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A new ReI complex has been synthesized by reflux methods, viz. μ-ethyl­ene-1,2-di-4-pyridyl-κ2N:N′-bis­[fac-tri­carbonyl(4,4′-tert-butyl-2,2′-bi­pyridine)­rhenium(I)] hexa­fluoro­phos­phate di­chloro­methane disolvate, [Re(μ-C12H12N2)(C18H24N2)2(CO)6](PF6)2·2CH2Cl2. The compound is a centrosymmetric dinuclear complex. The self-assembled structure contains octahedral Re centers, connected by a 1,2-bis(4-pyridyl)­ethyl­ene linking group.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536803004094/lh6039sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536803004094/lh6039Isup2.hkl
Contains datablock I

CCDC reference: 206747

Key indicators

  • Single-crystal X-ray study
  • T = 110 K
  • Mean [sigma](C-C) = 0.007 Å
  • R factor = 0.035
  • wR factor = 0.099
  • Data-to-parameter ratio = 19.6

checkCIF results

No syntax errors found

ADDSYM reports no extra symmetry








Computing details top

Data collection: SMART (Bruker, 1999); cell refinement: SAINT (Bruker, 1999); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1990); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 (Farrugia, 1997) and ATOMS (Dowty, 1999); software used to prepare material for publication: SHELXL97.

µ-ethylene-1,2-di-4-pyridyl-κ2N:N'-bis[fac-tricarbonyl(4,4'-tert-butyl- 2,2'-bipyridine)rhenium(I)] hexafluorophosphate dichloromethane solvate top
Crystal data top
[Re(C12H12N2)(C18H24N2)2(CO)6](PF6)2·2CH2Cl2F(000) = 1692
Mr = 1721.28Dx = 1.791 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 6778 reflections
a = 12.0280 (7) Åθ = 5.1–62.8°
b = 10.2060 (6) ŵ = 4.09 mm1
c = 26.1366 (14) ÅT = 110 K
β = 95.695 (2)°Prism, light yellow
V = 3192.6 (3) Å30.35 × 0.24 × 0.18 mm
Z = 2
Data collection top
Bruker SMART Apex CCD
diffractometer
7907 independent reflections
Radiation source: fine-focus sealed tube7044 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.033
ω scansθmax = 28.3°, θmin = 1.8°
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)
h = 1615
Tmin = 0.342, Tmax = 0.479k = 1313
32788 measured reflectionsl = 3434
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.035Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.099H-atom parameters constrained
S = 1.05 w = 1/[σ2(Fo2) + (0.0534P)2 + 12.0416P]
where P = (Fo2 + 2Fc2)/3
