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The solid-state structure of [{(C24H25)P(H)}Rb(C4H6N2)]2 or [Rb2(C24H26P)2(C4H6N2)2], a novel base adduct of tetrameric [DmpP(H)Rb]4 (Dmp = 2,6-dimesityl­phenyl), is reported. It exhibits a dimeric centrosymmetric arrangement.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536803023353/lh6118sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536803023353/lh6118Isup2.hkl
Contains datablock I

CCDC reference: 226668

Key indicators

  • Single-crystal X-ray study
  • T = 198 K
  • Mean [sigma](C-C) = 0.004 Å
  • R factor = 0.038
  • wR factor = 0.109
  • Data-to-parameter ratio = 14.8

checkCIF/PLATON results

No syntax errors found



Alert level A PLAT029_ALERT_3_A _diffrn_measured_fraction_theta_full Low ....... 0.96
Author Response: Parameter settings for data collection were less than required for a hemisphere in two theta. Hence, data fraction at 50 degrees is two theta is 96 percent rather than 100 percent. The data fraction at 55 degrees in two theta is 88 percent. The uniqueness of this structure may warrant consideration for publication of this structue eventhough the data collection is less than 100 percent.

Alert level C PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings Differ .... ? PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............ 2.00 Ratio PLAT764_ALERT_4_C Overcomplete CIF Bond list Detected (Rep/Expd) . 1.43 Ratio PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ...... 21.00 Deg. RB1 -P1 -H1A 2.666 1.555 1.555
1 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 5 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 3 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 1 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 1 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Bruker, 2001); cell refinement: SMART; data reduction: SAINT (Bruker, 2001); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 2001); software used to prepare material for publication: SHELXTL.

Bis(µ-2,2'-4,4'-6,6'-hexamethyl-µ-terphenyl-2'- phosphanido)bis[(N-methylimidazole)rubidium(I)] top
Crystal data top
[Rb2(C24H26P)2(C4H6N2)2]Z = 1
Mr = 1026.00F(000) = 532
Triclinic, P1Dx = 1.306 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 8.6940 (3) ÅCell parameters from 3500 reflections
b = 12.3225 (4) Åθ = 2.0–25.0°
c = 13.6724 (5) ŵ = 1.98 mm1
