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The crystal structure of the cluster compound, trans-[Re6Se8(MeCN)2(Et3P)4](SbF6)2, originally determined at room temperature [Zheng, Gray & Holm (1999). Inorg. Chem. 38, 4888–4895], has been redetermined at 150 K. The cation lies on a crystallographic inversion center, and the SbF6 counter-ions are fully ordered.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536807004989/lh2304sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536807004989/lh2304Isup2.hkl
Contains datablock I

CCDC reference: 640413

Key indicators

  • Single-crystal X-ray study
  • T = 150 K
  • Mean [sigma](C-C) = 0.008 Å
  • R factor = 0.023
  • wR factor = 0.045
  • Data-to-parameter ratio = 22.9

checkCIF/PLATON results

No syntax errors found



Alert level C PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT063_ALERT_3_C Crystal Probably too Large for Beam Size ....... 0.62 mm PLAT153_ALERT_1_C The su's on the Cell Axes are Equal (x 100000) . 300 Ang. PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Re1 - Se1 .. 9.04 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Re1 - Se2 .. 7.52 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Re1 - Se3 .. 6.86 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Re1 - Se4 .. 7.26 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Re2 - Se2 .. 9.22 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Re2 - Se4 .. 8.69 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Re2 - Se1_a .. 9.44 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Re2 - Se3_a .. 9.30 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Re3 - Se3 .. 9.23 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Re3 - Se4 .. 6.99 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Re3 - Se1_a .. 7.16 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Re3 - Se2_a .. 6.91 su PLAT244_ALERT_4_C Low 'Solvent' Ueq as Compared to Neighbors for Sb1 PLAT432_ALERT_2_C Short Inter X...Y Contact F3 .. C13 .. 2.95 Ang. PLAT764_ALERT_4_C Overcomplete CIF Bond List Detected (Rep/Expd) . 1.17 Ratio
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 18 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 13 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 2 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check

Computing details top

