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The asymmetric unit of the title complex, [PtCl2(C14H38B10P2)]·0.5CH2Cl2 or cis-[PtCl2{1,2-(PiPr2)2-1,2-C2B10H10}]·0.5CH2Cl2, contains one disordered solvent mol­ecule and two mol­ecules of the complex, in which each PtII atom displays slightly distorted square-planar coordination geometry. The P atoms connected to the cage C atoms are coordinated to the PtII atom. The Pt—P distances vary slightly [2.215 (3) and 2.235 (4) Å] and the Pt—Cl distances are equal [2.348 (3) and 2.353 (5) Å].

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S0108270102002184/jz1494sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S0108270102002184/jz1494Isup2.hkl
Contains datablock I

CCDC reference: 184469

Computing details top

Data collection: MSC/AFC Diffractometer Control Software (Molecular Structure Corporation, 1993); cell refinement: MSC/AFC Diffractometer Control Software; data reduction: PROCESS in TEXSAN (Molecular Structure Corporation, 1993); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL/PC (Sheldrick, 1990); software used to prepare material for publication: SHELXL97.

cis-[1,2-Bis(diisopropylphosphino-κP)-1,2-dicarba-closo- dodecaborane]dichloroplatinum(II) dichloromethane hemisolvate top
Crystal data top
[PtCl2(C14H38B10P2)]·0.5CH2Cl2F(000) = 5360
Mr = 684.94Dx = 1.688 Mg m3
Monoclinic, C2/cMo Kα radiation, λ = 0.71073 Å
a = 42.785 (12) ÅCell parameters from 23 reflections
b = 10.320 (14) Åθ = 5.9–11.9°
c = 32.238 (11) ŵ = 5.63 mm1
β = 130.785 (12)°T = 193 K
V = 10778 (15) Å3Prismatic, colourless
Z = 160.27 × 0.20 × 0.10 mm
Data collection top
Rigaku AFC-7S
diffractometer
6434 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tubeRint = 0.053
Graphite monochromatorθmax = 25.3°, θmin = 2.5°
ω/2θ scansh = 051
Absorption correction: ψ
(North et al., 1968)
k = 012
Tmin = 0.295, Tmax = 0.570l = 3829
9888 measured reflections3 standard reflections every 150 reflections
9749 independent reflections intensity decay: <1%
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.068Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.146H-atom parameters constrained
S = 1.04 w = 1/[σ2(Fo2) + (0.0528P)2 + 56.0903P]
where P = (Fo2 + 2Fc2)/3
9749 reflections(Δ/σ)max = 0.001
324 parametersΔρmax = 2.12 e Å3
6 restraintsΔρmin = 1.69 e Å3
Special details top

Experimental. The biggest final residual electron peak and hole found in the vicinity of Pt1A:

Fourier peaks appended to. res file

x y z Peak Distances to nearest atom (including symmetry equivalents)

0.1864 0.7837 0.0986 2.12 0.99 PT1A 0.2029 0.6408 0.1322 - 1.69 0.94 PT1A

The biggest final residual electron peak and hole found in the vicinity of Pt1B:

Fourier peaks appended to. res file

x y z Peak Distances to nearest atom (including symmetry equivalents)

