Download citation
Download citation
link to html
Two new two-dimensional lanthanide coordination polymers, namely poly[[tetra-μ2-acetato-tetra­aqua­bis­(μ4-biphenyl-3,3′,5,5′-tetra­carboxyl­ato)tetra­kis­(di­methyl­acetamide)­tetra­terbium(III)] penta­hydrate], {[Tb4(C16H6O8)2(C2H3O2)4(C4H9NO)4(H2O)4]·5H2O}n, (1), and poly[[tetra-μ2-acetato-tetra­aqua­bis­(μ5-biphenyl-3,3′,5,5′-tetra­carboxyl­ato)tetra­kis­(di­methyl­acetamide)­tetra­europium(III)] tetra­hydrate], {[Eu4(C16H6O8)2(C2H3O2)4(C4H9NO)4(H2O)4]·4H2O}n, (2), have been synthesized from biphenyl-3,3′,5,5′-tetra­carb­oxy­lic acid (H4bpt) and Ln(NO3)3·6H2O (Ln = Tb and Eu) under solvothermal conditions. Single-crystal X-ray structure analysis shows that the two compounds are isostructural and crystallize in the monoclinic P21/n space group. The crystal structures are constructed from bpt4− ligands (as linkers) and {Ln22-CH3COO)2} building units (as nodes), which topological analysis shows to be a (4,6)-connected network with sql topology. Compounds (1) and (2) have been characterized by elemental analysis, IR spectroscopy, powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA) and fluorescence analysis in the solid state. In addition, a magnetic investigation shows the presence of anti­ferromagnetic inter­actions in compound (1).

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S205322961800205X/lf3071sup1.cif
Contains datablocks global, 140901b, 140903a

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S205322961800205X/lf3071140901bsup3.hkl
Contains datablock 140901b

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S205322961800205X/lf3071140903asup2.hkl
Contains datablock 140903a

pdf

Portable Document Format (PDF) file https://doi.org/10.1107/S205322961800205X/lf3071sup4.pdf
A perspective view of the ligand environment, as well as PXRD, TGA and IR spectra

CCDC references: 1814160; 1814159

Computing details top

For both structures, data collection: APEX2 (Bruker, 2014); cell refinement: SAINT (Bruker, 2014); data reduction: SAINT (Bruker, 2014); program(s) used to solve structure: SHELXS2015 (Sheldrick, 2015a); program(s) used to refine structure: SHELXL2015 (Sheldrick, 2015b); molecular graphics: Please provide; software used to prepare material for publication: SHELXL2015 (Sheldrick, 2015b).