7907 reflections(Δ/σ)max = 0.003
403 parametersΔρmax = 2.62 e Å3
0 restraintsΔρmin = 1.61 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles, correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Re10.21451 (1)0.29153 (2)0.79394 (1)0.01789 (6)
C10.2654 (3)0.3586 (4)0.73119 (16)0.0214 (8)
O10.2957 (3)0.3944 (3)0.69372 (13)0.0291 (7)
C20.1185 (4)0.1724 (4)0.75334 (17)0.0219 (8)
O20.0571 (3)0.1042 (3)0.72950 (13)0.0312 (7)
C30.3330 (4)0.1620 (4)0.79719 (17)0.0228 (8)
O30.4015 (3)0.0841 (3)0.80028 (14)0.0313 (7)
C40.2329 (4)0.1850 (5)0.90675 (19)0.0282 (9)
H40.30780.20530.90510.034*
N10.1583 (3)0.2145 (3)0.86650 (15)0.0219 (7)
C50.2012 (4)0.1255 (5)0.95036 (19)0.0309 (10)
H50.25450.10830.97780.037*
C60.0524 (4)0.1851 (5)0.87012 (18)0.0284 (9)
H60.00020.20640.84270.034*
C70.0152 (4)0.1244 (5)0.91234 (19)0.0320 (10)
H70.06030.10590.91320.038*
C80.0918 (4)0.0912 (5)0.95366 (18)0.0288 (9)
C90.0598 (4)0.0206 (6)1.00082 (18)0.0339 (11)
H9A0.10630.05681.00610.041*
H9B0.07670.07731.03040.041*
N20.0898 (3)0.4417 (3)0.80076 (13)0.0189 (7)
N30.2979 (3)0.4403 (3)0.84296 (13)0.0190 (7)
C100.0156 (4)0.4373 (4)0.77867 (17)0.0237 (8)
H100.03750.36440.75880.028*
C110.0933 (4)0.5345 (4)0.78362 (17)0.0245 (8)
H110.16570.52570.76790.029*
C120.0628 (3)0.6455 (4)0.81231 (16)0.0224 (8)
C130.0470 (3)0.6507 (4)0.83518 (16)0.0214 (8)
H130.07100.72370.85450.026*
C140.1208 (3)0.5489 (4)0.82947 (15)0.0184 (7)
C150.2383 (3)0.5483 (4)0.85309 (15)0.0184 (7)
C160.2853 (3)0.6500 (4)0.88320 (16)0.0211 (8)
H160.24220.72310.88920.025*
C170.3960 (3)0.6444 (4)0.90456 (15)0.0208 (8)
C180.4557 (3)0.5313 (4)0.89428 (16)0.0226 (8)
H180.52950.52180.90820.027*
C190.4051 (3)0.4337 (4)0.86351 (16)0.0217 (8)
H190.44690.36020.85670.026*
C200.1429 (4)0.7596 (5)0.82037 (19)0.0273 (9)
C210.2608 (4)0.7318 (6)0.7947 (2)0.0337 (11)
H21A0.28820.65180.80820.051*
H21B0.25850.72330.75830.051*
H21C0.30960.80270.80170.051*
C220.0983 (4)0.8851 (5)0.7969 (2)0.0381 (12)
H22A0.14770.95670.80200.057*
H22B0.09420.87230.76070.057*
H22C0.02520.90450.81330.057*
C230.1480 (5)0.7800 (6)0.8781 (2)0.0375 (12)
H23A0.17480.70140.89300.056*
H23B0.19770.85110.88350.056*
H23C0.07470.80010.89410.056*
C240.4519 (4)0.7553 (5)0.93672 (18)0.0262 (9)
C250.4925 (6)0.7007 (6)0.9904 (2)0.0444 (14)
H25A0.52830.76931.01110.067*
H25B0.54470.63090.98690.067*
H25C0.42980.66811.00650.067*