0.0780 1.4795 0.2181 - 1.66 0.91 PT1B 0.0940 1.4769 0.2506 1.64 0.95 PT1B

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Pt1A0.184238 (13)0.71090 (5)0.116498 (18)0.03081 (13)
Cl1A0.17184 (9)0.6898 (3)0.17729 (12)0.0391 (7)
Cl2A0.18994 (11)0.4841 (3)0.11847 (14)0.0476 (8)
P1A0.18007 (9)0.9262 (3)0.11562 (12)0.0312 (7)
P2A0.20067 (9)0.7106 (3)0.06406 (13)0.0352 (7)
C1A0.1819 (3)0.9902 (12)0.0626 (4)0.033 (3)*
C2A0.1919 (3)0.8748 (11)0.0343 (4)0.030 (3)*
B3A0.1428 (4)0.9398 (15)0.0031 (6)0.040 (4)*
H3A0.11550.88330.01550.048*
B4A0.1498 (4)1.1052 (15)0.0159 (6)0.039 (3)*
H4A0.12701.15960.01560.046*
B5A0.2037 (4)1.1338 (16)0.0662 (6)0.043 (4)*
H5A0.21681.20770.09920.052*
B6A0.2296 (4)0.9850 (15)0.0788 (6)0.040 (3)*
H6A0.25920.95850.12030.048*
B7A0.1643 (4)0.9102 (16)0.0333 (6)0.042 (3)*
H7A0.15100.83550.06620.050*
B8A0.1398 (5)1.0574 (16)0.0446 (7)0.050 (4)*
H8A0.10981.08200.08600.059*
B9A0.1767 (5)1.1792 (18)0.0027 (7)0.053 (4)*
H9A0.17171.28300.01580.064*
B10A0.2261 (5)1.1023 (17)0.0373 (6)0.052 (4)*
H10A0.25411.15640.05100.062*
B11A0.2189 (5)0.9409 (16)0.0185 (6)0.049 (4)*
H11A0.24220.88680.01970.059*
B12A0.1857 (5)1.0560 (17)0.0325 (7)0.053 (4)*
H12A0.18671.07860.06560.064*
C13A0.2242 (3)1.0120 (12)0.1776 (4)0.036 (3)*
H13A0.24561.02020.17380.043*
C14A0.2442 (4)0.9316 (14)0.2298 (5)0.054 (4)*
H14A0.26930.97530.26130.081*
H14B0.25130.84540.22550.081*
H14C0.22470.92300.23600.081*
C15A0.2158 (4)1.1507 (14)0.1860 (5)0.051 (4)*
H15A0.20281.14670.20210.077*
H15B0.19731.19520.15060.077*
H15C0.24191.19830.21060.077*
C16A0.1328 (3)0.9943 (13)0.0978 (5)0.039 (3)*
H16A0.13171.08790.08890.047*
C17A0.1332 (4)0.9883 (14)0.1455 (5)0.048 (3)*
H17A0.11051.04040.13690.072*
H17B0.15961.02230.17860.072*
H17C0.13000.89810.15170.072*
C18A0.0930 (4)0.9314 (14)0.0475 (5)0.055 (4)*
H18A0.09550.83700.05150.082*
H18B0.08850.95640.01460.082*
H18C0.06970.96070.04410.082*
C19A0.2568 (4)0.6732 (13)0.1053 (5)0.043 (3)*
H19A0.26750.73140.09220.052*
C20A0.2810 (4)0.7039 (14)0.1661 (5)0.051 (4)*
H20A0.27210.64530.18060.077*
H20B0.27570.79370.16980.077*
H20C0.31060.69220.18670.077*
C21A0.2655 (5)0.5350 (15)0.0999 (6)0.064 (4)*
H21A0.29520.52420.12100.096*
H21B0.25050.51550.06130.096*
H21C0.25650.47580.11410.096*
C22A0.1720 (4)0.5933 (14)0.0078 (5)0.049 (3)*
H22A0.18090.50730.02660.058*
C23A0.1827 (5)0.5863 (16)0.0289 (6)0.066 (4)*
H23A0.18770.49590.03250.099*
H23B0.20760.63760.01270.099*
H23C0.15970.62100.06520.099*
C24A0.1264 (4)0.5963 (15)0.0238 (6)0.058 (4)*
H24A0.11520.67990.04240.088*
H24B0.12130.58440.00150.088*
H24C0.11300.52640.05090.088*
Pt1B0.095268 (14)1.40974 (5)0.231749 (18)0.03398 (14)
Cl1B0.13864 (10)1.3774 (4)0.32680 (12)0.0520 (9)
Cl2B0.09764 (10)1.1843 (3)0.22331 (13)0.0479 (8)
P1B0.09413 (9)1.6237 (3)0.24138 (12)0.0341 (8)
P2B0.05980 (9)1.4363 (3)0.14269 (12)0.0305 (7)
C1B0.0472 (3)1.6889 (12)0.1735 (4)0.033 (3)*
C2B0.0282 (3)1.5870 (12)0.1216 (4)0.032 (3)*
B3B0.0023 (4)1.6010 (15)0.1456 (6)0.038 (3)*
H3B0.00081.52250.16820.045*
B4B0.0058 (4)1.7640 (14)0.1620 (6)0.034 (3)*
