Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804002442/lh6164sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536804002442/lh6164Isup2.hkl |
CCDC reference: 236022
Key indicators
- Single-crystal X-ray study
- T = 293 K
- Mean (C-C) = 0.028 Å
- H-atom completeness 93%
- R factor = 0.054
- wR factor = 0.126
- Data-to-parameter ratio = 13.6
checkCIF/PLATON results
No syntax errors found
Alert level A PLAT029_ALERT_3_A _diffrn_measured_fraction_theta_full Low ....... 0.93
Author Response: We have tried to cut of the higher angle region of the present reflection data to solve this problem. However, we have been unsuccessful in solving this problem thus far. |
PLAT306_ALERT_2_A Isolated Oxygen Atom (H-atoms Missing ?) ....... O7
Author Response: It is generally hard to locate the H atoms of water molecules in the X-ray structure determination of platinum complexes. Some suggest that H atoms of water molecules should be located based on the method of Nardelli. However, we usually do not locate them, since we believe that crystallography is the method to extract the positions of atoms from the experimental data and we therefore do not want to rely on the mere calculations. |
Alert level B PLAT342_ALERT_3_B Low Bond Precision on C-C bonds (x 1000) Ang ... 28 PLAT430_ALERT_2_B Short Inter D...A Contact O5 .. O7 = 2.82 Ang.
Alert level C REFLT03_ALERT_3_C Reflection count < 95% complete From the CIF: _diffrn_reflns_theta_max 68.24 From the CIF: _diffrn_reflns_theta_full 0.00 From the CIF: _reflns_number_total 3014 TEST2: Reflns within _diffrn_reflns_theta_max Count of symmetry unique reflns 3247 Completeness (_total/calc) 92.82% PLAT022_ALERT_3_C Ratio Unique / Expected Reflections too Low .... 0.93 PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings Differ .... ? PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT068_ALERT_1_C Reported F000 Differs from Calcd (or Missing)... ? PLAT213_ALERT_2_C Atom N5 has ADP max/min Ratio ............. 3.20 oblate PLAT241_ALERT_2_C Check High U(eq) as Compared to Neighbors .... C7 PLAT244_ALERT_4_C Low Solvent U(eq) as Compared to Neighbors .... S1 PLAT420_ALERT_2_C D-H Without Acceptor N3 - H3C ... ? PLAT430_ALERT_2_C Short Inter D...A Contact O3 .. O7 = 2.88 Ang. PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 2 O4 S PLAT790_ALERT_4_C Centre of Gravity not Within Unit Cell: Resd. # 3 O
Alert level G FORMU01_ALERT_2_G There is a discrepancy between the atom counts in the _chemical_formula_sum and the formula from the _atom_site* data. Atom count from _chemical_formula_sum:C8 H26 N6 O7 Pt2 S1 Atom count from the _atom_site data: C8 H24 N6 O7 Pt2 S1 CELLZ01_ALERT_1_G Difference between formula and atom_site contents detected. CELLZ01_ALERT_1_G WARNING: H atoms missing from atom site list. Is this intentional? From the CIF: _cell_formula_units_Z 2 From the CIF: _chemical_formula_sum C8 H26 N6 O7 Pt2 S TEST: Compare cell contents of formula and atom_site data atom Z*formula cif sites diff C 16.00 16.00 0.00 H 52.00 48.00 4.00 N 12.00 12.00 0.00 O 14.00 14.00 0.00 Pt 4.00 4.00 0.00 S 2.00 2.00 0.00
2 ALERT level A = In general: serious problem 2 ALERT level B = Potentially serious problem 12 ALERT level C = Check and explain 3 ALERT level G = General alerts; check 5 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 7 ALERT type 2 Indicator that the structure model may be wrong or deficient 4 ALERT type 3 Indicator that the structure quality may be low 3 ALERT type 4 Improvement, methodology, query or suggestion
Data collection: PROCESS-AUTO (Rigaku, 1998); cell refinement: PROCESS-AUTO; data reduction: PROCESS-AUTO; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: KENX (Sakai, 2002); software used to prepare material for publication: SHELXL97, TEXSAN (Molecular Structure Corporation, 2001), KENX and ORTEPII (Johnson, 1976).