C260.5525 (6)0.8042 (6)0.9104 (3)0.0463 (15)
H26A0.52770.83420.87630.069*
H26B0.60490.73390.90830.069*
H26C0.58790.87500.92990.069*
C270.3723 (5)0.8697 (6)0.9431 (3)0.0490 (15)
H27A0.41070.93660.96380.073*
H27B0.30930.83940.95970.073*
H27C0.34700.90500.90990.073*
P10.67141 (12)0.19133 (14)0.87212 (6)0.0349 (3)
F10.6693 (3)0.3340 (4)0.89769 (16)0.0600 (10)
F20.7363 (3)0.1347 (4)0.92414 (14)0.0565 (10)
F30.7890 (3)0.2230 (4)0.85094 (16)0.0566 (10)
F40.6720 (3)0.0496 (4)0.84669 (15)0.0549 (9)
F50.6071 (3)0.2484 (4)0.82040 (13)0.0441 (8)
F60.5547 (3)0.1604 (4)0.89377 (13)0.0437 (8)
C280.8517 (8)0.4152 (9)0.9797 (4)0.080 (3)
H28A0.79710.35210.96510.096*
H28B0.89710.44170.95280.096*
Cl10.93614 (16)0.3422 (2)1.02952 (8)0.0671 (5)
Cl20.7824 (2)0.5526 (2)1.00162 (13)0.0985 (9)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Re10.01677 (9)0.01731 (9)0.01945 (9)0.00098 (5)0.00106 (6)0.00150 (6)
C10.0214 (19)0.020 (2)0.023 (2)0.0006 (15)0.0038 (15)0.0018 (15)
O10.0339 (18)0.0274 (17)0.0265 (16)0.0011 (13)0.0068 (13)0.0010 (13)
C20.023 (2)0.0205 (19)0.022 (2)0.0017 (16)0.0021 (16)0.0004 (16)
O20.0277 (17)0.0320 (18)0.0331 (18)0.0034 (14)0.0004 (14)0.0078 (14)
C30.0198 (19)0.024 (2)0.025 (2)0.0015 (16)0.0013 (16)0.0038 (16)
O30.0254 (16)0.0280 (17)0.0393 (19)0.0074 (13)0.0028 (14)0.0086 (14)
C40.026 (2)0.030 (2)0.027 (2)0.0005 (18)0.0020 (18)0.0052 (18)
N10.0207 (17)0.0217 (17)0.0226 (17)0.0025 (13)0.0010 (14)0.0003 (13)
C50.029 (2)0.035 (2)0.028 (2)0.001 (2)0.0043 (18)0.0072 (19)
C60.026 (2)0.035 (2)0.023 (2)0.0019 (18)0.0003 (17)0.0043 (18)
C70.023 (2)0.043 (3)0.030 (2)0.003 (2)0.0031 (18)0.010 (2)
C80.029 (2)0.033 (2)0.024 (2)0.0024 (18)0.0026 (18)0.0039 (18)
C90.032 (3)0.046 (3)0.023 (2)0.002 (2)0.0020 (19)0.010 (2)
N20.0178 (16)0.0218 (17)0.0169 (15)0.0003 (13)0.0000 (12)0.0001 (13)
N30.0164 (15)0.0196 (17)0.0212 (16)0.0003 (13)0.0022 (13)0.0011 (13)
C100.022 (2)0.023 (2)0.025 (2)0.0007 (16)0.0030 (16)0.0029 (16)
C110.0183 (19)0.027 (2)0.027 (2)0.0003 (16)0.0020 (16)0.0002 (17)
C120.0181 (19)0.025 (2)0.023 (2)0.0063 (16)0.0006 (15)0.0001 (16)
C130.0175 (19)0.022 (2)0.025 (2)0.0015 (15)0.0013 (15)0.0022 (16)
C140.0168 (18)0.0212 (19)0.0175 (18)0.0004 (15)0.0028 (14)0.0014 (15)
C150.0148 (17)0.0208 (19)0.0196 (18)0.0007 (14)0.0026 (14)0.0005 (15)
C160.0198 (19)0.021 (2)0.0228 (19)0.0010 (15)0.0012 (15)0.0018 (15)
