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The title centrosymmetric dimer, [Mn2(C7H4O5S)2(C10H8N2)4]·2H2O, was obtained by hydro­thermal synthesis. The coordination geometry of the MnII atom is distorted octa­hedral, defined by four N atoms from two 2,2′-bipyridine ligands and two O atoms from two carboxyl­ate groups of two μ-3-sulfonatobenzoate ligands. In the crystal structure, MnII complex mol­ecules are linked, through water mol­ecules, by inter­molecular O—H...O hydrogen bonds, forming extended one-dimensional chains along [1\overline{1}1].

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806026766/lh2123sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536806026766/lh2123Isup2.hkl
Contains datablock I

CCDC reference: 618274

Key indicators

  • Single-crystal X-ray study
  • T = 295 K
  • Mean [sigma](C-C) = 0.007 Å
  • R factor = 0.054
  • wR factor = 0.153
  • Data-to-parameter ratio = 12.6

checkCIF/PLATON results

No syntax errors found



Alert level C PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT094_ALERT_2_C Ratio of Maximum / Minimum Residual Density .... 3.74 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for S1 PLAT341_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 7 PLAT601_ALERT_2_C Structure Contains Solvent Accessible VOIDS of . 38.00 A   3
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 5 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 3 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 0 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Bruker, 2002); cell refinement: SAINT (Bruker, 2002); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997); software used to prepare material for publication: WinGX (Farrugia, 1999).

Bis(µ-3-sulfonatobenzoato)bis[bis(2,2'-bipyridine)manganese(II)] dihydrate top
Crystal data top
[Mn2(C7H4O5S)2(C10H8N2)4]·2H2OZ = 1
Mr = 1170.97F(000) = 602
Triclinic, P1Dx = 1.519 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 10.1223 (15) ÅCell parameters from 2142 reflections
b = 12.0573 (17) Åθ = 2.5–23.0°
c = 12.3757 (18) ŵ = 0.65 mm1
α = 62.927 (2)°T = 295 K
β = 79.505 (2)°Block, pale yellow
γ = 72.400 (2)°0.17 × 0.10 × 0.10 mm
V = 1280.2 (3) Å3
Data collection top
Bruker APEX area-detector
diffractometer
4515 independent reflections
