Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536807004989/lh2304sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536807004989/lh2304Isup2.hkl |
CCDC reference: 640413
Key indicators
- Single-crystal X-ray study
- T = 150 K
- Mean (C-C) = 0.008 Å
- R factor = 0.023
- wR factor = 0.045
- Data-to-parameter ratio = 22.9
checkCIF/PLATON results
No syntax errors found
Alert level C PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT063_ALERT_3_C Crystal Probably too Large for Beam Size ....... 0.62 mm PLAT153_ALERT_1_C The su's on the Cell Axes are Equal (x 100000) . 300 Ang. PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Re1 - Se1 .. 9.04 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Re1 - Se2 .. 7.52 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Re1 - Se3 .. 6.86 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Re1 - Se4 .. 7.26 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Re2 - Se2 .. 9.22 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Re2 - Se4 .. 8.69 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Re2 - Se1_a .. 9.44 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Re2 - Se3_a .. 9.30 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Re3 - Se3 .. 9.23 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Re3 - Se4 .. 6.99 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Re3 - Se1_a .. 7.16 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Re3 - Se2_a .. 6.91 su PLAT244_ALERT_4_C Low 'Solvent' Ueq as Compared to Neighbors for Sb1 PLAT432_ALERT_2_C Short Inter X...Y Contact F3 .. C13 .. 2.95 Ang. PLAT764_ALERT_4_C Overcomplete CIF Bond List Detected (Rep/Expd) . 1.17 Ratio
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 18 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 13 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 2 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check
Data collection: COLLECT (Nonius, 1998); cell refinement: EVALCCD (Duisenberg et al., 2003); data reduction: EVALCCD; program(s) used to solve structure: using known coordinates (Reference?); program(s) used to refine structure: SHELXTL (Sheldrick, 2001); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997); software used to prepare material for publication: SHELXTL and local programs.
[Re6Se8(C2H3N)2(C6H15P)4](SbF6)2 | F(000) = 2480 |
Mr = 2775.09 | Dx = 3.185 Mg m−3 |
Monoclinic, P21/n | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -P 2yn | Cell parameters from 17172 reflections |