Poly[[tetraaquatetra-µ2-acetato-bis(µ4-biphenyl-3,3',5,5'-tetracarboxylato)tetrakis(dimethylacetamide)tetraterbium(III)] pentahydrate] (140901b) top
Crystal data top
[Tb4(C16H6O8)2(C2H3O2)4(C4H9NO)4(H2O)4]·5H2OF(000) = 940
Mr = 2026.53Dx = 1.726 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
a = 9.3676 (7) ÅCell parameters from 2165 reflections
b = 17.6232 (14) Åθ = 2.9–25.9°
c = 11.3172 (9) ŵ = 3.83 mm1
β = 94.351 (2)°T = 298 K
V = 1862.9 (3) Å3Bloc, colorless
Z = 10.15 × 0.13 × 0.12 mm
Data collection top
Bruker APEXII CCD
diffractometer
2200 reflections with I > 2σ(I)
φ and ω scansRint = 0.072
Absorption correction: multi-scan
(SADABS; Bruker, 2014)
θmax = 25.0°, θmin = 2.9°
Tmin = 0.597, Tmax = 0.656h = 1011
8955 measured reflectionsk = 2020
3162 independent reflectionsl = 1113
Refinement top
Refinement on F2448 restraints
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.060H-atom parameters constrained
wR(F2) = 0.155 w = 1/[σ2(Fo2) + (0.0882P)2]
where P = (Fo2 + 2Fc2)/3
S = 1.01(Δ/σ)max = 0.001
3162 reflectionsΔρmax = 1.50 e Å3
221 parametersΔρmin = 1.58 e Å3
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Tb10.48343 (5)0.10111 (2)0.06839 (4)0.0370 (2)
C10.822 (2)0.0588 (10)0.1747 (16)0.098 (4)
H1A0.9053100.0844510.1398510.147*
H1B0.7999260.0773860.2537160.147*
H1C0.8404860.0052550.1773380.147*
C20.6939 (15)0.0737 (7)0.0994 (12)0.061 (2)
C30.5268 (15)0.2595 (6)0.1013 (11)0.0549 (17)
C40.5558 (13)0.3410 (6)0.1141 (10)0.0487 (17)
C50.4995 (14)0.3955 (6)0.0340 (11)0.0509 (18)
H50.4370690.3795670.0289340.061*
C60.5315 (13)0.4707 (6)0.0433 (10)0.0490 (19)
C70.6304 (12)0.4920 (5)0.1372 (9)0.0463 (19)
H70.6564620.5427380.1448990.056*
C80.6904 (13)0.4403 (5)0.2188 (10)0.0490 (18)
C90.7897 (13)0.4650 (5)0.3233 (10)0.048 (2)
C100.6527 (13)0.3644 (6)0.2052 (10)0.0487 (17)
H100.6932960.3286760.2581670.058*
C110.221 (2)0.1696 (9)0.2219 (15)0.081 (2)
C120.262 (2)0.1960 (12)0.3475 (18)0.118 (4)
H12A0.1852380.2252460.3757520.178*
H12B0.3467640.2268390.3483570.178*
H12C0.2804730.1527330.3978410.178*
C130.025 (2)0.1418 (13)0.0616 (17)0.111 (4)
H13A0.0240260.1758730.0046830.167*
H13B0.0702950.1238330.0703920.167*
H13C0.0864550.0995460.0482890.167*
C140.038 (2)0.2328 (12)0.2245 (18)0.116 (4)
H14A0.0171340.2480150.3053850.174*
H14B0.1234680.2024040.2184500.174*
H14C0.0524550.2770350.1755110.174*
O80.6689 (7)0.0340 (4)0.1736 (6)0.0394 (11)