H4B0.00611.79400.19570.041*
B5B0.0364 (4)1.8473 (15)0.1525 (6)0.038 (3)*
H5B0.05651.93080.17920.046*
B6B0.0507 (4)1.7332 (14)0.1256 (5)0.033 (3)*
H6B0.08051.74220.13410.040*
B7B0.0251 (4)1.5921 (15)0.0740 (5)0.037 (3)*
H7B0.04551.50800.04830.044*
B8B0.0389 (4)1.7052 (15)0.0999 (6)0.039 (3)*
H8B0.06871.69610.09150.047*
B9B0.0193 (4)1.8579 (16)0.1030 (6)0.044 (4)*
H9B0.03601.94980.09630.053*
B10B0.0095 (4)1.8383 (16)0.0800 (6)0.041 (4)*
H10B0.01201.91700.05830.049*
B11B0.0055 (4)1.6694 (15)0.0629 (6)0.041 (4)*
H11B0.00561.63490.03020.049*
B12B0.0375 (4)1.7492 (15)0.0482 (6)0.041 (4)*
H12B0.06611.77050.00510.050*
C13B0.1381 (3)1.7056 (12)0.2537 (5)0.035 (3)*
H13B0.13301.69660.21880.042*
C14B0.1785 (4)1.6337 (14)0.2971 (5)0.052 (4)*
H14D0.20041.66950.29860.077*
H14E0.17491.54150.28780.077*
H14F0.18601.64400.33290.077*
C15B0.1428 (4)1.8494 (15)0.2655 (6)0.059 (4)*
H15D0.14721.86450.29900.089*
H15E0.11771.89450.23480.089*
H15F0.16651.88250.27050.089*
C16B0.0887 (4)1.6867 (14)0.2899 (5)0.049 (3)*
H16B0.07651.77550.27730.058*
C17B0.1288 (4)1.6984 (14)0.3482 (5)0.055 (4)*
H17D0.12321.73000.37150.082*
H17E0.14701.75940.34980.082*
H17F0.14211.61320.36130.082*
C18B0.0588 (4)1.6031 (14)0.2899 (5)0.049 (3)*
H18D0.06431.51120.28950.073*
H18E0.03031.62310.25730.073*
H18F0.06271.62180.32280.073*
C19B0.0972 (3)1.4656 (12)0.1328 (4)0.033 (3)*
H19B0.11161.54800.15280.040*
C20B0.1309 (4)1.3604 (13)0.1622 (5)0.046 (3)*
H20D0.11961.27930.14130.069*
H20E0.14071.34640.19910.069*
H20F0.15411.38850.16480.069*
C21B0.0801 (4)1.4873 (13)0.0746 (5)0.044 (3)*
H21D0.10191.52300.07560.066*
H21E0.05701.54830.05580.066*
H21F0.07061.40460.05480.066*
C22B0.0205 (4)1.3192 (13)0.0919 (5)0.041 (3)*
H22B0.00101.36750.05660.049*
C23B0.0370 (4)1.2046 (12)0.0806 (5)0.042 (3)*
H23D0.05451.14990.11340.062*
H23E0.05331.23740.07140.062*
H23F0.01381.15340.05000.062*
C24B0.0054 (4)1.2656 (13)0.1059 (5)0.044 (3)*
H24D0.02791.21190.07550.067*
H24E0.01701.33790.11170.067*
H24F0.01221.21310.13930.067*
C25A0.0661 (11)1.149 (2)0.3045 (15)0.071 (10)*0.525 (18)
H25A0.09651.14170.32830.086*0.525 (18)
H25B0.05571.19980.27160.086*0.525 (18)
Cl3A0.0444 (4)0.9966 (10)0.2853 (5)0.101 (5)*0.525 (18)
Cl4A0.0534 (3)1.2231 (11)0.3392 (5)0.078 (3)*0.525 (18)
C25B0.0581 (12)1.177 (2)0.2881 (14)0.077 (14)*0.475 (18)
H25C0.03461.17510.24810.092*0.475 (18)
H25D0.08051.22760.29440.092*0.475 (18)
Cl3B0.0752 (6)1.0207 (14)0.3101 (7)0.128 (7)*0.475 (18)
Cl4B0.0427 (5)1.2557 (14)0.3191 (7)0.109 (5)*0.475 (18)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Pt1A0.0305 (2)0.0342 (3)0.0321 (2)0.0005 (2)0.0224 (2)0.0007 (2)
Cl1A0.0458 (16)0.044 (2)0.0434 (16)0.0039 (14)0.0360 (15)0.0030 (14)
Cl2A0.071 (2)0.0303 (18)0.062 (2)0.0045 (16)0.0527 (19)0.0016 (16)
P1A0.0273 (14)0.0350 (18)0.0323 (15)0.0007 (14)0.0198 (13)0.0005 (15)
P2A0.0342 (16)0.040 (2)0.0364 (16)0.0039 (15)0.0254 (14)0.0023 (15)
Pt1B0.0335 (2)0.0370 (3)0.0318 (2)0.0018 (2)0.0215 (2)0.0016 (2)
Cl1B0.057 (2)0.055 (2)0.0356 (16)0.0086 (17)0.0267 (16)0.0045 (16)
