Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536803028447/lh6153sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536803028447/lh6153Isup2.hkl |
CCDC reference: 231837
Data collection: CAD-4-PC Software (Enraf-Nonius, 1992); cell refinement: SET4 and CELDIM (Enraf-Nonius, 1992); data reduction: DATRD2 in NRCVAX94 (Gabe et al., 1989); program(s) used to solve structure: SOLVER in NRCVAX94; program(s) used to refine structure: SHELXL97 (Sheldrick, 1993) and WinGX (Farrugia, 1997); molecular graphics: PLATON (Spek, 2003); software used to prepare material for publication: SHELXL97.
[As(C6H5)(C18H15OSi)2] | F(000) = 1456 |
Mr = 702.80 | ? #Insert any comments here. |
Monoclinic, P21/n | Dx = 1.268 Mg m−3 |
Hall symbol: -P 2yn | Mo Kα radiation, λ = 0.71073 Å |
a = 9.8563 (14) Å | Cell parameters from 25 reflections |
b = 11.3662 (15) Å | θ = 8.1–17.6° |
c = 32.868 (3) Å | µ = 1.02 mm−1 |
β = 91.124 (13)° | T = 294 K |
V = 3681.4 (8) Å3 | Block, colourless |
Z = 4 | 0.35 × 0.35 × 0.28 mm |
Enraf-Nonius CAD-4 diffractometer | 2602 reflections with I > 2σ(I) |
Radiation source: X-ray tube | Rint = 0.016 |
Graphite monochromator | θmax = 27°, θmin = 2° |
θ/2θ scans | h = −12→12 |
Absorption correction: ψ scan (North et al., 1968) | k = 0→14 |
Tmin = 0.640, Tmax = 0.750 | l = 0→41 |
8126 measured reflections | 3 standard reflections every 120 min |
7995 independent reflections | intensity decay: 2.3% |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.060 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.185 | H-atom parameters constrained |
S = 0.88 | w = 1/[σ2(Fo2) + (0.0874P)2] where P = (Fo2 + 2Fc2)/3 |
7995 reflections | (Δ/σ)max = 0.001 |
545 parameters | Δρmax = 0.61 e Å−3 |
772 restraints | Δρmin = −0.67 e Å−3 |
Experimental. ? #Insert any special details here. |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
x | y | z | Uiso*/Ueq | Occ. (<1) | |
As1 | 0.63324 (6) | 0.54077 (5) | 0.164701 (19) | 0.0538 (2) | |
Si1 | 0.41317 (16) | 0.34333 (14) | 0.15481 (5) | 0.0537 (4) | |
Si2 | 0.60224 (18) | 0.74158 (15) | 0.09912 (5) | 0.0602 (5) | |
O1 | 0.4874 (4) | 0.4580 (3) | 0.17543 (11) | 0.0621 (10) | |
O2 | 0.5524 (4) | 0.6300 (3) | 0.12662 (11) | 0.0644 (11) | |
C11 | 0.6164 (5) | 0.6446 (5) | 0.21088 (16) | 0.0445 (13) | |
C12 | 0.4918 (6) | 0.6732 (5) | 0.22784 (18) | 0.0571 (16) | |
H12 | 0.4121 | 0.6406 | 0.2172 | 0.069* | |
C13 | 0.4869 (6) | 0.7492 (6) | 0.26006 (19) | 0.0676 (18) | |
H13 | 0.4032 | 0.7686 | 0.2708 | 0.081* | |
C14 | 0.6031 (7) | 0.7976 (6) | 0.27700 (19) | 0.0706 (19) | |
H14 | 0.5984 | 0.8484 | 0.2991 | 0.085* | |
C15 | 0.7255 (7) | 0.7693 (6) | 0.2606 (2) | 0.0710 (19) | |
H15 | 0.8045 | 0.8027 | 0.2714 | 0.085* | |
C16 | 0.7333 (6) | 0.6921 (6) | 0.22842 (19) | 0.0611 (17) | |
H16 | 0.8177 | 0.6717 | 0.2184 | 0.073* | |
C21 | 0.3957 (5) | 0.2305 (5) | 0.19605 (17) | 0.0535 (15) | |
C22 | 0.4033 (6) | 0.2623 (6) | 0.2361 (2) | 0.0623 (17) | |
H22 | 0.4212 | 0.3402 | 0.2431 | 0.075* | |
C23 | 0.3848 (6) | 0.1801 (8) | 0.2666 (2) | 0.082 (2) | |
H23 | 0.3898 | 0.2036 | 0.2937 | 0.099* | |
C24 | 0.3593 (7) | 0.0658 (8) | 0.2574 (3) | 0.090 (2) | |
H24 | 0.3472 | 0.0106 | 0.2779 | 0.108* | |
C25 | 0.3520 (8) | 0.0337 (7) | 0.2178 (3) | 0.101 (3) | |
H25 | 0.3341 | −0.0443 | 0.2110 | 0.121* | |
C26 | 0.3708 (7) | 0.1154 (7) | 0.1874 (2) | 0.081 (2) | |
H26 | 0.3663 | 0.0912 | 0.1604 | 0.097* | |
C31A | 0.2401 (8) | 0.3984 (13) | 0.1386 (5) | 0.083 (2) | 0.50 |
C32A | 0.2293 (7) | 0.5189 (12) | 0.1321 (5) | 0.091 (3) | 0.50 |
H32A | 0.3042 | 0.5673 | 0.1366 | 0.109* | 0.50 |
C33A | 0.1064 (10) | 0.5672 (9) | 0.1190 (4) | 0.098 (3) | 0.50 |
H33A | 0.0992 | 0.6479 | 0.1147 | 0.117* | 0.50 |
