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The title complex, [ZnCl(C12H8N2)2(H2O)]2(C10H8O6)·2H2O (C10H8O6 = benzene-1,4-dioxy­acetate and phen = 1,10-phenanthroline) consists of two [ZnCl(phen)2(H2O)]2+ cations, a benzene-1,4-dioxy­acetate dianion and two water mol­ecules. In the cation, the ZnII atom is coordinated by four N atoms from two phen ligands, one Cl anion and one water mol­ecule, forming a distorted octahedral coordination environment. The benzene-1,4-dioxy­acetate dianion lies on an inversion center, with anions and cations forming one-dimensional chains through O—H...O hydrogen bonds.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804009079/lh6202sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536804009079/lh6202Isup2.hkl
Contains datablock I

CCDC reference: 239071

Key indicators

  • Single-crystal X-ray study
  • T = 293 K
  • Mean [sigma](C-C) = 0.004 Å
  • R factor = 0.042
  • wR factor = 0.104
  • Data-to-parameter ratio = 15.8

checkCIF/PLATON results

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Alert level C PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings Differ .... ? PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............ 2.00 Ratio PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........ 4 PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 2 C10 H8 O6 PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 3 H2 O
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 6 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 3 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 0 ALERT type 2 Indicator that the structure model may be wrong or deficient 0 ALERT type 3 Indicator that the structure quality may be low 3 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: RAPID-AUTO (Rigaku, 1998); cell refinement: RAPID-AUTO; data reduction: CrystalStructure (Rigaku/MSC, 2002); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.

Bis[bis(1,10-phenanthroline)aquachlorozinc(II)] benzene-1,4-dioxyacetate dihydrate top
Crystal data top
[ZnCl(C12H8N2)2(H2O)]2(C10H8O6)·2H2OZ = 1
Mr = 1218.72F(000) = 626
Triclinic, P1Dx = 1.554 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 9.950 (6) ÅCell parameters from 6638 reflections
b = 12.06 (1) Åθ = 3.3–27.5°
c = 12.81 (1) ŵ = 1.09 mm1
α = 61.95 (3)°T = 293 K
β = 80.65 (4)°Prism, colorless
γ = 73.92 (3)°0.37 × 0.25 × 0.18 mm