Radiation source: fine-focus sealed tube3553 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.034
φ and ω scansθmax = 25.1°, θmin = 1.9°
Absorption correction: multi-scan
(SADABS; Bruker, 2002)
h = 1211
Tmin = 0.898, Tmax = 0.938k = 1414
9370 measured reflectionsl = 1414
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.054Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.153H-atom parameters constrained
S = 0.96 w = 1/[σ2(Fo2) + (0.0869P)2 + 0.9109P]
where P = (Fo2 + 2Fc2)/3
4515 reflections(Δ/σ)max = 0.001
358 parametersΔρmax = 0.97 e Å3
4 restraintsΔρmin = 0.26 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Mn10.60729 (5)0.53886 (5)0.12441 (5)0.03080 (19)
S10.93893 (12)0.12924 (10)0.34533 (10)0.0513 (3)
O10.6709 (3)0.3583 (2)0.1191 (2)0.0441 (7)
O20.5912 (3)0.3862 (2)0.0500 (2)0.0442 (6)
O30.9803 (5)0.2567 (3)0.3543 (4)0.1007 (14)
O40.8328 (4)0.1141 (4)0.4372 (3)0.0808 (11)
O51.0499 (4)0.0778 (4)0.3429 (3)0.0820 (11)
N10.8214 (3)0.5129 (3)0.1773 (3)0.0364 (7)
N20.7217 (3)0.6560 (3)0.0438 (3)0.0359 (7)
N30.5404 (3)0.6945 (3)0.1964 (3)0.0399 (7)
N40.5028 (3)0.4567 (3)0.3115 (3)0.0404 (7)
C10.8643 (4)0.4426 (4)0.2899 (4)0.0474 (10)
H10.81090.38910.34700.057*
C20.9842 (5)0.4452 (5)0.3263 (4)0.0591 (12)
H21.01080.39500.40590.071*
C31.0623 (5)0.5236 (5)0.2419 (5)0.0626 (13)
H31.14280.52880.26350.075*
C41.0209 (4)0.5948 (4)0.1246 (4)0.0493 (10)
H41.07430.64720.06590.059*
C50.8998 (4)0.5883 (3)0.0944 (3)0.0363 (8)
C60.8480 (4)0.6622 (3)0.0310 (3)0.0346 (8)
C70.9252 (4)0.7328 (4)0.1287 (4)0.0493 (10)
H71.01210.73640.11780.059*
C80.8723 (5)0.7976 (4)0.2422 (4)0.0552 (11)
H80.92260.84600.30840.066*
C90.7455 (5)0.7902 (4)0.2567 (4)0.0546 (11)
H90.70840.83210.33290.066*
C100.6733 (4)0.7188 (4)0.1555 (4)0.0475 (10)
H100.58660.71400.16540.057*
C110.5722 (4)0.8087 (4)0.1444 (4)0.0543 (11)
H110.63750.82380.07930.065*
C120.5134 (5)0.9043 (5)0.1824 (5)0.0658 (13)
H120.53890.98190.14450.079*
C130.4166 (6)0.8829 (5)0.2769 (5)0.0711 (14)
H130.37390.94650.30370.085*
C140.3829 (5)0.7669 (5)0.3321 (4)0.0612 (13)
H140.31730.75110.39690.073*
C150.4468 (4)0.6737 (4)0.2910 (3)0.0397 (9)
C160.4192 (4)0.5444 (4)0.3496 (3)0.0404 (9)
C170.3151 (5)0.5127 (5)0.4392 (4)0.0604 (12)
H170.25660.57480.46270.073*
C180.2982 (5)0.3901 (6)0.4933 (4)0.0698 (15)
H180.22800.36830.55290.084*