C34A | −0.0056 (7) | 0.4950 (9) | 0.1124 (4) | 0.093 (3) | 0.50 |
H34A | −0.0878 | 0.5273 | 0.1036 | 0.111* | 0.50 |
C35A | 0.0052 (8) | 0.3744 (9) | 0.1188 (4) | 0.095 (3) | 0.50 |
H35A | −0.0697 | 0.3261 | 0.1143 | 0.115* | 0.50 |
C36A | 0.1281 (11) | 0.3261 (9) | 0.1319 (4) | 0.090 (3) | 0.50 |
H36A | 0.1353 | 0.2455 | 0.1362 | 0.108* | 0.50 |
C31B | 0.2379 (7) | 0.3806 (13) | 0.1353 (5) | 0.083 (2) | 0.50 |
C32B | 0.1850 (8) | 0.4939 (11) | 0.1339 (5) | 0.089 (2) | 0.50 |
H32B | 0.2395 | 0.5577 | 0.1411 | 0.107* | 0.50 |
C33B | 0.0506 (9) | 0.5119 (9) | 0.1219 (4) | 0.094 (3) | 0.50 |
H33B | 0.0152 | 0.5877 | 0.1210 | 0.113* | 0.50 |
C34B | −0.0308 (6) | 0.4165 (10) | 0.1112 (4) | 0.093 (3) | 0.50 |
H34B | −0.1207 | 0.4286 | 0.1031 | 0.111* | 0.50 |
C35B | 0.0221 (9) | 0.3032 (9) | 0.1125 (4) | 0.097 (3) | 0.50 |
H35B | −0.0324 | 0.2394 | 0.1053 | 0.116* | 0.50 |
C36B | 0.1565 (10) | 0.2852 (10) | 0.1245 (4) | 0.089 (3) | 0.50 |
H36B | 0.1919 | 0.2094 | 0.1254 | 0.107* | 0.50 |
C41 | 0.5127 (5) | 0.2824 (5) | 0.11169 (17) | 0.0594 (17) | |
C42 | 0.6276 (7) | 0.2156 (5) | 0.1190 (2) | 0.0706 (19) | |
H42 | 0.6549 | 0.2006 | 0.1457 | 0.085* | |
C43 | 0.7034 (8) | 0.1701 (7) | 0.0876 (3) | 0.086 (2) | |
H43 | 0.7805 | 0.1250 | 0.0928 | 0.104* | |
C44 | 0.6618 (10) | 0.1935 (9) | 0.0492 (3) | 0.106 (3) | |
H44 | 0.7114 | 0.1623 | 0.0280 | 0.128* | |
C45 | 0.5534 (10) | 0.2588 (9) | 0.0400 (2) | 0.110 (3) | |
H45 | 0.5305 | 0.2747 | 0.0130 | 0.133* | |
C46 | 0.4749 (7) | 0.3032 (7) | 0.0710 (2) | 0.085 (2) | |
H46 | 0.3972 | 0.3467 | 0.0648 | 0.103* | |
C51A | 0.7251 (16) | 0.839 (2) | 0.1278 (7) | 0.066 (2) | 0.50 |
C52A | 0.6774 (10) | 0.9126 (19) | 0.1582 (6) | 0.073 (3) | 0.50 |
H52A | 0.5847 | 0.9176 | 0.1627 | 0.087* | 0.50 |
C53A | 0.7681 (10) | 0.9784 (14) | 0.1817 (4) | 0.080 (3) | 0.50 |
H53A | 0.7362 | 1.0275 | 0.2021 | 0.096* | 0.50 |
C54A | 0.9066 (9) | 0.9708 (10) | 0.1749 (3) | 0.081 (3) | 0.50 |
H54A | 0.9673 | 1.0149 | 0.1907 | 0.097* | 0.50 |
C55A | 0.9543 (11) | 0.8975 (12) | 0.1445 (4) | 0.080 (3) | 0.50 |
H55A | 1.0470 | 0.8924 | 0.1400 | 0.097* | 0.50 |
C56A | 0.8636 (17) | 0.8317 (17) | 0.1210 (6) | 0.071 (3) | 0.50 |
H56A | 0.8955 | 0.7826 | 0.1006 | 0.086* | 0.50 |
C51B | 0.7046 (16) | 0.845 (2) | 0.1320 (7) | 0.066 (3) | 0.50 |
C52B | 0.6370 (10) | 0.909 (2) | 0.1614 (7) | 0.069 (2) | 0.50 |
H52B | 0.5430 | 0.9048 | 0.1629 | 0.083* | 0.50 |
C53B | 0.7100 (9) | 0.9800 (14) | 0.1885 (4) | 0.074 (3) | 0.50 |
H53B | 0.6648 | 1.0229 | 0.2081 | 0.088* | 0.50 |
C54B | 0.8504 (8) | 0.9865 (10) | 0.1862 (3) | 0.072 (3) | 0.50 |
H54B | 0.8993 | 1.0338 | 0.2043 | 0.086* | 0.50 |
C55B | 0.9180 (10) | 0.9222 (11) | 0.1569 (4) | 0.076 (3) | 0.50 |
H55B | 1.0120 | 0.9266 | 0.1554 | 0.091* | 0.50 |
C56B | 0.8450 (16) | 0.8515 (16) | 0.1298 (5) | 0.069 (3) | 0.50 |
H56B | 0.8902 | 0.8085 | 0.1101 | 0.083* | 0.50 |
C61A | 0.4372 (9) | 0.8134 (13) | 0.0816 (4) | 0.079 (2) | 0.50 |
C62A | 0.3357 (13) | 0.7361 (9) | 0.0688 (4) | 0.085 (2) | 0.50 |
H62A | 0.3515 | 0.6554 | 0.0691 | 0.102* | 0.50 |
C63A | 0.2106 (11) | 0.7794 (9) | 0.0556 (4) | 0.091 (3) | 0.50 |
H63A | 0.1426 | 0.7277 | 0.0471 | 0.109* | 0.50 |
C64A | 0.1869 (7) | 0.8999 (10) | 0.0551 (4) | 0.095 (3) | 0.50 |
H64A | 0.1032 | 0.9289 | 0.0463 | 0.114* | 0.50 |
C65A | 0.2884 (10) | 0.9772 (8) | 0.0679 (4) | 0.090 (3) | 0.50 |
H65A | 0.2726 | 1.0579 | 0.0676 | 0.107* | 0.50 |
C66A | 0.4136 (8) | 0.9339 (12) | 0.0811 (4) | 0.086 (2) | 0.50 |
H66A | 0.4815 | 0.9856 | 0.0897 | 0.103* | 0.50 |
C61B | 0.4407 (9) | 0.8161 (13) | 0.0806 (4) | 0.078 (2) | 0.50 |
C62B | 0.3158 (12) | 0.7594 (9) | 0.0783 (4) | 0.087 (2) | 0.50 |
H62B | 0.3087 | 0.6810 | 0.0860 | 0.104* | 0.50 |