a = 13.010 (3) Å | θ = 2.5–27.5° |
b = 17.155 (3) Å | µ = 18.62 mm−1 |
c = 13.438 (3) Å | T = 150 K |
β = 105.24 (3)° | Prism, orange |
V = 2893.8 (10) Å3 | 0.62 × 0.42 × 0.40 mm |
Z = 2 |
Nonius KappaCCD area-detector diffractometer | 6605 independent reflections |
Radiation source: sealed tube | 5470 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.039 |
φ and ω scans | θmax = 27.5°, θmin = 4.6° |
Absorption correction: gaussian (SADABS; Sheldrick, 2006) | h = −16→16 |
Tmin = 0.031, Tmax = 0.050 | k = −21→22 |
30352 measured reflections | l = −14→17 |
Refinement on F2 | Secondary atom site location: difference Fourier map |
Least-squares matrix: full | Hydrogen site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.024 | H-atom parameters constrained |
wR(F2) = 0.045 | w = 1/[σ2(Fo2) + 7.3346P] where P = (Fo2 + 2Fc2)/3 |
S = 1.14 | (Δ/σ)max = 0.002 |
6605 reflections | Δρmax = 0.80 e Å−3 |
288 parameters | Δρmin = −1.01 e Å−3 |
0 restraints | Extinction correction: SHELXTL (Sheldrick, 2001), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4 |
Primary atom site location: using known coordinates | Extinction coefficient: 0.000341 (16) |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Re1 | 0.639696 (13) | 0.533058 (11) | 0.560393 (14) | 0.01103 (5) | |
Re2 | 0.449147 (14) | 0.598005 (11) | 0.524497 (14) | 0.01107 (5) | |
Re3 | 0.511667 (14) | 0.533872 (11) | 0.372036 (14) | 0.01126 (5) | |
Se1 | 0.66998 (3) | 0.40526 (3) | 0.65705 (4) | 0.01443 (10) | |
Se2 | 0.57342 (4) | 0.59239 (3) | 0.70395 (4) | 0.01448 (10) | |
Se3 | 0.69244 (4) | 0.47042 (3) | 0.41186 (4) | 0.01476 (10) | |
Se4 | 0.59530 (4) | 0.65752 (3) | 0.45748 (4) | 0.01462 (10) | |
P1 | 0.82377 (9) | 0.57933 (7) | 0.64057 (10) | 0.0149 (3) | |
P2 | 0.37905 (9) | 0.72502 (7) | 0.56445 (10) | 0.0146 (3) | |
N1 | 0.5254 (3) | 0.5711 (2) | 0.2262 (3) | 0.0151 (9) | |
C1 | 0.8958 (4) | 0.5289 (3) | 0.7580 (4) | 0.0225 (12) | |
H1A | 0.8993 | 0.4728 | 0.7419 | 0.027* | |
H1B | 0.9698 | 0.5489 | 0.7781 | 0.027* | |
C2 | 0.8495 (5) | 0.5366 (4) | 0.8501 (4) | 0.0326 (14) | |
H2A | 0.8418 | 0.5919 | 0.8649 | 0.049* | |
H2B | 0.8972 | 0.5115 | 0.9103 | 0.049* | |
H2C | 0.7795 | 0.5113 | 0.8345 | 0.049* | |
C3 | 0.9178 (4) | 0.5694 (3) | 0.5620 (4) | 0.0228 (12) | |
H3A | 0.9898 | 0.5830 | 0.6049 | 0.027* | |
H3B | 0.9196 | 0.5140 | 0.5416 | 0.027* | |
C4 | 0.8933 (4) | 0.6196 (4) | 0.4644 (4) | 0.0318 (14) | |