C170.0208 (19)0.024 (2)0.0178 (18)0.0018 (16)0.0005 (15)0.0007 (15)
C180.0160 (18)0.028 (2)0.024 (2)0.0022 (16)0.0001 (15)0.0002 (17)
C190.0183 (19)0.022 (2)0.025 (2)0.0052 (15)0.0001 (15)0.0011 (16)
C200.019 (2)0.031 (2)0.031 (2)0.0097 (18)0.0015 (17)0.0029 (19)
C210.020 (2)0.043 (3)0.037 (3)0.009 (2)0.0027 (19)0.005 (2)
C220.034 (3)0.029 (3)0.052 (3)0.008 (2)0.001 (2)0.001 (2)
C230.031 (3)0.051 (3)0.031 (3)0.017 (2)0.001 (2)0.007 (2)
C240.022 (2)0.027 (2)0.029 (2)0.0033 (17)0.0004 (17)0.0071 (18)
C250.050 (3)0.046 (3)0.034 (3)0.001 (3)0.010 (3)0.007 (2)
C260.046 (3)0.042 (3)0.053 (4)0.018 (3)0.010 (3)0.005 (3)
C270.040 (3)0.039 (3)0.064 (4)0.002 (2)0.011 (3)0.024 (3)
P10.0293 (6)0.0424 (8)0.0330 (7)0.0142 (5)0.0026 (5)0.0008 (5)
F10.060 (2)0.052 (2)0.065 (3)0.0078 (19)0.0077 (19)0.0170 (19)
F20.0414 (19)0.084 (3)0.0429 (19)0.0211 (19)0.0013 (15)0.0160 (19)
F30.0306 (17)0.077 (3)0.062 (2)0.0101 (17)0.0073 (16)0.018 (2)
F40.063 (2)0.047 (2)0.056 (2)0.0194 (18)0.0135 (18)0.0058 (17)
F50.0368 (17)0.0559 (19)0.0386 (17)0.0125 (16)0.0008 (14)0.0077 (16)
F60.0353 (17)0.057 (2)0.0395 (17)0.0129 (15)0.0069 (13)0.0026 (15)
C280.083 (6)0.064 (5)0.084 (6)0.005 (4)0.035 (5)0.002 (4)
Cl10.0579 (10)0.0827 (13)0.0602 (11)0.0101 (9)0.0035 (8)0.0113 (10)
Cl20.0854 (16)0.0706 (14)0.145 (2)0.0225 (12)0.0412 (16)0.0296 (15)
Geometric parameters (Å, º) top
Re1—C21.922 (4)C17—C181.399 (6)
Re1—C11.932 (4)C17—C241.525 (6)
Re1—C31.939 (4)C18—C191.383 (6)
Re1—N22.164 (3)C18—H180.9300
Re1—N32.167 (3)C19—H190.9300
Re1—N12.220 (4)C20—C231.531 (7)
C1—O11.138 (5)C20—C211.534 (7)
C2—O21.152 (5)C20—C221.539 (8)
C3—O31.143 (5)C21—H21A0.9600
C4—N11.347 (6)C21—H21B0.9600
C4—C51.378 (7)C21—H21C0.9600
C4—H40.9300C22—H22A0.9600
N1—C61.321 (6)C22—H22B0.9600
C5—C81.373 (7)C22—H22C0.9600
C5—H50.9300C23—H23A0.9600
C6—C71.378 (6)C23—H23B0.9600
C6—H60.9300C23—H23C0.9600
C7—C81.390 (7)C24—C271.529 (7)
C7—H70.9300C24—C261.534 (7)
C8—C91.510 (6)C24—C251.542 (7)
C9—C9i1.495 (10)C25—H25A0.9600
C9—H9A0.9700C25—H25B0.9600
C9—H9B0.9700C25—H25C0.9600
N2—C101.340 (5)C26—H26A0.9600
N2—C141.358 (5)C26—H26B0.9600
N3—C191.348 (5)C26—H26C0.9600
N3—C151.355 (5)C27—H27A0.9600
C10—C111.378 (6)C27—H27B0.9600
C10—H100.9300C27—H27C0.9600
C11—C121.388 (6)P1—F41.592 (4)
C11—H110.9300P1—F61.597 (4)
C12—C131.396 (6)P1—F51.599 (3)
C12—C201.540 (6)P1—F31.602 (4)