C63B | 0.2015 (9) | 0.8200 (10) | 0.0644 (4) | 0.094 (3) | 0.50 |
H63B | 0.1179 | 0.7821 | 0.0628 | 0.113* | 0.50 |
C64B | 0.2121 (8) | 0.9372 (10) | 0.0528 (4) | 0.098 (3) | 0.50 |
H64B | 0.1356 | 0.9777 | 0.0435 | 0.118* | 0.50 |
C65B | 0.3370 (10) | 0.9939 (9) | 0.0551 (4) | 0.093 (3) | 0.50 |
H65B | 0.3440 | 1.0723 | 0.0474 | 0.111* | 0.50 |
C66B | 0.4512 (8) | 0.9333 (13) | 0.0691 (4) | 0.087 (2) | 0.50 |
H66B | 0.5348 | 0.9712 | 0.0706 | 0.104* | 0.50 |
C71A | 0.6995 (16) | 0.6888 (16) | 0.0537 (4) | 0.067 (2) | 0.50 |
C72A | 0.7153 (13) | 0.5702 (15) | 0.0445 (4) | 0.071 (2) | 0.50 |
H72A | 0.6740 | 0.5134 | 0.0605 | 0.085* | 0.50 |
C73A | 0.7930 (12) | 0.5365 (10) | 0.0117 (4) | 0.077 (3) | 0.50 |
H73A | 0.8036 | 0.4572 | 0.0056 | 0.093* | 0.50 |
C74A | 0.8548 (13) | 0.6215 (10) | −0.0121 (3) | 0.080 (3) | 0.50 |
H74A | 0.9067 | 0.5990 | −0.0341 | 0.096* | 0.50 |
C75A | 0.8389 (15) | 0.7400 (9) | −0.0030 (4) | 0.078 (3) | 0.50 |
H75A | 0.8803 | 0.7969 | −0.0189 | 0.094* | 0.50 |
C76A | 0.7613 (17) | 0.7737 (12) | 0.0299 (4) | 0.072 (2) | 0.50 |
H76A | 0.7507 | 0.8530 | 0.0360 | 0.087* | 0.50 |
C71B | 0.6975 (16) | 0.6792 (16) | 0.0545 (4) | 0.066 (2) | 0.50 |
C72B | 0.6775 (13) | 0.5604 (16) | 0.0463 (4) | 0.071 (2) | 0.50 |
H72B | 0.6206 | 0.5160 | 0.0625 | 0.086* | 0.50 |
C73B | 0.7427 (12) | 0.5080 (11) | 0.0138 (4) | 0.079 (3) | 0.50 |
H73B | 0.7293 | 0.4285 | 0.0083 | 0.094* | 0.50 |
C74B | 0.8278 (12) | 0.5743 (9) | −0.0104 (3) | 0.077 (3) | 0.50 |
H74B | 0.8713 | 0.5393 | −0.0321 | 0.092* | 0.50 |
C75B | 0.8477 (14) | 0.6931 (9) | −0.0022 (4) | 0.076 (3) | 0.50 |
H75B | 0.9047 | 0.7375 | −0.0184 | 0.091* | 0.50 |
C76B | 0.7826 (17) | 0.7455 (11) | 0.0303 (4) | 0.072 (2) | 0.50 |
H76B | 0.7959 | 0.8250 | 0.0358 | 0.086* | 0.50 |
U11 | U22 | U33 | U12 | U13 | U23 | |
As1 | 0.0495 (3) | 0.0583 (4) | 0.0538 (4) | 0.0075 (4) | 0.0056 (3) | −0.0003 (4) |
Si1 | 0.0479 (9) | 0.0586 (11) | 0.0547 (11) | −0.0011 (8) | 0.0019 (8) | −0.0025 (9) |
Si2 | 0.0831 (13) | 0.0535 (11) | 0.0441 (10) | 0.0087 (10) | 0.0018 (9) | 0.0007 (9) |
O1 | 0.073 (3) | 0.059 (2) | 0.056 (2) | −0.010 (2) | 0.011 (2) | −0.012 (2) |
O2 | 0.085 (3) | 0.066 (3) | 0.042 (2) | 0.003 (2) | −0.003 (2) | 0.002 (2) |
C11 | 0.045 (3) | 0.048 (3) | 0.040 (3) | −0.002 (3) | 0.001 (3) | −0.003 (3) |
C12 | 0.050 (4) | 0.069 (4) | 0.052 (4) | −0.003 (3) | 0.003 (3) | −0.004 (3) |
C13 | 0.058 (4) | 0.077 (5) | 0.068 (5) | 0.004 (4) | 0.006 (3) | −0.014 (4) |
C14 | 0.090 (5) | 0.069 (5) | 0.053 (4) | −0.001 (4) | −0.009 (4) | −0.013 (3) |
C15 | 0.067 (5) | 0.083 (5) | 0.063 (5) | −0.010 (4) | −0.019 (4) | −0.005 (4) |
C16 | 0.050 (4) | 0.081 (5) | 0.052 (4) | −0.002 (3) | 0.005 (3) | 0.014 (4) |
C21 | 0.044 (3) | 0.055 (4) | 0.061 (4) | −0.002 (3) | 0.000 (3) | 0.000 (3) |
C22 | 0.051 (4) | 0.068 (4) | 0.068 (5) | −0.002 (3) | 0.001 (3) | 0.004 (4) |
C23 | 0.061 (4) | 0.120 (7) | 0.066 (5) | 0.005 (5) | 0.004 (4) | 0.010 (5) |
C24 | 0.085 (5) | 0.093 (7) | 0.092 (7) | 0.023 (5) | 0.025 (5) | 0.026 (5) |
C25 | 0.115 (7) | 0.056 (5) | 0.134 (8) | −0.012 (5) | 0.036 (6) | 0.011 (6) |
C26 | 0.093 (5) | 0.076 (5) | 0.074 (5) | −0.006 (4) | 0.015 (4) | 0.013 (4) |
C31A | 0.051 (4) | 0.125 (6) | 0.074 (5) | 0.015 (4) | −0.007 (4) | 0.000 (5) |
C32A | 0.052 (4) | 0.129 (6) | 0.091 (5) | 0.021 (5) | −0.007 (5) | 0.006 (5) |
C33A | 0.052 (5) | 0.137 (6) | 0.103 (5) | 0.021 (4) | −0.008 (5) | 0.001 (6) |
C34A | 0.048 (4) | 0.138 (7) | 0.092 (5) | 0.023 (5) | −0.008 (4) | −0.006 (6) |
C35A | 0.050 (4) | 0.139 (7) | 0.097 (5) | 0.021 (5) | −0.006 (4) | −0.004 (6) |
C36A | 0.050 (4) | 0.134 (6) | 0.087 (5) | 0.017 (4) | −0.008 (4) | −0.001 (5) |