Cl2B0.0542 (19)0.037 (2)0.0472 (18)0.0048 (15)0.0307 (16)0.0007 (15)
P1B0.0294 (15)0.039 (2)0.0298 (15)0.0009 (14)0.0176 (13)0.0052 (14)
P2B0.0292 (15)0.0313 (18)0.0323 (15)0.0011 (13)0.0207 (13)0.0020 (13)
Geometric parameters (Å, º) top
Pt1A—P1A2.227 (4)P1B—C13B1.855 (12)
Pt1A—P2A2.215 (3)P1B—C16B1.844 (14)
Pt1A—Cl1A2.351 (3)P2B—C19B1.847 (12)
Pt1A—Cl2A2.350 (5)P2B—C22B1.836 (13)
P1A—C13A1.848 (12)P1B—C1B1.879 (11)
P1A—C16A1.844 (12)P2B—C2B1.872 (12)
P2A—C19A1.875 (12)C1B—C2B1.672 (16)
P2A—C22A1.831 (14)C1B—B6B1.709 (17)
P1A—C1A1.880 (12)C1B—B5B1.714 (19)
P2A—C2A1.861 (12)C1B—B4B1.738 (17)
C1A—B4A1.692 (18)C1B—B3B1.749 (18)
C1A—B3A1.712 (17)C2B—B11B1.685 (18)
C1A—B5A1.715 (19)C2B—B3B1.724 (18)
C1A—C2A1.716 (16)C2B—B7B1.731 (16)
C1A—B6A1.746 (18)C2B—B6B1.747 (18)
C2A—B11A1.68 (2)B3B—B4B1.74 (2)
C2A—B7A1.707 (18)B3B—B8B1.74 (2)
C2A—B6A1.712 (18)B3B—B7B1.781 (19)
C2A—B3A1.734 (17)B3B—H3B1.1200
B3A—B8A1.75 (2)B4B—B8B1.742 (19)
B3A—B7A1.75 (2)B4B—B9B1.74 (2)
B3A—B4A1.77 (2)B4B—B5B1.75 (2)
B3A—H3A1.1200B4B—H4B1.1200
B4A—B8A1.77 (2)B5B—B6B1.79 (2)
B4A—B5A1.77 (2)B5B—B9B1.81 (2)
B4A—B9A1.78 (2)B5B—B10B1.81 (2)
B4A—H4A1.1200B5B—H5B1.1200
B5A—B10A1.75 (2)B6B—B10B1.75 (2)
B5A—B9A1.77 (2)B6B—B11B1.774 (19)
B5A—B6A1.78 (2)B6B—H6B1.1200
B5A—H5A1.1200B7B—B12B1.74 (2)
B6A—B10A1.74 (2)B7B—B8B1.75 (2)
B6A—B11A1.74 (2)B7B—B11B1.76 (2)
B6A—H6A1.1200B7B—H7B1.1200
B7A—B8A1.74 (2)B8B—B9B1.76 (2)
B7A—B12A1.75 (2)B8B—B12B1.77 (2)
B7A—B11A1.80 (2)B8B—H8B1.1200
B7A—H7A1.1200B9B—B12B1.79 (2)
B8A—B12A1.74 (2)B9B—B10B1.82 (2)
B8A—B9A1.76 (2)B9B—H9B1.1200
B8A—H8A1.1200B10B—B11B1.80 (2)
B9A—B12A1.78 (2)B10B—B12B1.80 (2)
B9A—B10A1.79 (2)B10B—H10B1.1200
B9A—H9A1.1200B11B—B12B1.77 (2)
B10A—B11A1.73 (2)B11B—H11B1.1200
B10A—B12A1.79 (2)B12B—H12B1.1200
B10A—H10A1.1200C13B—C15B1.513 (18)
B11A—B12A1.75 (2)C13B—C14B1.528 (16)
B11A—H11A1.1200C13B—H13B1.0000
B12A—H12A1.1200C14B—H14D0.9800
C13A—C14A1.541 (17)C14B—H14E0.9800
C13A—C15A1.543 (18)C14B—H14F0.9800
C13A—H13A1.0000C15B—H15D0.9800
C14A—H14A0.9800C15B—H15E0.9800
C14A—H14B0.9800C15B—H15F0.9800
C14A—H14C0.9800C16B—C17B1.510 (18)
C15A—H15A0.9800C16B—C18B1.543 (18)
C15A—H15B0.9800C16B—H16B1.0000
C15A—H15C0.9800C17B—H17D0.9800
C16A—C17A1.527 (17)C17B—H17E0.9800
C16A—C18A1.529 (17)C17B—H17F0.9800
C16A—H16A1.0000C18B—H18D0.9800
C17A—H17A0.9800C18B—H18E0.9800
C17A—H17B0.9800C18B—H18F0.9800
C17A—H17C0.9800C19B—C21B1.523 (16)
C18A—H18A0.9800C19B—C20B1.542 (16)
C18A—H18B0.9800C19B—H19B1.0000
C18A—H18C0.9800C20B—H20D0.9800
C19A—C21A1.512 (19)C20B—H20E0.9800
C19A—C20A1.537 (17)C20B—H20F0.9800
C19A—H19A1.0000C21B—H21D0.9800
C20A—H20A0.9800C21B—H21E0.9800
C20A—H20B0.9800C21B—H21F0.9800
C20A—H20C0.9800C22B—C23B1.538 (17)
C21A—H21A0.9800C22B—C24B1.546 (17)
C21A—H21B0.9800C22B—H22B1.0000
C21A—H21C0.9800C23B—H23D0.9800
C22A—C24A1.498 (17)C23B—H23E0.9800
C22A—C23A1.524 (19)C23B—H23F0.9800
C22A—H22A1.0000C24B—H24D0.9800
C23A—H23A0.9800C24B—H24E0.9800
C23A—H23B0.9800C24B—H24F0.9800
C23A—H23C0.9800C25A—Cl4A1.715 (10)
C24A—H24A0.9800C25A—Cl3A1.718 (10)