H4A | 0.8205 | 0.6091 | 0.4231 | 0.048* | |
H4B | 0.9437 | 0.6071 | 0.4239 | 0.048* | |
H4C | 0.8999 | 0.6748 | 0.4836 | 0.048* | |
C5 | 0.8285 (4) | 0.6833 (3) | 0.6753 (4) | 0.0232 (12) | |
H5A | 0.7970 | 0.7137 | 0.6120 | 0.028* | |
H5B | 0.7828 | 0.6914 | 0.7229 | 0.028* | |
C6 | 0.9390 (4) | 0.7167 (3) | 0.7261 (5) | 0.0323 (14) | |
H6A | 0.9711 | 0.6878 | 0.7896 | 0.048* | |
H6B | 0.9323 | 0.7718 | 0.7426 | 0.048* | |
H6C | 0.9843 | 0.7119 | 0.6786 | 0.048* | |
C7 | 0.2559 (4) | 0.7573 (3) | 0.4713 (4) | 0.0211 (11) | |
H7A | 0.2402 | 0.8113 | 0.4887 | 0.025* | |
H7B | 0.2684 | 0.7583 | 0.4018 | 0.025* | |
C8 | 0.1574 (4) | 0.7066 (3) | 0.4672 (4) | 0.0285 (13) | |
H8A | 0.1692 | 0.6540 | 0.4438 | 0.043* | |
H8B | 0.0949 | 0.7297 | 0.4190 | 0.043* | |
H8C | 0.1453 | 0.7037 | 0.5361 | 0.043* | |
C9 | 0.3480 (4) | 0.7250 (3) | 0.6890 (4) | 0.0212 (11) | |
H9A | 0.2999 | 0.6804 | 0.6901 | 0.025* | |
H9B | 0.4149 | 0.7152 | 0.7429 | 0.025* | |
C10 | 0.2969 (5) | 0.7976 (4) | 0.7188 (5) | 0.0402 (16) | |
H10A | 0.3437 | 0.8425 | 0.7194 | 0.060* | |
H10B | 0.2858 | 0.7907 | 0.7876 | 0.060* | |
H10C | 0.2282 | 0.8067 | 0.6687 | 0.060* | |
C11 | 0.4646 (4) | 0.8098 (3) | 0.5668 (4) | 0.0204 (11) | |
H11A | 0.4814 | 0.8136 | 0.4992 | 0.024* | |
H11B | 0.4243 | 0.8572 | 0.5751 | 0.024* | |
C12 | 0.5696 (4) | 0.8091 (3) | 0.6519 (5) | 0.0297 (14) | |
H12A | 0.5546 | 0.8154 | 0.7192 | 0.045* | |
H12B | 0.6150 | 0.8520 | 0.6407 | 0.045* | |
H12C | 0.6063 | 0.7594 | 0.6503 | 0.045* | |
C13 | 0.5351 (4) | 0.5874 (3) | 0.1478 (4) | 0.0206 (11) | |
C14 | 0.5478 (4) | 0.6082 (4) | 0.0466 (4) | 0.0337 (15) | |
H14A | 0.6217 | 0.5992 | 0.0450 | 0.051* | |
H14B | 0.5299 | 0.6633 | 0.0328 | 0.051* | |
H14C | 0.5001 | 0.5760 | −0.0062 | 0.051* | |
Sb1 | 0.73332 (3) | 0.91633 (2) | 0.39924 (3) | 0.02375 (9) | |
F1 | 0.7830 (4) | 0.8151 (2) | 0.4290 (4) | 0.0704 (14) | |
F2 | 0.8103 (3) | 0.9449 (3) | 0.5322 (3) | 0.0697 (14) | |
F3 | 0.8542 (3) | 0.9374 (2) | 0.3531 (3) | 0.0460 (10) | |
F4 | 0.6602 (3) | 0.8872 (3) | 0.2656 (3) | 0.0634 (13) | |
F5 | 0.6120 (3) | 0.8954 (2) | 0.4439 (3) | 0.0502 (10) | |
F6 | 0.6871 (4) | 1.0185 (2) | 0.3723 (4) | 0.0855 (17) |
U11 | U22 | U33 | U12 | U13 | U23 | |
Re1 | 0.01019 (9) | 0.01073 (10) | 0.01163 (10) | −0.00072 (7) | 0.00191 (7) | −0.00061 (8) |
Re2 | 0.01140 (9) | 0.00994 (10) | 0.01146 (10) | 0.00004 (7) | 0.00230 (7) | −0.00060 (8) |
Re3 | 0.01176 (9) | 0.01113 (10) | 0.01079 (10) | −0.00032 (7) | 0.00276 (7) | −0.00004 (8) |