C31B | 0.052 (4) | 0.122 (6) | 0.076 (5) | 0.019 (4) | −0.007 (4) | 0.002 (5) |
C32B | 0.052 (4) | 0.127 (6) | 0.087 (5) | 0.022 (4) | −0.003 (5) | 0.007 (5) |
C33B | 0.049 (5) | 0.137 (6) | 0.096 (5) | 0.025 (4) | 0.000 (5) | 0.004 (5) |
C34B | 0.047 (4) | 0.141 (7) | 0.090 (5) | 0.027 (4) | −0.006 (4) | 0.002 (6) |
C35B | 0.050 (4) | 0.141 (6) | 0.098 (6) | 0.022 (5) | −0.009 (4) | −0.008 (6) |
C36B | 0.046 (4) | 0.130 (6) | 0.092 (6) | 0.020 (4) | −0.008 (5) | −0.004 (6) |
C41 | 0.050 (4) | 0.061 (4) | 0.067 (5) | −0.013 (3) | −0.006 (3) | −0.013 (3) |
C42 | 0.064 (4) | 0.065 (4) | 0.083 (5) | 0.003 (4) | −0.003 (4) | −0.010 (4) |
C43 | 0.076 (5) | 0.086 (5) | 0.099 (7) | 0.000 (4) | 0.024 (5) | −0.020 (5) |
C44 | 0.107 (7) | 0.129 (8) | 0.085 (7) | −0.012 (6) | 0.037 (6) | −0.038 (6) |
C45 | 0.111 (7) | 0.164 (9) | 0.056 (5) | 0.005 (7) | 0.001 (5) | −0.041 (6) |
C46 | 0.077 (5) | 0.105 (6) | 0.074 (5) | 0.009 (4) | −0.015 (4) | −0.002 (5) |
C51A | 0.099 (5) | 0.058 (4) | 0.042 (5) | 0.011 (5) | 0.009 (5) | −0.004 (3) |
C52A | 0.101 (6) | 0.066 (4) | 0.051 (5) | 0.012 (5) | 0.008 (5) | −0.008 (4) |
C53A | 0.111 (6) | 0.070 (4) | 0.059 (5) | 0.009 (6) | 0.010 (6) | −0.018 (4) |
C54A | 0.110 (6) | 0.073 (5) | 0.060 (6) | 0.005 (6) | 0.001 (5) | −0.030 (4) |
C55A | 0.107 (6) | 0.077 (6) | 0.057 (6) | 0.008 (5) | 0.001 (5) | −0.028 (4) |
C56A | 0.100 (5) | 0.063 (5) | 0.051 (6) | 0.009 (5) | 0.002 (5) | −0.018 (4) |
C51B | 0.096 (5) | 0.059 (4) | 0.042 (5) | 0.009 (5) | 0.007 (5) | −0.003 (3) |
C52B | 0.097 (6) | 0.065 (4) | 0.047 (5) | 0.006 (5) | 0.008 (5) | −0.009 (4) |
C53B | 0.096 (6) | 0.067 (5) | 0.058 (5) | 0.006 (6) | 0.009 (6) | −0.014 (4) |
C54B | 0.093 (6) | 0.068 (5) | 0.054 (5) | 0.008 (5) | 0.007 (5) | −0.026 (4) |
C55B | 0.102 (5) | 0.072 (5) | 0.053 (6) | 0.009 (5) | 0.007 (5) | −0.031 (4) |
C56B | 0.099 (5) | 0.061 (5) | 0.047 (6) | 0.008 (5) | 0.006 (5) | −0.021 (4) |
C61A | 0.084 (4) | 0.075 (4) | 0.079 (5) | 0.011 (4) | 0.001 (4) | 0.003 (4) |
C62A | 0.085 (4) | 0.081 (4) | 0.089 (5) | 0.011 (4) | 0.005 (4) | −0.002 (5) |
C63A | 0.085 (4) | 0.087 (5) | 0.101 (6) | 0.008 (4) | 0.003 (5) | −0.006 (5) |
C64A | 0.085 (5) | 0.087 (6) | 0.112 (6) | 0.009 (4) | 0.002 (5) | 0.015 (5) |
C65A | 0.087 (5) | 0.078 (5) | 0.103 (6) | 0.011 (4) | −0.005 (5) | 0.010 (5) |
C66A | 0.089 (5) | 0.076 (4) | 0.092 (6) | 0.010 (4) | −0.004 (4) | 0.005 (5) |
C61B | 0.084 (4) | 0.074 (4) | 0.078 (5) | 0.012 (4) | 0.001 (4) | 0.001 (4) |
C62B | 0.080 (4) | 0.082 (5) | 0.098 (5) | 0.015 (4) | 0.007 (5) | 0.008 (5) |
C63B | 0.084 (4) | 0.087 (5) | 0.112 (6) | 0.013 (4) | 0.001 (4) | 0.008 (5) |
C64B | 0.094 (5) | 0.087 (5) | 0.113 (6) | 0.017 (5) | −0.002 (5) | 0.013 (5) |
C65B | 0.099 (5) | 0.077 (5) | 0.102 (6) | 0.012 (4) | −0.011 (5) | 0.008 (5) |
C66B | 0.093 (4) | 0.075 (4) | 0.091 (6) | 0.009 (4) | −0.006 (5) | 0.003 (4) |
C71A | 0.071 (4) | 0.078 (5) | 0.051 (4) | 0.015 (4) | 0.001 (3) | 0.000 (4) |
C72A | 0.077 (5) | 0.081 (5) | 0.054 (4) | 0.014 (5) | 0.006 (4) | −0.006 (4) |
C73A | 0.083 (6) | 0.088 (5) | 0.061 (4) | 0.011 (5) | 0.012 (4) | −0.007 (4) |
C74A | 0.091 (5) | 0.093 (7) | 0.056 (4) | 0.020 (5) | 0.017 (4) | −0.002 (5) |
C75A | 0.089 (5) | 0.089 (6) | 0.056 (4) | 0.024 (5) | 0.011 (4) | 0.009 (5) |
C76A | 0.082 (5) | 0.083 (5) | 0.053 (4) | 0.022 (5) | 0.010 (4) | 0.008 (4) |
C71B | 0.070 (4) | 0.079 (5) | 0.049 (4) | 0.016 (4) | 0.002 (3) | 0.003 (4) |
C72B | 0.077 (5) | 0.083 (5) | 0.053 (4) | 0.013 (5) | 0.006 (4) | −0.005 (4) |
C73B | 0.085 (6) | 0.090 (6) | 0.062 (5) | 0.007 (5) | 0.014 (5) | −0.008 (4) |
C74B | 0.088 (5) | 0.087 (6) | 0.056 (5) | 0.014 (5) | 0.016 (4) | −0.003 (4) |
C75B | 0.090 (5) | 0.082 (6) | 0.056 (4) | 0.019 (5) | 0.015 (3) | 0.002 (5) |
