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The central molecular fragment of the first title complex, [Mn2Br(C6H12P)(CO)8], is a four-membered non-planar Mn2BrP ring with a cyclohexyl ring and a H atom attached to the bridging P atom. In the related second title complex, [Mn3Br(PH)(CO)13], the cyclohexyl ligand is substituted by an Mn(CO)5 group which displays an unusual ecliptic arrangement with the axial CO ligands of the ring Mn atoms.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks I, II, default

fcf

Structure factor file (CIF format)
Contains datablock I

fcf

Structure factor file (CIF format)
Contains datablock II

CCDC references: 128832; 128833

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