C13—C141.384 (6)P1—F11.603 (4)
C13—H130.9300P1—F21.607 (4)
C14—C151.484 (5)C28—Cl11.738 (8)
C15—C161.389 (6)C28—Cl21.757 (10)
C16—C171.393 (6)C28—H28A0.9700
C16—H160.9300C28—H28B0.9700
C2—Re1—C188.79 (18)C17—C18—H18120.0
C2—Re1—C389.52 (18)N3—C19—C18123.0 (4)
C1—Re1—C389.16 (18)N3—C19—H19118.5
C2—Re1—N296.31 (16)C18—C19—H19118.5
C1—Re1—N295.71 (15)C23—C20—C21109.3 (4)
C3—Re1—N2172.47 (15)C23—C20—C22109.3 (4)
C2—Re1—N3170.71 (16)C21—C20—C22108.9 (4)
C1—Re1—N394.97 (16)C23—C20—C12108.9 (4)
C3—Re1—N399.01 (16)C21—C20—C12111.3 (4)
N2—Re1—N374.89 (13)C22—C20—C12109.1 (4)
C2—Re1—N191.74 (16)C20—C21—H21A109.5
C1—Re1—N1179.27 (16)C20—C21—H21B109.5
C3—Re1—N190.35 (16)H21A—C21—H21B109.5
N2—Re1—N184.72 (13)C20—C21—H21C109.5
N3—Re1—N184.58 (13)H21A—C21—H21C109.5
O1—C1—Re1177.9 (4)H21B—C21—H21C109.5
O2—C2—Re1177.1 (4)C20—C22—H22A109.5
O3—C3—Re1178.0 (4)C20—C22—H22B109.5
N1—C4—C5121.8 (4)H22A—C22—H22B109.5
N1—C4—H4119.1C20—C22—H22C109.5
C5—C4—H4119.1H22A—C22—H22C109.5
C6—N1—C4117.7 (4)H22B—C22—H22C109.5
C6—N1—Re1121.3 (3)C20—C23—H23A109.5
C4—N1—Re1120.7 (3)C20—C23—H23B109.5
C8—C5—C4120.6 (4)H23A—C23—H23B109.5
C8—C5—H5119.7C20—C23—H23C109.5
C4—C5—H5119.7H23A—C23—H23C109.5
N1—C6—C7123.4 (4)H23B—C23—H23C109.5
N1—C6—H6118.3C17—C24—C27112.4 (4)
C7—C6—H6118.3C17—C24—C26108.5 (4)
C6—C7—C8119.3 (4)C27—C24—C26109.3 (5)
C6—C7—H7120.3C17—C24—C25108.4 (4)
C8—C7—H7120.3C27—C24—C25108.8 (5)
C5—C8—C7117.0 (4)C26—C24—C25109.4 (5)
C5—C8—C9119.7 (4)C24—C25—H25A109.5
C7—C8—C9123.2 (4)C24—C25—H25B109.5
C9i—C9—C8115.7 (5)H25A—C25—H25B109.5
C9i—C9—H9A108.4C24—C25—H25C109.5
C8—C9—H9A108.4H25A—C25—H25C109.5
C9i—C9—H9B108.4H25B—C25—H25C109.5
C8—C9—H9B108.4C24—C26—H26A109.5
H9A—C9—H9B107.4C24—C26—H26B109.5
C10—N2—C14117.5 (4)H26A—C26—H26B109.5
C10—N2—Re1125.1 (3)C24—C26—H26C109.5
C14—N2—Re1117.5 (3)H26A—C26—H26C109.5
C19—N3—C15117.8 (4)H26B—C26—H26C109.5
C19—N3—Re1124.7 (3)C24—C27—H27A109.5
C15—N3—Re1117.5 (3)C24—C27—H27B109.5
N2—C10—C11123.8 (4)H27A—C27—H27B109.5
N2—C10—H10118.1C24—C27—H27C109.5
C11—C10—H10118.1H27A—C27—H27C109.5
C10—C11—C12119.5 (4)H27B—C27—H27C109.5
C10—C11—H11120.2F4—P1—F690.5 (2)
C12—C11—H11120.2F4—P1—F590.0 (2)
C11—C12—C13116.8 (4)F6—P1—F590.18 (19)
C11—C12—C20123.8 (4)F4—P1—F389.9 (2)
C13—C12—C20119.4 (4)F6—P1—F3179.4 (2)
C14—C13—C12121.0 (4)F5—P1—F390.2 (2)
C14—C13—H13119.5F4—P1—F1179.3 (2)
C12—C13—H13119.5F6—P1—F188.9 (2)
