metal-organic compounds
In the crystal structure of dichloro[3,6,9,12,15,18-hexaoxa-24,27-diazatricyclo[24.4.0.020,25]- triaconta-1(26),20,22,24,27,29-hexaene-N,N']palladium(II), [PdCl2(C22H30N2O6)], the Pd atom is tetracoordinated by the two pyridyl N atoms and two Cl atoms. The planes formed by atoms Pd1, N21, N31 and atoms Pd1, Cl1, Cl2 make an angle of 12.12 (9)° with one another. The twist of the two pyridyl rings of 31.59 (9)° is associated with the ortho substitution, and the complexation of PdCl2 seems to alter the shape of the crown ether cavity, so that it is less suitable for complexing metal cations.
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (CIF format) |
CCDC reference: 130321