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The crystal structure of the title complex, [Cu{ONC(CN)2}(C12H8N2)2(H2O)][ONC(CN)2], is composed of discrete [Cu(dcnm)H2O(phen)2]+ cations and dcnm anions [phen is 1,10-phenanthroline and dcnm is dicyanonitrosomethanide, ONC(CN)2-]. The coordination polyhedron of the CuII atom is a distorted elongated tetragonal bipyramid with a CuN4O2 chromophore. The water molecule occupies an axial position, while the dcnm anion occupies an equatorial position.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks fn2a, global

fcf

Structure factor file (CIF format)
Contains datablock fn2a

CCDC reference: 129795

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