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Four crystalline phases were found for 4'-octyloxy-4-cyanobiphenyl, C21H25NO. These were square-plate, needle and long parallelepiped crystals, which are all metastable, and a phase found in a commercially available powder specimen, which was the most stable. The structures of the needle and long parallelepiped crystals have been determined at room temperature and 243 K, respectively.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks I, II, global

fcf

Structure factor file (CIF format)
Contains datablock I

fcf

Structure factor file (CIF format)
Contains datablock shelxl

CCDC references: 126962; 126963

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