V = 1302.6 (17) Å3
Data collection top
Rigaku R-AXIS RAPID
diffractometer
5884 independent reflections
Radiation source: fine-focus sealed tube4682 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.034
Detector resolution: 10 pixels mm-1θmax = 27.5°, θmin = 3.2°
ω scansh = 1211
Absorption correction: multi-scan
(ABSCOR; Higashi, 1995)
k = 1515
Tmin = 0.687, Tmax = 0.827l = 1616
12345 measured reflections
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.042Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.104H atoms treated by a mixture of independent and constrained refinement
S = 1.04 w = 1/[σ2(Fo2) + (0.0583P)2 + 0.3253P]
where P = (Fo2 + 2Fc2)/3
5884 reflections(Δ/σ)max = 0.001
373 parametersΔρmax = 0.59 e Å3
6 restraintsΔρmin = 0.39 e Å3
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Zn10.32051 (3)0.12679 (3)0.21566 (2)0.0308 (1)
Cl10.44774 (6)0.05143 (6)0.37346 (5)0.0390 (2)
N10.2258 (2)0.3121 (2)0.0597 (2)0.0319 (4)
N20.3827 (2)0.2758 (2)0.2313 (2)0.0334 (4)
N30.1919 (2)0.0274 (2)0.1901 (2)0.0302 (4)
N40.1210 (2)0.1584 (2)0.3217 (2)0.0321 (4)
O10.4593 (2)0.2385 (2)0.1558 (2)0.0448 (4)
O20.3147 (2)0.1175 (2)0.1358 (2)0.0418 (4)
O30.1561 (2)0.3256 (2)0.3037 (2)0.0416 (4)
O1W0.4822 (2)0.1093 (2)0.0884 (2)0.0372 (4)
O2W0.6472 (4)0.2968 (4)0.3756 (4)0.122 (1)
C10.4536 (3)0.2576 (3)0.3197 (3)0.0437 (6)
C20.4955 (3)0.3581 (3)0.3223 (3)0.0536 (8)
C30.4649 (3)0.4787 (3)0.2314 (3)0.0537 (8)
C40.3884 (3)0.5025 (3)0.1368 (3)0.0421 (6)
C50.3504 (3)0.6267 (3)0.0377 (3)0.0545 (8)
C60.2732 (3)0.6446 (3)0.0473 (3)0.0546 (8)
C70.2267 (3)0.5408 (2)0.0439 (2)0.0430 (6)
C80.1433 (3)0.5541 (3)0.1291 (2)0.0520 (7)
C90.1025 (3)0.4499 (3)0.1185 (3)0.0505 (7)
C100.1474 (3)0.3298 (3)0.0227 (2)0.0409 (6)
C110.2650 (2)0.4164 (2)0.0506 (2)0.0329 (5)
C120.3480 (2)0.3965 (2)0.1425 (2)0.0331 (5)
C130.2276 (3)0.0370 (2)0.1257 (2)0.0375 (5)
C140.1364 (3)0.0970 (3)0.1093 (2)0.0441 (6)
C150.0055 (3)0.0917 (2)0.1622 (2)0.0412 (6)
C160.0356 (2)0.0263 (2)0.2330 (2)0.0347 (5)
C170.1700 (3)0.0191 (3)0.2944 (2)0.0405 (6)
C180.2032 (2)0.0421 (3)0.3641 (2)0.0415 (6)
C190.1079 (2)0.1050 (2)0.3755 (2)0.0344 (5)
C200.1377 (3)0.1714 (3)0.4452 (2)0.0421 (6)
C210.0417 (3)0.2305 (3)0.4501 (2)0.0446 (6)
C220.0865 (3)0.2217 (2)0.3870 (2)0.0396 (6)
C230.0247 (2)0.1011 (2)0.3154 (2)0.0296 (5)
C240.0616 (2)0.0326 (2)0.2438 (2)0.0293 (5)
C250.3625 (2)0.2161 (2)0.1886 (2)0.0329 (5)