α = 67.228 (1)°T = 198 K
β = 75.138 (1)°Block, orange
γ = 85.917 (1)°0.50 × 0.40 × 0.40 mm
V = 1304.75 (8) Å3
Data collection top
Siemens Bruker P4 1K CCD detector
diffractometer
4422 independent reflections
Radiation source: fine-focus sealed tube3920 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.025
ω scansθmax = 25.0°, θmin = 1.7°
Absorption correction: multi-scan
(SADABS; Bruker, 2001)
h = 910
Tmin = 0.393, Tmax = 0.454k = 1414
7167 measured reflectionsl = 1416
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.039Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.110H atoms treated by a mixture of independent and constrained refinement
S = 1.05 w = 1/[σ2(Fo2) + (0.0741P)2 + 0.1125P]
where P = (Fo2 + 2Fc2)/3
4422 reflections(Δ/σ)max = 0.001
299 parametersΔρmax = 0.91 e Å3
0 restraintsΔρmin = 0.86 e Å3
Special details top

Experimental. A crystal of approximately 0.40 x 0.40 x 0.50 mm3 on an edge was handled under a nitrogen atomosphere and mounted on a glass fiber with Paratone-N oil and then cooled to 198 K. The data were collected on a Siemens Bruker 1 K P4/CCD diffractometer with Mo radiation (Bruker,2001). The strucure was solved by direct methods and completed from subsequent difference Fourier syntheses. Diffraction symmetry indiated a triclinic crystal system and the solution successfully solved in P-1 space group. All non-hydrogen atoms were refined with anisotropic thermal parameters.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Rb10.74970 (3)0.55673 (2)0.28931 (2)0.03288 (12)
P10.42706 (9)0.65670 (6)0.41498 (7)0.0364 (2)
N10.5913 (3)0.4171 (2)0.2103 (2)0.0413 (6)
N20.4434 (3)0.2520 (2)0.2906 (2)0.0337 (5)
C10.5788 (3)0.7800 (2)0.1120 (2)0.0265 (6)
C20.7296 (3)0.7633 (2)0.0521 (2)0.0300 (6)
H2A0.73510.73920.01060.036*
C30.8683 (3)0.8042 (2)0.0600 (2)0.0298 (6)
C40.8552 (3)0.8605 (2)0.1333 (2)0.0305 (6)
H4A0.95360.89360.13800.037*
C50.7071 (3)0.8796 (2)0.1937 (2)0.0276 (6)
C60.5671 (3)0.8401 (2)0.1823 (2)0.0231 (5)
C70.4061 (3)0.8671 (2)0.2413 (2)0.0234 (5)
C80.3345 (3)0.9694 (2)0.1850 (2)0.0302 (6)
H8A0.38631.01760.11180.036*
C90.1872 (3)1.0014 (2)0.2353 (2)0.0337 (6)
H9A0.13871.07120.19740.040*
C100.1132 (3)0.9290 (2)0.3419 (2)0.0305 (6)
H10A0.01360.95070.37670.037*
C110.1804 (3)0.8258 (2)0.3991 (2)0.0242 (5)
C120.3304 (3)0.7907 (2)0.3493 (2)0.0230 (5)
C130.0925 (3)0.7529 (2)0.5145 (2)0.0236 (5)
C140.1240 (3)0.7697 (2)0.6036 (2)0.0249 (5)