Data collection: COLLECT (Nonius, 1998); cell refinement: EVALCCD (Duisenberg et al., 2003); data reduction: EVALCCD; program(s) used to solve structure: using known coordinates (Reference?); program(s) used to refine structure: SHELXTL (Sheldrick, 2001); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997); software used to prepare material for publication: SHELXTL and local programs.

bis(acetonitrile-κN)octa-µ3selenido-tetrakis(triethylphosphine- κP)hexarhenium(III) top
Crystal data top
[Re6Se8(C2H3N)2(C6H15P)4](SbF6)2F(000) = 2480
Mr = 2775.09Dx = 3.185 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 17172 reflections
a = 13.010 (3) Åθ = 2.5–27.5°
b = 17.155 (3) ŵ = 18.62 mm1
c = 13.438 (3) ÅT = 150 K
β = 105.24 (3)°Prism, orange
V = 2893.8 (10) Å30.62 × 0.42 × 0.40 mm
Z = 2
Data collection top
Nonius KappaCCD area-detector
diffractometer
6605 independent reflections
Radiation source: sealed tube5470 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.039
φ and ω scansθmax = 27.5°, θmin = 4.6°
Absorption correction: gaussian
(SADABS; Sheldrick, 2006)
h = 1616
Tmin = 0.031, Tmax = 0.050k = 2122
30352 measured reflectionsl = 1417
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.024H-atom parameters constrained
wR(F2) = 0.045 w = 1/[σ2(Fo2) + 7.3346P]
where P = (Fo2 + 2Fc2)/3
S = 1.14(Δ/σ)max = 0.002
6605 reflectionsΔρmax = 0.80 e Å3
288 parametersΔρmin = 1.01 e Å3
0 restraintsExtinction correction: SHELXTL (Sheldrick, 2001), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
Primary atom site location: using known coordinatesExtinction coefficient: 0.000341 (16)
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Re10.639696 (13)0.533058 (11)0.560393 (14)0.01103 (5)
Re20.449147 (14)0.598005 (11)0.524497 (14)0.01107 (5)
Re30.511667 (14)0.533872 (11)0.372036 (14)0.01126 (5)
Se10.66998 (3)0.40526 (3)0.65705 (4)0.01443 (10)
Se20.57342 (4)0.59239 (3)0.70395 (4)0.01448 (10)
Se30.69244 (4)0.47042 (3)0.41186 (4)0.01476 (10)
Se40.59530 (4)0.65752 (3)0.45748 (4)0.01462 (10)
P10.82377 (9)0.57933 (7)0.64057 (10)0.0149 (3)
P20.37905 (9)0.72502 (7)0.56445 (10)0.0146 (3)
N10.5254 (3)0.5711 (2)0.2262 (3)0.0151 (9)
C10.8958 (4)0.5289 (3)0.7580 (4)0.0225 (12)
H1A0.89930.47280.74190.027*
H1B0.96980.54890.77810.027*
C20.8495 (5)0.5366 (4)0.8501 (4)0.0326 (14)
H2A0.84180.59190.86490.049*
H2B0.89720.51150.91030.049*
H2C0.77950.51130.83450.049*