Se1 | 0.0140 (2) | 0.0139 (2) | 0.0142 (2) | 0.00134 (18) | 0.00157 (17) | 0.0007 (2) |
Se2 | 0.0156 (2) | 0.0142 (2) | 0.0129 (2) | −0.00072 (18) | 0.00240 (18) | −0.0024 (2) |
Se3 | 0.0137 (2) | 0.0156 (2) | 0.0158 (2) | 0.00021 (18) | 0.00523 (17) | −0.0011 (2) |
Se4 | 0.0150 (2) | 0.0120 (2) | 0.0165 (2) | −0.00182 (18) | 0.00345 (18) | 0.0006 (2) |
P1 | 0.0123 (6) | 0.0155 (6) | 0.0154 (6) | −0.0016 (5) | 0.0011 (5) | 0.0000 (5) |
P2 | 0.0169 (6) | 0.0134 (6) | 0.0135 (6) | 0.0012 (5) | 0.0040 (5) | −0.0007 (5) |
N1 | 0.017 (2) | 0.011 (2) | 0.018 (2) | 0.0004 (16) | 0.0061 (16) | 0.0020 (18) |
C1 | 0.014 (2) | 0.027 (3) | 0.023 (3) | 0.000 (2) | −0.003 (2) | 0.003 (2) |
C2 | 0.032 (3) | 0.042 (4) | 0.020 (3) | −0.006 (3) | 0.001 (2) | 0.005 (3) |
C3 | 0.015 (2) | 0.029 (3) | 0.027 (3) | 0.002 (2) | 0.009 (2) | −0.001 (3) |
C4 | 0.028 (3) | 0.041 (4) | 0.027 (3) | −0.005 (3) | 0.009 (2) | 0.005 (3) |
C5 | 0.019 (3) | 0.020 (3) | 0.028 (3) | 0.000 (2) | 0.001 (2) | −0.001 (2) |
C6 | 0.024 (3) | 0.023 (3) | 0.044 (4) | −0.005 (2) | −0.001 (3) | −0.007 (3) |
C7 | 0.022 (3) | 0.019 (3) | 0.022 (3) | 0.007 (2) | 0.005 (2) | 0.001 (2) |
C8 | 0.020 (3) | 0.031 (3) | 0.032 (3) | 0.005 (2) | 0.003 (2) | −0.008 (3) |
C9 | 0.030 (3) | 0.018 (3) | 0.017 (3) | 0.000 (2) | 0.008 (2) | −0.003 (2) |
C10 | 0.068 (5) | 0.033 (4) | 0.022 (3) | 0.017 (3) | 0.015 (3) | −0.002 (3) |
C11 | 0.027 (3) | 0.014 (3) | 0.021 (3) | 0.002 (2) | 0.006 (2) | 0.002 (2) |
C12 | 0.029 (3) | 0.021 (3) | 0.035 (4) | −0.012 (2) | 0.003 (2) | −0.009 (3) |
C13 | 0.019 (3) | 0.019 (3) | 0.022 (3) | −0.002 (2) | 0.002 (2) | 0.000 (2) |
C14 | 0.030 (3) | 0.050 (4) | 0.020 (3) | −0.016 (3) | 0.005 (2) | 0.009 (3) |
Sb1 | 0.01872 (17) | 0.0293 (2) | 0.0237 (2) | −0.00210 (14) | 0.00649 (14) | 0.00040 (17) |
F1 | 0.083 (3) | 0.045 (3) | 0.091 (4) | 0.020 (2) | 0.036 (3) | 0.022 (3) |
F2 | 0.035 (2) | 0.135 (4) | 0.038 (2) | −0.001 (2) | 0.0072 (17) | −0.038 (3) |
F3 | 0.0253 (18) | 0.080 (3) | 0.036 (2) | −0.0141 (18) | 0.0136 (15) | 0.002 (2) |
F4 | 0.032 (2) | 0.122 (4) | 0.035 (2) | −0.016 (2) | 0.0068 (17) | −0.023 (2) |
F5 | 0.0293 (19) | 0.084 (3) | 0.044 (2) | −0.0110 (19) | 0.0200 (16) | −0.005 (2) |
F6 | 0.080 (3) | 0.038 (3) | 0.144 (5) | 0.022 (2) | 0.037 (3) | 0.025 (3) |
Re1—Re2 | 2.6440 (6) | C3—H3A | 0.9900 |
Re1—Re2i | 2.6457 (5) | C3—H3B | 0.9900 |
Re1—Re3 | 2.6392 (9) | C3—C4 | 1.532 (7) |