C150.0430 (3)0.7007 (2)0.7101 (2)0.0299 (6)
H15A0.06550.71280.76960.036*
C160.0704 (3)0.6142 (2)0.7318 (2)0.0308 (6)
C170.1021 (3)0.5983 (2)0.6432 (2)0.0318 (6)
H17A0.17870.53970.65640.038*
C180.0238 (3)0.6665 (2)0.5356 (2)0.0275 (6)
C190.4302 (4)0.7330 (3)0.1009 (3)0.0421 (7)
H19A0.35330.70290.17250.063*
H19B0.45840.66920.07420.063*
H19C0.38280.79650.04900.063*
C201.0293 (4)0.7896 (3)0.0078 (3)0.0438 (8)
H20A1.09950.75020.04050.066*
H20B1.07580.86710.05930.066*
H20C1.01720.74190.04870.066*
C210.6980 (4)0.9425 (3)0.2701 (3)0.0401 (7)
H21A0.63190.89540.34270.060*
H21B0.65081.01950.24140.060*
H21C0.80530.95350.27590.060*
C220.2461 (3)0.8623 (2)0.5839 (3)0.0337 (6)
H22A0.34530.85270.53460.051*
H22B0.26670.85330.65380.051*
H22C0.20550.94080.55060.051*
C230.1578 (4)0.5403 (3)0.8484 (3)0.0494 (9)
H23A0.09860.54420.89920.074*
H23B0.16670.45830.85630.074*
H23C0.26450.57060.86520.074*
C240.0651 (4)0.6489 (3)0.4423 (3)0.0394 (7)
H24A0.13010.57630.47080.059*
H24B0.03290.64290.39010.059*
H24C0.12510.71590.40530.059*
C250.4988 (3)0.3453 (3)0.3020 (2)0.0361 (7)
H25A0.47360.35740.36880.043*
C260.5041 (4)0.2648 (3)0.1848 (3)0.0419 (7)
H26A0.48650.21350.15150.050*
C270.5949 (4)0.3656 (3)0.1360 (3)0.0464 (8)
H27A0.65270.39650.06140.056*
C280.3406 (4)0.1539 (3)0.3776 (3)0.0452 (8)
H28A0.31820.09840.34710.068*
H28B0.24040.18470.40750.068*
H28C0.39480.11340.43600.068*
H1A0.339 (4)0.614 (3)0.492 (3)0.053 (10)*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Rb10.03266 (18)0.03651 (18)0.03025 (18)0.00743 (11)0.00708 (12)0.01514 (13)
P10.0366 (4)0.0297 (4)0.0310 (4)0.0136 (3)0.0047 (3)0.0035 (3)
N10.0409 (15)0.0432 (14)0.0391 (15)0.0034 (11)0.0071 (12)0.0162 (12)
N20.0333 (13)0.0329 (12)0.0309 (13)0.0016 (10)0.0066 (10)0.0089 (10)
C10.0269 (14)0.0300 (13)0.0213 (13)0.0008 (10)0.0085 (11)0.0069 (11)
C20.0372 (15)0.0338 (14)0.0174 (13)0.0059 (11)0.0051 (11)0.0101 (11)
C30.0276 (14)0.0297 (14)0.0239 (14)0.0058 (10)0.0026 (11)0.0046 (11)
C40.0227 (13)0.0306 (14)0.0334 (15)0.0007 (10)0.0050 (11)0.0081 (12)
C50.0280 (14)0.0248 (13)0.0267 (14)0.0013 (10)0.0060 (11)0.0071 (11)
C60.0236 (13)0.0219 (12)0.0179 (12)0.0009 (9)0.0026 (10)0.0028 (10)
C70.0219 (13)0.0256 (12)0.0239 (13)0.0029 (10)0.0080 (10)0.0095 (11)
C80.0304 (14)0.0287 (13)0.0247 (14)0.0013 (11)0.0054 (11)0.0038 (11)
C90.0326 (15)0.0303 (14)0.0326 (16)0.0131 (11)0.0129 (13)0.0051 (12)