C24A—H24B0.9800C25A—H25A0.9900
C24A—H24C0.9800C25A—H25B0.9900
Pt1B—P1B2.235 (4)C25B—Cl3B1.719 (10)
Pt1B—P2B2.220 (3)C25B—Cl4B1.720 (10)
Pt1B—Cl1B2.348 (3)C25B—H25C0.9900
Pt1B—Cl2B2.353 (5)C25B—H25D0.9900
P1A—Pt1A—Cl1A92.47 (11)H24A—C24A—H24C109.5
P1A—Pt1A—Cl2A178.97 (13)H24B—C24A—H24C109.5
P1A—Pt1A—P2A93.13 (12)C16B—P1B—C13B109.4 (6)
P2A—Pt1A—Cl1A173.27 (12)C16B—P1B—C1B103.3 (6)
P2A—Pt1A—Cl2A86.57 (12)C13B—P1B—C1B104.4 (5)
Cl1A—Pt1A—Cl2A87.78 (12)C16B—P1B—Pt1B119.5 (5)
C1A—C2A—P2A113.2 (7)C13B—P1B—Pt1B111.6 (4)
C2A—C1A—P1A114.4 (8)C1B—P1B—Pt1B107.2 (4)
P1B—Pt1B—Cl1B91.69 (12)C22B—P2B—C19B110.2 (6)
P1B—Pt1B—Cl2B178.93 (13)C22B—P2B—C2B101.5 (5)
P1B—Pt1B—P2B89.95 (12)C19B—P2B—C2B107.5 (5)
P2B—Pt1B—Cl1B174.20 (12)C22B—P2B—Pt1B121.8 (4)
P2B—Pt1B—Cl2B90.98 (12)C19B—P2B—Pt1B107.8 (4)
Cl1B—Pt1B—Cl2B87.33 (12)C2B—P2B—Pt1B107.1 (4)
C1B—C2B—P2B113.3 (7)C2B—C1B—B6B62.2 (7)
C2B—C1B—P1B113.0 (8)C2B—C1B—B5B112.0 (9)
C16A—P1A—C13A107.1 (6)B6B—C1B—B5B63.1 (8)
C16A—P1A—C1A105.7 (5)C2B—C1B—B4B107.9 (8)
C13A—P1A—C1A101.2 (5)B6B—C1B—B4B111.5 (9)
C16A—P1A—Pt1A116.5 (4)B5B—C1B—B4B61.0 (8)
C13A—P1A—Pt1A116.6 (4)C2B—C1B—B3B60.5 (7)
C1A—P1A—Pt1A108.2 (4)B6B—C1B—B3B112.8 (9)
C22A—P2A—C2A108.2 (6)B5B—C1B—B3B111.6 (9)
C22A—P2A—C19A106.6 (6)B4B—C1B—B3B59.9 (7)
C2A—P2A—C19A106.7 (6)B6B—C1B—P1B119.4 (8)
C22A—P2A—Pt1A114.6 (5)B5B—C1B—P1B127.5 (8)
C2A—P2A—Pt1A109.5 (4)B4B—C1B—P1B125.0 (8)
C19A—P2A—Pt1A111.0 (4)B3B—C1B—P1B113.1 (8)
B4A—C1A—B3A62.7 (8)C1B—C2B—B11B110.7 (10)
B4A—C1A—B5A62.8 (8)C1B—C2B—B3B62.0 (7)
B3A—C1A—B5A113.2 (10)B11B—C2B—B3B113.0 (9)
B4A—C1A—C2A110.5 (9)C1B—C2B—B7B111.4 (9)
B3A—C1A—C2A60.8 (7)B11B—C2B—B7B61.9 (8)
B5A—C1A—C2A108.7 (9)B3B—C2B—B7B62.1 (7)
B4A—C1A—B6A113.4 (10)C1B—C2B—B6B60.0 (7)
B3A—C1A—B6A111.5 (9)B11B—C2B—B6B62.2 (8)
B5A—C1A—B6A61.8 (8)B3B—C2B—B6B112.2 (10)
C2A—C1A—B6A59.3 (7)B7B—C2B—B6B112.5 (9)
B4A—C1A—P1A124.4 (8)B11B—C2B—P2B125.4 (8)
B3A—C1A—P1A115.5 (8)B3B—C2B—P2B115.4 (8)
B5A—C1A—P1A126.0 (8)B7B—C2B—P2B124.6 (8)
B6A—C1A—P1A116.9 (8)B6B—C2B—P2B117.4 (7)
B11A—C2A—B7A64.2 (8)C2B—B3B—B4B105.5 (10)
B11A—C2A—B6A61.8 (8)C2B—B3B—B8B105.4 (10)
B7A—C2A—B6A114.5 (10)B4B—B3B—B8B60.0 (8)
B11A—C2A—C1A109.8 (10)C2B—B3B—C1B57.5 (7)
B7A—C2A—C1A109.1 (9)B4B—B3B—C1B59.7 (8)
B6A—C2A—C1A61.2 (7)B8B—B3B—C1B106.3 (10)
B11A—C2A—B3A113.1 (10)C2B—B3B—B7B59.2 (7)
B7A—C2A—B3A61.1 (8)B4B—B3B—B7B107.3 (10)
B6A—C2A—B3A112.1 (10)B8B—B3B—B7B59.4 (8)
C1A—C2A—B3A59.5 (7)C1B—B3B—B7B105.5 (10)
B11A—C2A—P2A125.3 (9)C2B—B3B—H3B124.0
B7A—C2A—P2A126.3 (9)B4B—B3B—H3B122.0
B6A—C2A—P2A114.2 (8)B8B—B3B—H3B122.6
B3A—C2A—P2A117.1 (8)C1B—B3B—H3B123.4
C1A—B3A—C2A59.7 (7)B7B—B3B—H3B122.4
C1A—B3A—B8A105.1 (10)C1B—B4B—B3B60.4 (8)
C2A—B3A—B8A104.5 (10)C1B—B4B—B8B106.9 (10)
C1A—B3A—B7A107.3 (10)B3B—B4B—B8B60.1 (8)
C2A—B3A—B7A58.7 (8)C1B—B4B—B9B107.2 (10)
B8A—B3A—B7A59.9 (9)B3B—B4B—B9B109.6 (10)
C1A—B3A—B4A58.1 (7)B8B—B4B—B9B60.5 (8)
C2A—B3A—B4A106.1 (10)C1B—B4B—B5B58.8 (8)
B8A—B3A—B4A60.4 (9)B3B—B4B—B5B110.2 (10)
B7A—B3A—B4A109.1 (11)B8B—B4B—B5B110.8 (10)
C1A—B3A—H3A123.2B9B—B4B—B5B62.3 (8)