N10.085 (2)0.1871 (10)0.1837 (18)0.128 (5)
O10.6106 (9)0.0205 (4)0.0793 (7)0.0507 (16)
O20.6799 (10)0.1354 (5)0.0524 (7)0.0604 (16)
O30.4373 (10)0.2369 (4)0.0145 (7)0.0597 (15)
O40.5873 (9)0.2110 (4)0.1704 (7)0.0533 (14)
O50.2821 (12)0.1275 (6)0.1533 (9)0.083 (2)
O60.4559 (15)0.0818 (7)0.2856 (9)0.100 (3)
O70.3366 (10)0.0867 (4)0.1050 (8)0.0585 (17)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Tb10.0467 (4)0.0168 (3)0.0444 (3)0.0029 (2)0.0169 (2)0.0035 (2)
C10.102 (9)0.091 (8)0.103 (9)0.019 (8)0.023 (8)0.002 (8)
C20.073 (5)0.046 (4)0.065 (4)0.010 (4)0.006 (4)0.004 (4)
C30.073 (3)0.033 (3)0.055 (3)0.000 (3)0.016 (3)0.007 (3)
C40.067 (4)0.024 (3)0.051 (3)0.002 (3)0.019 (3)0.001 (3)
C50.069 (4)0.028 (3)0.052 (3)0.000 (3)0.022 (3)0.001 (3)
C60.069 (4)0.023 (3)0.052 (4)0.003 (3)0.020 (4)0.001 (3)
C70.065 (4)0.024 (3)0.046 (4)0.002 (3)0.024 (3)0.002 (3)
C80.064 (4)0.026 (3)0.053 (4)0.001 (3)0.021 (3)0.004 (3)
C90.065 (5)0.024 (4)0.050 (4)0.001 (4)0.025 (4)0.001 (4)
C100.069 (4)0.026 (3)0.048 (3)0.002 (3)0.020 (3)0.000 (3)
C110.095 (5)0.064 (4)0.080 (5)0.003 (4)0.004 (4)0.012 (4)
C120.129 (9)0.114 (9)0.111 (9)0.013 (8)0.005 (8)0.020 (8)
C130.116 (9)0.103 (9)0.115 (9)0.005 (8)0.010 (8)0.000 (8)
C140.124 (9)0.115 (9)0.109 (9)0.008 (8)0.009 (8)0.015 (8)
O80.0396 (13)0.0377 (13)0.0400 (14)0.0038 (9)0.0037 (9)0.0020 (9)
N10.105 (12)0.124 (14)0.151 (14)0.002 (10)0.020 (11)0.038 (10)
O10.065 (4)0.029 (3)0.057 (4)0.006 (3)0.001 (3)0.000 (3)
O20.080 (4)0.040 (3)0.061 (3)0.011 (3)0.003 (3)0.007 (3)
O30.079 (3)0.035 (3)0.062 (3)0.001 (3)0.021 (3)0.007 (3)
O40.073 (3)0.030 (3)0.054 (3)0.003 (3)0.017 (3)0.004 (2)
O50.094 (4)0.066 (4)0.088 (4)0.005 (4)0.007 (4)0.013 (3)
O60.136 (7)0.115 (6)0.049 (2)0.001 (6)0.000 (5)0.000 (5)
O70.077 (4)0.037 (3)0.059 (4)0.003 (3)0.018 (3)0.009 (3)
Geometric parameters (Å, º) top
Tb1—O52.229 (11)C6—C71.407 (15)
Tb1—O1i2.324 (7)C6—C6ii1.51 (2)
Tb1—O72.323 (8)C7—C81.385 (14)
Tb1—O82.350 (7)C7—H70.9300
Tb1—O42.421 (7)C8—C101.390 (15)
Tb1—O22.451 (9)C8—C91.512 (15)
Tb1—O32.499 (7)C9—O7iii1.276 (12)
Tb1—O62.514 (10)C9—O8iv1.276 (12)
Tb1—O12.555 (8)C10—H100.9300
Tb1—Tb1i3.9071 (9)C11—O51.244 (18)
C1—C21.55 (2)C11—N11.35 (2)
C1—H1A0.9600C11—C121.52 (2)
C1—H1B0.9600C12—H12A0.9600
C1—H1C0.9600C12—H12B0.9600
C2—O21.221 (15)C12—H12C0.9600
C2—O11.252 (14)C13—N11.66 (3)
C3—O41.263 (14)C13—H13A0.9600