C190.3865 (5)0.3005 (5)0.4578 (4)0.0644 (13)
H190.37900.21590.49490.077*
C200.4868 (5)0.3366 (4)0.3667 (4)0.0515 (11)
H200.54570.27500.34250.062*
C210.6600 (3)0.3196 (3)0.0432 (3)0.0317 (8)
C220.7369 (3)0.1832 (3)0.0672 (3)0.0336 (8)
C230.7943 (4)0.1000 (3)0.1790 (3)0.0357 (8)
H230.78690.12960.23790.043*
C240.8621 (4)0.0264 (3)0.2033 (4)0.0395 (9)
C250.8739 (4)0.0703 (4)0.1154 (4)0.0483 (10)
H250.91840.15560.13190.058*
C260.8199 (4)0.0118 (4)0.0038 (4)0.0522 (11)
H260.82940.01770.05540.063*
C270.7513 (4)0.1384 (4)0.0207 (4)0.0431 (9)
H270.71480.19360.09620.052*
O1W0.8052 (5)0.1239 (5)0.4632 (4)0.1074 (16)
H1A0.830 (4)0.054 (3)0.455 (4)0.080*
H1B0.860 (4)0.121 (4)0.509 (4)0.080*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Mn10.0286 (3)0.0319 (3)0.0330 (3)0.0054 (2)0.0020 (2)0.0159 (2)
S10.0531 (7)0.0339 (5)0.0541 (7)0.0075 (5)0.0121 (5)0.0069 (5)
O10.0523 (16)0.0345 (14)0.0464 (16)0.0017 (12)0.0124 (13)0.0223 (13)
O20.0325 (14)0.0443 (15)0.0517 (16)0.0046 (12)0.0139 (12)0.0215 (13)
O30.155 (4)0.0353 (18)0.090 (3)0.010 (2)0.044 (3)0.0161 (18)
O40.074 (2)0.087 (3)0.055 (2)0.021 (2)0.0036 (18)0.0095 (19)
O50.074 (2)0.086 (3)0.073 (2)0.035 (2)0.0269 (19)0.005 (2)
N10.0309 (16)0.0389 (17)0.0371 (17)0.0043 (13)0.0018 (13)0.0172 (14)
N20.0318 (16)0.0407 (17)0.0346 (17)0.0070 (13)0.0004 (13)0.0175 (14)
N30.0320 (16)0.0460 (19)0.0474 (19)0.0054 (14)0.0018 (14)0.0276 (16)
N40.0406 (18)0.0460 (19)0.0359 (17)0.0113 (15)0.0028 (14)0.0179 (15)
C10.039 (2)0.058 (3)0.042 (2)0.0069 (19)0.0029 (18)0.021 (2)
C20.055 (3)0.068 (3)0.054 (3)0.000 (2)0.023 (2)0.028 (2)
C30.050 (3)0.073 (3)0.077 (3)0.015 (2)0.022 (2)0.035 (3)
C40.036 (2)0.056 (3)0.062 (3)0.0141 (19)0.0067 (19)0.027 (2)
C50.0306 (19)0.0340 (19)0.049 (2)0.0048 (15)0.0003 (16)0.0241 (18)
C60.0319 (19)0.0311 (18)0.043 (2)0.0039 (15)0.0002 (16)0.0207 (17)
C70.049 (2)0.048 (2)0.054 (3)0.023 (2)0.009 (2)0.022 (2)
C80.067 (3)0.048 (2)0.045 (3)0.026 (2)0.012 (2)0.014 (2)
C90.063 (3)0.052 (3)0.036 (2)0.009 (2)0.003 (2)0.011 (2)
C100.045 (2)0.054 (2)0.040 (2)0.0083 (19)0.0060 (18)0.018 (2)
C110.049 (3)0.054 (3)0.071 (3)0.015 (2)0.004 (2)0.037 (2)
C120.070 (3)0.050 (3)0.087 (4)0.005 (2)0.009 (3)0.041 (3)
C130.081 (4)0.057 (3)0.081 (4)0.005 (3)0.001 (3)0.050 (3)
C140.061 (3)0.064 (3)0.056 (3)0.004 (2)0.002 (2)0.037 (2)