C2A—B3A—H3A123.7C1B—B4B—H4B123.4
B8A—B3A—H3A123.4B3B—B4B—H4B120.5
B7A—B3A—H3A121.2B8B—B4B—H4B121.3
B4A—B3A—H3A121.8B9B—B4B—H4B120.8
C1A—B4A—B8A105.0 (10)B5B—B4B—H4B119.8
C1A—B4A—B3A59.2 (8)C1B—B5B—B4B60.2 (8)
B8A—B4A—B3A59.1 (8)C1B—B5B—B6B58.3 (8)
C1A—B4A—B5A59.3 (8)B4B—B5B—B6B107.1 (11)
B8A—B4A—B5A106.8 (11)C1B—B5B—B9B105.4 (10)
B3A—B4A—B5A107.6 (10)B4B—B5B—B9B58.6 (8)
C1A—B4A—B9A106.0 (10)B6B—B5B—B9B106.4 (10)
B8A—B4A—B9A59.6 (9)C1B—B5B—B10B103.9 (10)
B3A—B4A—B9A107.4 (11)B4B—B5B—B10B106.5 (10)
B5A—B4A—B9A59.8 (8)B6B—B5B—B10B58.0 (8)
C1A—B4A—H4A123.6B9B—B5B—B10B60.4 (8)
B8A—B4A—H4A123.2C1B—B5B—H5B123.8
B3A—B4A—H4A121.9B4B—B5B—H5B122.0
B5A—B4A—H4A121.9B6B—B5B—H5B122.9
B9A—B4A—H4A122.2B9B—B5B—H5B122.6
C1A—B5A—B10A105.6 (11)B10B—B5B—H5B123.4
C1A—B5A—B9A105.3 (11)C1B—B6B—C2B57.8 (7)
B10A—B5A—B9A61.2 (9)C1B—B6B—B10B107.0 (10)
C1A—B5A—B4A58.0 (8)C2B—B6B—B10B105.7 (9)
B10A—B5A—B4A108.6 (11)C1B—B6B—B11B104.8 (10)
B9A—B5A—B4A60.2 (8)C2B—B6B—B11B57.2 (7)
C1A—B5A—B6A59.9 (8)B10B—B6B—B11B61.5 (8)
B10A—B5A—B6A59.1 (9)C1B—B6B—B5B58.6 (8)
B9A—B5A—B6A108.4 (11)C2B—B6B—B5B105.0 (10)
B4A—B5A—B6A108.0 (11)B10B—B6B—B5B61.6 (8)
C1A—B5A—H5A124.2B11B—B6B—B5B109.4 (10)
B10A—B5A—H5A121.9C1B—B6B—H6B123.9
B9A—B5A—H5A121.7C2B—B6B—H6B124.9
B4A—B5A—H5A121.7B10B—B6B—H6B121.0
B6A—B5A—H5A121.5B11B—B6B—H6B122.0
C2A—B6A—B10A104.9 (10)B5B—B6B—H6B121.4
C2A—B6A—B11A58.3 (8)C2B—B7B—B12B105.4 (10)
B10A—B6A—B11A59.6 (9)C2B—B7B—B8B105.0 (9)
C2A—B6A—C1A59.5 (7)B12B—B7B—B8B60.9 (8)
B10A—B6A—C1A104.7 (10)C2B—B7B—B11B57.8 (7)
B11A—B6A—C1A105.7 (10)B12B—B7B—B11B60.9 (8)
C2A—B6A—B5A106.1 (10)B8B—B7B—B11B108.8 (11)
B10A—B6A—B5A59.6 (9)C2B—B7B—B3B58.8 (7)
B11A—B6A—B5A107.4 (11)B12B—B7B—B3B108.0 (11)
C1A—B6A—B5A58.3 (8)B8B—B7B—B3B59.2 (8)
C2A—B6A—H6A123.4B11B—B7B—B3B106.9 (10)
B10A—B6A—H6A123.4C2B—B7B—H7B124.8
B11A—B6A—H6A122.4B12B—B7B—H7B121.4
C1A—B6A—H6A123.6B8B—B7B—H7B121.9
B5A—B6A—H6A122.3B11B—B7B—H7B121.6
C2A—B7A—B8A105.8 (11)B3B—B7B—H7B122.3
C2A—B7A—B3A60.2 (8)B4B—B8B—B3B59.9 (8)
B8A—B7A—B3A60.0 (9)B4B—B8B—B7B108.8 (10)
C2A—B7A—B12A104.2 (10)B3B—B8B—B7B61.3 (8)
B8A—B7A—B12A59.5 (9)B4B—B8B—B9B59.8 (8)
B3A—B7A—B12A107.5 (12)B3B—B8B—B9B108.8 (10)
C2A—B7A—B11A57.2 (8)B7B—B8B—B9B109.1 (11)
B8A—B7A—B11A106.2 (11)B4B—B8B—B12B107.9 (10)
B3A—B7A—B11A106.8 (10)B3B—B8B—B12B108.4 (10)
B12A—B7A—B11A59.1 (9)B7B—B8B—B12B59.3 (8)
C2A—B7A—H7A124.1B9B—B8B—B12B60.9 (8)
B8A—B7A—H7A122.5B4B—B8B—H8B121.9
B3A—B7A—H7A121.3B3B—B8B—H8B121.1
B12A—B7A—H7A123.0B7B—B8B—H8B121.0
B11A—B7A—H7A123.3B9B—B8B—H8B121.0
B12A—B8A—B7A60.4 (9)B12B—B8B—H8B121.9
B12A—B8A—B3A108.4 (12)B4B—B9B—B8B59.7 (8)
B7A—B8A—B3A60.1 (9)B4B—B9B—B12B106.9 (11)
B12A—B8A—B9A61.2 (9)B8B—B9B—B12B59.8 (8)
B7A—B8A—B9A110.2 (11)B4B—B9B—B5B59.1 (8)
B3A—B8A—B9A109.2 (11)B8B—B9B—B5B107.6 (11)
B12A—B8A—B4A109.2 (11)B12B—B9B—B5B107.9 (11)
B7A—B8A—B4A109.5 (11)B4B—B9B—B10B106.6 (10)
B3A—B8A—B4A60.5 (9)B8B—B9B—B10B107.6 (11)
B9A—B8A—B4A60.4 (9)B12B—B9B—B10B60.0 (8)
B12A—B8A—H8A121.2B5B—B9B—B10B59.9 (8)
B7A—B8A—H8A120.7B4B—B9B—H9B122.9
B3A—B8A—H8A121.6B8B—B9B—H9B121.8