C3—O31.305 (14)C13—H13B0.9600
C3—C41.467 (15)C13—H13C0.9600
C4—C51.396 (15)C14—N11.51 (3)
C4—C101.384 (15)C14—H14A0.9600
C5—C61.362 (15)C14—H14B0.9600
C5—H50.9300C14—H14C0.9600
O5—Tb1—O1i80.4 (3)O3—C3—C4118.5 (10)
O5—Tb1—O785.5 (4)C5—C4—C10118.2 (9)
O1i—Tb1—O775.0 (3)C5—C4—C3123.5 (10)
O5—Tb1—O8120.3 (3)C10—C4—C3118.1 (10)
O1i—Tb1—O877.1 (3)C6—C5—C4123.4 (10)
O7—Tb1—O8137.8 (2)C6—C5—H5118.3
O5—Tb1—O487.1 (3)C4—C5—H5118.3
O1i—Tb1—O4148.5 (3)C5—C6—C7116.5 (10)
O7—Tb1—O4132.9 (2)C5—C6—C6ii122.9 (12)
O8—Tb1—O484.6 (2)C7—C6—C6ii120.7 (11)
O5—Tb1—O2152.2 (4)C8—C7—C6122.7 (9)
O1i—Tb1—O2124.1 (3)C8—C7—H7118.7
O7—Tb1—O288.7 (3)C6—C7—H7118.7
O8—Tb1—O281.3 (3)C7—C8—C10118.2 (9)
O4—Tb1—O277.1 (3)C7—C8—C9121.8 (8)
O5—Tb1—O376.6 (3)C10—C8—C9120.0 (9)
O1i—Tb1—O3146.8 (3)O7iii—C9—O8iv125.0 (10)
O7—Tb1—O379.5 (3)O7iii—C9—C8116.9 (8)
O8—Tb1—O3135.5 (3)O8iv—C9—C8117.6 (9)
O4—Tb1—O353.6 (2)C4—C10—C8121.1 (10)
O2—Tb1—O375.6 (3)C4—C10—H10119.5
O5—Tb1—O656.9 (4)C8—C10—H10119.5
O1i—Tb1—O675.9 (4)O5—C11—N1113.7 (16)
O7—Tb1—O6135.5 (4)O5—C11—C12132.2 (17)
O8—Tb1—O664.1 (3)N1—C11—C12113.4 (17)
O4—Tb1—O673.1 (3)C11—C12—H12A109.5
O2—Tb1—O6135.7 (4)C11—C12—H12B109.5
O3—Tb1—O6109.9 (3)H12A—C12—H12B109.5
O5—Tb1—O1148.1 (3)C11—C12—H12C109.5
O1i—Tb1—O173.7 (3)H12A—C12—H12C109.5
O7—Tb1—O170.3 (3)H12B—C12—H12C109.5
O8—Tb1—O171.8 (2)N1—C13—H13A109.5
O4—Tb1—O1124.5 (3)N1—C13—H13B109.5
O2—Tb1—O150.6 (2)H13A—C13—H13B109.5
O3—Tb1—O1116.9 (3)N1—C13—H13C109.5
O6—Tb1—O1130.7 (3)H13A—C13—H13C109.5
O5—Tb1—Tb1i117.2 (3)H13B—C13—H13C109.5
O1i—Tb1—Tb1i38.88 (19)N1—C14—H14A109.5
O7—Tb1—Tb1i68.02 (18)N1—C14—H14B109.5
O8—Tb1—Tb1i70.35 (16)H14A—C14—H14B109.5
O4—Tb1—Tb1i151.3 (2)N1—C14—H14C109.5
O2—Tb1—Tb1i85.32 (19)H14A—C14—H14C109.5
O3—Tb1—Tb1i142.58 (18)H14B—C14—H14C109.5
O6—Tb1—Tb1i106.3 (3)C9v—O8—Tb1134.9 (7)
O1—Tb1—Tb1i34.82 (16)C11—N1—C14138.6 (19)
C2—C1—H1A109.5C11—N1—C13114.3 (17)
C2—C1—H1B109.5C14—N1—C13106.9 (15)
H1A—C1—H1B109.5C2—O1—Tb1i160.8 (8)
C2—C1—H1C109.5C2—O1—Tb191.8 (7)
H1A—C1—H1C109.5Tb1i—O1—Tb1106.3 (3)
H1B—C1—H1C109.5C2—O2—Tb197.7 (8)
O2—C2—O1119.9 (12)C3—O3—Tb191.1 (6)
O2—C2—C1120.3 (12)C3—O4—Tb195.8 (6)
O1—C2—C1119.6 (12)C11—O5—Tb1146.9 (11)
O4—C3—O3119.5 (10)C9vi—O7—Tb1140.2 (7)
O4—C3—C4122.0 (10)
Symmetry codes: (i) x+1, y, z; (ii) x+1, y+1, z; (iii) x+1/2, y+1/2, z+1/2; (iv) x+3/2, y+1/2, z+1/2; (v) x+3/2, y1/2, z+1/2; (vi) x1/2, y+1/2, z1/2.