C260.3016 (2)0.3205 (2)0.3075 (2)0.0390 (6)
C270.0839 (2)0.4140 (2)0.4042 (2)0.0338 (5)
C280.0608 (3)0.4344 (3)0.3904 (2)0.0402 (6)
C290.1445 (3)0.5199 (3)0.4858 (2)0.0403 (6)
H1W10.538 (3)0.035 (2)0.109 (2)0.056*
H1W20.469 (3)0.144 (2)0.015 (1)0.056*
H2W10.617 (6)0.250 (6)0.397 (6)0.183*
H2W20.587 (5)0.309 (7)0.323 (5)0.183*
H10.47630.17520.38200.052*
H20.54400.34220.38600.064*
H30.49440.54540.23150.064*
H50.38010.69590.03240.065*
H60.24910.72650.11020.066*
H80.11550.63430.19320.062*
H90.04560.45880.17410.061*
H100.12060.25900.01680.049*
H130.31680.04240.09000.045*
H140.16480.14030.06270.053*
H150.05600.13090.15150.049*
H170.23480.05690.28610.049*
H180.28930.04310.40510.050*
H200.22260.17500.48790.050*
H210.06110.27610.49460.054*
H220.15110.26230.39120.048*
H26A0.31470.40360.32240.047*
H26B0.34940.30030.37090.047*
H280.10190.39050.31660.048*
H290.24130.53290.47600.048*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Zn10.0307 (2)0.0286 (2)0.0317 (2)0.0088 (1)0.0029 (1)0.0108 (1)
Cl10.0393 (3)0.0367 (3)0.0315 (3)0.0055 (2)0.0050 (2)0.0083 (3)
O1W0.0354 (9)0.0346 (9)0.0302 (9)0.0011 (7)0.0014 (7)0.0091 (8)
O2W0.107 (3)0.125 (3)0.146 (4)0.052 (2)0.032 (2)0.067 (3)
O10.042 (1)0.047 (1)0.044 (1)0.0094 (8)0.0147 (8)0.0152 (9)
O20.0407 (9)0.0339 (9)0.041 (1)0.0065 (8)0.0080 (8)0.0082 (8)
O30.0337 (9)0.043 (1)0.035 (1)0.0062 (7)0.0110 (7)0.0044 (8)
N10.0317 (9)0.029 (1)0.032 (1)0.0021 (8)0.0018 (8)0.0132 (9)
N20.032 (1)0.031 (1)0.035 (1)0.0075 (8)0.0043 (8)0.0121 (9)
N30.0282 (9)0.030 (1)0.031 (1)0.0050 (8)0.0015 (8)0.0125 (8)
N40.034 (1)0.031 (1)0.030 (1)0.0067 (8)0.0021 (8)0.0126 (9)
C10.040 (1)0.044 (2)0.049 (2)0.005 (1)0.012 (1)0.021 (1)
C20.045 (2)0.063 (2)0.070 (2)0.012 (1)0.013 (1)0.040 (2)
C30.043 (2)0.052 (2)0.085 (2)0.017 (1)0.000 (2)0.043 (2)
C40.032 (1)0.036 (1)0.062 (2)0.012 (1)0.007 (1)0.026 (1)
C50.049 (2)0.032 (1)0.079 (2)0.014 (1)0.010 (2)0.024 (2)
C60.059 (2)0.025 (1)0.058 (2)0.006 (1)0.008 (2)0.007 (1)
C70.043 (1)0.031 (1)0.038 (1)0.002 (1)0.006 (1)0.008 (1)
C80.056 (2)0.040 (2)0.034 (2)0.008 (1)0.005 (1)0.005 (1)
C90.051 (2)0.055 (2)0.037 (2)0.008 (1)0.014 (1)0.020 (1)
C100.039 (1)0.043 (1)0.041 (2)0.003 (1)0.005 (1)0.021 (1)
C110.031 (1)0.028 (1)0.032 (1)0.0028 (9)0.0023 (9)0.010 (1)
C120.028 (1)0.030 (1)0.039 (1)0.0065 (9)0.004 (1)0.015 (1)
C130.037 (1)0.037 (1)0.037 (1)0.006 (1)0.003 (1)0.019 (1)
C140.051 (2)0.046 (2)0.044 (2)0.011 (1)0.001 (1)0.028 (1)