C76B | 0.081 (5) | 0.081 (6) | 0.054 (4) | 0.020 (4) | 0.012 (4) | 0.004 (4) |
As1—O1 | 1.759 (4) | C45—H45 | 0.93 |
As1—O2 | 1.786 (4) | C46—H46 | 0.93 |
As1—C11 | 1.932 (5) | C51A—C52A | 1.39 |
Si1—O1 | 1.635 (4) | C51A—C56A | 1.39 |
Si1—C41 | 1.872 (4) | C52A—C53A | 1.39 |
Si1—C31B | 1.880 (4) | C52A—H52A | 0.93 |
Si1—C31A | 1.885 (4) | C53A—C54A | 1.39 |
Si1—C21 | 1.877 (4) | C53A—H53A | 0.93 |
Si2—O2 | 1.638 (4) | C54A—C55A | 1.39 |
Si2—C51A | 1.882 (4) | C54A—H54A | 0.93 |
Si2—C51B | 1.877 (4) | C55A—C56A | 1.39 |
Si2—C61B | 1.893 (4) | C55A—H55A | 0.93 |
Si2—C61A | 1.899 (4) | C56A—H56A | 0.93 |
Si2—C71A | 1.889 (4) | C51B—C52B | 1.39 |
Si2—C71B | 1.894 (4) | C51B—C56B | 1.39 |
C11—C16 | 1.388 (7) | C52B—C53B | 1.39 |
C11—C12 | 1.397 (7) | C52B—H52B | 0.93 |
C12—C13 | 1.368 (8) | C53B—C54B | 1.39 |
C12—H12 | 0.93 | C53B—H53B | 0.93 |
C13—C14 | 1.378 (8) | C54B—C55B | 1.39 |
C13—H13 | 0.93 | C54B—H54B | 0.93 |
C14—C15 | 1.369 (8) | C55B—C56B | 1.39 |
C14—H14 | 0.93 | C55B—H55B | 0.93 |
C15—C16 | 1.379 (8) | C56B—H56B | 0.93 |
C15—H15 | 0.93 | C61A—C62A | 1.39 |
C16—H16 | 0.93 | C61A—C66A | 1.39 |
C21—C26 | 1.360 (8) | C62A—C63A | 1.39 |
C21—C22 | 1.367 (8) | C62A—H62A | 0.93 |
C22—C23 | 1.383 (9) | C63A—C64A | 1.39 |
C22—H22 | 0.93 | C63A—H63A | 0.93 |
C23—C24 | 1.356 (10) | C64A—C65A | 1.39 |
C23—H23 | 0.93 | C64A—H64A | 0.93 |
C24—C25 | 1.352 (11) | C65A—C66A | 1.39 |
C24—H24 | 0.93 | C65A—H65A | 0.93 |
C25—C26 | 1.380 (10) | C66A—H66A | 0.93 |
C25—H25 | 0.93 | C61B—C62B | 1.39 |
C26—H26 | 0.93 | C61B—C66B | 1.39 |
C31A—C32A | 1.39 | C62B—C63B | 1.39 |
C31A—C36A | 1.39 | C62B—H62B | 0.93 |
C32A—C33A | 1.39 | C63B—C64B | 1.39 |
C32A—H32A | 0.93 | C63B—H63B | 0.93 |
C33A—C34A | 1.39 | C64B—C65B | 1.39 |
C33A—H33A | 0.93 | C64B—H64B | 0.93 |
C34A—C35A | 1.39 | C65B—C66B | 1.39 |
C34A—H34A | 0.93 | C65B—H65B | 0.93 |
C35A—C36A | 1.39 | C66B—H66B | 0.93 |
C35A—H35A | 0.93 | C71A—C72A | 1.39 |
C36A—H36A | 0.93 | C71A—C76A | 1.39 |
C31B—C32B | 1.39 | C72A—C73A | 1.39 |
C31B—C36B | 1.39 | C72A—H72A | 0.93 |
C32B—C33B | 1.39 | C73A—C74A | 1.39 |
C32B—H32B | 0.93 | C73A—H73A | 0.93 |
C33B—C34B | 1.39 | C74A—C75A | 1.39 |
C33B—H33B | 0.93 | C74A—H74A | 0.93 |
C34B—C35B | 1.39 | C75A—C76A | 1.39 |
C34B—H34B | 0.93 | C75A—H75A | 0.93 |
C35B—C36B | 1.39 | C76A—H76A | 0.93 |
C35B—H35B | 0.93 | C71B—C72B | 1.39 |
C36B—H36B | 0.93 | C71B—C76B | 1.39 |
C41—C42 | 1.381 (8) | C72B—C73B | 1.39 |
C41—C46 | 1.401 (8) | C72B—H72B | 0.93 |
C42—C43 | 1.387 (9) | C73B—C74B | 1.39 |
C42—H42 | 0.93 | C73B—H73B | 0.93 |
C43—C44 | 1.344 (10) | C74B—C75B | 1.39 |
C43—H43 | 0.93 | C74B—H74B | 0.93 |
C44—C45 | 1.331 (11) | C75B—C76B | 1.39 |
C44—H44 | 0.93 | C75B—H75B | 0.93 |
C45—C46 | 1.386 (10) | C76B—H76B | 0.93 |
O1—As1—O2 | 95.12 (19) | C43—C44—H44 | 118.3 |
O1—As1—C11 | 94.9 (2) | C44—C45—C46 | 119.6 (8) |
O2—As1—C11 | 99.2 (2) | C44—C45—H45 | 120.2 |
O1—Si1—C41 | 111.8 (2) | C46—C45—H45 | 120.2 |
O1—Si1—C31B | 111.3 (5) | C45—C46—C41 | 119.8 (7) |
C41—Si1—C31B | 108.5 (5) | C45—C46—H46 | 120.1 |
O1—Si1—C31A | 104.3 (5) | C41—C46—H46 | 120.1 |
C41—Si1—C31A | 113.2 (6) | C52A—C51A—C56A | 120 |
O1—Si1—C21 | 107.0 (2) | C52A—C51A—Si2 | 119.3 (10) |
C41—Si1—C21 | 110.5 (3) | C56A—C51A—Si2 | 120.5 (10) |
C31B—Si1—C21 | 107.7 (5) | C51A—C52A—C53A | 120 |
C31A—Si1—C21 | 109.7 (5) | C51A—C52A—H52A | 120 |
O2—Si2—C51A | 112.1 (9) | C53A—C52A—H52A | 120 |
O2—Si2—C51B | 109.3 (9) | C54A—C53A—C52A | 120 |
O2—Si2—C61B | 105.3 (5) | C54A—C53A—H53A | 120 |
C51A—Si2—C61B | 115.2 (9) | C52A—C53A—H53A | 120 |
C51B—Si2—C61B | 110.1 (9) | C53A—C54A—C55A | 120 |
O2—Si2—C61A | 103.6 (5) | C53A—C54A—H54A | 120 |
C51A—Si2—C61A | 115.9 (9) | C55A—C54A—H54A | 120 |