C150.0293 (19)0.052 (2)0.039 (2)0.0021 (17)0.0092 (16)0.0263 (19)
C160.033 (2)0.054 (2)0.036 (2)0.0071 (17)0.0083 (16)0.0215 (19)
C170.049 (3)0.090 (4)0.046 (3)0.020 (3)0.009 (2)0.036 (3)
C180.060 (3)0.113 (5)0.044 (3)0.043 (3)0.013 (2)0.032 (3)
C190.074 (3)0.074 (3)0.045 (3)0.041 (3)0.003 (2)0.011 (2)
C200.061 (3)0.050 (2)0.045 (2)0.020 (2)0.005 (2)0.017 (2)
C210.0257 (18)0.0320 (18)0.037 (2)0.0087 (15)0.0004 (15)0.0147 (16)
C220.0271 (18)0.0321 (19)0.041 (2)0.0051 (15)0.0027 (15)0.0162 (16)
C230.0348 (19)0.0341 (19)0.042 (2)0.0081 (16)0.0026 (16)0.0190 (17)
C240.037 (2)0.0317 (19)0.050 (2)0.0078 (16)0.0038 (17)0.0167 (18)
C250.040 (2)0.036 (2)0.071 (3)0.0014 (17)0.008 (2)0.028 (2)
C260.051 (2)0.054 (3)0.068 (3)0.005 (2)0.010 (2)0.043 (2)
C270.038 (2)0.046 (2)0.049 (2)0.0029 (18)0.0088 (18)0.0259 (19)
O1W0.128 (4)0.103 (3)0.088 (3)0.029 (3)0.046 (3)0.059 (3)
Geometric parameters (Å, º) top
Mn1—O12.104 (2)C8—H80.9300
Mn1—O2i2.126 (2)C9—C101.382 (6)
Mn1—N12.268 (3)C9—H90.9300
Mn1—N22.259 (3)C10—H100.9300
Mn1—N32.304 (3)C11—C121.371 (6)
Mn1—N42.262 (3)C11—H110.9300
S1—O31.422 (4)C12—C131.362 (7)
S1—O41.451 (4)C12—H120.9300
S1—O51.428 (3)C13—C141.368 (7)
S1—C241.779 (4)C13—H130.9300
O1—C211.257 (4)C14—C151.379 (6)
O2—C211.253 (4)C14—H140.9300
O2—Mn1i2.126 (2)C15—C161.481 (6)
N1—C11.331 (5)C16—C171.385 (6)
N1—C51.341 (5)C17—C181.368 (7)
N2—C101.340 (5)C17—H170.9300
N2—C61.344 (4)C18—C191.364 (7)
N3—C111.342 (5)C18—H180.9300
N3—C151.343 (5)C19—C201.377 (6)
N4—C201.338 (5)C19—H190.9300
N4—C161.351 (5)C20—H200.9300
C1—C21.382 (6)C21—C221.505 (5)
C1—H10.9300C22—C271.387 (5)
C2—C31.365 (7)C22—C231.391 (5)
C2—H20.9300C23—C241.382 (5)
C3—C41.374 (6)C23—H230.9300
C3—H30.9300C24—C251.383 (6)
C4—C51.379 (5)C25—C261.375 (6)
C4—H40.9300C25—H250.9300
C5—C61.493 (5)C26—C271.385 (6)
C6—C71.386 (5)C26—H260.9300
C7—C81.375 (6)C27—H270.9300
C7—H70.9300O1W—H1A0.85 (4)
C8—C91.363 (6)O1W—H1B0.85 (5)
O1—Mn1—O2i101.61 (10)C8—C9—C10118.3 (4)
O1—Mn1—N2101.14 (11)C8—C9—H9120.8
O2i—Mn1—N296.64 (11)C10—C9—H9120.8
O1—Mn1—N491.86 (11)N2—C10—C9123.4 (4)
O2i—Mn1—N488.72 (11)N2—C10—H10118.3
N2—Mn1—N4164.60 (11)C9—C10—H10118.3
O1—Mn1—N190.50 (10)N3—C11—C12123.4 (4)
O2i—Mn1—N1165.13 (11)N3—C11—H11118.3
N2—Mn1—N172.31 (11)C12—C11—H11118.3
N4—Mn1—N199.59 (11)C13—C12—C11118.4 (5)
O1—Mn1—N3161.48 (11)C13—C12—H12120.8