C150.046 (1)0.041 (1)0.042 (2)0.017 (1)0.008 (1)0.017 (1)
C160.035 (1)0.032 (1)0.033 (1)0.010 (1)0.005 (1)0.009 (1)
C170.032 (1)0.043 (1)0.043 (2)0.015 (1)0.002 (1)0.013 (1)
C180.028 (1)0.044 (2)0.041 (1)0.009 (1)0.003 (1)0.012 (1)
C190.029 (1)0.032 (1)0.031 (1)0.0015 (9)0.0004 (9)0.009 (1)
C200.038 (1)0.042 (1)0.034 (1)0.000 (1)0.006 (1)0.014 (1)
C210.054 (2)0.041 (2)0.037 (1)0.001 (1)0.000 (1)0.022 (1)
C220.045 (1)0.036 (1)0.040 (1)0.007 (1)0.005 (1)0.019 (1)
C230.031 (1)0.026 (1)0.025 (1)0.0043 (9)0.0011 (9)0.0065 (9)
C240.028 (1)0.025 (1)0.029 (1)0.0047 (8)0.0030 (9)0.0074 (9)
C250.032 (1)0.031 (1)0.034 (1)0.0003 (9)0.004 (1)0.016 (1)
C260.036 (1)0.038 (1)0.035 (1)0.008 (1)0.009 (1)0.007 (1)
C270.034 (1)0.031 (1)0.033 (1)0.0049 (9)0.011 (1)0.010 (1)
C280.036 (1)0.043 (1)0.030 (1)0.008 (1)0.003 (1)0.008 (1)
C290.029 (1)0.045 (2)0.038 (1)0.004 (1)0.008 (1)0.012 (1)
Geometric parameters (Å, º) top
Zn1—Cl12.355 (2)C8—C91.366 (4)
Zn1—N12.263 (2)C8—H80.9300
Zn1—N22.156 (2)C9—C101.397 (4)
Zn1—N32.130 (2)C9—H90.9300
Zn1—N42.264 (2)C10—H100.9300
Zn1—O1W2.138 (2)C11—C121.437 (3)
N1—C101.316 (3)C13—C141.400 (4)
N1—C111.366 (3)C13—H130.9300
N2—C11.329 (3)C14—C151.367 (4)
N2—C121.350 (3)C14—H140.9300
N3—C131.328 (3)C15—C161.409 (4)
N3—C241.365 (3)C15—H150.9300
N4—C221.327 (3)C16—C241.406 (3)
N4—C231.359 (3)C16—C171.439 (4)
O1—C251.249 (3)C17—C181.357 (4)
O2—C251.245 (3)C17—H170.9300
O3—C261.426 (3)C18—C191.429 (4)
O3—C271.377 (3)C18—H180.9300
O1W—H1W10.85 (4)C19—C201.408 (4)
O1W—H1W20.84 (1)C19—C231.416 (3)
O2W—H2W10.87 (7)C20—C211.365 (4)
O2W—H2W20.87 (7)C20—H200.9300
C1—C21.403 (4)C21—C221.401 (4)
C1—H10.9300C21—H210.9300
C2—C31.357 (5)C22—H220.9300
C2—H20.9300C23—C241.447 (3)
C3—C41.408 (4)C25—C261.531 (3)
C3—H30.9300C26—H26A0.9700
C4—C51.432 (4)C26—H26B0.9700
C4—C121.411 (3)C27—C29i1.385 (4)
C5—C61.335 (5)C27—C281.388 (3)
C5—H50.9300C28—C291.386 (3)
C6—C71.431 (4)C28—H280.9300
C6—H60.9300C29—C27i1.385 (4)
C7—C81.399 (4)C29—H290.9300
C7—C111.409 (4)
N1—Zn1—Cl1171.26 (5)C8—C7—C6124.1 (3)
N1—Zn1—N487.94 (8)C8—C7—C11116.7 (3)
N2—Zn1—Cl197.48 (8)C8—C9—C10118.9 (3)
N2—Zn1—N175.33 (9)C8—C9—H9120.5
N2—Zn1—N489.26 (8)C9—C8—C7120.3 (3)
N3—Zn1—Cl197.56 (8)C9—C8—H8119.8
N3—Zn1—N190.59 (9)C9—C10—H10118.5
N3—Zn1—N2160.13 (7)C10—N1—Zn1129.4 (2)
N3—Zn1—N476.07 (8)C10—N1—C11118.2 (2)
N3—Zn1—O1W96.63 (8)C10—C9—H9120.5
N4—Zn1—Cl197.05 (7)C11—N1—Zn1112.4 (2)