Re1—Re3i | 2.6383 (6) | C4—H4A | 0.9800 |
Re1—Se1 | 2.5259 (6) | C4—H4B | 0.9800 |
Re1—Se2 | 2.5250 (7) | C4—H4C | 0.9800 |
Re1—Se3 | 2.5159 (7) | C5—H5A | 0.9900 |
Re1—Se4 | 2.5269 (7) | C5—H5B | 0.9900 |
Re1—P1 | 2.4839 (13) | C5—C6 | 1.531 (7) |
Re2—Re1i | 2.6457 (5) | C6—H6A | 0.9800 |
Re2—Re3 | 2.6355 (6) | C6—H6B | 0.9800 |
Re2—Re3i | 2.6341 (5) | C6—H6C | 0.9800 |
Re2—Se1i | 2.5239 (10) | C7—H7A | 0.9900 |
Re2—Se2 | 2.5278 (10) | C7—H7B | 0.9900 |
Re2—Se3i | 2.5161 (7) | C7—C8 | 1.537 (7) |
Re2—Se4 | 2.5237 (7) | C8—H8A | 0.9800 |
Re2—P2 | 2.4749 (13) | C8—H8B | 0.9800 |
Re3—Re1i | 2.6383 (6) | C8—H8C | 0.9800 |
Re3—Re2i | 2.6342 (5) | C9—H9A | 0.9900 |
Re3—Se1i | 2.5184 (7) | C9—H9B | 0.9900 |
Re3—Se2i | 2.5231 (7) | C9—C10 | 1.515 (7) |
Re3—Se3 | 2.5181 (7) | C10—H10A | 0.9800 |
Re3—Se4 | 2.5188 (7) | C10—H10B | 0.9800 |
Re3—N1 | 2.113 (4) | C10—H10C | 0.9800 |
Se1—Re2i | 2.5239 (10) | C11—H11A | 0.9900 |
Se1—Re3i | 2.5184 (7) | C11—H11B | 0.9900 |
Se2—Re3i | 2.5232 (7) | C11—C12 | 1.534 (7) |
Se3—Re2i | 2.5161 (7) | C12—H12A | 0.9800 |
P1—C1 | 1.828 (5) | C12—H12B | 0.9800 |
P1—C3 | 1.822 (5) | C12—H12C | 0.9800 |
P1—C5 | 1.841 (5) | C13—C14 | 1.457 (7) |
P2—C7 | 1.840 (5) | C14—H14A | 0.9800 |
P2—C9 | 1.822 (5) | C14—H14B | 0.9800 |
P2—C11 | 1.827 (5) | C14—H14C | 0.9800 |
N1—C13 | 1.129 (6) | Sb1—F1 | 1.860 (4) |
C1—H1A | 0.9900 | Sb1—F2 | 1.870 (4) |
C1—H1B | 0.9900 | Sb1—F3 | 1.872 (3) |
C1—C2 | 1.518 (8) | Sb1—F4 | 1.865 (4) |
C2—H2A | 0.9800 | Sb1—F5 | 1.866 (3) |
C2—H2B | 0.9800 | Sb1—F6 | 1.857 (4) |
C2—H2C | 0.9800 | ||
Re2—Re1—Re2i | 89.829 (19) | Re1—Se3—Re2i | 63.44 (2) |
Re2—Re1—Re3 | 59.85 (2) | Re1—Se3—Re3 | 63.24 (3) |
Re2—Re1—Re3i | 59.824 (15) | Re2i—Se3—Re3 | 63.102 (18) |
Re2i—Re1—Re3i | 59.835 (13) | Re1—Se4—Re2 | 63.137 (18) |
Re2i—Re1—Re3 | 59.792 (14) | Re1—Se4—Re3 | 63.07 (2) |
Re2—Re1—Se1 | 118.139 (19) | Re2—Se4—Re3 | 63.021 (16) |
Re2i—Re1—Se1 | 58.37 (2) | Re1—P1—C1 | 116.14 (17) |
Re2—Re1—Se2 | 58.50 (2) | Re1—P1—C3 | 115.88 (18) |
Re2i—Re1—Se2 | 118.283 (17) | Re1—P1—C5 | 112.56 (16) |
Re2—Re1—Se3 | 118.25 (3) | C1—P1—C3 | 100.7 (2) |
Re2i—Re1—Se3 | 58.283 (16) | C1—P1—C5 | 105.3 (2) |
Re2—Re1—Se4 | 58.372 (19) | C3—P1—C5 | 104.8 (3) |
Re2i—Re1—Se4 | 118.10 (2) | Re2—P2—C7 | 114.97 (17) |
Re2—Re1—P1 | 134.05 (3) | Re2—P2—C9 | 112.47 (17) |
Re2i—Re1—P1 | 136.12 (3) | Re2—P2—C11 | 116.55 (18) |
Re3—Re1—Re3i | 89.56 (2) | C7—P2—C9 | 105.1 (2) |
Re3—Re1—Se1 | 118.139 (15) | C7—P2—C11 | 100.9 (2) |