C51B—Si2—C61A | 110.7 (9) | C56A—C55A—C54A | 120 |
O2—Si2—C71A | 110.7 (6) | C56A—C55A—H55A | 120 |
C51A—Si2—C71A | 104.6 (8) | C54A—C55A—H55A | 120 |
C51B—Si2—C71A | 112.3 (8) | C55A—C56A—C51A | 120 |
C61B—Si2—C71A | 109.0 (7) | C55A—C56A—H56A | 120 |
C61A—Si2—C71A | 110.0 (7) | C51A—C56A—H56A | 120 |
O2—Si2—C71B | 107.2 (6) | C52B—C51B—C56B | 120 |
C51A—Si2—C71B | 106.5 (8) | C52B—C51B—Si2 | 118.0 (10) |
C51B—Si2—C71B | 114.3 (8) | C56B—C51B—Si2 | 121.8 (10) |
C61B—Si2—C71B | 110.2 (7) | C51B—C52B—C53B | 120 |
C61A—Si2—C71B | 111.1 (7) | C51B—C52B—H52B | 120 |
Si1—O1—As1 | 134.7 (2) | C53B—C52B—H52B | 120 |
Si2—O2—As1 | 133.8 (3) | C54B—C53B—C52B | 120 |
C16—C11—C12 | 118.2 (5) | C54B—C53B—H53B | 120 |
C16—C11—As1 | 118.7 (4) | C52B—C53B—H53B | 120 |
C12—C11—As1 | 123.0 (4) | C53B—C54B—C55B | 120 |
C13—C12—C11 | 120.0 (5) | C53B—C54B—H54B | 120 |
C13—C12—H12 | 120 | C55B—C54B—H54B | 120 |
C11—C12—H12 | 120 | C54B—C55B—C56B | 120 |
C12—C13—C14 | 121.5 (6) | C54B—C55B—H55B | 120 |
C12—C13—H13 | 119.2 | C56B—C55B—H55B | 120 |
C14—C13—H13 | 119.2 | C55B—C56B—C51B | 120 |
C15—C14—C13 | 118.7 (6) | C55B—C56B—H56B | 120 |
C15—C14—H14 | 120.7 | C51B—C56B—H56B | 120 |
C13—C14—H14 | 120.7 | C62A—C61A—C66A | 120 |
C14—C15—C16 | 121.0 (6) | C62A—C61A—Si2 | 115.3 (8) |
C14—C15—H15 | 119.5 | C66A—C61A—Si2 | 124.7 (8) |
C16—C15—H15 | 119.5 | C61A—C62A—C63A | 120 |
C15—C16—C11 | 120.5 (6) | C61A—C62A—H62A | 120 |
C15—C16—H16 | 119.7 | C63A—C62A—H62A | 120 |
C11—C16—H16 | 119.7 | C62A—C63A—C64A | 120 |
C26—C21—C22 | 117.5 (5) | C62A—C63A—H63A | 120 |
C26—C21—Si1 | 121.7 (5) | C64A—C63A—H63A | 120 |
C22—C21—Si1 | 120.8 (5) | C65A—C64A—C63A | 120 |
C21—C22—C23 | 120.8 (6) | C65A—C64A—H64A | 120 |
C21—C22—H22 | 119.6 | C63A—C64A—H64A | 120 |
C23—C22—H22 | 119.6 | C66A—C65A—C64A | 120 |
C24—C23—C22 | 120.9 (7) | C66A—C65A—H65A | 120 |
C24—C23—H23 | 119.5 | C64A—C65A—H65A | 120 |
C22—C23—H23 | 119.5 | C65A—C66A—C61A | 120 |
C25—C24—C23 | 118.5 (8) | C65A—C66A—H66A | 120 |
C25—C24—H24 | 120.7 | C61A—C66A—H66A | 120 |
C23—C24—H24 | 120.7 | C62B—C61B—C66B | 120 |
C24—C25—C26 | 120.7 (8) | C62B—C61B—Si2 | 123.3 (8) |
C24—C25—H25 | 119.6 | C66B—C61B—Si2 | 116.7 (8) |
C26—C25—H25 | 119.6 | C63B—C62B—C61B | 120 |
C21—C26—C25 | 121.4 (7) | C63B—C62B—H62B | 120 |
C21—C26—H26 | 119.3 | C61B—C62B—H62B | 120 |
C25—C26—H26 | 119.3 | C64B—C63B—C62B | 120 |
C32A—C31A—C36A | 120 | C64B—C63B—H63B | 120 |
C32A—C31A—Si1 | 115.9 (8) | C62B—C63B—H63B | 120 |
C36A—C31A—Si1 | 124.1 (8) | C63B—C64B—C65B | 120 |
C31A—C32A—C33A | 120 | C63B—C64B—H64B | 120 |
C31A—C32A—H32A | 120 | C65B—C64B—H64B | 120 |
C33A—C32A—H32A | 120 | C66B—C65B—C64B | 120 |
C34A—C33A—C32A | 120 | C66B—C65B—H65B | 120 |
C34A—C33A—H33A | 120 | C64B—C65B—H65B | 120 |
C32A—C33A—H33A | 120 | C65B—C66B—C61B | 120 |
C33A—C34A—C35A | 120 | C65B—C66B—H66B | 120 |
C33A—C34A—H34A | 120 | C61B—C66B—H66B | 120 |
C35A—C34A—H34A | 120 | C72A—C71A—C76A | 120 |
C34A—C35A—C36A | 120 | C72A—C71A—Si2 | 122.6 (10) |
C34A—C35A—H35A | 120 | C76A—C71A—Si2 | 117.3 (10) |
C36A—C35A—H35A | 120 | C73A—C72A—C71A | 120 |
C35A—C36A—C31A | 120 | C73A—C72A—H72A | 120 |
C35A—C36A—H36A | 120 | C71A—C72A—H72A | 120 |
C31A—C36A—H36A | 120 | C74A—C73A—C72A | 120 |
C32B—C31B—C36B | 120 | C74A—C73A—H73A | 120 |
C32B—C31B—Si1 | 124.1 (8) | C72A—C73A—H73A | 120 |
C36B—C31B—Si1 | 115.7 (8) | C75A—C74A—C73A | 120 |
C31B—C32B—C33B | 120 | C75A—C74A—H74A | 120 |
C31B—C32B—H32B | 120 | C73A—C74A—H74A | 120 |
C33B—C32B—H32B | 120 | C74A—C75A—C76A | 120 |
C32B—C33B—C34B | 120 | C74A—C75A—H75A | 120 |
C32B—C33B—H33B | 120 | C76A—C75A—H75A | 120 |
C34B—C33B—H33B | 120 | C75A—C76A—C71A | 120 |
C35B—C34B—C33B | 120 | C75A—C76A—H76A | 120 |