O1W—Zn1—Cl192.24 (7)C11—C7—C6119.1 (3)
O1W—Zn1—N183.66 (8)C12—N2—Zn1116.5 (2)
O1W—Zn1—N295.68 (8)C12—C4—C5119.5 (3)
O1W—Zn1—N4168.84 (7)C13—N3—Zn1125.5 (2)
Zn1—O1W—H1W1116 (2)C13—N3—C24118.1 (2)
Zn1—O1W—H1W2123 (2)C13—C14—H14120.2
N1—C10—C9123.1 (3)C14—C13—H13118.7
N1—C10—H10118.5C14—C15—C16119.5 (2)
N1—C11—C7122.7 (2)C14—C15—H15120.2
N1—C11—C12117.7 (2)C15—C14—C13119.6 (2)
N2—C1—C2122.4 (3)C15—C14—H14120.2
N2—C1—H1118.8C15—C16—C17123.1 (2)
N2—C12—C4123.1 (2)C16—C15—H15120.2
N2—C12—C11117.8 (2)C16—C17—H17119.6
N3—C13—C14122.7 (2)C16—C24—C23119.5 (2)
N3—C13—H13118.7C17—C18—C19121.1 (2)
N3—C24—C16122.8 (2)C17—C18—H18119.5
N3—C24—C23117.7 (2)C18—C17—C16120.8 (2)
N4—C22—C21123.6 (2)C18—C17—H17119.6
N4—C22—H22118.2C19—C18—H18119.5
N4—C23—C19123.3 (2)C19—C20—H20120.1
N4—C23—C24117.5 (2)C19—C23—C24119.2 (2)
O1—C25—C26115.3 (2)C20—C19—C18123.5 (2)
O2—C25—O1126.4 (2)C20—C19—C23116.9 (2)
O2—C25—C26118.3 (2)C20—C21—C22119.1 (2)
O3—C26—C25108.8 (2)C20—C21—H21120.5
O3—C26—H26A109.9C21—C20—C19119.8 (2)
O3—C26—H26B109.9C21—C20—H20120.1
O3—C27—C28115.3 (2)C21—C22—H22118.2
O3—C27—C29i125.2 (2)C22—N4—Zn1130.3 (2)
C1—N2—Zn1125.3 (2)C22—N4—C23117.4 (2)
C1—N2—C12118.2 (2)C22—C21—H21120.5
C1—C2—H2120.2C23—N4—Zn1112.3 (2)
C2—C1—H1118.8C24—N3—Zn1116.4 (2)
C2—C3—C4119.8 (2)C24—C16—C15117.3 (2)
C2—C3—H3120.1C24—C16—C17119.7 (2)
C3—C2—C1119.6 (3)C23—C19—C18119.7 (2)
C3—C2—H2120.2C25—C26—H26A109.9
C3—C4—C12116.8 (3)C25—C26—H26B109.9
C3—C4—C5123.7 (2)C27—O3—C26116.9 (2)
C4—C3—H3120.1C27—C28—H28119.8
C4—C5—H5119.5C27i—C29—C28120.0 (2)
C4—C12—C11119.2 (2)C27i—C29—H29120.0
C5—C6—C7121.5 (3)C28—C29—H29120.0
C5—C6—H6119.2C29i—C27—C28119.5 (2)
C6—C5—C4121.0 (3)C29—C28—C27120.4 (2)
C6—C5—H5119.5C29—C28—H28119.8
C7—C6—H6119.2H1W1—O1W—H1W2110 (2)
C7—C8—H8119.8H2W1—O2W—H2W2106 (6)
C7—C11—C12119.6 (2)H26A—C26—H26B108.3
Zn1—N1—C10—C9176.2 (2)C1—N2—C12—C11176.8 (2)
Zn1—N1—C11—C7175.8 (2)C1—C2—C3—C41.6 (5)
Zn1—N1—C11—C124.6 (3)C2—C3—C4—C5179.5 (3)
Zn1—N2—C1—C2177.5 (2)C2—C3—C4—C120.3 (4)
Zn1—N2—C12—C4176.2 (2)C3—C4—C5—C6177.4 (3)
Zn1—N2—C12—C114.2 (3)C3—C4—C12—N21.9 (4)
Zn1—N3—C13—C14177.9 (2)C3—C4—C12—C11177.6 (2)
Zn1—N3—C24—C16178.8 (2)C4—C5—C6—C70.8 (5)
Zn1—N3—C24—C231.9 (3)C5—C4—C12—N2178.3 (2)
Zn1—N4—C22—C21178.6 (2)C5—C4—C12—C112.2 (4)
Zn1—N4—C23—C19179.0 (2)C5—C6—C7—C8178.7 (3)
Zn1—N4—C23—C240.7 (2)C5—C6—C7—C110.9 (4)
Cl1—Zn1—N2—C18.9 (2)C6—C7—C8—C9179.4 (3)
Cl1—Zn1—N2—C12170.0 (2)C6—C7—C11—N1179.4 (2)