B9A—B8A—H8A120.4B12B—B9B—H9B121.9
B4A—B8A—H8A121.0B5B—B9B—H9B121.9
B8A—B9A—B5A107.2 (12)B10B—B9B—H9B122.1
B8A—B9A—B4A60.0 (9)B6B—B10B—B11B60.0 (8)
B5A—B9A—B4A60.0 (9)B6B—B10B—B12B107.4 (11)
B8A—B9A—B12A58.7 (9)B11B—B10B—B12B58.9 (8)
B5A—B9A—B12A107.0 (12)B6B—B10B—B5B60.4 (8)
B4A—B9A—B12A106.9 (12)B11B—B10B—B5B107.3 (11)
B8A—B9A—B10A106.4 (12)B12B—B10B—B5B106.9 (11)
B5A—B9A—B10A58.8 (9)B6B—B10B—B9B107.8 (11)
B4A—B9A—B10A106.6 (12)B11B—B10B—B9B106.0 (11)
B12A—B9A—B10A60.1 (9)B12B—B10B—B9B59.1 (8)
B8A—B9A—H9A122.6B5B—B10B—B9B59.7 (8)
B5A—B9A—H9A122.2B6B—B10B—H10B121.4
B4A—B9A—H9A122.1B11B—B10B—H10B122.8
B12A—B9A—H9A122.4B12B—B10B—H10B122.6
B10A—B9A—H9A122.7B5B—B10B—H10B121.9
B11A—B10A—B6A60.4 (9)B9B—B10B—H10B122.6
B11A—B10A—B5A109.4 (13)C2B—B11B—B7B60.3 (8)
B6A—B10A—B5A61.3 (9)C2B—B11B—B12B105.9 (10)
B11A—B10A—B12A59.8 (9)B7B—B11B—B12B59.0 (8)
B6A—B10A—B12A108.0 (12)C2B—B11B—B6B60.6 (7)
B5A—B10A—B12A107.7 (11)B7B—B11B—B6B109.9 (10)
B11A—B10A—B9A108.5 (12)B12B—B11B—B6B107.6 (11)
B6A—B10A—B9A109.3 (12)C2B—B11B—B10B106.0 (10)
B5A—B10A—B9A60.0 (9)B7B—B11B—B10B108.3 (11)
B12A—B10A—B9A59.7 (9)B12B—B11B—B10B60.6 (8)
B11A—B10A—H10A121.2B6B—B11B—B10B58.5 (8)
B6A—B10A—H10A120.9C2B—B11B—H11B122.8
B5A—B10A—H10A121.1B7B—B11B—H11B120.8
B12A—B10A—H10A122.4B12B—B11B—H11B122.7
B9A—B10A—H10A121.4B6B—B11B—H11B121.2
C2A—B11A—B10A106.5 (12)B10B—B11B—H11B122.5
C2A—B11A—B6A59.9 (8)B7B—B12B—B8B59.8 (8)
B10A—B11A—B6A60.0 (9)B7B—B12B—B11B60.0 (8)
C2A—B11A—B12A105.2 (11)B8B—B12B—B11B107.2 (10)
B10A—B11A—B12A61.7 (9)B7B—B12B—B9B108.2 (11)
B6A—B11A—B12A109.3 (12)B8B—B12B—B9B59.2 (8)
C2A—B11A—B7A58.6 (8)B11B—B12B—B9B108.7 (10)
B10A—B11A—B7A108.7 (12)B7B—B12B—B10B108.9 (10)
B6A—B11A—B7A108.4 (11)B8B—B12B—B10B107.9 (10)
B12A—B11A—B7A59.0 (9)B11B—B12B—B10B60.4 (8)
C2A—B11A—H11A123.9B9B—B12B—B10B60.9 (8)
B10A—B11A—H11A121.1B7B—B12B—H12B121.4
B6A—B11A—H11A120.8B8B—B12B—H12B122.6
B12A—B11A—H11A121.9B11B—B12B—H12B121.7
B7A—B11A—H11A122.0B9B—B12B—H12B121.4
B8A—B12A—B7A60.0 (9)B10B—B12B—H12B120.9
B8A—B12A—B11A108.8 (13)C15B—C13B—C14B111.2 (10)
B7A—B12A—B11A61.9 (9)C15B—C13B—P1B116.6 (9)
B8A—B12A—B9A60.2 (9)C14B—C13B—P1B110.8 (9)
B7A—B12A—B9A109.1 (12)C15B—C13B—H13B105.8
B11A—B12A—B9A107.9 (12)C14B—C13B—H13B105.8
B8A—B12A—B10A107.7 (12)P1B—C13B—H13B105.8
B7A—B12A—B10A108.4 (12)C13B—C14B—H14D109.5
B11A—B12A—B10A58.5 (9)C13B—C14B—H14E109.5
B9A—B12A—B10A60.2 (9)H14D—C14B—H14E109.5
B8A—B12A—H12A121.7C13B—C14B—H14F109.5
B7A—B12A—H12A120.6H14D—C14B—H14F109.5
B11A—B12A—H12A121.5H14E—C14B—H14F109.5
B9A—B12A—H12A121.4C13B—C15B—H15D109.5
B10A—B12A—H12A122.4C13B—C15B—H15E109.5
C14A—C13A—C15A109.5 (10)H15D—C15B—H15E109.5
C14A—C13A—P1A111.7 (9)C13B—C15B—H15F109.5
C15A—C13A—P1A116.3 (8)H15D—C15B—H15F109.5
C14A—C13A—H13A106.2H15E—C15B—H15F109.5
C15A—C13A—H13A106.2C17B—C16B—C18B108.2 (11)
P1A—C13A—H13A106.2C17B—C16B—P1B114.5 (10)
C13A—C14A—H14A109.5C18B—C16B—P1B111.5 (9)
C13A—C14A—H14B109.5C17B—C16B—H16B107.5
H14A—C14A—H14B109.5C18B—C16B—H16B107.5
C13A—C14A—H14C109.5P1B—C16B—H16B107.5
