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The reaction of MnCl2 with [Mg{OCH2CH(CH2)3O}2] in EtOH results in a mixed MgII/MnII tetranuclear complex, tetrakis(μ3-tetrahydrofuran-2-ylmethanolato-O,O':O':O')tetrakis{chloro(ethoxo)[manganese(II),magnesium(II)]} hemiethanol solvate, [(Mg2,Mn2)Cl4(C2H6O)4(C5H9O2)4].0.5C2H6O, in which all metal sites have distorted octahedral coordination spheres and metal ions together with alkoxo O atoms form a cubane-like framework.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks JERZYK, default

CCDC reference: 129185

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