C35B—C34B—H34B | 120 | C71A—C76A—H76A | 120 |
C33B—C34B—H34B | 120 | C72B—C71B—C76B | 120 |
C36B—C35B—C34B | 120 | C72B—C71B—Si2 | 116.4 (10) |
C36B—C35B—H35B | 120 | C76B—C71B—Si2 | 123.6 (10) |
C34B—C35B—H35B | 120 | C73B—C72B—C71B | 120 |
C35B—C36B—C31B | 120 | C73B—C72B—H72B | 120 |
C35B—C36B—H36B | 120 | C71B—C72B—H72B | 120 |
C31B—C36B—H36B | 120 | C72B—C73B—C74B | 120 |
C42—C41—C46 | 117.5 (5) | C72B—C73B—H73B | 120 |
C42—C41—Si1 | 120.8 (5) | C74B—C73B—H73B | 120 |
C46—C41—Si1 | 121.7 (5) | C73B—C74B—C75B | 120 |
C41—C42—C43 | 121.8 (7) | C73B—C74B—H74B | 120 |
C41—C42—H42 | 119.1 | C75B—C74B—H74B | 120 |
C43—C42—H42 | 119.1 | C74B—C75B—C76B | 120 |
C44—C43—C42 | 117.8 (8) | C74B—C75B—H75B | 120 |
C44—C43—H43 | 121.1 | C76B—C75B—H75B | 120 |
C42—C43—H43 | 121.1 | C75B—C76B—C71B | 120 |
C45—C44—C43 | 123.4 (8) | C75B—C76B—H76B | 120 |
C45—C44—H44 | 118.3 | C71B—C76B—H76B | 120 |
C41—Si1—O1—As1 | 4.0 (5) | C52A—C53A—C54A—C55A | 0.0 |
C31B—Si1—O1—As1 | −117.4 (6) | C53A—C54A—C55A—C56A | 0.0 |
C31A—Si1—O1—As1 | −118.6 (6) | C54A—C55A—C56A—C51A | 0.0 |
C21—Si1—O1—As1 | 125.2 (3) | C52A—C51A—C56A—C55A | 0.0 |
O2—As1—O1—Si1 | 82.7 (4) | Si2—C51A—C56A—C55A | −175.0 (18) |
C11—As1—O1—Si1 | −177.6 (4) | O2—Si2—C51B—C52B | −70.1 (11) |
C51A—Si2—O2—As1 | −34.6 (8) | C51A—Si2—C51B—C52B | 177 (14) |
C51B—Si2—O2—As1 | −42.4 (8) | C61B—Si2—C51B—C52B | 45.1 (12) |
C61B—Si2—O2—As1 | −160.6 (5) | C61A—Si2—C51B—C52B | 43.4 (13) |
C61A—Si2—O2—As1 | −160.4 (5) | C71A—Si2—C51B—C52B | 166.7 (9) |
C71A—Si2—O2—As1 | 81.8 (7) | C71B—Si2—C51B—C52B | 169.8 (9) |
C71B—Si2—O2—As1 | 82.0 (6) | O2—Si2—C51B—C56B | 104.9 (11) |
O1—As1—O2—Si2 | 176.3 (3) | C51A—Si2—C51B—C56B | −8 (13) |
C11—As1—O2—Si2 | 80.5 (4) | C61B—Si2—C51B—C56B | −139.9 (11) |
O1—As1—C11—C16 | 150.3 (4) | C61A—Si2—C51B—C56B | −141.6 (11) |
O2—As1—C11—C16 | −113.7 (4) | C71A—Si2—C51B—C56B | −18.3 (16) |
O1—As1—C11—C12 | −29.0 (5) | C71B—Si2—C51B—C56B | −15.2 (17) |
O2—As1—C11—C12 | 67.0 (5) | C56B—C51B—C52B—C53B | 0.0 |
C16—C11—C12—C13 | 2.0 (9) | Si2—C51B—C52B—C53B | 175.1 (18) |
As1—C11—C12—C13 | −178.7 (5) | C51B—C52B—C53B—C54B | 0.0 |
C11—C12—C13—C14 | −1.1 (10) | C52B—C53B—C54B—C55B | 0.0 |
C12—C13—C14—C15 | 0.8 (10) | C53B—C54B—C55B—C56B | 0.0 |
C13—C14—C15—C16 | −1.4 (10) | C54B—C55B—C56B—C51B | 0.0 |
C14—C15—C16—C11 | 2.4 (10) | C52B—C51B—C56B—C55B | 0.0 |
C12—C11—C16—C15 | −2.6 (9) | Si2—C51B—C56B—C55B | −174.9 (19) |
As1—C11—C16—C15 | 178.0 (5) | O2—Si2—C61A—C62A | −42.8 (7) |
O1—Si1—C21—C26 | −162.8 (5) | C51A—Si2—C61A—C62A | −166.1 (10) |
C41—Si1—C21—C26 | −40.8 (6) | C51B—Si2—C61A—C62A | −159.8 (10) |
C31B—Si1—C21—C26 | 77.5 (7) | C61B—Si2—C61A—C62A | 129 (31) |
C31A—Si1—C21—C26 | 84.6 (7) | C71A—Si2—C61A—C62A | 75.6 (9) |
O1—Si1—C21—C22 | 19.4 (5) | C71B—Si2—C61A—C62A | 72.1 (9) |
C41—Si1—C21—C22 | 141.3 (5) | O2—Si2—C61A—C66A | 136.9 (7) |
C31B—Si1—C21—C22 | −100.4 (7) | C51A—Si2—C61A—C66A | 13.5 (13) |
C31A—Si1—C21—C22 | −93.2 (7) | C51B—Si2—C61A—C66A | 19.8 (12) |
C26—C21—C22—C23 | −0.7 (9) | C61B—Si2—C61A—C66A | −51 (30) |
Si1—C21—C22—C23 | 177.2 (5) | C71A—Si2—C61A—C66A | −104.8 (10) |
C21—C22—C23—C24 | 0.4 (10) | C71B—Si2—C61A—C66A | −108.3 (10) |
C22—C23—C24—C25 | −0.2 (11) | C66A—C61A—C62A—C63A | 0.0 |
C23—C24—C25—C26 | 0.4 (12) | Si2—C61A—C62A—C63A | 179.6 (9) |
C22—C21—C26—C25 | 0.8 (10) | C61A—C62A—C63A—C64A | 0.0 |
Si1—C21—C26—C25 | −177.1 (5) | C62A—C63A—C64A—C65A | 0.0 |
C24—C25—C26—C21 | −0.7 (12) | C63A—C64A—C65A—C66A | 0.0 |
O1—Si1—C31A—C32A | 23.6 (7) | C64A—C65A—C66A—C61A | 0.0 |
C41—Si1—C31A—C32A | −98.2 (7) | C62A—C61A—C66A—C65A | 0.0 |
C31B—Si1—C31A—C32A | −147 (8) | Si2—C61A—C66A—C65A | −179.6 (10) |
C21—Si1—C31A—C32A | 137.9 (6) | O2—Si2—C61B—C62B | −22.0 (8) |