Cl1—Zn1—N3—C1384.4 (2)C6—C7—C11—C121.0 (4)
Cl1—Zn1—N3—C2496.5 (2)C7—C8—C9—C101.2 (4)
Cl1—Zn1—N4—C2283.2 (2)C7—C11—C12—N2179.9 (2)
Cl1—Zn1—N4—C2396.3 (2)C7—C11—C12—C40.5 (3)
N1—Zn1—N2—C1176.2 (2)C8—C7—C11—N11.0 (4)
N1—Zn1—N2—C124.9 (2)C8—C7—C11—C12178.6 (2)
N1—Zn1—N3—C1392.5 (2)C8—C9—C10—N11.2 (4)
N1—Zn1—N3—C2486.6 (2)C10—N1—C11—C71.0 (3)
N1—Zn1—N4—C2289.5 (2)C10—N1—C11—C12178.6 (2)
N1—Zn1—N4—C2390.9 (2)C11—N1—C10—C90.1 (4)
N2—Zn1—N1—C10178.6 (2)C11—C7—C8—C90.2 (4)
N2—Zn1—N1—C115.0 (2)C12—N2—C1—C21.3 (4)
N2—Zn1—N3—C13136.7 (2)C12—C4—C5—C62.4 (4)
N2—Zn1—N3—C2442.4 (3)C13—N3—C24—C160.4 (3)
N2—Zn1—N4—C2214.2 (2)C13—N3—C24—C23179.0 (2)
N2—Zn1—N4—C23166.3 (2)C13—C14—C15—C160.3 (4)
N2—C1—C2—C30.8 (5)C14—C15—C16—C17178.3 (2)
N1—C11—C12—N20.5 (3)C14—C15—C16—C241.0 (4)
N1—C11—C12—C4179.1 (2)C15—C16—C17—C18178.2 (2)
N3—Zn1—N1—C1012.8 (2)C15—C16—C24—N30.7 (3)
N3—Zn1—N1—C11170.8 (2)C15—C16—C24—C23180.0 (2)
N3—Zn1—N2—C1130.1 (2)C16—C17—C18—C192.2 (4)
N3—Zn1—N2—C1251.1 (3)C17—C16—C24—N3178.6 (2)
N3—Zn1—N4—C22179.3 (2)C17—C16—C24—C230.7 (3)
N3—Zn1—N4—C230.2 (2)C17—C18—C19—C20179.1 (2)
N3—C13—C14—C150.8 (4)C17—C18—C19—C231.5 (4)
N4—Zn1—N3—C13179.8 (2)C18—C19—C20—C21179.1 (2)
N4—Zn1—N1—C1088.9 (2)C18—C19—C23—N4180.0 (2)
N4—Zn1—N1—C1194.8 (2)C18—C19—C23—C240.4 (3)
N4—Zn1—N2—C188.2 (2)C19—C20—C21—C221.3 (4)
N4—Zn1—N2—C1293.0 (2)C19—C23—C24—N3178.0 (2)
N4—Zn1—N3—C241.1 (2)C19—C23—C24—C161.4 (3)
N4—C23—C24—N31.7 (3)C20—C19—C23—N40.5 (3)
N4—C23—C24—C16178.9 (2)C20—C19—C23—C24179.1 (2)
O1—C25—C26—O3146.9 (2)C20—C21—C22—N40.1 (4)
O2—C25—C26—O334.7 (3)C22—N4—C23—C190.6 (3)
O3—C27—C28—C29179.1 (2)C22—N4—C23—C24179.7 (2)
O1W—Zn1—N1—C1083.8 (2)C23—N4—C22—C210.9 (4)
O1W—Zn1—N1—C1192.6 (2)C23—C19—C20—C211.5 (4)
O1W—Zn1—N2—C1101.9 (2)C24—N3—C13—C141.2 (4)
O1W—Zn1—N2—C1277.0 (2)C24—C16—C17—C181.1 (4)
O1W—Zn1—N3—C138.8 (2)C26—O3—C27—C28167.9 (2)
O1W—Zn1—N3—C24170.3 (2)C26—O3—C27—C29i12.8 (4)
O1W—Zn1—N4—C22130.6 (3)C27—O3—C26—C25179.5 (2)
O1W—Zn1—N4—C2349.8 (4)C27—C28—C29—C27i0.3 (4)
C1—N2—C12—C42.7 (4)C29i—C27—C28—C290.3 (4)
Symmetry code: (i) x, y+1, z1.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O1W—H1W1···O2ii0.85 (4)1.93 (3)2.776 (3)171 (3)
O1W—H1W2···O10.84 (1)1.94 (1)2.778 (3)172 (3)
O2W—H2W1···Cl1ii0.87 (7)2.52 (7)3.333 (5)156 (7)
O2W—H2W2···O10.87 (7)2.22 (4)3.013 (5)152 (6)
Symmetry code: (ii) x+1, y, z.
 

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