trans,trans-Bis[μ-1,5-bis­(diisopropyl­phos­phino)­pentane-κ²P:P′]bis­[dichloro­nickel(II)]

In the title crystal structure, [Ni₂Cl₄{CH₂(CH₂CH₂PPrⁱ₂)₂}₂], there are two independent mol­ecules, one of which lies on a crystallographic inversion center. The Ni^II atoms in each dinuclear mol­ecule are in slightly distorted square-planar geometries. The two independent mol­ecules have markedly different conformations due to the relative orientations of the Cl/Ni/Cl groups with respect to the plane defined by the four P and the two Ni^II atoms.

Key indicators

• Single-crystal X-ray study
• T = 220 K
• Mean [sigma](C-C) = 0.005 Å
• R factor = 0.043
• wR factor = 0.110
• Data-to-parameter ratio = 21.8

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT152_ALERT_1_C Supplied and Calc Volume s.u. Inconsistent .....          ?
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       2.56 Ratio
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.20 Ratio
PLAT222_ALERT_3_C Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       3.20 Ratio
PLAT222_ALERT_3_C Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       3.96 Ratio
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C14
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        Ni3
PLAT360_ALERT_2_C Short  C(sp3)-C(sp3) Bond  C40    -   C45    ...       1.38 Ang.

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   8 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   5 ALERT type 2 Indicator that the structure model may be wrong or deficient
   2 ALERT type 3 Indicator that the structure quality may be low
   0 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

---

Computing details

Data collection: SMART (Bruker, 1999); cell refinement: SAINT (Bruker, 1999); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1997); software used to prepare material for publication: UdMX (Maris, 2004).

trans,trans-Bis[µ-1,5-bis(diisopropylphosphino)pentane- κ²P:P']bis[dichloronickel(II)]

Crystal data

[Ni2Cl4(C17H38P2)2]	F(000) = 2784
Mr = 868.05	Dx = 1.257 Mg m^−3
Monoclinic, P21/c	Cu Kα radiation, λ = 1.54178 Å
Hall symbol: -P 2ybc	Cell parameters from 6417 reflections
a = 21.1322 (9) Å	θ = 3.1–72.5°
b = 28.9229 (10) Å	µ = 4.63 mm^−1
c = 11.4019 (4) Å	T = 220 K
β = 99.212 (3)°	Block, purple
V = 6879.0 (4) Å^3	0.48 × 0.27 × 0.23 mm
Z = 6

Data collection

Bruker SMART 2000 diffractometer	13507 independent reflections
Radiation source: Sealed Tube	9282 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.038
Detector resolution: 5.5 pixels mm^-1	θmax = 72.9°, θmin = 2.1°
ω scans	h = −25→23
Absorption correction: multi-scan (SADABS; Bruker, 1999)	k = −35→35
Tmin = 0.238, Tmax = 0.345	l = −13→13
55920 measured reflections

Refinement

Refinement on F^2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.044	H-atom parameters constrained
wR(F^2) = 0.110	w = 1/[σ^2(Fo^2) + (0.0579P)^2] where P = (Fo^2 + 2Fc^2)/3
S = 0.91	(Δ/σ)max = 0.002
13507 reflections	Δρmax = 0.64 e Å^−3
620 parameters	Δρmin = −0.44 e Å^−3
0 restraints	Extinction correction: SHELXL97, Fc^*=kFc[1+0.001xFc^2λ^3/sin(2θ)]^-1/4
Primary atom site location: structure-invariant direct methods	Extinction coefficient: 0.000034 (10)