C100.0257 (14)0.0321 (14)0.0344 (15)0.0092 (11)0.0079 (12)0.0146 (12)
C110.0228 (12)0.0267 (13)0.0243 (13)0.0023 (10)0.0058 (10)0.0114 (11)
C120.0243 (13)0.0240 (12)0.0215 (13)0.0033 (10)0.0066 (10)0.0094 (10)
C130.0192 (12)0.0240 (12)0.0280 (14)0.0065 (9)0.0044 (10)0.0122 (11)
C140.0231 (13)0.0251 (13)0.0266 (14)0.0043 (10)0.0042 (11)0.0120 (11)
C150.0335 (15)0.0307 (14)0.0261 (14)0.0079 (11)0.0051 (12)0.0143 (12)
C160.0297 (14)0.0261 (13)0.0274 (15)0.0071 (11)0.0011 (12)0.0067 (11)
C170.0239 (13)0.0229 (13)0.0434 (17)0.0027 (10)0.0026 (12)0.0112 (12)
C180.0235 (13)0.0272 (13)0.0345 (15)0.0050 (10)0.0061 (11)0.0160 (12)
C190.0349 (16)0.059 (2)0.0409 (18)0.0063 (14)0.0084 (14)0.0274 (16)
C200.0314 (16)0.0532 (19)0.0383 (18)0.0101 (14)0.0024 (14)0.0141 (15)
C210.0350 (16)0.0448 (17)0.053 (2)0.0026 (13)0.0141 (15)0.0302 (16)
C220.0355 (15)0.0329 (14)0.0378 (16)0.0009 (12)0.0105 (13)0.0176 (13)
C230.053 (2)0.0425 (18)0.0340 (18)0.0021 (15)0.0043 (15)0.0037 (15)
C240.0439 (17)0.0381 (16)0.0424 (18)0.0021 (13)0.0152 (14)0.0188 (14)
C250.0354 (16)0.0430 (16)0.0322 (16)0.0003 (13)0.0070 (13)0.0174 (13)
C260.0509 (19)0.0427 (17)0.0365 (17)0.0006 (14)0.0100 (15)0.0203 (14)
C270.054 (2)0.0489 (19)0.0286 (17)0.0057 (15)0.0024 (15)0.0133 (14)
C280.0395 (17)0.0378 (16)0.047 (2)0.0034 (13)0.0037 (15)0.0083 (15)
Geometric parameters (Å, º) top
Rb1—N12.927 (3)C11—C121.429 (4)
Rb1—C23.297 (3)C11—C131.504 (4)
Rb1—P13.3185 (8)C13—C141.406 (4)
Rb1—C16i3.393 (3)C13—C181.416 (3)
Rb1—C33.403 (3)C14—C151.393 (4)
Rb1—C13.429 (3)C14—C221.513 (3)
Rb1—C253.441 (3)C15—C161.397 (4)
Rb1—C24ii3.476 (3)C15—Rb1i3.533 (3)
Rb1—C15i3.533 (3)C15—H15A0.9500
Rb1—C43.565 (3)C16—C171.394 (4)
Rb1—C17i3.625 (3)C16—C231.518 (4)
Rb1—C63.647 (2)C16—Rb1i3.393 (3)
Rb1—C53.700 (3)C17—C181.395 (4)
P1—C121.811 (3)C17—Rb1i3.625 (3)
P1—Rb1i3.8448 (8)C17—H17A0.9500
P1—H1A1.09 (4)C18—C241.504 (4)
N1—C251.315 (4)C19—H19A0.9800
N1—C271.383 (4)C19—H19B0.9800
N2—C251.354 (4)C19—H19C0.9800
N2—C261.356 (4)C20—H20A0.9800
N2—C281.473 (4)C20—H20B0.9800
C1—C61.404 (4)C20—H20C0.9800
C1—C21.405 (4)C21—H21A0.9800
C1—C191.517 (4)C21—H21B0.9800
C2—C31.384 (4)C21—H21C0.9800
C2—H2A1.0000C22—H22A0.9800
C3—C41.403 (4)C22—H22B0.9800
C3—C201.510 (4)C22—H22C0.9800
C4—C51.399 (4)C23—H23A0.9800
C4—H4A1.0000C23—H23B0.9800
C5—C61.408 (4)C23—H23C0.9800
C5—C211.508 (4)C24—H24A0.9800
C6—C71.511 (3)C24—H24B0.9800
C7—C81.397 (4)C24—H24C0.9800