C30.9178 (4)0.5694 (3)0.5620 (4)0.0228 (12)
H3A0.98980.58300.60490.027*
H3B0.91960.51400.54160.027*
C40.8933 (4)0.6196 (4)0.4644 (4)0.0318 (14)
H4A0.82050.60910.42310.048*
H4B0.94370.60710.42390.048*
H4C0.89990.67480.48360.048*
C50.8285 (4)0.6833 (3)0.6753 (4)0.0232 (12)
H5A0.79700.71370.61200.028*
H5B0.78280.69140.72290.028*
C60.9390 (4)0.7167 (3)0.7261 (5)0.0323 (14)
H6A0.97110.68780.78960.048*
H6B0.93230.77180.74260.048*
H6C0.98430.71190.67860.048*
C70.2559 (4)0.7573 (3)0.4713 (4)0.0211 (11)
H7A0.24020.81130.48870.025*
H7B0.26840.75830.40180.025*
C80.1574 (4)0.7066 (3)0.4672 (4)0.0285 (13)
H8A0.16920.65400.44380.043*
H8B0.09490.72970.41900.043*
H8C0.14530.70370.53610.043*
C90.3480 (4)0.7250 (3)0.6890 (4)0.0212 (11)
H9A0.29990.68040.69010.025*
H9B0.41490.71520.74290.025*
C100.2969 (5)0.7976 (4)0.7188 (5)0.0402 (16)
H10A0.34370.84250.71940.060*
H10B0.28580.79070.78760.060*
H10C0.22820.80670.66870.060*
C110.4646 (4)0.8098 (3)0.5668 (4)0.0204 (11)
H11A0.48140.81360.49920.024*
H11B0.42430.85720.57510.024*
C120.5696 (4)0.8091 (3)0.6519 (5)0.0297 (14)
H12A0.55460.81540.71920.045*
H12B0.61500.85200.64070.045*
H12C0.60630.75940.65030.045*
C130.5351 (4)0.5874 (3)0.1478 (4)0.0206 (11)
C140.5478 (4)0.6082 (4)0.0466 (4)0.0337 (15)
H14A0.62170.59920.04500.051*
H14B0.52990.66330.03280.051*
H14C0.50010.57600.00620.051*
Sb10.73332 (3)0.91633 (2)0.39924 (3)0.02375 (9)
F10.7830 (4)0.8151 (2)0.4290 (4)0.0704 (14)
F20.8103 (3)0.9449 (3)0.5322 (3)0.0697 (14)
F30.8542 (3)0.9374 (2)0.3531 (3)0.0460 (10)
F40.6602 (3)0.8872 (3)0.2656 (3)0.0634 (13)
F50.6120 (3)0.8954 (2)0.4439 (3)0.0502 (10)
F60.6871 (4)1.0185 (2)0.3723 (4)0.0855 (17)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Re10.01019 (9)0.01073 (10)0.01163 (10)0.00072 (7)0.00191 (7)0.00061 (8)
Re20.01140 (9)0.00994 (10)0.01146 (10)0.00004 (7)0.00230 (7)0.00060 (8)
Re30.01176 (9)0.01113 (10)0.01079 (10)0.00032 (7)0.00276 (7)0.00004 (8)
Se10.0140 (2)0.0139 (2)0.0142 (2)0.00134 (18)0.00157 (17)0.0007 (2)
Se20.0156 (2)0.0142 (2)0.0129 (2)0.00072 (18)0.00240 (18)0.0024 (2)
Se30.0137 (2)0.0156 (2)0.0158 (2)0.00021 (18)0.00523 (17)0.0011 (2)
Se40.0150 (2)0.0120 (2)0.0165 (2)0.00182 (18)0.00345 (18)0.0006 (2)
P10.0123 (6)0.0155 (6)0.0154 (6)0.0016 (5)0.0011 (5)0.0000 (5)
P20.0169 (6)0.0134 (6)0.0135 (6)0.0012 (5)0.0040 (5)0.0007 (5)
N10.017 (2)0.011 (2)0.018 (2)0.0004 (16)0.0061 (16)0.0020 (18)
