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In the crystal structure of the title complex, [Pt(C9H6NS)2], although the aromatic ligands are coordinated to a central heavy metal atom, T-shaped and shifted π-stacked arrangements of the aromatic moieties are preferred, leading to a sandwich herring-bone type of crystal-packing motif. The crystal structure is therefore consistent with the view that the arene–arene interactions are determined by electrostatics (multipole–multipole).

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, 1

fcf

Structure factor file (CIF format)
Contains datablock stoe4

CCDC reference: 128653

-1
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