Poly[[tetraaquatetra-µ2-acetato-bis(µ5-biphenyl-3,3',5,5'-tetracarboxylato)tetrakis(dimethylacetamide)tetraeuropium(III)] tetraahydrate] (140903a) top
Crystal data top
[Eu4(C16H6O8)2(C2H3O2)4(C4H9NO)4(H2O)4]·4H2OF(000) = 932
Mr = 1908.92Dx = 1.678 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
a = 9.4453 (5) ÅCell parameters from 2715 reflections
b = 17.7439 (14) Åθ = 2.5–24.7°
c = 11.3019 (8) ŵ = 3.36 mm1
β = 94.278 (1)°T = 298 K
V = 1888.9 (2) Å3Bloc, colorless
Z = 10.16 × 0.14 × 0.13 mm
Data collection top
Bruker APEXII CCD
diffractometer
2250 reflections with I > 2σ(I)
φ and ω scansRint = 0.101
Absorption correction: multi-scan
(SADABS; Bruker, 2014)
θmax = 25.0°, θmin = 2.5°
Tmin = 0.562, Tmax = 0.610h = 1011
8950 measured reflectionsk = 1221
3206 independent reflectionsl = 1313
Refinement top
Refinement on F2479 restraints
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.072H-atom parameters constrained
wR(F2) = 0.196 w = 1/[σ2(Fo2) + (0.130P)2]
where P = (Fo2 + 2Fc2)/3
S = 0.96(Δ/σ)max = 0.009
3206 reflectionsΔρmax = 1.42 e Å3
208 parametersΔρmin = 2.35 e Å3
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Eu10.51698 (6)0.89862 (3)0.92988 (5)0.0376 (3)
N10.9264 (13)0.8207 (8)0.8248 (12)0.100 (3)
O10.4120 (10)0.7872 (5)0.8308 (8)0.0592 (16)
O20.5616 (10)0.7626 (5)0.9825 (8)0.0625 (16)
O30.7192 (13)0.8708 (7)0.8418 (11)0.085 (2)
O40.6641 (11)0.9131 (5)1.1088 (9)0.0650 (19)
O50.3915 (10)0.9787 (5)1.0828 (8)0.0582 (18)
O60.3212 (11)0.8642 (5)1.0502 (9)0.0670 (18)
O70.3275 (10)0.9667 (4)0.8285 (8)0.0635 (19)
C10.4730 (16)0.7393 (7)0.8984 (12)0.0600 (18)
C20.4446 (9)0.6571 (2)0.8898 (7)0.0526 (18)
C30.5031 (9)0.6042 (3)0.9700 (6)0.0540 (19)
H30.5661750.6194951.0325620.065*
C40.4674 (9)0.5286 (3)0.9567 (6)0.052 (2)
C50.3731 (8)0.5058 (2)0.8632 (6)0.052 (2)
H50.3492380.4551350.8542960.062*
C60.3146 (9)0.5586 (3)0.7830 (6)0.0520 (19)
C130.3504 (9)0.6343 (3)0.7964 (6)0.0521 (18)
H130.3112020.6697040.7427190.063*
C70.2154 (14)0.5359 (6)0.6759 (11)0.054 (2)
C80.3091 (17)0.9273 (8)1.1000 (14)0.067 (2)
C90.193 (2)0.9383 (11)1.1838 (17)0.091 (4)
H9A0.2207010.9144101.2582130.137*
H9B0.1068050.9163221.1500120.137*
H9C0.1794360.9912211.1963540.137*
C100.7862 (14)0.8291 (10)0.7675 (13)0.086 (2)
C110.740 (2)0.8014 (12)0.6496 (14)0.114 (4)
H11A0.8150690.7723180.6190420.171*
H11B0.6575760.7704130.6539850.171*
H11C0.7178870.8433940.5978680.171*