Special details

Experimental. X-ray crystallographic data for I were collected from a single-crystal sample, which was mounted on a loop fiber. Data were collected using a Bruker Platform diffractometer, equipped with a Bruker SMART 2 K Charged-Coupled Device (CCD) Area Detector using the program SMART and normal focus sealed tube source graphite monochromated Cu—Kα radiation. The crystal-to-detector distance was 4.908 cm, and the data collection was carried out in 512 x 512 pixel mode, utilizing 4 x 4 pixel binning. The initial unit-cell parameters were determined by a least-squares fit of the angular setting of strong reflections, collected by a 9.0 degree scan in 30 frames over four different parts of the reciprocal space (120 frames total). One complete sphere of data was collected, to better than 0.8 Å resolution. Upon completion of the data collection, the first 101 frames were recollected in order to improve the decay correction analysis.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Ni1	0.06205 (2)	0.621237 (17)	0.37432 (4)	0.03648 (12)
Ni2	0.26923 (2)	0.377533 (16)	0.47184 (4)	0.03510 (12)
Ni3	0.38849 (2)	0.614486 (16)	0.98496 (4)	0.03479 (12)
Cl1	0.14048 (4)	0.59963 (3)	0.28631 (7)	0.0555 (2)
Cl2	−0.01549 (4)	0.65607 (3)	0.44078 (8)	0.0597 (2)
Cl3	0.20718 (4)	0.36691 (4)	0.60182 (8)	0.0626 (2)
Cl4	0.32412 (4)	0.39954 (3)	0.33549 (6)	0.04658 (18)
Cl5	0.32715 (4)	0.58111 (3)	0.83886 (7)	0.0592 (2)
Cl6	0.45459 (4)	0.64287 (3)	1.13177 (7)	0.0534 (2)
P1	−0.00810 (4)	0.58477 (2)	0.23542 (6)	0.03591 (17)
P2	0.19864 (3)	0.34392 (2)	0.32711 (7)	0.03362 (16)
P3	0.34363 (4)	0.41184 (2)	0.60777 (7)	0.03556 (17)
P4	0.13100 (4)	0.64875 (2)	0.52875 (7)	0.03487 (16)
P5	0.43974 (4)	0.64753 (3)	0.84771 (7)	0.04289 (19)
P6	0.66247 (3)	0.41922 (2)	0.87907 (6)	0.03390 (16)
C1	0.02215 (14)	0.53213 (9)	0.1736 (3)	0.0405 (7)
H1A	−0.0137	0.5172	0.1223	0.049*
H1B	0.0534	0.5413	0.1231	0.049*
C2	0.05350 (15)	0.49641 (10)	0.2622 (3)	0.0437 (7)
H2A	0.0855	0.5117	0.3213	0.052*
H2B	0.0209	0.4829	0.3041	0.052*
C3	0.08560 (14)	0.45821 (10)	0.2027 (3)	0.0413 (7)
H3A	0.1147	0.4722	0.1539	0.050*
H3B	0.0527	0.4412	0.1494	0.050*
C4	0.12348 (15)	0.42407 (10)	0.2894 (3)	0.0428 (7)
H4A	0.1544	0.4412	0.3466	0.051*
H4B	0.0939	0.4081	0.3338	0.051*
C5	0.15935 (14)	0.38828 (10)	0.2263 (2)	0.0382 (7)
H5A	0.1917	0.4041	0.1883	0.046*
H5B	0.1290	0.3733	0.1637	0.046*
C6	0.34093 (14)	0.47368 (9)	0.5751 (3)	0.0403 (7)
H6A	0.3742	0.4895	0.6306	0.048*
H6B	0.3501	0.4786	0.4945	0.048*
C7	0.27564 (14)	0.49469 (9)	0.5851 (3)	0.0431 (7)
H7A	0.2421	0.4769	0.5351	0.052*
H7B	0.2682	0.4921	0.6675	0.052*
C8	0.27007 (14)	0.54520 (9)	0.5478 (3)	0.0386 (7)
H8A	0.3069	0.5622	0.5902	0.046*
H8B	0.2717	0.5474	0.4626	0.046*
C9	0.20866 (14)	0.56765 (9)	0.5731 (3)	0.0408 (7)
H9A	0.2036	0.5614	0.6556	0.049*
H9B	0.1720	0.5540	0.5212	0.049*
C10	0.20921 (13)	0.61998 (9)	0.5528 (3)	0.0388 (7)
H10A	0.2302	0.6260	0.4836	0.047*
H10B	0.2356	0.6343	0.6217	0.047*
C11	0.10085 (15)	0.64609 (10)	0.6720 (3)	0.0435 (7)
H11	0.0652	0.6685	0.6668	0.052*
C12	0.15541 (16)	0.70997 (10)	0.5164 (3)	0.0537 (9)
H12	0.1891	0.7162	0.5854	0.064*
C13	−0.08441 (15)	0.56830 (12)	0.2837 (3)	0.0496 (8)
H13	−0.1055	0.5975	0.3015	0.060*
C14	−0.03323 (17)	0.61964 (11)	0.1002 (3)	0.0512 (8)
H14	−0.0597	0.5995	0.0416	0.061*
C18	0.23314 (15)	0.30144 (10)	0.2321 (3)	0.0479 (8)
H18	0.1996	0.2779	0.2076	0.057*
C17	0.13075 (14)	0.31264 (10)	0.3748 (3)	0.0426 (7)
H17	0.1125	0.3337	0.4292	0.051*
C15	0.42834 (14)	0.39292 (11)	0.6111 (3)	0.0445 (7)
H15	0.4500	0.3958	0.6944	0.053*
C16	0.33314 (16)	0.40861 (11)	0.7658 (3)	0.0469 (8)
H16	0.2878	0.4164	0.7691	0.056*
C19	0.10217 (18)	0.74438 (12)	0.5233 (4)	0.0760 (12)
H19A	0.1190	0.7756	0.5225	0.114*
H19B	0.0849	0.7395	0.5962	0.114*
H19C	0.0685	0.7402	0.4557	0.114*
C20	0.1855 (2)	0.71767 (13)	0.4070 (4)	0.0958 (17)
H20A	0.1532	0.7143	0.3368	0.144*
H20B	0.2192	0.6951	0.4046	0.144*
H20C	0.2035	0.7485	0.4090	0.144*
C21	0.07274 (17)	0.59853 (12)	0.6933 (3)	0.0569 (9)
H21A	0.1069	0.5758	0.7053	0.085*
H21B	0.0416	0.5899	0.6248	0.085*
H21C	0.0520	0.5998	0.7632	0.085*
C22	0.15062 (19)	0.66070 (13)	0.7780 (3)	0.0703 (11)
H22A	0.1307	0.6620	0.8489	0.105*
H22B	0.1674	0.6910	0.7629	0.105*
H22C	0.1854	0.6384	0.7894	0.105*
C23	0.43103 (18)	0.34161 (12)	0.5778 (3)	0.0691 (11)
H23A	0.4126	0.3376	0.4948	0.104*