[Pt2(C4H6NO)2(NH3)4](SO4)·H2O | Z = 2 |
Mr = 740.59 | F(000) = 688 |
Triclinic, P1 | Dx = 2.777 Mg m−3 |
Hall symbol: -P 1 | Cu Kα radiation, λ = 1.54180 Å |
a = 6.859 (2) Å | Cell parameters from 1567 reflections |
b = 10.229 (2) Å | θ = 5.1–68.2° |
c = 12.896 (2) Å | µ = 30.63 mm−1 |
α = 99.569 (10)° | T = 293 K |
β = 93.538 (10)° | Needle, colorless |
γ = 95.146 (10)° | 0.13 × 0.05 × 0.03 mm |
V = 885.8 (3) Å3 |
Rigaku R-AXIS RAPID diffractometer | 3014 independent reflections |
Radiation source: fine-focus sealed tube | 2176 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.072 |
ω scans | θmax = 68.2°, θmin = 5.1° |
Absorption correction: multi-scan (ABSCOR; Higashi, 1995) | h = −7→7 |
Tmin = 0.098, Tmax = 0.465 | k = −12→12 |
3014 measured reflections | l = −15→15 |
Refinement on F2 | Secondary atom site location: difference Fourier map |
Least-squares matrix: full | Hydrogen site location: inferred from neighbouring sites |
R[F2 > 2σ(F2)] = 0.054 | H-atom parameters constrained |
wR(F2) = 0.127 | w = 1/[σ2(Fo2) + (0.0513P)2] where P = (Fo2 + 2Fc2)/3 |
S = 1.05 | (Δ/σ)max < 0.001 |
3014 reflections | Δρmax = 2.52 e Å−3 |
222 parameters | Δρmin = −2.15 e Å−3 |
0 restraints | Extinction correction: SHELXL97, Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4 |
Primary atom site location: structure-invariant direct methods | Extinction coefficient: 0.00037 (8) |
Experimental. The first 50 frames were rescanned at the end of data collection to evaluate any possible decay phenomenon. Since it was judged to be negligible, no decay correction was applied to the data. |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. Mean-plane data from final SHELXL refinement run:- Least-squares planes (x,y,z in crystal coordinates) and deviations from them (* indicates atom used to define plane) 6.4829 (0.0115) x - 1.3311 (0.0493) y - 4.7492 (0.0590) z = 1.5729 (0.0194) * 0.0085 (0.0063) O1 * -0.0087 (0.0064) O2 * -0.0089 (0.0066) N3 * 0.0091 (0.0067) N4 - 0.0936 (0.0065) Pt1 - 2.9362 (0.0072) Pt2 Rms deviation of fitted atoms = 0.0088 -4.5054 (0.0267) x + 1.2023 (0.0500) y + 9.9212 (0.0417) z = 2.6877 (0.0184) Angle to previous plane (with approximate e.s.d.) = 29.94 (1/2) * -0.0013 (0.0069) N1 * 0.0013 (0.0068) N2 * 0.0013 (0.0068) N5 * -0.0012 (0.0067) N6 0.0217 (0.0068) Pt2 - 2.8781 (0.0078) Pt1 Rms deviation of fitted atoms = 0.0013 |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Pt1 | 0.36898 (10) | 0.27545 (7) | 0.11499 (5) | 0.0357 (2) | |
