metal-organic compounds
In the crystal structure of the title complex, [Pt(C9H6NS)2], although the aromatic ligands are coordinated to a central heavy metal atom, T-shaped and shifted π-stacked arrangements of the aromatic moieties are preferred, leading to a sandwich herring-bone type of crystal-packing motif. The crystal structure is therefore consistent with the view that the arene–arene interactions are determined by electrostatics (multipole–multipole).
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (CIF format) |
CCDC reference: 128653