N2—C14—C13121.3 (4)F5—P1—F189.7 (2)
N2—C14—C15115.1 (3)F3—P1—F190.7 (2)
C13—C14—C15123.5 (4)F4—P1—F290.3 (2)
N3—C15—C16121.7 (4)F6—P1—F289.97 (19)
N3—C15—C14115.0 (4)F5—P1—F2179.7 (3)
C16—C15—C14123.3 (4)F3—P1—F289.6 (2)
C15—C16—C17121.0 (4)F1—P1—F290.0 (2)
C15—C16—H16119.5Cl1—C28—Cl2111.0 (5)
C17—C16—H16119.5Cl1—C28—H28A109.4
C16—C17—C18116.4 (4)Cl2—C28—H28A109.4
C16—C17—C24122.8 (4)Cl1—C28—H28B109.4
C18—C17—C24120.7 (4)Cl2—C28—H28B109.4
C19—C18—C17120.1 (4)H28A—C28—H28B108.0
C19—C18—H18120.0
C5—C4—N1—C60.4 (7)C10—C11—C12—C20179.9 (4)
C5—C4—N1—Re1173.7 (4)C11—C12—C13—C140.4 (6)
C2—Re1—N1—C640.4 (4)C20—C12—C13—C14178.9 (4)
C3—Re1—N1—C6129.9 (4)C10—N2—C14—C130.8 (6)
N2—Re1—N1—C655.8 (4)Re1—N2—C14—C13178.9 (3)
N3—Re1—N1—C6131.1 (4)C10—N2—C14—C15179.9 (4)
C2—Re1—N1—C4133.5 (4)Re1—N2—C14—C150.4 (4)
C3—Re1—N1—C443.9 (4)C12—C13—C14—N21.2 (6)
N2—Re1—N1—C4130.4 (4)C12—C13—C14—C15179.6 (4)
N3—Re1—N1—C455.1 (3)C19—N3—C15—C160.6 (6)
N1—C4—C5—C81.6 (8)Re1—N3—C15—C16178.6 (3)
C4—N1—C6—C71.0 (7)C19—N3—C15—C14179.8 (4)
Re1—N1—C6—C7173.0 (4)Re1—N3—C15—C141.0 (4)
N1—C6—C7—C80.2 (8)N2—C14—C15—N30.4 (5)
C4—C5—C8—C72.7 (8)C13—C14—C15—N3179.7 (4)
C4—C5—C8—C9177.2 (5)N2—C14—C15—C16179.3 (4)
C6—C7—C8—C52.0 (8)C13—C14—C15—C160.0 (6)
C6—C7—C8—C9177.9 (5)N3—C15—C16—C170.5 (6)
C5—C8—C9—C9i175.9 (6)C14—C15—C16—C17179.9 (4)
C7—C8—C9—C9i4.0 (9)C15—C16—C17—C180.4 (6)
C2—Re1—N2—C102.6 (4)C15—C16—C17—C24178.4 (4)
C1—Re1—N2—C1086.8 (4)C16—C17—C18—C191.2 (6)
N3—Re1—N2—C10179.6 (4)C24—C17—C18—C19177.6 (4)
N1—Re1—N2—C1093.8 (4)C15—N3—C19—C180.3 (6)
C2—Re1—N2—C14177.7 (3)Re1—N3—C19—C18179.4 (3)
C1—Re1—N2—C1492.9 (3)C17—C18—C19—N31.2 (7)
N3—Re1—N2—C140.7 (3)C11—C12—C20—C23123.1 (5)
N1—Re1—N2—C1486.5 (3)C13—C12—C20—C2356.2 (6)
C1—Re1—N3—C1985.5 (4)C11—C12—C20—C212.5 (6)
C3—Re1—N3—C194.4 (4)C13—C12—C20—C21176.8 (4)
N2—Re1—N3—C19179.9 (4)C11—C12—C20—C22117.7 (5)
N1—Re1—N3—C1993.9 (3)C13—C12—C20—C2263.0 (5)
C1—Re1—N3—C1593.6 (3)C16—C17—C24—C270.9 (7)
C3—Re1—N3—C15176.4 (3)C18—C17—C24—C27179.7 (5)
N2—Re1—N3—C151.0 (3)C16—C17—C24—C26120.1 (5)
N1—Re1—N3—C1586.9 (3)C18—C17—C24—C2658.7 (6)
C14—N2—C10—C110.3 (6)C16—C17—C24—C25121.1 (5)
Re1—N2—C10—C11179.9 (3)C18—C17—C24—C2560.1 (6)
N2—C10—C11—C121.0 (7)C8—C9—C9i—C8i180.000 (3)
C10—C11—C12—C130.6 (6)
Symmetry code: (i) x, y, z+2.
 

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