Pt2 | 0.04202 (10) | 0.32841 (6) | 0.25238 (5) | 0.0320 (2) | |
S1 | −0.2172 (6) | 0.2402 (4) | −0.1152 (3) | 0.0352 (9) | |
O1 | 0.4881 (18) | 0.4458 (12) | 0.2083 (9) | 0.047 (3) | |
O2 | 0.4409 (17) | 0.1671 (12) | 0.2256 (10) | 0.048 (3) | |
O3 | −0.422 (2) | 0.2011 (19) | −0.1427 (13) | 0.090 (6) | |
O4 | −0.136 (2) | 0.1445 (13) | −0.0575 (11) | 0.066 (4) | |
O5 | −0.108 (2) | 0.2489 (13) | −0.2066 (11) | 0.062 (4) | |
O6 | −0.197 (3) | 0.3696 (13) | −0.0458 (11) | 0.081 (5) | |
O7 | 0.202 (2) | 0.0886 (14) | −0.2468 (12) | 0.065 (4) | |
N1 | 0.238 (2) | 0.4775 (13) | 0.3212 (10) | 0.037 (3) | |
N2 | 0.174 (2) | 0.2013 (14) | 0.3256 (11) | 0.039 (3) | |
N3 | 0.315 (2) | 0.3740 (12) | −0.0046 (11) | 0.042 (3) | |
H3A | 0.4071 | 0.3624 | −0.0498 | 0.062* | |
H3B | 0.3150 | 0.4605 | 0.0207 | 0.062* | |
H3C | 0.1978 | 0.3427 | −0.0376 | 0.062* | |
N4 | 0.277 (2) | 0.1081 (14) | 0.0149 (11) | 0.048 (4) | |
H4A | 0.3661 | 0.0910 | −0.0317 | 0.072* | |
H4B | 0.1635 | 0.1176 | −0.0189 | 0.072* | |
H4C | 0.2607 | 0.0409 | 0.0504 | 0.072* | |
N5 | −0.0889 (17) | 0.4588 (14) | 0.1751 (11) | 0.037 (3) | |
H5A | −0.0036 | 0.5292 | 0.1735 | 0.056* | |
H5B | −0.1921 | 0.4851 | 0.2084 | 0.056* | |
H5C | −0.1283 | 0.4191 | 0.1094 | 0.056* | |
N6 | −0.1564 (19) | 0.1773 (14) | 0.1783 (12) | 0.042 (3) | |
H6A | −0.1353 | 0.1594 | 0.1102 | 0.063* | |
H6B | −0.2772 | 0.2012 | 0.1849 | 0.063* | |
H6C | −0.1436 | 0.1051 | 0.2072 | 0.063* | |
C1 | 0.413 (2) | 0.5057 (16) | 0.2883 (13) | 0.038 (4) | |
C2 | 0.522 (3) | 0.6238 (18) | 0.3557 (15) | 0.058 (6) | |
H2A | 0.5483 | 0.6952 | 0.3160 | 0.069* | |
H2B | 0.6455 | 0.6017 | 0.3858 | 0.069* | |
C3 | 0.384 (3) | 0.663 (2) | 0.4410 (17) | 0.072 (6) | |
H3D | 0.4441 | 0.6542 | 0.5094 | 0.086* | |
H3E | 0.3566 | 0.7543 | 0.4431 | 0.086* | |
C4 | 0.198 (3) | 0.571 (2) | 0.4151 (16) | 0.061 (6) | |
H4D | 0.1702 | 0.5242 | 0.4730 | 0.073* | |
H4E | 0.0881 | 0.6197 | 0.4001 | 0.073* | |
C5 | 0.331 (2) | 0.1455 (16) | 0.2985 (13) | 0.036 (4) | |
C6 | 0.389 (3) | 0.0468 (16) | 0.3669 (13) | 0.043 (4) | |
H6D | 0.5144 | 0.0758 | 0.4064 | 0.052* | |
H6E | 0.3927 | −0.0413 | 0.3258 | 0.052* | |