O2i—Mn1—N386.74 (10)C11—C12—H12120.8
N2—Mn1—N394.18 (11)C12—C13—C14119.5 (4)
N4—Mn1—N371.64 (12)C12—C13—H13120.3
N1—Mn1—N384.25 (11)C14—C13—H13120.3
O3—S1—O5115.0 (3)C13—C14—C15119.6 (4)
O3—S1—O4112.9 (3)C13—C14—H14120.2
O5—S1—O4110.1 (2)C15—C14—H14120.2
O3—S1—C24107.6 (2)N3—C15—C14121.5 (4)
O5—S1—C24104.69 (19)N3—C15—C16116.1 (3)
O4—S1—C24105.84 (19)C14—C15—C16122.4 (4)
C21—O1—Mn1133.6 (2)N4—C16—C17120.9 (4)
C21—O2—Mn1i147.1 (2)N4—C16—C15116.2 (3)
C1—N1—C5118.3 (3)C17—C16—C15123.0 (4)
C1—N1—Mn1123.6 (3)C18—C17—C16120.2 (5)
C5—N1—Mn1117.2 (2)C18—C17—H17119.9
C10—N2—C6117.7 (3)C16—C17—H17119.9
C10—N2—Mn1124.7 (3)C19—C18—C17118.6 (4)
C6—N2—Mn1117.6 (2)C19—C18—H18120.7
C11—N3—C15117.6 (3)C17—C18—H18120.7
C11—N3—Mn1126.4 (3)C18—C19—C20119.4 (5)
C15—N3—Mn1115.4 (2)C18—C19—H19120.3
C20—N4—C16118.3 (3)C20—C19—H19120.3
C20—N4—Mn1123.4 (3)N4—C20—C19122.5 (4)
C16—N4—Mn1115.3 (2)N4—C20—H20118.7
N1—C1—C2123.3 (4)C19—C20—H20118.7
N1—C1—H1118.3O2—C21—O1124.9 (3)
C2—C1—H1118.3O2—C21—C22118.5 (3)
C3—C2—C1118.0 (4)O1—C21—C22116.6 (3)
C3—C2—H2121.0C27—C22—C23119.1 (3)
C1—C2—H2121.0C27—C22—C21120.9 (3)
C2—C3—C4119.4 (4)C23—C22—C21119.9 (3)
C2—C3—H3120.3C24—C23—C22120.5 (3)
C4—C3—H3120.3C24—C23—H23119.8
C3—C4—C5119.7 (4)C22—C23—H23119.8
C3—C4—H4120.1C23—C24—C25119.8 (4)
C5—C4—H4120.1C23—C24—S1119.5 (3)
N1—C5—C4121.2 (4)C25—C24—S1120.7 (3)
N1—C5—C6115.8 (3)C26—C25—C24120.2 (4)
C4—C5—C6123.0 (3)C26—C25—H25119.9
N2—C6—C7121.7 (4)C24—C25—H25119.9
N2—C6—C5116.0 (3)C25—C26—C27120.2 (4)
C7—C6—C5122.3 (3)C25—C26—H26119.9
C8—C7—C6119.4 (4)C27—C26—H26119.9
C8—C7—H7120.3C26—C27—C22120.2 (4)
C6—C7—H7120.3C26—C27—H27119.9
C9—C8—C7119.5 (4)C22—C27—H27119.9
C9—C8—H8120.3H1A—O1W—H1B109 (4)
C7—C8—H8120.3
O2i—Mn1—O1—C2139.5 (3)C4—C5—C6—N2173.5 (3)
N2—Mn1—O1—C2159.7 (3)N1—C5—C6—C7172.8 (3)
N4—Mn1—O1—C21128.6 (3)C4—C5—C6—C76.6 (6)
N1—Mn1—O1—C21131.8 (3)N2—C6—C7—C80.6 (6)
N3—Mn1—O1—C21155.0 (3)C5—C6—C7—C8179.3 (3)
O1—Mn1—N1—C180.2 (3)C6—C7—C8—C90.6 (6)
O2i—Mn1—N1—C1135.0 (4)C7—C8—C9—C101.0 (6)
N2—Mn1—N1—C1178.3 (3)C6—N2—C10—C91.0 (6)
N4—Mn1—N1—C111.8 (3)Mn1—N2—C10—C9179.8 (3)
N3—Mn1—N1—C182.0 (3)C8—C9—C10—N20.2 (6)
O1—Mn1—N1—C5110.4 (3)C15—N3—C11—C120.6 (6)
O2i—Mn1—N1—C534.4 (5)Mn1—N3—C11—C12170.5 (3)
N2—Mn1—N1—C58.9 (2)N3—C11—C12—C130.7 (7)
N4—Mn1—N1—C5157.6 (2)C11—C12—C13—C141.1 (8)