C10.014 (2)0.027 (3)0.023 (3)0.000 (2)0.003 (2)0.003 (2)
C20.032 (3)0.042 (4)0.020 (3)0.006 (3)0.001 (2)0.005 (3)
C30.015 (2)0.029 (3)0.027 (3)0.002 (2)0.009 (2)0.001 (3)
C40.028 (3)0.041 (4)0.027 (3)0.005 (3)0.009 (2)0.005 (3)
C50.019 (3)0.020 (3)0.028 (3)0.000 (2)0.001 (2)0.001 (2)
C60.024 (3)0.023 (3)0.044 (4)0.005 (2)0.001 (3)0.007 (3)
C70.022 (3)0.019 (3)0.022 (3)0.007 (2)0.005 (2)0.001 (2)
C80.020 (3)0.031 (3)0.032 (3)0.005 (2)0.003 (2)0.008 (3)
C90.030 (3)0.018 (3)0.017 (3)0.000 (2)0.008 (2)0.003 (2)
C100.068 (5)0.033 (4)0.022 (3)0.017 (3)0.015 (3)0.002 (3)
C110.027 (3)0.014 (3)0.021 (3)0.002 (2)0.006 (2)0.002 (2)
C120.029 (3)0.021 (3)0.035 (4)0.012 (2)0.003 (2)0.009 (3)
C130.019 (3)0.019 (3)0.022 (3)0.002 (2)0.002 (2)0.000 (2)
C140.030 (3)0.050 (4)0.020 (3)0.016 (3)0.005 (2)0.009 (3)
Sb10.01872 (17)0.0293 (2)0.0237 (2)0.00210 (14)0.00649 (14)0.00040 (17)
F10.083 (3)0.045 (3)0.091 (4)0.020 (2)0.036 (3)0.022 (3)
F20.035 (2)0.135 (4)0.038 (2)0.001 (2)0.0072 (17)0.038 (3)
F30.0253 (18)0.080 (3)0.036 (2)0.0141 (18)0.0136 (15)0.002 (2)
F40.032 (2)0.122 (4)0.035 (2)0.016 (2)0.0068 (17)0.023 (2)
F50.0293 (19)0.084 (3)0.044 (2)0.0110 (19)0.0200 (16)0.005 (2)
F60.080 (3)0.038 (3)0.144 (5)0.022 (2)0.037 (3)0.025 (3)
Geometric parameters (Å, º) top
Re1—Re22.6440 (6)C3—H3A0.9900
Re1—Re2i2.6457 (5)C3—H3B0.9900
Re1—Re32.6392 (9)C3—C41.532 (7)
Re1—Re3i2.6383 (6)C4—H4A0.9800
Re1—Se12.5259 (6)C4—H4B0.9800
Re1—Se22.5250 (7)C4—H4C0.9800
Re1—Se32.5159 (7)C5—H5A0.9900
Re1—Se42.5269 (7)C5—H5B0.9900
Re1—P12.4839 (13)C5—C61.531 (7)
Re2—Re1i2.6457 (5)C6—H6A0.9800
Re2—Re32.6355 (6)C6—H6B0.9800
Re2—Re3i2.6341 (5)C6—H6C0.9800
Re2—Se1i2.5239 (10)C7—H7A0.9900
Re2—Se22.5278 (10)C7—H7B0.9900
Re2—Se3i2.5161 (7)C7—C81.537 (7)
Re2—Se42.5237 (7)C8—H8A0.9800
Re2—P22.4749 (13)C8—H8B0.9800
Re3—Re1i2.6383 (6)C8—H8C0.9800
Re3—Re2i2.6342 (5)C9—H9A0.9900
Re3—Se1i2.5184 (7)C9—H9B0.9900
Re3—Se2i2.5231 (7)C9—C101.515 (7)
Re3—Se32.5181 (7)C10—H10A0.9800
Re3—Se42.5188 (7)C10—H10B0.9800
Re3—N12.113 (4)C10—H10C0.9800
Se1—Re2i2.5239 (10)C11—H11A0.9900
Se1—Re3i2.5184 (7)C11—H11B0.9900
Se2—Re3i2.5232 (7)C11—C121.534 (7)
Se3—Re2i2.5161 (7)C12—H12A0.9800
P1—C11.828 (5)C12—H12B0.9800
P1—C31.822 (5)C12—H12C0.9800
P1—C51.841 (5)C13—C141.457 (7)
P2—C71.840 (5)C14—H14A0.9800
P2—C91.822 (5)C14—H14B0.9800
P2—C111.827 (5)C14—H14C0.9800
N1—C131.129 (6)Sb1—F11.860 (4)