C7 | 0.217 (3) | 0.051 (2) | 0.4399 (15) | 0.065 (6) | |
H7A | 0.1442 | −0.0368 | 0.4304 | 0.078* | |
H7B | 0.2690 | 0.0742 | 0.5130 | 0.078* | |
C8 | 0.084 (3) | 0.1494 (18) | 0.4150 (13) | 0.043 (4) | |
H8A | 0.0811 | 0.2202 | 0.4749 | 0.052* | |
H8B | −0.0479 | 0.1077 | 0.3942 | 0.052* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Pt1 | 0.0335 (5) | 0.0343 (4) | 0.0410 (4) | 0.0056 (3) | 0.0039 (3) | 0.0096 (3) |
Pt2 | 0.0297 (5) | 0.0340 (4) | 0.0342 (4) | 0.0050 (3) | −0.0005 (3) | 0.0112 (3) |
S1 | 0.039 (3) | 0.034 (2) | 0.0329 (18) | 0.0071 (17) | 0.0009 (17) | 0.0064 (15) |
O1 | 0.043 (8) | 0.046 (7) | 0.050 (7) | 0.007 (6) | 0.000 (6) | −0.003 (6) |
O2 | 0.045 (8) | 0.054 (8) | 0.051 (7) | 0.019 (6) | 0.009 (6) | 0.025 (6) |
O3 | 0.035 (9) | 0.146 (16) | 0.077 (11) | −0.001 (9) | 0.006 (8) | −0.010 (10) |
O4 | 0.095 (12) | 0.050 (8) | 0.060 (8) | 0.017 (8) | 0.000 (8) | 0.027 (7) |
O5 | 0.078 (10) | 0.053 (8) | 0.063 (8) | 0.026 (7) | 0.023 (8) | 0.022 (7) |
O6 | 0.140 (15) | 0.039 (8) | 0.061 (9) | 0.008 (9) | 0.002 (10) | 0.001 (7) |
O7 | 0.055 (9) | 0.061 (9) | 0.077 (10) | 0.011 (7) | 0.014 (7) | −0.002 (7) |
N1 | 0.032 (9) | 0.042 (8) | 0.037 (7) | 0.005 (6) | −0.003 (6) | 0.007 (6) |
N2 | 0.030 (9) | 0.043 (8) | 0.044 (8) | 0.009 (6) | 0.001 (6) | 0.003 (6) |
N3 | 0.056 (10) | 0.026 (7) | 0.045 (8) | 0.011 (6) | 0.010 (7) | 0.006 (6) |
N4 | 0.065 (11) | 0.045 (9) | 0.038 (7) | 0.007 (7) | −0.002 (7) | 0.017 (6) |
N5 | 0.009 (7) | 0.061 (9) | 0.049 (8) | 0.010 (6) | 0.000 (6) | 0.024 (7) |
N6 | 0.023 (8) | 0.051 (9) | 0.056 (9) | 0.003 (6) | −0.002 (6) | 0.020 (7) |
C1 | 0.023 (10) | 0.043 (10) | 0.046 (9) | 0.000 (7) | −0.016 (8) | 0.011 (8) |
C2 | 0.068 (15) | 0.041 (10) | 0.053 (11) | −0.027 (9) | −0.017 (10) | 0.001 (9) |
C3 | 0.083 (17) | 0.063 (14) | 0.058 (12) | −0.004 (12) | −0.003 (12) | −0.014 (11) |
C4 | 0.072 (15) | 0.051 (12) | 0.062 (12) | 0.029 (11) | 0.014 (11) | −0.004 (10) |
C5 | 0.026 (10) | 0.035 (9) | 0.048 (9) | 0.005 (7) | −0.009 (8) | 0.012 (7) |
C6 | 0.059 (13) | 0.030 (9) | 0.041 (9) | 0.013 (8) | −0.015 (8) | 0.008 (7) |
C7 | 0.075 (15) | 0.090 (16) | 0.045 (10) | 0.016 (12) | 0.021 (10) | 0.049 (11) |
C8 | 0.043 (11) | 0.055 (11) | 0.038 (9) | 0.013 (9) | 0.012 (8) | 0.017 (8) |
Pt1—N4 | 1.991 (14) | C7—C8 | 1.48 (2) |