N3—Mn1—N1—C587.4 (3)C12—C13—C14—C150.3 (8)
O1—Mn1—N2—C1087.5 (3)C11—N3—C15—C141.4 (5)
O2i—Mn1—N2—C1015.8 (3)Mn1—N3—C15—C14170.6 (3)
N4—Mn1—N2—C10125.5 (4)C11—N3—C15—C16177.3 (3)
N1—Mn1—N2—C10174.4 (3)Mn1—N3—C15—C1610.7 (4)
N3—Mn1—N2—C10103.0 (3)C13—C14—C15—N31.1 (7)
O1—Mn1—N2—C691.8 (2)C13—C14—C15—C16177.6 (4)
O2i—Mn1—N2—C6164.9 (2)C20—N4—C16—C173.2 (5)
N4—Mn1—N2—C655.2 (5)Mn1—N4—C16—C17157.8 (3)
N1—Mn1—N2—C64.9 (2)C20—N4—C16—C15176.3 (3)
N3—Mn1—N2—C677.7 (3)Mn1—N4—C16—C1522.7 (4)
O1—Mn1—N3—C11144.4 (4)N3—C15—C16—N47.8 (5)
O2i—Mn1—N3—C1197.9 (3)C14—C15—C16—N4170.9 (3)
N2—Mn1—N3—C111.5 (3)N3—C15—C16—C17172.7 (3)
N4—Mn1—N3—C11172.4 (3)C14—C15—C16—C178.6 (6)
N1—Mn1—N3—C1170.2 (3)N4—C16—C17—C182.0 (6)
O1—Mn1—N3—C1544.3 (5)C15—C16—C17—C18177.4 (4)
O2i—Mn1—N3—C1573.3 (3)C16—C17—C18—C190.6 (7)
N2—Mn1—N3—C15169.8 (2)C17—C18—C19—C202.0 (7)
N4—Mn1—N3—C1516.4 (2)C16—N4—C20—C191.8 (6)
N1—Mn1—N3—C15118.5 (3)Mn1—N4—C20—C19157.6 (3)
O1—Mn1—N4—C208.0 (3)C18—C19—C20—N40.8 (7)
O2i—Mn1—N4—C2093.6 (3)Mn1i—O2—C21—O180.7 (5)
N2—Mn1—N4—C20155.7 (4)Mn1i—O2—C21—C2299.7 (5)
N1—Mn1—N4—C2098.8 (3)Mn1—O1—C21—O27.1 (6)
N3—Mn1—N4—C20179.4 (3)Mn1—O1—C21—C22172.4 (2)
O1—Mn1—N4—C16168.0 (3)O2—C21—C22—C2710.8 (5)
O2i—Mn1—N4—C1666.4 (3)O1—C21—C22—C27168.8 (3)
N2—Mn1—N4—C1644.3 (5)O2—C21—C22—C23168.9 (3)
N1—Mn1—N4—C16101.2 (3)O1—C21—C22—C2311.4 (5)
N3—Mn1—N4—C1620.6 (2)C27—C22—C23—C241.4 (5)
C5—N1—C1—C21.2 (6)C21—C22—C23—C24178.4 (3)
Mn1—N1—C1—C2168.1 (3)C22—C23—C24—C250.4 (5)
N1—C1—C2—C30.3 (7)C22—C23—C24—S1178.1 (3)
C1—C2—C3—C41.1 (7)O3—S1—C24—C23170.4 (3)
C2—C3—C4—C51.4 (7)O5—S1—C24—C2366.8 (4)
C1—N1—C5—C40.9 (5)O4—S1—C24—C2349.5 (4)
Mn1—N1—C5—C4169.1 (3)O3—S1—C24—C2511.9 (4)
C1—N1—C5—C6178.5 (3)O5—S1—C24—C25110.9 (4)
Mn1—N1—C5—C611.5 (4)O4—S1—C24—C25132.8 (3)
C3—C4—C5—N10.4 (6)C23—C24—C25—C260.8 (6)
C3—C4—C5—C6179.8 (4)S1—C24—C25—C26176.8 (3)
C10—N2—C6—C71.4 (5)C24—C25—C26—C271.1 (6)
Mn1—N2—C6—C7179.3 (3)C25—C26—C27—C220.1 (6)
C10—N2—C6—C5178.5 (3)C23—C22—C27—C261.1 (6)
Mn1—N2—C6—C50.8 (4)C21—C22—C27—C26178.6 (3)
N1—C5—C6—N27.1 (4)
Symmetry code: (i) x+1, y+1, z.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O1W—H1A···O40.85 (4)2.13 (4)2.956 (6)165 (4)
O1W—H1B···O5ii0.85 (5)1.98 (2)2.793 (5)161 (5)
Symmetry code: (ii) x+2, y, z+1.
 

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