H23B	0.4068	0.3236	0.6270	0.104*
H23C	0.4753	0.3313	0.5904	0.104*
C24	0.46674 (15)	0.42194 (13)	0.5359 (3)	0.0574 (9)
H24A	0.5106	0.4109	0.5463	0.086*
H24B	0.4663	0.4540	0.5606	0.086*
H24C	0.4477	0.4194	0.4529	0.086*
C25	0.37418 (18)	0.44271 (13)	0.8464 (3)	0.0658 (10)
H25A	0.3660	0.4391	0.9272	0.099*
H25B	0.3636	0.4740	0.8195	0.099*
H25C	0.4191	0.4368	0.8439	0.099*
C26	0.34441 (19)	0.35945 (13)	0.8145 (3)	0.0662 (10)
H26A	0.3895	0.3517	0.8203	0.099*
H26B	0.3190	0.3379	0.7614	0.099*
H26C	0.3319	0.3576	0.8926	0.099*
C27	0.29014 (17)	0.27605 (12)	0.3040 (3)	0.0639 (10)
H27A	0.3047	0.2519	0.2556	0.096*
H27B	0.2771	0.2624	0.3741	0.096*
H27C	0.3248	0.2978	0.3281	0.096*
C28	0.25147 (16)	0.32131 (12)	0.1187 (3)	0.0571 (9)
H28A	0.2843	0.3447	0.1388	0.086*
H28B	0.2140	0.3351	0.0713	0.086*
H28C	0.2678	0.2968	0.0738	0.086*
C29	0.15356 (17)	0.26980 (11)	0.4473 (3)	0.0609 (10)
H29A	0.1187	0.2576	0.4841	0.091*
H29B	0.1892	0.2780	0.5085	0.091*
H29C	0.1673	0.2465	0.3956	0.091*
C30	0.07575 (16)	0.30063 (13)	0.2746 (3)	0.0607 (10)
H30A	0.0917	0.2809	0.2171	0.091*
H30B	0.0585	0.3288	0.2360	0.091*
H30C	0.0423	0.2846	0.3075	0.091*
C31	−0.13195 (18)	0.54306 (16)	0.1881 (4)	0.0842 (14)
H31A	−0.1148	0.5130	0.1726	0.126*
H31B	−0.1383	0.5611	0.1155	0.126*
H31C	−0.1726	0.5392	0.2160	0.126*
C32	−0.07350 (18)	0.54036 (13)	0.3993 (3)	0.0644 (10)
H32A	−0.1131	0.5388	0.4319	0.097*
H32B	−0.0407	0.5552	0.4560	0.097*
H32C	−0.0598	0.5093	0.3831	0.097*
C33	0.0243 (2)	0.63535 (15)	0.0449 (3)	0.0835 (14)
H33A	0.0095	0.6530	−0.0266	0.125*
H33B	0.0480	0.6085	0.0250	0.125*
H33C	0.0520	0.6545	0.1011	0.125*
C34	−0.0746 (2)	0.66048 (13)	0.1232 (4)	0.0980 (18)
H34A	−0.0514	0.6796	0.1857	0.147*
H34B	−0.1138	0.6494	0.1475	0.147*
H34C	−0.0850	0.6786	0.0511	0.147*
C35	0.47097 (16)	0.60169 (11)	0.7618 (3)	0.0491 (8)
H35A	0.4350	0.5850	0.7154	0.059*
H35B	0.4963	0.6156	0.7061	0.059*
C36	0.51274 (17)	0.56770 (11)	0.8424 (3)	0.0526 (9)
H36A	0.5500	0.5842	0.8848	0.063*
H36B	0.4882	0.5557	0.9018	0.063*
C37	0.53582 (16)	0.52742 (10)	0.7752 (3)	0.0464 (8)
H37A	0.4985	0.5104	0.7348	0.056*
H37B	0.5591	0.5396	0.7141	0.056*
C38	0.57899 (16)	0.49410 (11)	0.8533 (3)	0.0475 (8)
H38A	0.5547	0.4799	0.9103	0.057*
H38B	0.6147	0.5114	0.8986	0.057*
C39	0.60597 (14)	0.45596 (10)	0.7830 (2)	0.0388 (7)
H39A	0.6277	0.4700	0.7220	0.047*
H39B	0.5706	0.4370	0.7427	0.047*
C40	0.3839 (2)	0.68059 (16)	0.7369 (4)	0.0859 (15)
H40	0.3553	0.6552	0.7027	0.103*
C41	0.51036 (18)	0.68326 (12)	0.9031 (3)	0.0601 (10)
H41	0.5343	0.6663	0.9716	0.072*
C42	0.72971 (15)	0.45894 (11)	0.9327 (3)	0.0466 (8)
H42	0.7157	0.4784	0.9951	0.056*
C43	0.69697 (15)	0.37768 (10)	0.7822 (3)	0.0430 (7)
H43	0.7359	0.3922	0.7606	0.052*
C44	0.33637 (18)	0.70884 (13)	0.7952 (3)	0.0706 (11)
H44A	0.3589	0.7337	0.8412	0.106*
H44B	0.3162	0.6890	0.8472	0.106*
H44C	0.3038	0.7217	0.7343	0.106*
C45	0.4015 (2)	0.6979 (2)	0.6343 (4)	0.124 (2)
H45A	0.3634	0.7057	0.5783	0.186*
H45B	0.4262	0.6749	0.5995	0.186*
H45C	0.4274	0.7255	0.6529	0.186*
C46	0.4910 (2)	0.72955 (12)	0.9528 (4)	0.0840 (14)
H46A	0.5284	0.7442	0.9978	0.126*
H46B	0.4594	0.7241	1.0043	0.126*
H46C	0.4728	0.7495	0.8877	0.126*
C47	0.55844 (18)	0.69136 (15)	0.8165 (4)	0.0825 (13)
H47A	0.5385	0.7103	0.7505	0.124*
H47B	0.5709	0.6619	0.7868	0.124*
H47C	0.5961	0.7071	0.8578	0.124*
C48	0.74676 (18)	0.49177 (13)	0.8381 (3)	0.0682 (11)
H48A	0.7809	0.5123	0.8733	0.102*
H48B	0.7093	0.5099	0.8060	0.102*
H48C	0.7609	0.4741	0.7748	0.102*
C49	0.78992 (15)	0.43314 (12)	0.9912 (3)	0.0563 (9)
H49A	0.8076	0.4156	0.9315	0.084*
H49B	0.7788	0.4122	1.0512	0.084*
H49C	0.8215	0.4552	1.0281	0.084*
C50	0.71854 (18)	0.33367 (11)	0.8525 (3)	0.0619 (10)
H50A	0.6812	0.3168	0.8684	0.093*
H50B	0.7450	0.3420	0.9271	0.093*
H50C	0.7431	0.3144	0.8066	0.093*
C51	0.65307 (16)	0.36590 (12)	0.6663 (3)	0.0566 (9)
H51A	0.6760	0.3465	0.6178	0.085*
H51B	0.6398	0.3942	0.6236	0.085*
H51C	0.6156	0.3496	0.6838	0.085*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ni1	0.0354 (3)	0.0383 (3)	0.0367 (3)	0.0062 (2)	0.0087 (2)	−0.0037 (2)
Ni2	0.0389 (3)	0.0301 (2)	0.0367 (3)	0.0013 (2)	0.0072 (2)	−0.0024 (2)
Ni3	0.0395 (3)	0.0343 (3)	0.0316 (3)	0.0016 (2)	0.0087 (2)	−0.0007 (2)
Cl1	0.0420 (5)	0.0789 (6)	0.0485 (5)	0.0045 (4)	0.0162 (3)	−0.0143 (4)
Cl2	0.0424 (5)	0.0718 (6)	0.0652 (6)	0.0128 (4)	0.0096 (4)	−0.0277 (4)
Cl3	0.0553 (5)	0.0860 (7)	0.0511 (5)	−0.0148 (5)	0.0222 (4)	−0.0166 (5)