C7—C121.419 (4)C25—H25A0.9500
C8—C91.398 (4)C26—C271.356 (4)
C8—H8A0.9500C26—H26A0.9500
C9—C101.388 (4)C27—H27A0.9500
C9—H9A0.9500C28—H28A0.9800
C10—C111.389 (4)C28—H28B0.9800
C10—H10A0.9500C28—H28C0.9800
N1—Rb1—C281.50 (7)C7—C6—Rb1121.97 (15)
N1—Rb1—P198.17 (6)C8—C7—C12121.5 (2)
C2—Rb1—P190.35 (5)C8—C7—C6117.4 (2)
N1—Rb1—C16i87.90 (7)C12—C7—C6121.1 (2)
C2—Rb1—C16i112.77 (7)C7—C8—C9120.5 (2)
P1—Rb1—C16i156.77 (5)C7—C8—H8A119.7
N1—Rb1—C3102.00 (7)C9—C8—H8A119.7
C2—Rb1—C323.77 (7)C10—C9—C8118.7 (2)
P1—Rb1—C399.16 (5)C10—C9—H9A120.7
C16i—Rb1—C3101.48 (6)C8—C9—H9A120.7
N1—Rb1—C180.97 (7)C9—C10—C11122.0 (2)
C2—Rb1—C124.02 (7)C9—C10—H10A119.0
P1—Rb1—C166.83 (5)C11—C10—H10A119.0
C16i—Rb1—C1136.40 (7)C10—C11—C12120.5 (2)
C3—Rb1—C141.85 (6)C10—C11—C13118.5 (2)
N1—Rb1—C2521.98 (7)C12—C11—C13121.0 (2)
C2—Rb1—C2599.79 (7)C7—C12—C11116.7 (2)
P1—Rb1—C2585.98 (5)C7—C12—P1118.96 (18)
C16i—Rb1—C2591.96 (7)C11—C12—P1124.30 (19)
C3—Rb1—C25122.18 (7)C14—C13—C18118.7 (2)
C1—Rb1—C2592.82 (7)C14—C13—C11120.5 (2)
N1—Rb1—C24ii164.28 (7)C18—C13—C11120.8 (2)
C2—Rb1—C24ii114.19 (7)C15—C14—C13119.9 (2)
P1—Rb1—C24ii83.28 (6)C15—C14—C22120.0 (2)
C16i—Rb1—C24ii85.02 (8)C13—C14—C22120.1 (2)
C3—Rb1—C24ii93.17 (7)C14—C15—C16121.7 (3)
C1—Rb1—C24ii113.65 (7)C14—C15—Rb1i94.31 (15)
C25—Rb1—C24ii144.29 (7)C16—C15—Rb1i72.80 (15)
N1—Rb1—C15i67.97 (7)C14—C15—H15A119.1
C2—Rb1—C15i118.51 (7)C16—C15—H15A119.1
P1—Rb1—C15i143.91 (5)Rb1i—C15—H15A103.1
C16i—Rb1—C15i23.15 (7)C17—C16—C15118.2 (2)
C3—Rb1—C15i116.00 (6)C17—C16—C23120.9 (3)
C1—Rb1—C15i137.10 (7)C15—C16—C23120.9 (3)
C25—Rb1—C15i69.05 (7)C17—C16—Rb1i88.07 (16)
C24ii—Rb1—C15i101.73 (7)C15—C16—Rb1i84.05 (16)
N1—Rb1—C4121.98 (7)C23—C16—Rb1i98.13 (18)
C2—Rb1—C440.48 (7)C16—C17—C18121.4 (2)
P1—Rb1—C484.57 (5)C16—C17—Rb1i69.33 (15)
C16i—Rb1—C4111.23 (6)C18—C17—Rb1i94.48 (16)
C3—Rb1—C423.08 (7)C16—C17—H17A119.3
C1—Rb1—C446.92 (6)C18—C17—H17A119.3
C25—Rb1—C4138.87 (7)Rb1i—C17—H17A106.3
C24ii—Rb1—C473.73 (7)C17—C18—C13120.0 (3)
C15i—Rb1—C4131.34 (6)C17—C18—C24119.7 (2)
N1—Rb1—C17i107.03 (7)C13—C18—C24120.3 (2)
C2—Rb1—C17i126.43 (7)C1—C19—H19A109.5
P1—Rb1—C17i137.40 (5)C1—C19—H19B109.5
C16i—Rb1—C17i22.61 (7)H19A—C19—H19B109.5
C3—Rb1—C17i108.18 (6)C1—C19—H19C109.5
C1—Rb1—C17i149.65 (6)H19A—C19—H19C109.5
C25—Rb1—C17i105.13 (7)H19B—C19—H19C109.5
C24ii—Rb1—C17i63.58 (7)C3—C20—H20A109.5
C15i—Rb1—C17i39.06 (6)C3—C20—H20B109.5
C4—Rb1—C17i108.80 (6)H20A—C20—H20B109.5