Re3i—Re1—Se1 | 58.326 (16) | C9—P2—C11 | 105.4 (2) |
Re3—Re1—Se2 | 118.326 (18) | Re3—N1—C13 | 176.5 (4) |
Re3i—Re1—Se2 | 58.46 (2) | P1—C1—H1A | 108.3 |
Re3—Re1—Se3 | 58.422 (17) | P1—C1—H1B | 108.3 |
Re3i—Re1—Se3 | 118.10 (2) | P1—C1—C2 | 116.1 (4) |
Re3—Re1—Se4 | 58.314 (15) | H1A—C1—H1B | 107.4 |
Re3i—Re1—Se4 | 118.175 (18) | H1A—C1—C2 | 108.3 |
Re3—Re1—P1 | 135.06 (4) | H1B—C1—C2 | 108.3 |
Re3i—Re1—P1 | 135.36 (3) | C1—C2—H2A | 109.5 |
Se1—Re1—Se2 | 89.74 (2) | C1—C2—H2B | 109.5 |
Se1—Re1—Se3 | 89.95 (2) | C1—C2—H2C | 109.5 |
Se1—Re1—Se4 | 175.697 (16) | H2A—C2—H2B | 109.5 |
Se1—Re1—P1 | 92.98 (4) | H2A—C2—H2C | 109.5 |
Se2—Re1—Se3 | 175.91 (4) | H2B—C2—H2C | 109.5 |
Se2—Re1—Se4 | 90.16 (2) | P1—C3—H3A | 108.5 |
Se2—Re1—P1 | 91.35 (4) | P1—C3—H3B | 108.5 |
Se3—Re1—Se4 | 89.85 (2) | P1—C3—C4 | 115.0 (4) |
Se3—Re1—P1 | 92.74 (4) | H3A—C3—H3B | 107.5 |
Se4—Re1—P1 | 91.32 (4) | H3A—C3—C4 | 108.5 |
Re1—Re2—Re1i | 90.17 (2) | H3B—C3—C4 | 108.5 |
Re1—Re2—Re3 | 59.99 (2) | C3—C4—H4A | 109.5 |
Re1—Re2—Re3i | 59.979 (15) | C3—C4—H4B | 109.5 |
Re1i—Re2—Re3i | 59.98 (2) | C3—C4—H4C | 109.5 |
Re1i—Re2—Re3 | 59.942 (13) | H4A—C4—H4B | 109.5 |
Re1—Re2—Se1i | 118.37 (3) | H4A—C4—H4C | 109.5 |
Re1i—Re2—Se1i | 58.441 (16) | H4B—C4—H4C | 109.5 |
Re1—Re2—Se2 | 58.40 (2) | P1—C5—H5A | 108.3 |
Re1i—Re2—Se2 | 118.453 (18) | P1—C5—H5B | 108.3 |
Re1—Re2—Se3i | 118.457 (19) | P1—C5—C6 | 116.1 (4) |
Re1i—Re2—Se3i | 58.276 (17) | H5A—C5—H5B | 107.4 |
Re1—Re2—Se4 | 58.491 (18) | H5A—C5—C6 | 108.3 |
Re1i—Re2—Se4 | 118.336 (17) | H5B—C5—C6 | 108.3 |
Re1—Re2—P2 | 135.45 (3) | C5—C6—H6A | 109.5 |
Re1i—Re2—P2 | 134.24 (3) | C5—C6—H6B | 109.5 |
Re3—Re2—Re3i | 89.732 (14) | C5—C6—H6C | 109.5 |
Re3i—Re2—Se1i | 118.402 (16) | H6A—C6—H6B | 109.5 |
Re3—Re2—Se1i | 58.386 (17) | H6A—C6—H6C | 109.5 |
Re3—Re2—Se2 | 118.364 (19) | H6B—C6—H6C | 109.5 |
Re3i—Re2—Se2 | 58.481 (14) | P2—C7—H7A | 108.5 |
Re3i—Re2—Se3i | 58.488 (17) | P2—C7—H7B | 108.5 |
Re3—Re2—Se3i | 118.20 (2) | P2—C7—C8 | 115.0 (4) |
Re3—Re2—Se4 | 58.40 (2) | H7A—C7—H7B | 107.5 |
Re3i—Re2—Se4 | 118.449 (17) | H7A—C7—C8 | 108.5 |
Re3—Re2—P2 | 137.97 (3) | H7B—C7—C8 | 108.5 |
Re3i—Re2—P2 | 132.29 (3) | C7—C8—H8A | 109.5 |
Se1i—Re2—Se2 | 176.107 (18) | C7—C8—H8B | 109.5 |
Se1i—Re2—Se3i | 89.99 (3) | C7—C8—H8C | 109.5 |
Se1i—Re2—Se4 | 89.59 (3) | H8A—C8—H8B | 109.5 |
Se1i—Re2—P2 | 93.53 (3) | H8A—C8—H8C | 109.5 |
Se2—Re2—Se3i | 89.99 (3) | H8B—C8—H8C | 109.5 |
