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mer-[TcCl3(Me2PhP)3] reacts with potassium thiocyanate with the replacement of only one Cl ligand by NCS and forms selectively (OC-6–12)dichlorotris(dimethylphenylphosphine)(thiocyanato-κN)technetium(III) {mer,trans-[TcCl2(NCS)(Me2PhP)3]}. No evidence could be found for the formation of the cis analogue. The title compound crystallizes in monomeric units. The Tc atom is coordinated in a distorted octahedral manner with the two chloride ligands in trans positions to each other. The NCS ligand is N-bonded with a Tc—N bond length of 2.104 (3) Å.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks ncs, default

CCDC reference: 126438

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