H14A—C14A—H14C109.5C16B—C17B—H17D109.5
H14B—C14A—H14C109.5C16B—C17B—H17E109.5
C13A—C15A—H15A109.5H17D—C17B—H17E109.5
C13A—C15A—H15B109.5C16B—C17B—H17F109.5
H15A—C15A—H15B109.5H17D—C17B—H17F109.5
C13A—C15A—H15C109.5H17E—C17B—H17F109.5
H15A—C15A—H15C109.5C16B—C18B—H18D109.5
H15B—C15A—H15C109.5C16B—C18B—H18E109.5
C17A—C16A—C18A109.0 (10)H18D—C18B—H18E109.5
C17A—C16A—P1A112.3 (8)C16B—C18B—H18F109.5
C18A—C16A—P1A113.7 (9)H18D—C18B—H18F109.5
C17A—C16A—H16A107.1H18E—C18B—H18F109.5
C18A—C16A—H16A107.1C21B—C19B—C20B111.3 (10)
P1A—C16A—H16A107.1C21B—C19B—P2B117.7 (8)
C16A—C17A—H17A109.5C20B—C19B—P2B110.4 (8)
C16A—C17A—H17B109.5C21B—C19B—H19B105.5
H17A—C17A—H17B109.5C20B—C19B—H19B105.5
C16A—C17A—H17C109.5P2B—C19B—H19B105.5
H17A—C17A—H17C109.5C19B—C20B—H20D109.5
H17B—C17A—H17C109.5C19B—C20B—H20E109.5
C16A—C18A—H18A109.5H20D—C20B—H20E109.5
C16A—C18A—H18B109.5C19B—C20B—H20F109.5
H18A—C18A—H18B109.5H20D—C20B—H20F109.5
C16A—C18A—H18C109.5H20E—C20B—H20F109.5
H18A—C18A—H18C109.5C19B—C21B—H21D109.5
H18B—C18A—H18C109.5C19B—C21B—H21E109.5
C21A—C19A—C20A109.3 (11)H21D—C21B—H21E109.5
C21A—C19A—P2A114.2 (9)C19B—C21B—H21F109.5
C20A—C19A—P2A110.1 (9)H21D—C21B—H21F109.5
C21A—C19A—H19A107.7H21E—C21B—H21F109.5
C20A—C19A—H19A107.7C23B—C22B—C24B108.7 (11)
P2A—C19A—H19A107.7C23B—C22B—P2B115.0 (8)
C19A—C20A—H20A109.5C24B—C22B—P2B112.9 (9)
C19A—C20A—H20B109.5C23B—C22B—H22B106.6
H20A—C20A—H20B109.5C24B—C22B—H22B106.6
C19A—C20A—H20C109.5P2B—C22B—H22B106.6
H20A—C20A—H20C109.5C22B—C23B—H23D109.5
H20B—C20A—H20C109.5C22B—C23B—H23E109.5
C19A—C21A—H21A109.5H23D—C23B—H23E109.5
C19A—C21A—H21B109.5C22B—C23B—H23F109.5
H21A—C21A—H21B109.5H23D—C23B—H23F109.5
C19A—C21A—H21C109.5H23E—C23B—H23F109.5
H21A—C21A—H21C109.5C22B—C24B—H24D109.5
H21B—C21A—H21C109.5C22B—C24B—H24E109.5
C24A—C22A—C23A113.1 (11)H24D—C24B—H24E109.5
C24A—C22A—P2A113.0 (10)C22B—C24B—H24F109.5
C23A—C22A—P2A117.0 (10)H24D—C24B—H24F109.5
C24A—C22A—H22A104.0H24E—C24B—H24F109.5
C23A—C22A—H22A104.0Cl4A—C25A—Cl3A108.5 (9)
P2A—C22A—H22A104.0Cl4A—C25A—H25A110.0
C22A—C23A—H23A109.5Cl3A—C25A—H25A110.0
C22A—C23A—H23B109.5Cl4A—C25A—H25B110.0
H23A—C23A—H23B109.5Cl3A—C25A—H25B110.0
C22A—C23A—H23C109.5H25A—C25A—H25B108.4
H23A—C23A—H23C109.5Cl3B—C25B—Cl4B115.1 (12)
H23B—C23A—H23C109.5Cl3B—C25B—H25C108.5
C22A—C24A—H24A109.5Cl4B—C25B—H25C108.5
C22A—C24A—H24B109.5Cl3B—C25B—H25D108.5
H24A—C24A—H24B109.5Cl4B—C25B—H25D108.5
C22A—C24A—H24C109.5H25C—C25B—H25D107.5
P1A—C1A—C2A—P2A2.0 (10)P1B—C1B—C2B—P2B3.0 (10)
Cl1A—Pt1A—P1A—C13A73.9 (5)Cl1B—Pt1B—P1B—C13B86.8 (4)
Cl1A—Pt1A—P1A—C16A54.2 (4)Cl1B—Pt1B—P1B—C16B42.5 (5)
Cl2A—Pt1A—P2A—C19A73.5 (5)Cl2B—Pt1B—P2B—C19B91.7 (4)
Cl2A—Pt1A—P2A—C22A47.3 (5)Cl2B—Pt1B—P2B—C22B36.9 (5)
C1A—C2A—P2A—C19A110.0 (8)C1B—C2B—P2B—C19B92.8 (8)
C1A—C2A—P2A—C22A135.6 (7)C1B—C2B—P2B—C22B151.5 (8)
C2A—C1A—P1A—C13A116.1 (8)C2B—C1B—P1B—C13B100.6 (8)
C2A—C1A—P1A—C16A132.4 (8)C2B—C1B—P1B—C16B145.1 (8)
C13A—P1A—P2A—C19A6.7 (7)C13B—P1B—P2B—C19B2.9 (5)
C22A—P2A—P1A—C16A5.4 (10)C22B—P2B—P1B—C16B3.4 (12)
 

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