C1—H1A0.9900Sb1—F21.870 (4)
C1—H1B0.9900Sb1—F31.872 (3)
C1—C21.518 (8)Sb1—F41.865 (4)
C2—H2A0.9800Sb1—F51.866 (3)
C2—H2B0.9800Sb1—F61.857 (4)
C2—H2C0.9800
Re2—Re1—Re2i89.829 (19)Re1—Se3—Re2i63.44 (2)
Re2—Re1—Re359.85 (2)Re1—Se3—Re363.24 (3)
Re2—Re1—Re3i59.824 (15)Re2i—Se3—Re363.102 (18)
Re2i—Re1—Re3i59.835 (13)Re1—Se4—Re263.137 (18)
Re2i—Re1—Re359.792 (14)Re1—Se4—Re363.07 (2)
Re2—Re1—Se1118.139 (19)Re2—Se4—Re363.021 (16)
Re2i—Re1—Se158.37 (2)Re1—P1—C1116.14 (17)
Re2—Re1—Se258.50 (2)Re1—P1—C3115.88 (18)
Re2i—Re1—Se2118.283 (17)Re1—P1—C5112.56 (16)
Re2—Re1—Se3118.25 (3)C1—P1—C3100.7 (2)
Re2i—Re1—Se358.283 (16)C1—P1—C5105.3 (2)
Re2—Re1—Se458.372 (19)C3—P1—C5104.8 (3)
Re2i—Re1—Se4118.10 (2)Re2—P2—C7114.97 (17)
Re2—Re1—P1134.05 (3)Re2—P2—C9112.47 (17)
Re2i—Re1—P1136.12 (3)Re2—P2—C11116.55 (18)
Re3—Re1—Re3i89.56 (2)C7—P2—C9105.1 (2)
Re3—Re1—Se1118.139 (15)C7—P2—C11100.9 (2)
Re3i—Re1—Se158.326 (16)C9—P2—C11105.4 (2)
Re3—Re1—Se2118.326 (18)Re3—N1—C13176.5 (4)
Re3i—Re1—Se258.46 (2)P1—C1—H1A108.3
Re3—Re1—Se358.422 (17)P1—C1—H1B108.3
Re3i—Re1—Se3118.10 (2)P1—C1—C2116.1 (4)
Re3—Re1—Se458.314 (15)H1A—C1—H1B107.4
Re3i—Re1—Se4118.175 (18)H1A—C1—C2108.3
Re3—Re1—P1135.06 (4)H1B—C1—C2108.3
Re3i—Re1—P1135.36 (3)C1—C2—H2A109.5
Se1—Re1—Se289.74 (2)C1—C2—H2B109.5
Se1—Re1—Se389.95 (2)C1—C2—H2C109.5
Se1—Re1—Se4175.697 (16)H2A—C2—H2B109.5
Se1—Re1—P192.98 (4)H2A—C2—H2C109.5
Se2—Re1—Se3175.91 (4)H2B—C2—H2C109.5
Se2—Re1—Se490.16 (2)P1—C3—H3A108.5
Se2—Re1—P191.35 (4)P1—C3—H3B108.5
Se3—Re1—Se489.85 (2)P1—C3—C4115.0 (4)
Se3—Re1—P192.74 (4)H3A—C3—H3B107.5
Se4—Re1—P191.32 (4)H3A—C3—C4108.5
Re1—Re2—Re1i90.17 (2)H3B—C3—C4108.5
Re1—Re2—Re359.99 (2)C3—C4—H4A109.5
Re1—Re2—Re3i59.979 (15)C3—C4—H4B109.5
Re1i—Re2—Re3i59.98 (2)C3—C4—H4C109.5
Re1i—Re2—Re359.942 (13)H4A—C4—H4B109.5
Re1—Re2—Se1i118.37 (3)H4A—C4—H4C109.5
Re1i—Re2—Se1i58.441 (16)H4B—C4—H4C109.5
Re1—Re2—Se258.40 (2)P1—C5—H5A108.3
Re1i—Re2—Se2118.453 (18)P1—C5—H5B108.3
Re1—Re2—Se3i118.457 (19)P1—C5—C6116.1 (4)
Re1i—Re2—Se3i58.276 (17)H5A—C5—H5B107.4
Re1—Re2—Se458.491 (18)H5A—C5—C6108.3
Re1i—Re2—Se4118.336 (17)H5B—C5—C6108.3
Re1—Re2—P2135.45 (3)C5—C6—H6A109.5
Re1i—Re2—P2134.24 (3)C5—C6—H6B109.5
Re3—Re2—Re3i89.732 (14)C5—C6—H6C109.5
Re3i—Re2—Se1i118.402 (16)H6A—C6—H6B109.5
Re3—Re2—Se1i58.386 (17)H6A—C6—H6C109.5
Re3—Re2—Se2118.364 (19)H6B—C6—H6C109.5
Re3i—Re2—Se258.481 (14)P2—C7—H7A108.5