Se2—Re2—Se4 | 90.17 (3) | P2—C9—H9A | 107.9 |
Se2—Re2—P2 | 90.36 (3) | P2—C9—H9B | 107.9 |
Se3i—Re2—Se4 | 176.040 (18) | P2—C9—C10 | 117.5 (4) |
Se3i—Re2—P2 | 89.57 (4) | H9A—C9—H9B | 107.2 |
Se4—Re2—P2 | 94.38 (4) | H9A—C9—C10 | 107.9 |
Re1—Re3—Re1i | 90.44 (2) | H9B—C9—C10 | 107.9 |
Re1—Re3—Re2 | 60.168 (15) | C9—C10—H10A | 109.5 |
Re1i—Re3—Re2i | 60.195 (13) | C9—C10—H10B | 109.5 |
Re1i—Re3—Re2 | 60.221 (18) | C9—C10—H10C | 109.5 |
Re1—Re3—Re2i | 60.227 (11) | H10A—C10—H10B | 109.5 |
Re1i—Re3—Se1i | 58.603 (18) | H10A—C10—H10C | 109.5 |
Re1—Re3—Se1i | 118.75 (3) | H10B—C10—H10C | 109.5 |
Re1i—Re3—Se2i | 58.527 (17) | P2—C11—H11A | 108.5 |
Re1—Re3—Se2i | 118.871 (18) | P2—C11—H11B | 108.5 |
Re1—Re3—Se3 | 58.34 (2) | P2—C11—C12 | 115.2 (4) |
Re1i—Re3—Se3 | 118.596 (19) | H11A—C11—H11B | 107.5 |
Re1—Re3—Se4 | 58.611 (17) | H11A—C11—C12 | 108.5 |
Re1i—Re3—Se4 | 118.794 (18) | H11B—C11—C12 | 108.5 |
Re1—Re3—N1 | 134.86 (10) | C11—C12—H12A | 109.5 |
Re1i—Re3—N1 | 134.70 (10) | C11—C12—H12B | 109.5 |
Re2—Re3—Re2i | 90.266 (15) | C11—C12—H12C | 109.5 |
Re2i—Re3—Se1i | 118.79 (2) | H12A—C12—H12B | 109.5 |
Re2—Re3—Se1i | 58.59 (3) | H12A—C12—H12C | 109.5 |
Re2i—Re3—Se2i | 58.65 (2) | H12B—C12—H12C | 109.5 |
Re2—Re3—Se2i | 118.738 (18) | N1—C13—C14 | 179.8 (6) |
Re2—Re3—Se3 | 118.49 (3) | C13—C14—H14A | 109.5 |
Re2i—Re3—Se3 | 58.412 (18) | C13—C14—H14B | 109.5 |
Re2—Re3—Se4 | 58.579 (17) | C13—C14—H14C | 109.5 |
Re2i—Re3—Se4 | 118.83 (2) | H14A—C14—H14B | 109.5 |
Re2—Re3—N1 | 135.53 (11) | H14A—C14—H14C | 109.5 |
Re2i—Re3—N1 | 134.20 (11) | H14B—C14—H14C | 109.5 |
Se1i—Re3—Se2i | 89.95 (2) | F1—Sb1—F2 | 88.3 (2) |
Se1i—Re3—Se3 | 176.492 (18) | F1—Sb1—F3 | 88.65 (19) |
Se1i—Re3—Se4 | 89.82 (2) | F1—Sb1—F4 | 91.0 (2) |
Se1i—Re3—N1 | 92.03 (11) | F1—Sb1—F5 | 91.6 (2) |
Se2i—Re3—Se3 | 90.05 (2) | F1—Sb1—F6 | 178.4 (2) |
Se2i—Re3—Se4 | 176.806 (18) | F2—Sb1—F3 | 88.87 (17) |
Se2i—Re3—N1 | 91.08 (11) | F2—Sb1—F4 | 178.32 (17) |
Se3—Re3—Se4 | 89.99 (2) | F2—Sb1—F5 | 91.66 (17) |
Se3—Re3—N1 | 91.48 (11) | F2—Sb1—F6 | 90.2 (2) |
Se4—Re3—N1 | 92.11 (11) | F3—Sb1—F4 | 89.60 (17) |
Re1—Se1—Re2i | 63.192 (15) | F3—Sb1—F5 | 179.44 (16) |
Re1—Se1—Re3i | 63.071 (19) | F3—Sb1—F6 | 90.6 (2) |
Re2i—Se1—Re3i | 63.02 (3) | F4—Sb1—F5 | 89.88 (17) |
Re1—Se2—Re2 | 63.105 (18) | F4—Sb1—F6 | 90.4 (2) |
Re1—Se2—Re3i | 63.016 (17) | F5—Sb1—F6 | 89.2 (2) |
Re2—Se2—Re3i | 62.868 (17) |
Symmetry code: (i) −x+1, −y+1, −z+1. |
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