O1—Si1—C31A—C36A | −158.2 (7) | C51A—Si2—C61B—C62B | −146.1 (10) |
C41—Si1—C31A—C36A | 80.1 (9) | C51B—Si2—C61B—C62B | −139.7 (10) |
C31B—Si1—C31A—C36A | 31 (7) | C61A—Si2—C61B—C62B | −30 (30) |
C21—Si1—C31A—C36A | −43.9 (10) | C71A—Si2—C61B—C62B | 96.7 (9) |
C36A—C31A—C32A—C33A | 0.0 | C71B—Si2—C61B—C62B | 93.3 (10) |
Si1—C31A—C32A—C33A | 178.3 (11) | O2—Si2—C61B—C66B | 158.0 (6) |
C31A—C32A—C33A—C34A | 0.0 | C51A—Si2—C61B—C66B | 33.9 (11) |
C32A—C33A—C34A—C35A | 0.0 | C51B—Si2—C61B—C66B | 40.3 (11) |
C33A—C34A—C35A—C36A | 0.0 | C61A—Si2—C61B—C66B | 150 (31) |
C34A—C35A—C36A—C31A | 0.0 | C71A—Si2—C61B—C66B | −83.2 (9) |
C32A—C31A—C36A—C35A | 0.0 | C71B—Si2—C61B—C66B | −86.7 (9) |
Si1—C31A—C36A—C35A | −178.1 (12) | C66B—C61B—C62B—C63B | 0.0 |
O1—Si1—C31B—C32B | 7.4 (9) | Si2—C61B—C62B—C63B | −180.0 (10) |
C41—Si1—C31B—C32B | −116.0 (8) | C61B—C62B—C63B—C64B | 0.0 |
C31A—Si1—C31B—C32B | 17 (7) | C62B—C63B—C64B—C65B | 0.0 |
C21—Si1—C31B—C32B | 124.4 (7) | C63B—C64B—C65B—C66B | 0.0 |
O1—Si1—C31B—C36B | −167.8 (6) | C64B—C65B—C66B—C61B | 0.0 |
C41—Si1—C31B—C36B | 68.8 (7) | C62B—C61B—C66B—C65B | 0.0 |
C31A—Si1—C31B—C36B | −158 (8) | Si2—C61B—C66B—C65B | 180.0 (10) |
C21—Si1—C31B—C36B | −50.9 (8) | O2—Si2—C71A—C72A | 4.2 (10) |
C36B—C31B—C32B—C33B | 0.0 | C51A—Si2—C71A—C72A | 125.2 (12) |
Si1—C31B—C32B—C33B | −175.1 (12) | C51B—Si2—C71A—C72A | 126.6 (13) |
C31B—C32B—C33B—C34B | 0.0 | C61B—Si2—C71A—C72A | −111.1 (9) |
C32B—C33B—C34B—C35B | 0.0 | C61A—Si2—C71A—C72A | −109.7 (10) |
C33B—C34B—C35B—C36B | 0.0 | C71B—Si2—C71A—C72A | 1 (17) |
C34B—C35B—C36B—C31B | 0.0 | O2—Si2—C71A—C76A | −173.0 (6) |
C32B—C31B—C36B—C35B | 0.0 | C51A—Si2—C71A—C76A | −52.1 (12) |
Si1—C31B—C36B—C35B | 175.5 (11) | C51B—Si2—C71A—C76A | −50.6 (13) |
O1—Si1—C41—C42 | 76.8 (5) | C61B—Si2—C71A—C76A | 71.6 (9) |
C31B—Si1—C41—C42 | −160.2 (7) | C61A—Si2—C71A—C76A | 73.1 (9) |
C31A—Si1—C41—C42 | −165.7 (7) | C71B—Si2—C71A—C76A | −177 (18) |
C21—Si1—C41—C42 | −42.3 (6) | C76A—C71A—C72A—C73A | 0.0 |
O1—Si1—C41—C46 | −102.7 (5) | Si2—C71A—C72A—C73A | −177.2 (12) |
C31B—Si1—C41—C46 | 20.3 (8) | C71A—C72A—C73A—C74A | 0.0 |
C31A—Si1—C41—C46 | 14.8 (8) | C72A—C73A—C74A—C75A | 0.0 |
C21—Si1—C41—C46 | 138.2 (5) | C73A—C74A—C75A—C76A | 0.0 |
C46—C41—C42—C43 | −0.1 (10) | C74A—C75A—C76A—C71A | 0.0 |
Si1—C41—C42—C43 | −179.6 (5) | C72A—C71A—C76A—C75A | 0.0 |
C41—C42—C43—C44 | 0.2 (11) | Si2—C71A—C76A—C75A | 177.4 (12) |
C42—C43—C44—C45 | 0.9 (13) | O2—Si2—C71B—C72B | 17.0 (9) |
C43—C44—C45—C46 | −2.2 (15) | C51A—Si2—C71B—C72B | 137.3 (12) |
C44—C45—C46—C41 | 2.2 (13) | C51B—Si2—C71B—C72B | 138.3 (12) |
C42—C41—C46—C45 | −1.1 (10) | C61B—Si2—C71B—C72B | −97.1 (9) |
Si1—C41—C46—C45 | 178.4 (6) | C61A—Si2—C71B—C72B | −95.6 (9) |
O2—Si2—C51A—C52A | −73.7 (11) | C71A—Si2—C71B—C72B | −166 (18) |
C51B—Si2—C51A—C52A | −4 (13) | O2—Si2—C71B—C76B | −163.6 (7) |
C61B—Si2—C51A—C52A | 46.7 (14) | C51A—Si2—C71B—C76B | −43.3 (13) |
C61A—Si2—C51A—C52A | 45.0 (14) | C51B—Si2—C71B—C76B | −42.3 (14) |
C71A—Si2—C51A—C52A | 166.3 (10) | C61B—Si2—C71B—C76B | 82.3 (10) |
C71B—Si2—C51A—C52A | 169.3 (10) | C61A—Si2—C71B—C76B | 83.8 (10) |
O2—Si2—C51A—C56A | 101.3 (10) | C71A—Si2—C71B—C76B | 13 (17) |
C51B—Si2—C51A—C56A | 171 (15) | C76B—C71B—C72B—C73B | 0.0 |
C61B—Si2—C51A—C56A | −138.3 (10) | Si2—C71B—C72B—C73B | 179.4 (11) |
C61A—Si2—C51A—C56A | −140.0 (10) | C71B—C72B—C73B—C74B | 0.0 |
C71A—Si2—C51A—C56A | −18.7 (14) | C72B—C73B—C74B—C75B | 0.0 |
C71B—Si2—C51A—C56A | −15.7 (15) | C73B—C74B—C75B—C76B | 0.0 |
C56A—C51A—C52A—C53A | 0.0 | C74B—C75B—C76B—C71B | 0.0 |
Si2—C51A—C52A—C53A | 175.0 (18) | C72B—C71B—C76B—C75B | 0.0 |
C51A—C52A—C53A—C54A | 0.0 | Si2—C71B—C76B—C75B | −179.4 (12) |