C121.0479 (16)0.7814 (12)0.7793 (16)0.110 (4)
H12A1.0245380.7664450.6985540.164*
H12B1.0702710.7375620.8268290.164*
H12C1.1284740.8145450.7827150.164*
C140.9812 (18)0.8599 (12)0.9338 (13)0.112 (4)
H14A1.0562260.8935340.9156050.168*
H14B1.0170850.8236000.9914000.168*
H14C0.9059640.8882320.9653050.168*
O100.5293 (16)0.9187 (8)0.7041 (12)0.107 (3)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Eu10.0459 (4)0.0217 (4)0.0418 (4)0.0030 (2)0.0201 (2)0.0038 (2)
N10.112 (6)0.085 (6)0.102 (6)0.008 (6)0.004 (6)0.003 (5)
O10.079 (3)0.035 (3)0.058 (3)0.003 (3)0.031 (3)0.003 (3)
O20.079 (3)0.038 (3)0.064 (3)0.000 (3)0.034 (3)0.005 (3)
O30.099 (4)0.067 (4)0.089 (4)0.004 (4)0.002 (4)0.011 (4)
O40.086 (4)0.038 (3)0.065 (4)0.004 (3)0.035 (3)0.011 (3)
O50.077 (4)0.031 (3)0.063 (4)0.002 (3)0.015 (3)0.009 (3)
O60.088 (4)0.042 (3)0.069 (3)0.008 (3)0.015 (3)0.006 (3)
O70.085 (4)0.029 (3)0.070 (4)0.004 (3)0.038 (4)0.006 (3)
C10.078 (4)0.039 (3)0.059 (3)0.000 (3)0.026 (3)0.002 (3)
C20.071 (4)0.030 (3)0.052 (3)0.001 (3)0.032 (3)0.001 (3)
C30.073 (4)0.031 (3)0.052 (3)0.002 (3)0.033 (3)0.004 (3)
C40.072 (4)0.028 (4)0.051 (4)0.001 (4)0.033 (4)0.001 (3)
C50.072 (4)0.028 (4)0.050 (4)0.003 (4)0.037 (4)0.002 (3)
C60.070 (4)0.030 (3)0.051 (4)0.000 (3)0.031 (3)0.001 (3)
C130.070 (4)0.031 (3)0.049 (3)0.003 (3)0.030 (3)0.002 (3)
C70.074 (5)0.029 (4)0.053 (4)0.003 (4)0.034 (4)0.001 (4)
C80.088 (5)0.039 (4)0.071 (5)0.005 (4)0.008 (4)0.008 (4)
C90.104 (9)0.083 (8)0.090 (9)0.015 (8)0.023 (8)0.019 (8)
C100.100 (5)0.068 (4)0.088 (4)0.003 (4)0.014 (4)0.007 (4)
C110.128 (8)0.102 (8)0.110 (8)0.012 (8)0.001 (7)0.011 (7)
C120.125 (8)0.098 (8)0.105 (8)0.018 (8)0.001 (8)0.004 (8)
C140.124 (8)0.097 (8)0.112 (8)0.012 (7)0.010 (7)0.000 (7)
O100.133 (7)0.103 (7)0.084 (5)0.017 (7)0.006 (6)0.006 (6)
Geometric parameters (Å, º) top
Eu1—O32.273 (12)C3—C41.3900
Eu1—O5i2.351 (8)C3—H30.9300
Eu1—O42.381 (9)C4—C51.3900
Eu1—O72.381 (8)C4—C4iv1.508 (7)
Eu1—O12.445 (8)C5—C61.3900
Eu1—O62.453 (11)C5—H50.9300
Eu1—O22.514 (9)C6—C131.3900
Eu1—O102.587 (14)C6—C71.529 (12)
Eu1—O52.592 (9)C13—H130.9300
Eu1—Eu1i3.9540 (10)C8—C91.51 (2)
N1—C101.437 (11)C9—H9A0.9600
N1—C121.468 (7)C9—H9B0.9600
N1—C141.475 (7)C9—H9C0.9600
O1—C11.255 (15)C10—C111.456 (10)
O2—C11.287 (16)C11—H11A0.9600
O3—C101.316 (18)C11—H11B0.9600
O4—C7ii1.255 (14)C11—H11C0.9600
O5—C81.223 (16)C12—H12A0.9600
