9900	C27—C28	1.385 (4)
C8—H8B	0.9900	C27—H27	0.9500
C9—C10	1.521 (3)	C28—C29	1.375 (4)
C9—H9A	0.9900	C28—H28	0.9500
C9—H9B	0.9900	C29—C30	1.386 (3)
C10—C11	1.521 (3)	C29—H29	0.9500
C10—H10A	0.9900	C30—H30	0.9500
N1—Pd1—P1	172.60 (4)	C9—C10—C11	110.31 (18)
N1—Pd1—Cl2	87.59 (5)	C9—C10—H10A	109.6
P1—Pd1—Cl2	93.13 (2)	C11—C10—H10A	109.6
N1—Pd1—Cl1	94.26 (5)	C9—C10—H10B	109.6
P1—Pd1—Cl1	86.00 (2)	C11—C10—H10B	109.6
Cl2—Pd1—Cl1	172.39 (2)	H10A—C10—H10B	108.1
Pd1—Cl2—H1N	60.9	C10—C11—C12	111.72 (18)
C19—P1—C25	104.67 (10)	C10—C11—H11A	109.3
C19—P1—C13	108.72 (10)	C12—C11—H11A	109.3
C25—P1—C13	103.92 (10)	C10—C11—H11B	109.3
C19—P1—Pd1	115.70 (7)	C12—C11—H11B	109.3
C25—P1—Pd1	114.25 (7)	H11A—C11—H11B	107.9
C13—P1—Pd1	108.83 (7)	C7—C12—C11	110.63 (17)
C1—N1—C7	115.37 (15)	C7—C12—H12A	109.5
C1—N1—Pd1	114.31 (12)	C11—C12—H12A	109.5
C7—N1—Pd1	113.53 (12)	C7—C12—H12B	109.5
C1—N1—H1N	103.9	C11—C12—H12B	109.5
C7—N1—H1N	103.9	H12A—C12—H12B	108.1
Pd1—N1—H1N	103.9	C18—C13—C14	118.2 (2)
N1—C1—C2	114.47 (17)	C18—C13—P1	124.03 (17)
N1—C1—C6	107.42 (16)	C14—C13—P1	117.71 (16)
C2—C1—C6	110.10 (17)	C15—C14—C13	121.2 (2)
N1—C1—H1	108.2	C15—C14—H14	119.4
C2—C1—H1	108.2	C13—C14—H14	119.4
C6—C1—H1	108.2	C16—C15—C14	119.8 (2)
C1—C2—C3	110.59 (18)	C16—C15—H15	120.1
C1—C2—H2A	109.5	C14—C15—H15	120.1
C3—C2—H2A	109.5	C15—C16—C17	120.0 (2)
C1—C2—H2B	109.5	C15—C16—H16	120.0
C3—C2—H2B	109.5	C17—C16—H16	120.0
H2A—C2—H2B	108.1	C16—C17—C18	120.6 (2)
C4—C3—C2	111.35 (19)	C16—C17—H17	119.7
C4—C3—H3A	109.4	C18—C17—H17	119.7
C2—C3—H3A	109.4	C13—C18—C17	120.2 (2)
C4—C3—H3B	109.4	C13—C18—H18	119.9
C2—C3—H3B	109.4	C17—C18—H18	119.9
H3A—C3—H3B	108.0	C20—C19—C24	118.7 (2)
C3—C4—C5	110.60 (19)	C20—C19—P1	119.93 (17)
C3—C4—H4A	109.5	C24—C19—P1	121.29 (17)
C5—C4—H4A	109.5	C21—C20—C19	120.2 (2)
C3—C4—H4B	109.5	C21—C20—H20	119.9
C5—C4—H4B	109.5	C19—C20—H20	119.9
H4A—C4—H4B	108.1	C22—C21—C20	120.7 (2)
C4—C5—C6	111.9 (2)	C22—C21—H21	119.7
C4—C5—H5A	109.2	C20—C21—H21	119.7
C6—C5—H5A	109.2	C21—C22—C23	119.6 (2)
C4—C5—H5B	109.2	C21—C22—H22	120.2
C6—C5—H5B	109.2	C23—C22—H22	120.2
H5A—C5—H5B	107.9	C22—C23—C24	120.3 (2)
C5—C6—C1	111.63 (18)	C22—C23—H23	119.8
C5—C6—H6A	109.3	C24—C23—H23	119.8
C1—C6—H6A	109.3	C23—C24—C19	120.4 (2)
C5—C6—H6B	109.3	C23—C24—H24	119.8
C1—C6—H6B	109.3	C19—C24—H24	119.8
H6A—C6—H6B	108.0	C30—C25—C26	118.7 (2)
N1—C7—C8	112.82 (16)	C30—C25—P1	121.08 (17)
N1—C7—C12	109.71 (16)	C26—C25—P1	119.89 (17)
C8—C7—C12	110.85 (17)	C27—C26—C25	120.6 (2)
N1—C7—H7	107.8	C27—C26—H26	119.7
C8—C7—H7	107.8	C25—C26—H26	119.7
C12—C7—H7	107.8	C26—C27—C28	120.2 (2)
C7—C8—C9	110.36 (18)	C26—C27—H27	119.9
C7—C8—H8A	109.6	C28—C27—H27	119.9
C9—C8—H8A	109.6	C29—C28—C27	119.7 (2)
C7—C8—H8B	109.6	C29—C28—H28	120.2
C9—C8—H8B	109.6	C27—C28—H28	120.2
H8A—C8—H8B	108.1	C28—C29—C30	120.5 (2)
C10—C9—C8	110.73 (18)	C28—C29—H29	119.7
C10—C9—H9A	109.5	C30—C29—H29	119.7
C8—C9—H9A	109.5	C29—C30—C25	120.3 (2)
C10—C9—H9B	109.5	C29—C30—H30	119.8
C8—C9—H9B	109.5	C25—C30—H30	119.8
H9A—C9—H9B	108.1
N1—Pd1—Cl2—H1N	2.9	C19—P1—C13—C14	160.53 (17)
P1—Pd1—Cl2—H1N	175.5	C25—P1—C13—C14	−88.40 (18)
Cl2—Pd1—P1—C19	107.58 (8)	Pd1—P1—C13—C14	33.71 (18)
Cl1—Pd1—P1—C19	−64.85 (8)	C18—C13—C14—C15	−1.6 (3)
Cl2—Pd1—P1—C25	−14.09 (8)	P1—C13—C14—C15	176.62 (18)
Cl1—Pd1—P1—C25	173.48 (8)	C13—C14—C15—C16	1.0 (4)
Cl2—Pd1—P1—C13	−129.71 (7)	C14—C15—C16—C17	0.0 (4)
Cl1—Pd1—P1—C13	57.86 (7)	C15—C16—C17—C18	−0.4 (4)
Cl2—Pd1—N1—C1	−120.10 (13)	C14—C13—C18—C17	1.2 (3)
Cl1—Pd1—N1—C1	52.50 (13)	P1—C13—C18—C17	−176.90 (19)
Cl2—Pd1—N1—C7	104.70 (13)	C16—C17—C18—C13	−0.2 (4)
Cl1—Pd1—N1—C7	−82.70 (13)	C25—P1—C19—C20	130.11 (17)
C7—N1—C1—C2	−42.9 (2)	C13—P1—C19—C20	−119.33 (18)
Pd1—N1—C1—C2	−177.23 (13)	Pd1—P1—C19—C20	3.4 (2)
C7—N1—C1—C6	−165.46 (17)	C25—P1—C19—C24	−47.0 (2)
Pd1—N1—C1—C6	60.18 (19)	C13—P1—C19—C24	63.6 (2)
N1—C1—C2—C3	−177.77 (17)	Pd1—P1—C19—C24	−173.66 (15)
C6—C1—C2—C3	−56.7 (2)	C24—C19—C20—C21	−0.3 (3)
C1—C2—C3—C4	58.1 (3)	P1—C19—C20—C21	−177.45 (17)
C2—C3—C4—C5	−56.5 (3)	C19—C20—C21—C22	−1.0 (3)
C3—C4—C5—C6	54.7 (3)	C20—C21—C22—C23	0.8 (3)
C4—C5—C6—C1	−54.6 (3)	C21—C22—C23—C24	0.5 (3)
N1—C1—C6—C5	−179.57 (19)	C22—C23—C24—C19	−1.8 (3)
C2—C1—C6—C5	55.2 (3)	C20—C19—C24—C23	1.6 (3)
C1—N1—C7—C8	−63.4 (2)	P1—C19—C24—C23	178.76 (17)
Pd1—N1—C7—C8	71.30 (18)	C19—P1—C25—C30	−30.0 (2)
C1—N1—C7—C12	172.48 (17)	C13—P1—C25—C30	−143.98 (18)
Pd1—N1—C7—C12	−52.81 (19)	Pd1—P1—C25—C30	97.58 (18)
N1—C7—C8—C9	179.14 (17)	C19—P1—C25—C26	156.80 (18)
C12—C7—C8—C9	−57.4 (2)	C13—P1—C25—C26	42.8 (2)
C7—C8—C9—C10	58.3 (2)	Pd1—P1—C25—C26	−75.64 (19)
C8—C9—C10—C11	−57.3 (3)	C30—C25—C26—C27	−0.3 (3)
C9—C10—C11—C12	56.0 (3)	P1—C25—C26—C27	173.11 (19)
N1—C7—C12—C11	−178.99 (17)	C25—C26—C27—C28	1.0 (4)
C8—C7—C12—C11	55.8 (2)	C26—C27—C28—C29	−0.6 (4)
C10—C11—C12—C7	−55.2 (2)	C27—C28—C29—C30	−0.7 (4)
C19—P1—C13—C18	−21.4 (2)	C28—C29—C30—C25	1.5 (3)
C25—P1—C13—C18	89.7 (2)	C26—C25—C30—C29	−1.0 (3)
Pd1—P1—C13—C18	−148.18 (18)	P1—C25—C30—C29	−174.27 (17)

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
N1—H1N···Cl2^i	0.93	2.64	3.471 (2)	148

Symmetry code: (i) −x+1, −y+1, −z+1.