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b(PNP)[Zn(ONO)Pc2-].H2O [Pc2- = (C32H16N8)2-] has been prepared from zinc phthalocyanine and bis(triphenylphosphine)iminium nitrite [(PNP)NO2] in acetone. The Zn atom has a tetragonal pyramidal coordination geometry with the Zn atom displaced out of the center (Ct) of the four inner N atoms (Niso) of the non-planar Pc ligand toward the nitrite ligand [Zn-Ct = 0.469 (3) Å]. The nitrite ion is monodentate O-coordinated [Zn-O = 2.059 (3) Å]. The average Zn-Niso distance is 2.032 Å. Pairs of weakly overlapping anions are present. The cation adopts a bent conformation [b(PNP): P1-N(K) = 1.576 (2); P2-N(K) = 1.582 (2) Å; P1-N(K)-P2 = 141.12 (13)°].

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks ZnONO, global

fcf

Structure factor file (CIF format)
Contains datablock znono

CCDC reference: 126569

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