N1—Rb1—C6100.37 (7)C3—C20—H20C109.5
C2—Rb1—C640.51 (6)H20A—C20—H20C109.5
P1—Rb1—C652.41 (4)H20B—C20—H20C109.5
C16i—Rb1—C6148.52 (6)C5—C21—H21A109.5
C3—Rb1—C647.18 (6)C5—C21—H21B109.5
C1—Rb1—C622.63 (6)H21A—C21—H21B109.5
C25—Rb1—C6107.05 (6)C5—C21—H21C109.5
C24ii—Rb1—C692.94 (7)H21A—C21—H21C109.5
C15i—Rb1—C6158.81 (6)H21B—C21—H21C109.5
C4—Rb1—C639.28 (6)C14—C22—H22A109.5
C17i—Rb1—C6147.13 (6)C14—C22—H22B109.5
C12—P1—Rb1124.35 (9)H22A—C22—H22B109.5
C12—P1—Rb1i122.32 (9)C14—C22—H22C109.5
Rb1—P1—Rb1i113.08 (2)H22A—C22—H22C109.5
C12—P1—H1A102.3 (19)H22B—C22—H22C109.5
Rb1—P1—H1A131.8 (19)C16—C23—H23A109.5
Rb1i—P1—H1A21.0 (19)C16—C23—H23B109.5
C25—N1—C27104.1 (2)H23A—C23—H23B109.5
C25—N1—Rb1101.61 (19)C16—C23—H23C109.5
C27—N1—Rb1149.7 (2)H23A—C23—H23C109.5
C25—N2—C26106.9 (2)H23B—C23—H23C109.5
C25—N2—C28126.3 (3)C18—C24—H24A109.5
C26—N2—C28126.8 (3)C18—C24—H24B109.5
C6—C1—C2119.4 (2)H24A—C24—H24B109.5
C6—C1—C19120.5 (2)C18—C24—H24C109.5
C2—C1—C19120.1 (3)H24A—C24—H24C109.5
C6—C1—Rb187.46 (15)H24B—C24—H24C109.5
C2—C1—Rb172.72 (15)N1—C25—N2112.3 (3)
C19—C1—Rb1109.60 (18)N1—C25—Rb156.41 (15)
C3—C2—C1122.1 (3)N2—C25—Rb1162.0 (2)
C3—C2—Rb182.43 (16)N1—C25—H25A123.8
C1—C2—Rb183.26 (15)N2—C25—H25A123.8
C3—C2—H2A118.1Rb1—C25—H25A69.1
C1—C2—H2A118.1C27—C26—N2106.2 (3)
Rb1—C2—H2A118.1C27—C26—H26A126.9
C2—C3—C4117.9 (2)N2—C26—H26A126.9
C2—C3—C20121.6 (3)C26—C27—N1110.4 (3)
C4—C3—C20120.5 (3)C26—C27—H27A124.8
C2—C3—Rb173.80 (15)N1—C27—H27A124.8
C4—C3—Rb184.95 (16)N2—C28—H28A109.5
C20—C3—Rb1111.04 (18)N2—C28—H28B109.5
C5—C4—C3121.7 (2)H28A—C28—H28B109.5
C5—C4—Rb184.41 (15)N2—C28—H28C109.5
C3—C4—Rb171.98 (15)H28A—C28—H28C109.5
C5—C4—H4A119.1H28B—C28—H28C109.5
C3—C4—H4A119.1C5—Rb1—C139.59 (6)
Rb1—C4—H4A119.1C5—Rb1—C246.47 (7)
C4—C5—C6119.6 (2)C5—Rb1—C340.01 (6)
C4—C5—C21120.0 (2)C5—Rb1—C422.10 (6)
C6—C5—C21120.4 (2)C5—Rb1—C622.08 (6)
C4—C5—Rb173.49 (15)C5—Rb1—P162.51 (4)
C6—C5—Rb176.83 (14)C5—Rb1—N1120.51 (7)
C21—C5—Rb1120.67 (18)C5—Rb1—C25129.12 (7)
C1—C6—C5119.3 (2)C5—Rb1—C15i153.43 (6)
C1—C6—C7120.5 (2)C5—Rb1—C16i132.47 (6)
C5—C6—C7120.1 (2)C5—Rb1—C17i125.31 (6)
C1—C6—Rb169.92 (15)P1—Rb1—P1i66.92 (2)
C5—C6—Rb181.09 (15)
Symmetry codes: (i) x+1, y+1, z+1; (ii) x+1, y, z.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
P1—H1A···Rb1i1.09 (4)2.85 (4)3.8448 (8)151 (3)
Symmetry code: (i) x+1, y+1, z+1.
 

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