Pt1—O2 | 2.011 (11) | N3—H3A | 0.8900 |
Pt1—N3 | 2.012 (12) | N3—H3B | 0.8900 |
Pt1—O1 | 2.020 (12) | N3—H3C | 0.8900 |
Pt2—N2 | 1.978 (13) | N4—H4A | 0.8900 |
Pt2—N1 | 1.990 (14) | N4—H4B | 0.8900 |
Pt2—N5 | 2.030 (11) | N4—H4C | 0.8900 |
Pt2—N6 | 2.031 (14) | N5—H5A | 0.8900 |
Pt1—Pt2 | 2.9749 (11) | N5—H5B | 0.8900 |
Pt1—Pt2i | 4.7921 (16) | N5—H5C | 0.8900 |
S1—O3 | 1.431 (15) | N6—H6A | 0.8900 |
S1—O5 | 1.444 (14) | N6—H6B | 0.8900 |
S1—O4 | 1.453 (12) | N6—H6C | 0.8900 |
S1—O6 | 1.460 (14) | C2—H2A | 0.9700 |
O1—C1 | 1.27 (2) | C2—H2B | 0.9700 |
O2—C5 | 1.28 (2) | C3—H3D | 0.9700 |
N1—C1 | 1.32 (2) | C3—H3E | 0.9700 |
N1—C4 | 1.47 (2) | C4—H4D | 0.9700 |
N2—C5 | 1.30 (2) | C4—H4E | 0.9700 |
N2—C8 | 1.49 (2) | C6—H6D | 0.9700 |
C1—C2 | 1.48 (2) | C6—H6E | 0.9700 |
C2—C3 | 1.52 (3) | C7—H7A | 0.9700 |
C3—C4 | 1.50 (3) | C7—H7B | 0.9700 |
C5—C6 | 1.510 (19) | C8—H8A | 0.9700 |
C6—C7 | 1.55 (3) | C8—H8B | 0.9700 |
O5···O7 | 2.820 (18) | O7···O3i | 2.88 (2) |
N4—Pt1—O2 | 89.7 (5) | H5A—N5—H5C | 109.5 |
N4—Pt1—N3 | 87.3 (5) | H5B—N5—H5C | 109.5 |
O2—Pt1—N3 | 174.4 (5) | Pt2—N6—H6A | 109.5 |
N4—Pt1—O1 | 174.0 (5) | Pt2—N6—H6B | 109.5 |
O2—Pt1—O1 | 91.5 (5) | H6A—N6—H6B | 109.5 |
N3—Pt1—O1 | 91.0 (5) | Pt2—N6—H6C | 109.5 |
N2—Pt2—N1 | 91.0 (5) | H6A—N6—H6C | 109.5 |
N2—Pt2—N5 | 178.8 (5) | H6B—N6—H6C | 109.5 |
N1—Pt2—N5 | 88.7 (5) | O1—C1—N1 | 127.8 (15) |
N2—Pt2—N6 | 89.8 (5) | O1—C1—C2 | 120.2 (16) |
N1—Pt2—N6 | 178.4 (5) | N1—C1—C2 | 112.0 (16) |
N5—Pt2—N6 | 90.4 (5) | C1—C2—C3 | 103.4 (16) |
N4—Pt1—Pt2 | 105.7 (4) | C1—C2—H2A | 111.1 |
O2—Pt1—Pt2 | 81.2 (3) | C3—C2—H2A | 111.1 |
N3—Pt1—Pt2 | 104.1 (4) | C1—C2—H2B | 111.1 |
O1—Pt1—Pt2 | 80.3 (4) | C3—C2—H2B | 111.1 |
N2—Pt2—Pt1 | 79.9 (4) | H2A—C2—H2B | 109.0 |
N1—Pt2—Pt1 | 80.9 (4) | C4—C3—C2 | 107.7 (16) |
N5—Pt2—Pt1 | 98.9 (4) | C4—C3—H3D | 110.2 |
N6—Pt2—Pt1 | 97.9 (4) | C2—C3—H3D | 110.2 |
O3—S1—O5 | 112.5 (9) | C4—C3—H3E | 110.2 |
O3—S1—O4 | 109.3 (10) | C2—C3—H3E | 110.2 |
O5—S1—O4 | 109.0 (8) | H3D—C3—H3E | 108.5 |
O3—S1—O6 | 108.2 (10) | N1—C4—C3 | 104.0 (16) |
O5—S1—O6 | 109.6 (9) | N1—C4—H4D | 111.0 |
O4—S1—O6 | 108.1 (8) | C3—C4—H4D | 111.0 |
C1—O1—Pt1 | 125.3 (11) | N1—C4—H4E | 111.0 |
C5—O2—Pt1 | 123.3 (10) | C3—C4—H4E | 111.0 |
C1—N1—C4 | 112.8 (15) | H4D—C4—H4E | 109.0 |
