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The coordination of the Sn atom in the title compound, [SnCl2(CH3)2(C14H14O2S2)[n, is octahedral, with chlorides at cis [Sn-Cl 2.482 (1) and 2.486 (1) Å] and methyl groups at trans positions [Sn-C 2.101 (4) and 2.105 (5) Å]. Completing the coordination, there are two different disulfoxide groups in a cis orientation [Sn-O 2.397 (3) and 2.404 (3) Å]. Each sulfoxide is bound to two Sn atoms, yielding infinite ribbons.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, Sn

CCDC reference: 126959

-1
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