Cl4	0.0504 (5)	0.0512 (4)	0.0384 (4)	−0.0114 (3)	0.0079 (3)	−0.0008 (3)
Cl5	0.0642 (6)	0.0752 (6)	0.0370 (4)	−0.0144 (4)	0.0048 (4)	−0.0120 (4)
Cl6	0.0505 (5)	0.0680 (5)	0.0415 (4)	−0.0198 (4)	0.0065 (3)	−0.0042 (4)
P1	0.0401 (4)	0.0317 (4)	0.0357 (4)	0.0071 (3)	0.0055 (3)	−0.0014 (3)
P2	0.0360 (4)	0.0257 (3)	0.0397 (4)	0.0022 (3)	0.0077 (3)	−0.0033 (3)
P3	0.0428 (4)	0.0282 (4)	0.0351 (4)	0.0054 (3)	0.0042 (3)	−0.0030 (3)
P4	0.0382 (4)	0.0263 (3)	0.0405 (4)	0.0032 (3)	0.0075 (3)	−0.0015 (3)
P5	0.0521 (5)	0.0379 (4)	0.0429 (5)	0.0115 (3)	0.0204 (4)	0.0072 (3)
P6	0.0366 (4)	0.0309 (4)	0.0351 (4)	0.0009 (3)	0.0085 (3)	−0.0010 (3)
C1	0.0488 (18)	0.0326 (15)	0.0403 (17)	0.0084 (13)	0.0079 (13)	−0.0039 (13)
C2	0.057 (2)	0.0334 (16)	0.0423 (18)	0.0111 (14)	0.0120 (14)	0.0016 (13)
C3	0.0472 (18)	0.0343 (15)	0.0432 (17)	0.0072 (13)	0.0091 (13)	−0.0017 (13)
C4	0.0518 (19)	0.0350 (16)	0.0416 (17)	0.0107 (13)	0.0077 (14)	−0.0007 (13)
C5	0.0421 (17)	0.0364 (15)	0.0365 (16)	0.0043 (12)	0.0070 (12)	−0.0003 (12)
C6	0.0444 (18)	0.0300 (15)	0.0459 (18)	0.0025 (12)	0.0054 (13)	−0.0008 (13)
C7	0.0442 (18)	0.0287 (15)	0.056 (2)	0.0068 (12)	0.0063 (14)	−0.0020 (13)
C8	0.0463 (18)	0.0297 (14)	0.0392 (16)	0.0057 (12)	0.0051 (13)	−0.0026 (12)
C9	0.0419 (17)	0.0289 (15)	0.0501 (18)	0.0064 (12)	0.0029 (13)	−0.0012 (13)
C10	0.0367 (16)	0.0281 (14)	0.0504 (18)	0.0032 (12)	0.0034 (13)	−0.0046 (13)
C11	0.054 (2)	0.0394 (17)	0.0394 (17)	0.0017 (14)	0.0143 (14)	−0.0043 (13)
C12	0.057 (2)	0.0297 (16)	0.076 (3)	0.0022 (14)	0.0127 (18)	0.0031 (16)
C13	0.0413 (19)	0.055 (2)	0.055 (2)	−0.0023 (15)	0.0145 (15)	−0.0126 (16)
C14	0.069 (2)	0.0388 (17)	0.0413 (18)	0.0136 (16)	−0.0043 (16)	0.0012 (14)
C18	0.0457 (19)	0.0355 (16)	0.065 (2)	0.0032 (13)	0.0180 (16)	−0.0170 (15)
C17	0.0392 (17)	0.0385 (16)	0.0524 (19)	−0.0028 (13)	0.0142 (14)	0.0009 (14)
C15	0.0445 (18)	0.0468 (18)	0.0391 (17)	0.0132 (14)	−0.0029 (13)	−0.0072 (14)
C16	0.062 (2)	0.0441 (18)	0.0357 (17)	0.0040 (15)	0.0107 (14)	−0.0042 (14)
C19	0.081 (3)	0.0341 (18)	0.117 (4)	0.0148 (18)	0.031 (3)	0.005 (2)
C20	0.122 (4)	0.047 (2)	0.135 (4)	0.017 (2)	0.072 (3)	0.030 (3)
C21	0.069 (2)	0.055 (2)	0.051 (2)	−0.0043 (18)	0.0217 (17)	0.0021 (17)
C22	0.095 (3)	0.069 (3)	0.045 (2)	−0.011 (2)	0.007 (2)	−0.0136 (19)
C23	0.077 (3)	0.048 (2)	0.078 (3)	0.0272 (19)	0.000 (2)	−0.0103 (19)
C24	0.045 (2)	0.077 (3)	0.051 (2)	0.0081 (18)	0.0094 (15)	−0.0052 (18)
C25	0.085 (3)	0.068 (3)	0.043 (2)	0.002 (2)	0.0042 (18)	−0.0138 (18)
C26	0.092 (3)	0.060 (2)	0.047 (2)	0.004 (2)	0.0107 (19)	0.0104 (18)
C27	0.063 (2)	0.044 (2)	0.089 (3)	0.0186 (17)	0.025 (2)	−0.0020 (19)
C28	0.052 (2)	0.065 (2)	0.057 (2)	0.0009 (17)	0.0155 (16)	−0.0233 (18)
C29	0.066 (2)	0.0386 (18)	0.079 (3)	−0.0063 (16)	0.0146 (19)	0.0115 (18)
C30	0.047 (2)	0.065 (2)	0.070 (3)	−0.0126 (17)	0.0108 (17)	−0.0067 (19)
C31	0.058 (3)	0.109 (4)	0.087 (3)	−0.032 (2)	0.015 (2)	−0.034 (3)
C32	0.066 (3)	0.059 (2)	0.075 (3)	−0.0067 (19)	0.034 (2)	−0.001 (2)
C33	0.105 (4)	0.075 (3)	0.066 (3)	−0.013 (3)	0.000 (2)	0.038 (2)
C34	0.152 (5)	0.064 (3)	0.070 (3)	0.064 (3)	−0.006 (3)	0.005 (2)
C35	0.060 (2)	0.0493 (19)	0.0423 (18)	0.0172 (16)	0.0198 (15)	0.0037 (15)
C36	0.063 (2)	0.050 (2)	0.047 (2)	0.0195 (16)	0.0165 (16)	0.0048 (15)
C37	0.054 (2)	0.0421 (17)	0.0455 (18)	0.0081 (14)	0.0151 (15)	0.0030 (14)
C38	0.058 (2)	0.0463 (18)	0.0394 (18)	0.0147 (15)	0.0126 (14)	0.0010 (14)
C39	0.0448 (18)	0.0388 (16)	0.0342 (16)	0.0045 (13)	0.0102 (12)	0.0008 (12)
C40	0.097 (3)	0.096 (3)	0.074 (3)	0.061 (3)	0.040 (2)	0.040 (3)
C41	0.066 (2)	0.049 (2)	0.071 (3)	−0.0046 (17)	0.031 (2)	0.0031 (18)
C42	0.0444 (19)	0.0406 (17)	0.054 (2)	−0.0057 (14)	0.0065 (14)	−0.0044 (14)
C43	0.0425 (18)	0.0400 (16)	0.0500 (19)	0.0031 (13)	0.0182 (14)	−0.0088 (14)
C44	0.075 (3)	0.061 (2)	0.080 (3)	0.031 (2)	0.024 (2)	0.019 (2)
C45	0.122 (4)	0.186 (6)	0.069 (3)	0.077 (4)	0.029 (3)	0.048 (4)
C46	0.104 (4)	0.042 (2)	0.118 (4)	−0.017 (2)	0.053 (3)	−0.006 (2)
C47	0.066 (3)	0.096 (3)	0.095 (3)	−0.017 (2)	0.041 (2)	0.006 (3)
C48	0.060 (2)	0.055 (2)	0.090 (3)	−0.0148 (18)	0.014 (2)	0.015 (2)
C49	0.044 (2)	0.063 (2)	0.060 (2)	−0.0041 (16)	0.0014 (16)	−0.0036 (18)
C50	0.071 (3)	0.045 (2)	0.074 (3)	0.0172 (17)	0.023 (2)	−0.0038 (18)
C51	0.063 (2)	0.061 (2)	0.050 (2)	−0.0008 (18)	0.0210 (17)	−0.0161 (17)

Geometric parameters (Å, º)

Ni1—Cl2	2.1613 (9)	C21—H21c	0.97
Ni1—Cl1	2.1627 (9)	C22—H22a	0.97
Ni1—P4	2.2440 (9)	C22—H22b	0.97
Ni1—P1	2.2508 (9)	C22—H22c	0.97
Ni2—Cl3	2.1524 (9)	C23—H23a	0.97
Ni2—Cl4	2.1782 (9)	C23—H23b	0.97
Ni2—P3	2.2535 (9)	C23—H23c	0.97
Ni2—P2	2.2595 (9)	C24—H24a	0.97
Ni3—Cl6	2.1629 (9)	C24—H24b	0.97
Ni3—Cl5	2.1670 (9)	C24—H24c	0.97
Ni3—P6^i	2.2468 (9)	C25—H25a	0.97
Ni3—P5	2.2535 (9)	C25—H25b	0.97
P1—C1	1.835 (3)	C25—H25c	0.97
P1—C14	1.848 (3)	C26—H26a	0.97
P1—C13	1.848 (3)	C26—H26b	0.97
P2—C5	1.831 (3)	C26—H26c	0.97
P2—C17	1.850 (3)	C27—H27a	0.97
P2—C18	1.862 (3)	C27—H27b	0.97
P3—C6	1.826 (3)	C27—H27c	0.97
P3—C16	1.853 (3)	C28—H28a	0.97
P3—C15	1.867 (3)	C28—H28b	0.97
P4—C10	1.831 (3)	C28—H28c	0.97
P4—C11	1.848 (3)	C29—H29a	0.97
P4—C12	1.856 (3)	C29—H29b	0.97
P5—C35	1.833 (3)	C29—H29c	0.97
P5—C41	1.842 (4)	C30—H30a	0.97
P5—C40	1.852 (4)	C30—H30b	0.97
P6—C39	1.827 (3)	C30—H30c	0.97
P6—C42	1.853 (3)	C31—H31a	0.97
P6—C43	1.858 (3)	C31—H31b	0.97
P6—Ni3^i	2.2468 (9)	C31—H31c	0.97
C1—C2	1.521 (4)	C32—H32a	0.97
C1—H1a	0.98	C32—H32b	0.97
C1—H1b	0.98	C32—H32c	0.97
C2—C3	1.513 (4)	C33—H33a	0.97
C2—H2a	0.98	C33—H33b	0.97
C2—H2b	0.98	C33—H33c	0.97
C3—C4	1.530 (4)	C34—H34a	0.97
C3—H3a	0.98	C34—H34b	0.97
C3—H3b	0.98	C34—H34c	0.97
C4—C5	1.530 (4)	C35—C36	1.526 (4)
C4—H4a	0.98	C35—H35a	0.98
C4—H4b	0.98	C35—H35b	0.98
C5—H5a	0.98	C36—C37	1.517 (4)
C5—H5b	0.98	C36—H36a	0.98
C6—C7	1.528 (4)	C36—H36b	0.98
C6—H6a	0.98	C37—C38	1.515 (4)
C6—H6b	0.98	C37—H37a	0.98
C7—C8	1.521 (4)	C37—H37b	0.98
C7—H7a	0.98	C38—C39	1.527 (4)
C7—H7b	0.98	C38—H38a	0.98
C8—C9	1.519 (4)	C38—H38b	0.98
C8—H8a	0.98	C39—H39a	0.98
C8—H8b	0.98	C39—H39b	0.98
C9—C10	1.532 (4)	C40—C45	1.378 (5)
C9—H9a	0.98	C40—C44	1.527 (5)
C9—H9b	0.98	C40—H40	0.99
C10—H10a	0.98	C41—C46	1.535 (5)
C10—H10b	0.98	C41—C47	1.544 (4)
C11—C22	1.529 (4)	C41—H41	0.99
C11—C21	1.533 (4)	C42—C48	1.523 (4)
C11—H11	0.99	C42—C49	1.533 (4)
C12—C20	1.505 (5)	C42—H42	0.99
C12—C19	1.514 (4)	C43—C51	1.527 (4)
C12—H12	0.99	C43—C50	1.535 (4)
C13—C32	1.531 (5)	C43—H43	0.99
C13—C31	1.543 (4)	C44—H44a	0.97
C13—H13	0.99	C44—H44b	0.97
C14—C34	1.517 (4)	C44—H44c	0.97
C14—C33	1.525 (5)	C45—H45a	0.97
C14—H14	0.99	C45—H45b	0.97
C18—C28	1.520 (4)	C45—H45c	0.97
C18—C27	1.532 (4)	C46—H46a	0.97
C18—H18	0.99	C46—H46b	0.97
C17—C29	1.524 (4)	C46—H46c	0.97
C17—C30	1.533 (4)	C47—H47a	0.97
C17—H17	0.99	C47—H47b	0.97
C15—C24	1.523 (4)	C47—H47c	0.97
C15—C23	1.535 (4)	C48—H48a	0.97
C15—H15	0.99	C48—H48b	0.97
C16—C25	1.521 (4)	C48—H48c	0.97
C16—C26	1.531 (4)	C49—H49a	0.97
C16—H16	0.99	C49—H49b	0.97
C19—H19a	0.97	C49—H49c	0.97
C19—H19b	0.97	C50—H50a	0.97
C19—H19c	0.97	C50—H50b	0.97
C20—H20a	0.97	C50—H50c	0.97
C20—H20b	0.97	C51—H51a	0.97
C20—H20c	0.97	C51—H51b	0.97
C21—H21a	0.97	C51—H51c	0.97
C21—H21b	0.97
Cl2—Ni1—Cl1	167.87 (5)	C11—C22—H22A	109.5
Cl2—Ni1—P4	89.60 (3)	C11—C22—H22B	109.5
Cl1—Ni1—P4	90.97 (3)	H22A—C22—H22B	109.5
Cl2—Ni1—P1	90.82 (3)	C11—C22—H22C	109.5
Cl1—Ni1—P1	90.31 (3)	H22A—C22—H22C	109.5
P4—Ni1—P1	171.91 (4)	H22B—C22—H22C	109.5
Cl3—Ni2—Cl4	170.36 (4)	C15—C23—H23A	109.5
Cl3—Ni2—P3	91.39 (3)	C15—C23—H23B	109.5
Cl4—Ni2—P3	88.26 (3)	H23A—C23—H23B	109.5
Cl3—Ni2—P2	92.16 (3)	C15—C23—H23C	109.5
Cl4—Ni2—P2	88.24 (3)	H23A—C23—H23C	109.5
P3—Ni2—P2	176.46 (4)	H23B—C23—H23C	109.5
Cl6—Ni3—Cl5	175.36 (4)	C15—C24—H24A	109.5
Cl6—Ni3—P6^i	87.26 (3)	C15—C24—H24B	109.5
Cl5—Ni3—P6^i	92.48 (3)	H24A—C24—H24B	109.5
Cl6—Ni3—P5	93.09 (4)	C15—C24—H24C	109.5
Cl5—Ni3—P5	87.13 (4)	H24A—C24—H24C	109.5
P6^i—Ni3—P5	179.37 (4)	H24B—C24—H24C	109.5
C1—P1—C14	101.75 (14)	C16—C25—H25A	109.5
C1—P1—C13	105.94 (15)	C16—C25—H25B	109.5
C14—P1—C13	103.97 (16)	H25A—C25—H25B	109.5
C1—P1—Ni1	115.37 (10)	C16—C25—H25C	109.5
C14—P1—Ni1	113.60 (11)	H25A—C25—H25C	109.5
C13—P1—Ni1	114.77 (11)	H25B—C25—H25C	109.5
C5—P2—C17	103.43 (14)	C16—C26—H26A	109.5
C5—P2—C18	106.11 (14)	C16—C26—H26B	109.5
C17—P2—C18	104.05 (14)	H26A—C26—H26B	109.5
C5—P2—Ni2	109.7 (1)	C16—C26—H26C	109.5
C17—P2—Ni2	116.62 (11)	H26A—C26—H26C	109.5
C18—P2—Ni2	115.75 (11)	H26B—C26—H26C	109.5
C6—P3—C16	104.07 (14)	C18—C27—H27A	109.5
C6—P3—C15	106.85 (14)	C18—C27—H27B	109.5
C16—P3—C15	103.25 (15)	H27A—C27—H27B	109.5
C6—P3—Ni2	107.19 (10)	C18—C27—H27C	109.5
C16—P3—Ni2	117.90 (11)	H27A—C27—H27C	109.5
C15—P3—Ni2	116.49 (10)	H27B—C27—H27C	109.5
C10—P4—C11	106.24 (15)	C18—C28—H28A	109.5
C10—P4—C12	100.93 (14)	C18—C28—H28B	109.5
C11—P4—C12	104.25 (15)	H28A—C28—H28B	109.5
C10—P4—Ni1	114.41 (10)	C18—C28—H28C	109.5
C11—P4—Ni1	113.99 (11)	H28A—C28—H28C	109.5
C12—P4—Ni1	115.61 (12)	H28B—C28—H28C	109.5
C35—P5—C41	104.35 (16)	C17—C29—H29A	109.5
C35—P5—C40	104.70 (17)	C17—C29—H29B	109.5
C41—P5—C40	109.7 (2)	H29A—C29—H29B	109.5
C35—P5—Ni3	108.57 (11)	C17—C29—H29C	109.5
C41—P5—Ni3	116.93 (12)	H29A—C29—H29C	109.5
C40—P5—Ni3	111.60 (14)	H29B—C29—H29C	109.5
C39—P6—C42	103.32 (14)	C17—C30—H30A	109.5
C39—P6—C43	107.48 (13)	C17—C30—H30B	109.5
C42—P6—C43	104.11 (14)	H30A—C30—H30B	109.5
C39—P6—Ni3^i	109.08 (10)	C17—C30—H30C	109.5
C42—P6—Ni3^i	117.93 (11)	H30A—C30—H30C	109.5
C43—P6—Ni3^i	113.99 (10)	H30B—C30—H30C	109.5
C2—C1—P1	116.7 (2)	C13—C31—H31A	109.5
C2—C1—H1A	108.1	C13—C31—H31B	109.5
P1—C1—H1A	108.1	H31A—C31—H31B	109.5
C2—C1—H1B	108.1	C13—C31—H31C	109.5
P1—C1—H1B	108.1	H31A—C31—H31C	109.5
H1A—C1—H1B	107.3	H31B—C31—H31C	109.5
C3—C2—C1	112.1 (2)	C13—C32—H32A	109.5
C3—C2—H2A	109.2	C13—C32—H32B	109.5
C1—C2—H2A	109.2	H32A—C32—H32B	109.5
C3—C2—H2B	109.2	C13—C32—H32C	109.5
C1—C2—H2B	109.2	H32A—C32—H32C	109.5
H2A—C2—H2B	107.9	H32B—C32—H32C	109.5
C2—C3—C4	114.0 (2)	C14—C33—H33A	109.5
C2—C3—H3A	108.7	C14—C33—H33B	109.5
C4—C3—H3A	108.7	H33A—C33—H33B	109.5
C2—C3—H3B	108.7	C14—C33—H33C	109.5
C4—C3—H3B	108.7	H33A—C33—H33C	109.5
H3A—C3—H3B	107.6	H33B—C33—H33C	109.5
C5—C4—C3	112.3 (2)	C14—C34—H34A	109.5
C5—C4—H4A	109.1	C14—C34—H34B	109.5
C3—C4—H4A	109.1	H34A—C34—H34B	109.5
C5—C4—H4B	109.1	C14—C34—H34C	109.5
C3—C4—H4B	109.1	H34A—C34—H34C	109.5
H4A—C4—H4B	107.9	H34B—C34—H34C	109.5
C4—C5—P2	112.81 (19)	C36—C35—P5	111.5 (2)
C4—C5—H5A	109	C36—C35—H35A	109.3
P2—C5—H5A	109	P5—C35—H35A	109.3
C4—C5—H5B	109	C36—C35—H35B	109.3
P2—C5—H5B	109	P5—C35—H35B	109.3
H5A—C5—H5B	107.8	H35A—C35—H35B	108
C7—C6—P3	111.9 (2)	C37—C36—C35	113.1 (3)
C7—C6—H6A	109.2	C37—C36—H36A	109
P3—C6—H6A	109.2	C35—C36—H36A	109
C7—C6—H6B	109.2	C37—C36—H36B	109
P3—C6—H6B	109.2	C35—C36—H36B	109
H6A—C6—H6B	107.9	H36A—C36—H36B	107.8
C8—C7—C6	113.1 (3)	C38—C37—C36	113.8 (3)
C8—C7—H7A	109	C38—C37—H37A	108.8
C6—C7—H7A	109	C36—C37—H37A	108.8
C8—C7—H7B	109	C38—C37—H37B	108.8
C6—C7—H7B	109	C36—C37—H37B	108.8
H7A—C7—H7B	107.8	H37A—C37—H37B	107.7
C9—C8—C7	112.8 (2)	C37—C38—C39	113.0 (2)
C9—C8—H8A	109	C37—C38—H38A	109
C7—C8—H8A	109	C39—C38—H38A	109
C9—C8—H8B	109	C37—C38—H38B	109
C7—C8—H8B	109	C39—C38—H38B	109
H8A—C8—H8B	107.8	H38A—C38—H38B	107.8
C8—C9—C10	111.5 (2)	C38—C39—P6	111.6 (2)
C8—C9—H9A	109.3	C38—C39—H39A	109.3
C10—C9—H9A	109.3	P6—C39—H39A	109.3
C8—C9—H9B	109.3	C38—C39—H39B	109.3
C10—C9—H9B	109.3	P6—C39—H39B	109.3
H9A—C9—H9B	108	H39A—C39—H39B	108
C9—C10—P4	116.3 (2)	C45—C40—C44	117.5 (4)
C9—C10—H10A	108.2	C45—C40—P5	122.5 (3)
P4—C10—H10A	108.2	C44—C40—P5	111.8 (3)
C9—C10—H10B	108.2	C45—C40—H40	99.6
P4—C10—H10B	108.2	C44—C40—H40	99.6
H10A—C10—H10B	107.4	P5—C40—H40	99.6
C22—C11—C21	111.0 (3)	C46—C41—C47	110.2 (3)
C22—C11—P4	113.3 (2)	C46—C41—P5	111.5 (3)
C21—C11—P4	112.0 (2)	C47—C41—P5	116.5 (3)
C22—C11—H11	106.7	C46—C41—H41	106
C21—C11—H11	106.7	C47—C41—H41	106
P4—C11—H11	106.7	P5—C41—H41	106
C20—C12—C19	111.2 (3)	C48—C42—C49	109.8 (3)
C20—C12—P4	111.3 (3)	C48—C42—P6	114.1 (2)
C19—C12—P4	113.9 (2)	C49—C42—P6	112.4 (2)
C20—C12—H12	106.6	C48—C42—H42	106.7
C19—C12—H12	106.6	C49—C42—H42	106.7
P4—C12—H12	106.6	P6—C42—H42	106.7
C32—C13—C31	110.5 (3)	C51—C43—C50	110.8 (3)
C32—C13—P1	112.0 (2)	C51—C43—P6	114.7 (2)
C31—C13—P1	114.3 (2)	C50—C43—P6	109.7 (2)
C32—C13—H13	106.5	C51—C43—H43	107.1
C31—C13—H13	106.5	C50—C43—H43	107.1
P1—C13—H13	106.5	P6—C43—H43	107.1
C34—C14—C33	111.0 (3)	C40—C44—H44A	109.5
C34—C14—P1	112.2 (3)	C40—C44—H44B	109.5
C33—C14—P1	111.5 (2)	H44A—C44—H44B	109.5
C34—C14—H14	107.3	C40—C44—H44C	109.5
C33—C14—H14	107.3	H44A—C44—H44C	109.5
P1—C14—H14	107.3	H44B—C44—H44C	109.5
C28—C18—C27	110.6 (3)	C40—C45—H45A	109.5
C28—C18—P2	114.9 (2)	C40—C45—H45B	109.5
C27—C18—P2	110.6 (2)	H45A—C45—H45B	109.5
C28—C18—H18	106.7	C40—C45—H45C	109.5
C27—C18—H18	106.7	H45A—C45—H45C	109.5
P2—C18—H18	106.7	H45B—C45—H45C	109.5
C29—C17—C30	110.9 (3)	C41—C46—H46A	109.5
C29—C17—P2	111.4 (2)	C41—C46—H46B	109.5
C30—C17—P2	115.0 (2)	H46A—C46—H46B	109.5
C29—C17—H17	106.3	C41—C46—H46C	109.5
C30—C17—H17	106.3	H46A—C46—H46C	109.5
P2—C17—H17	106.3	H46B—C46—H46C	109.5
C24—C15—C23	110.4 (3)	C41—C47—H47A	109.5
C24—C15—P3	115.0 (2)	C41—C47—H47B	109.5
C23—C15—P3	110.6 (2)	H47A—C47—H47B	109.5
C24—C15—H15	106.8	C41—C47—H47C	109.5
C23—C15—H15	106.8	H47A—C47—H47C	109.5
P3—C15—H15	106.8	H47B—C47—H47C	109.5
C25—C16—C26	110.0 (3)	C42—C48—H48A	109.5
C25—C16—P3	114.2 (2)	C42—C48—H48B	109.5
C26—C16—P3	111.3 (2)	H48A—C48—H48B	109.5
C25—C16—H16	107	C42—C48—H48C	109.5
C26—C16—H16	107	H48A—C48—H48C	109.5
P3—C16—H16	107	H48B—C48—H48C	109.5
C12—C19—H19A	109.5	C42—C49—H49A	109.5
C12—C19—H19B	109.5	C42—C49—H49B	109.5
H19A—C19—H19B	109.5	H49A—C49—H49B	109.5
C12—C19—H19C	109.5	C42—C49—H49C	109.5
H19A—C19—H19C	109.5	H49A—C49—H49C	109.5
H19B—C19—H19C	109.5	H49B—C49—H49C	109.5
C12—C20—H20A	109.5	C43—C50—H50A	109.5
C12—C20—H20B	109.5	C43—C50—H50B	109.5
H20A—C20—H20B	109.5	H50A—C50—H50B	109.5
C12—C20—H20C	109.5	C43—C50—H50C	109.5
H20A—C20—H20C	109.5	H50A—C50—H50C	109.5
H20B—C20—H20C	109.5	H50B—C50—H50C	109.5
C11—C21—H21A	109.5	C43—C51—H51A	109.5
C11—C21—H21B	109.5	C43—C51—H51B	109.5
H21A—C21—H21B	109.5	H51A—C51—H51B	109.5
C11—C21—H21C	109.5	C43—C51—H51C	109.5
H21A—C21—H21C	109.5	H51A—C51—H51C	109.5
H21B—C21—H21C	109.5	H51B—C51—H51C	109.5
Cl2—Ni1—P1—C1	−159.36 (11)	C14—P1—C13—C31	55.7 (3)
Cl1—Ni1—P1—C1	32.72 (11)	Ni1—P1—C13—C31	−179.6 (2)
Cl2—Ni1—P1—C14	83.71 (13)	C1—P1—C14—C34	166.4 (3)
Cl1—Ni1—P1—C14	−84.22 (13)	C13—P1—C14—C34	56.5 (3)
Cl2—Ni1—P1—C13	−35.74 (13)	Ni1—P1—C14—C34	−69.0 (3)
Cl1—Ni1—P1—C13	156.33 (13)	C1—P1—C14—C33	−68.4 (3)
Cl3—Ni2—P2—C5	105.71 (10)	C13—P1—C14—C33	−178.3 (3)
Cl4—Ni2—P2—C5	−64.65 (10)	Ni1—P1—C14—C33	56.3 (3)
Cl3—Ni2—P2—C17	−11.39 (11)	C5—P2—C18—C28	28.7 (3)
Cl4—Ni2—P2—C17	178.25 (11)	C17—P2—C18—C28	137.4 (2)
Cl3—Ni2—P2—C18	−134.29 (12)	Ni2—P2—C18—C28	−93.3 (2)
Cl4—Ni2—P2—C18	55.35 (12)	C5—P2—C18—C27	154.7 (2)
Cl3—Ni2—P3—C6	−106.46 (11)	C17—P2—C18—C27	−96.5 (2)
Cl4—Ni2—P3—C6	63.90 (11)	Ni2—P2—C18—C27	32.8 (3)
Cl3—Ni2—P3—C16	10.39 (12)	C5—P2—C17—C29	172.4 (2)
Cl4—Ni2—P3—C16	−179.25 (12)	C18—P2—C17—C29	61.7 (3)
Cl3—Ni2—P3—C15	134.00 (12)	Ni2—P2—C17—C29	−67.1 (3)
Cl4—Ni2—P3—C15	−55.64 (12)	C5—P2—C17—C30	45.2 (3)
Cl2—Ni1—P4—C10	164.84 (11)	C18—P2—C17—C30	−65.5 (3)
Cl1—Ni1—P4—C10	−27.27 (11)	Ni2—P2—C17—C30	165.7 (2)
Cl2—Ni1—P4—C11	42.29 (12)	C6—P3—C15—C24	−26.7 (3)
Cl1—Ni1—P4—C11	−149.83 (11)	C16—P3—C15—C24	−136.1 (2)
Cl2—Ni1—P4—C12	−78.51 (13)	Ni2—P3—C15—C24	93.0 (2)
Cl1—Ni1—P4—C12	89.37 (13)	C6—P3—C15—C23	−152.6 (2)
Cl6—Ni3—P5—C35	116.87 (12)	C16—P3—C15—C23	98.0 (3)
Cl5—Ni3—P5—C35	−58.49 (12)	Ni2—P3—C15—C23	−32.9 (3)
Cl6—Ni3—P5—C41	−0.77 (14)	C6—P3—C16—C25	−46.0 (3)
Cl5—Ni3—P5—C41	−176.13 (13)	C15—P3—C16—C25	65.5 (3)
Cl6—Ni3—P5—C40	−128.24 (18)	Ni2—P3—C16—C25	−164.5 (2)
Cl5—Ni3—P5—C40	56.40 (18)	C6—P3—C16—C26	−171.3 (3)
C14—P1—C1—C2	174.3 (2)	C15—P3—C16—C26	−59.8 (3)
C13—P1—C1—C2	−77.3 (3)	Ni2—P3—C16—C26	70.2 (3)
Ni1—P1—C1—C2	50.8 (3)	C41—P5—C35—C36	70.9 (3)
P1—C1—C2—C3	−171.1 (2)	C40—P5—C35—C36	−173.8 (3)
C1—C2—C3—C4	174.2 (3)	Ni3—P5—C35—C36	−54.5 (3)
C2—C3—C4—C5	−175.6 (3)	P5—C35—C36—C37	176.1 (2)
C3—C4—C5—P2	−174.5 (2)	C35—C36—C37—C38	178.3 (3)
C17—P2—C5—C4	66.1 (2)	C36—C37—C38—C39	−175.4 (3)
C18—P2—C5—C4	175.3 (2)	C37—C38—C39—P6	175.6 (2)
Ni2—P2—C5—C4	−59.0 (2)	C42—P6—C39—C38	−65.5 (3)
C16—P3—C6—C7	−64.1 (2)	C43—P6—C39—C38	−175.2 (2)
C15—P3—C6—C7	−172.9 (2)	Ni3^i—P6—C39—C38	60.7 (2)
Ni2—P3—C6—C7	61.5 (2)	C35—P5—C40—C45	−52.5 (5)
P3—C6—C7—C8	−174.9 (2)	C41—P5—C40—C45	58.9 (5)
C6—C7—C8—C9	−172.5 (3)	Ni3—P5—C40—C45	−169.8 (5)
C7—C8—C9—C10	171.2 (2)	C35—P5—C40—C44	159.9 (3)
C8—C9—C10—P4	159.5 (2)	C41—P5—C40—C44	−88.6 (4)
C11—P4—C10—C9	68.8 (3)	Ni3—P5—C40—C44	42.7 (4)
C12—P4—C10—C9	177.3 (2)	C35—P5—C41—C46	166.8 (3)
Ni1—P4—C10—C9	−57.8 (2)	C40—P5—C41—C46	55.1 (3)
C10—P4—C11—C22	47.7 (3)	Ni3—P5—C41—C46	−73.3 (3)
C12—P4—C11—C22	−58.5 (3)	C35—P5—C41—C47	39.1 (3)
Ni1—P4—C11—C22	174.6 (2)	C40—P5—C41—C47	−72.6 (3)
C10—P4—C11—C21	−78.8 (3)	Ni3—P5—C41—C47	159.0 (3)
C12—P4—C11—C21	175.1 (2)	C39—P6—C42—C48	−40.5 (3)
Ni1—P4—C11—C21	48.1 (3)	C43—P6—C42—C48	71.7 (3)
C10—P4—C12—C20	66.2 (3)	Ni3^i—P6—C42—C48	−160.8 (2)
C11—P4—C12—C20	176.3 (3)	C39—P6—C42—C49	−166.3 (2)
Ni1—P4—C12—C20	−57.8 (3)	C43—P6—C42—C49	−54.1 (3)
C10—P4—C12—C19	−167.0 (3)	Ni3^i—P6—C42—C49	73.3 (3)
C11—P4—C12—C19	−57.0 (3)	C39—P6—C43—C51	−28.3 (3)
Ni1—P4—C12—C19	69.0 (3)	C42—P6—C43—C51	−137.5 (2)
C1—P1—C13—C32	75.5 (3)	Ni3^i—P6—C43—C51	92.7 (2)
C14—P1—C13—C32	−177.7 (2)	C39—P6—C43—C50	−153.8 (2)
Ni1—P1—C13—C32	−53.0 (3)	C42—P6—C43—C50	97.0 (3)
C1—P1—C13—C31	−51.1 (3)	Ni3^i—P6—C43—C50	−32.8 (3)

Symmetry code: (i) −x+1, −y+1, −z+2.