Re3i—Re2—Se3i58.488 (17)P2—C7—H7B108.5
Re3—Re2—Se3i118.20 (2)P2—C7—C8115.0 (4)
Re3—Re2—Se458.40 (2)H7A—C7—H7B107.5
Re3i—Re2—Se4118.449 (17)H7A—C7—C8108.5
Re3—Re2—P2137.97 (3)H7B—C7—C8108.5
Re3i—Re2—P2132.29 (3)C7—C8—H8A109.5
Se1i—Re2—Se2176.107 (18)C7—C8—H8B109.5
Se1i—Re2—Se3i89.99 (3)C7—C8—H8C109.5
Se1i—Re2—Se489.59 (3)H8A—C8—H8B109.5
Se1i—Re2—P293.53 (3)H8A—C8—H8C109.5
Se2—Re2—Se3i89.99 (3)H8B—C8—H8C109.5
Se2—Re2—Se490.17 (3)P2—C9—H9A107.9
Se2—Re2—P290.36 (3)P2—C9—H9B107.9
Se3i—Re2—Se4176.040 (18)P2—C9—C10117.5 (4)
Se3i—Re2—P289.57 (4)H9A—C9—H9B107.2
Se4—Re2—P294.38 (4)H9A—C9—C10107.9
Re1—Re3—Re1i90.44 (2)H9B—C9—C10107.9
Re1—Re3—Re260.168 (15)C9—C10—H10A109.5
Re1i—Re3—Re2i60.195 (13)C9—C10—H10B109.5
Re1i—Re3—Re260.221 (18)C9—C10—H10C109.5
Re1—Re3—Re2i60.227 (11)H10A—C10—H10B109.5
Re1i—Re3—Se1i58.603 (18)H10A—C10—H10C109.5
Re1—Re3—Se1i118.75 (3)H10B—C10—H10C109.5
Re1i—Re3—Se2i58.527 (17)P2—C11—H11A108.5
Re1—Re3—Se2i118.871 (18)P2—C11—H11B108.5
Re1—Re3—Se358.34 (2)P2—C11—C12115.2 (4)
Re1i—Re3—Se3118.596 (19)H11A—C11—H11B107.5
Re1—Re3—Se458.611 (17)H11A—C11—C12108.5
Re1i—Re3—Se4118.794 (18)H11B—C11—C12108.5
Re1—Re3—N1134.86 (10)C11—C12—H12A109.5
Re1i—Re3—N1134.70 (10)C11—C12—H12B109.5
Re2—Re3—Re2i90.266 (15)C11—C12—H12C109.5
Re2i—Re3—Se1i118.79 (2)H12A—C12—H12B109.5
Re2—Re3—Se1i58.59 (3)H12A—C12—H12C109.5
Re2i—Re3—Se2i58.65 (2)H12B—C12—H12C109.5
Re2—Re3—Se2i118.738 (18)N1—C13—C14179.8 (6)
Re2—Re3—Se3118.49 (3)C13—C14—H14A109.5
Re2i—Re3—Se358.412 (18)C13—C14—H14B109.5
Re2—Re3—Se458.579 (17)C13—C14—H14C109.5
Re2i—Re3—Se4118.83 (2)H14A—C14—H14B109.5
Re2—Re3—N1135.53 (11)H14A—C14—H14C109.5
Re2i—Re3—N1134.20 (11)H14B—C14—H14C109.5
Se1i—Re3—Se2i89.95 (2)F1—Sb1—F288.3 (2)
Se1i—Re3—Se3176.492 (18)F1—Sb1—F388.65 (19)
Se1i—Re3—Se489.82 (2)F1—Sb1—F491.0 (2)
Se1i—Re3—N192.03 (11)F1—Sb1—F591.6 (2)
Se2i—Re3—Se390.05 (2)F1—Sb1—F6178.4 (2)
Se2i—Re3—Se4176.806 (18)F2—Sb1—F388.87 (17)
Se2i—Re3—N191.08 (11)F2—Sb1—F4178.32 (17)
Se3—Re3—Se489.99 (2)F2—Sb1—F591.66 (17)
Se3—Re3—N191.48 (11)F2—Sb1—F690.2 (2)
Se4—Re3—N192.11 (11)F3—Sb1—F489.60 (17)
Re1—Se1—Re2i63.192 (15)F3—Sb1—F5179.44 (16)
Re1—Se1—Re3i63.071 (19)F3—Sb1—F690.6 (2)
Re2i—Se1—Re3i63.02 (3)F4—Sb1—F589.88 (17)
Re1—Se2—Re263.105 (18)F4—Sb1—F690.4 (2)
Re1—Se2—Re3i63.016 (17)F5—Sb1—F689.2 (2)
Re2—Se2—Re3i62.868 (17)
Symmetry code: (i) x+1, y+1, z+1.
 

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