C1—N1—Pt2 | 125.2 (11) | O2—C5—N2 | 128.5 (15) |
C4—N1—Pt2 | 122.0 (13) | O2—C5—C6 | 117.8 (15) |
C5—N2—C8 | 112.8 (13) | N2—C5—C6 | 113.7 (16) |
C5—N2—Pt2 | 126.4 (12) | C5—C6—C7 | 100.0 (13) |
C8—N2—Pt2 | 120.6 (10) | C5—C6—H6D | 111.8 |
Pt1—N3—H3A | 109.5 | C7—C6—H6D | 111.8 |
Pt1—N3—H3B | 109.5 | C5—C6—H6E | 111.8 |
H3A—N3—H3B | 109.5 | C7—C6—H6E | 111.8 |
Pt1—N3—H3C | 109.5 | H6D—C6—H6E | 109.5 |
H3A—N3—H3C | 109.5 | C8—C7—C6 | 110.1 (13) |
H3B—N3—H3C | 109.5 | C8—C7—H7A | 109.6 |
Pt1—N4—H4A | 109.5 | C6—C7—H7A | 109.6 |
Pt1—N4—H4B | 109.5 | C8—C7—H7B | 109.6 |
H4A—N4—H4B | 109.5 | C6—C7—H7B | 109.6 |
Pt1—N4—H4C | 109.5 | H7A—C7—H7B | 108.1 |
H4A—N4—H4C | 109.5 | C7—C8—N2 | 103.3 (13) |
H4B—N4—H4C | 109.5 | C7—C8—H8A | 111.1 |
Pt2—N5—H5A | 109.5 | N2—C8—H8A | 111.1 |
Pt2—N5—H5B | 109.5 | C7—C8—H8B | 111.1 |
H5A—N5—H5B | 109.5 | N2—C8—H8B | 111.1 |
Pt2—N5—H5C | 109.5 | H8A—C8—H8B | 109.1 |
O2—Pt1—Pt2—N2 | −3.5 (5) | C1—N1—C4—C3 | −3 (2) |
O1—Pt1—Pt2—N1 | −3.9 (5) | C2—C3—C4—N1 | 4 (2) |
N3—Pt1—Pt2—N5 | −5.2 (6) | C8—N2—C5—O2 | −180.0 (16) |
N4—Pt1—Pt2—N6 | −4.7 (5) | C8—N2—C5—C6 | −3 (2) |
C4—N1—C1—O1 | −178.3 (16) | O2—C5—C6—C7 | −179.1 (16) |
C4—N1—C1—C2 | 0 (2) | N2—C5—C6—C7 | 3.2 (19) |
O1—C1—C2—C3 | −179.2 (16) | C5—C6—C7—C8 | −3 (2) |
N1—C1—C2—C3 | 2 (2) | C6—C7—C8—N2 | 1 (2) |
C1—C2—C3—C4 | −3 (2) | C5—N2—C8—C7 | 1 (2) |
Symmetry code: (i) x+1, y, z. |
D—H···A | D—H | H···A | D···A | D—H···A |
N4—H4B···O4 | 0.89 | 2.14 | 3.00 (2) | 164 |
N5—H5C···O6 | 0.89 | 2.00 | 2.87 (2) | 167 |
N6—H6A···O4 | 0.89 | 2.14 | 3.02 (2) | 167 |
N3—H3B···O6ii | 0.89 | 1.97 | 2.798 (18) | 154 |
N3—H3A···O3i | 0.89 | 2.32 | 3.08 (2) | 143 |
N4—H4C···O4iii | 0.89 | 2.03 | 2.829 (19) | 149 |
N4—H4A···O3i | 0.89 | 2.44 | 3.18 (2) | 141 |
N5—H5A···O5ii | 0.89 | 2.29 | 3.12 (2) | 155 |
N5—H5A···O6ii | 0.89 | 2.50 | 3.23 (2) | 140 |
N5—H5B···O1iv | 0.89 | 2.19 | 2.954 (17) | 143 |
N6—H6C···O7iii | 0.89 | 2.14 | 2.99 (2) | 161 |
N6—H6B···O2iv | 0.89 | 2.05 | 2.862 (18) | 151 |
Symmetry codes: (i) x+1, y, z; (ii) −x, −y+1, −z; (iii) −x, −y, −z; (iv) x−1, y, z. |
Subscribe to Acta Crystallographica Section E: Crystallographic Communications
The full text of this article is available to subscribers to the journal.
- Information on subscribing
- Sample issue
- If you have already subscribed, you may need to register