O6—C81.263 (18)C12—H12B0.9600
O7—C7iii1.293 (14)C12—H12C0.9600
C1—C21.484 (14)C14—H14A0.9600
C2—C31.3900C14—H14B0.9600
C2—C131.3900C14—H14C0.9600
O3—Eu1—O5i81.3 (4)C7iii—O7—Eu1136.3 (7)
O3—Eu1—O486.5 (4)O2—C1—O1118.4 (11)
O5i—Eu1—O476.0 (3)O2—C1—C2118.0 (10)
O3—Eu1—O7121.7 (4)O1—C1—C2123.6 (10)
O5i—Eu1—O776.6 (3)C3—C2—C13120.0
O4—Eu1—O7136.4 (3)C3—C2—C1124.0 (6)
O3—Eu1—O187.1 (4)C13—C2—C1116.0 (6)
O5i—Eu1—O1149.2 (3)C2—C3—C4120.0
O4—Eu1—O1131.9 (3)C2—C3—H3120.0
O7—Eu1—O185.7 (3)C4—C3—H3120.0
O3—Eu1—O6151.8 (4)C5—C4—C3120.0
O5i—Eu1—O6124.1 (3)C5—C4—C4iv120.3 (8)
O4—Eu1—O688.4 (4)C3—C4—C4iv119.7 (8)
O7—Eu1—O679.8 (4)C4—C5—C6120.0
O1—Eu1—O675.9 (3)C4—C5—H5120.0
O3—Eu1—O276.3 (4)C6—C5—H5120.0
O5i—Eu1—O2148.0 (3)C5—C6—C13120.0
O4—Eu1—O279.9 (3)C5—C6—C7121.9 (6)
O7—Eu1—O2135.0 (3)C13—C6—C7118.1 (6)
O1—Eu1—O252.2 (2)C6—C13—C2120.0
O6—Eu1—O275.5 (3)C6—C13—H13120.0
O3—Eu1—O1059.8 (4)C2—C13—H13120.0
O5i—Eu1—O1076.6 (4)O4v—C7—O7vi123.8 (10)
O4—Eu1—O10139.2 (5)O4v—C7—C6118.3 (9)
O7—Eu1—O1062.8 (4)O7vi—C7—C6116.9 (9)
O1—Eu1—O1072.9 (4)O5—C8—O6120.7 (14)
O6—Eu1—O10132.2 (4)O5—C8—C9120.1 (14)
O2—Eu1—O10110.3 (4)O6—C8—C9119.2 (14)
O3—Eu1—O5148.5 (4)C8—C9—H9A109.5
O5i—Eu1—O573.8 (3)C8—C9—H9B109.5
O4—Eu1—O569.0 (3)H9A—C9—H9B109.5
O7—Eu1—O571.2 (3)C8—C9—H9C109.5
O1—Eu1—O5124.0 (3)H9A—C9—H9C109.5
O6—Eu1—O550.6 (3)H9B—C9—H9C109.5
O2—Eu1—O5116.4 (3)O3—C10—C11130.5 (14)
O10—Eu1—O5129.7 (4)O3—C10—N1104.0 (10)
O3—Eu1—Eu1i118.0 (3)C11—C10—N1125.4 (13)
O5i—Eu1—Eu1i39.0 (2)C10—C11—H11A109.5
O4—Eu1—Eu1i67.7 (2)C10—C11—H11B109.5
O7—Eu1—Eu1i69.56 (19)H11A—C11—H11B109.5
O1—Eu1—Eu1i151.3 (2)C10—C11—H11C109.5
O6—Eu1—Eu1i85.3 (2)H11A—C11—H11C109.5
O2—Eu1—Eu1i142.7 (2)H11B—C11—H11C109.5
O10—Eu1—Eu1i106.3 (3)N1—C12—H12A109.5
O5—Eu1—Eu1i34.82 (19)N1—C12—H12B109.5
C10—N1—C12127.6 (8)H12A—C12—H12B109.5
C10—N1—C14125.5 (8)N1—C12—H12C109.5
C12—N1—C14106.3 (8)H12A—C12—H12C109.5
C1—O1—Eu196.7 (7)H12B—C12—H12C109.5
C1—O2—Eu192.6 (7)N1—C14—H14A109.5
C10—O3—Eu1149.4 (10)N1—C14—H14B109.5
C7ii—O4—Eu1139.9 (8)H14A—C14—H14B109.5
C8—O5—Eu1i160.2 (9)N1—C14—H14C109.5
C8—O5—Eu191.5 (8)H14A—C14—H14C109.5
Eu1i—O5—Eu1106.2 (3)H14B—C14—H14C109.5
C8—O6—Eu197.1 (9)
Symmetry codes: (i) x+1, y+2, z+2; (ii) x+1/2, y+3/2, z+1/2; (iii) x+1/2, y+1/2, z+3/2; (iv) x+1, y+1, z+2; (v) x1/2, y+3/2, z1/2; (vi) x+1/2, y1/2, z+3/2.
 

Follow Acta Cryst. C
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds