An unprecedented Zr-containing polyoxometalate tetra­mer with mixed trilacunary/dilacunary Keggin-type polyoxotungstate units

A novel zirconium(IV)-substituted tetra­mer polyoxotungstate, H₆K₄Na₁₆[Zr₄(β-GeW₁₀O₃₈)₂(A-α-PW₉O₃₄)₂]·37H₂O, was synthesized hydro­thermally and characterized by IR spectroscopy, elemental analysis, thermogravimetric analysis, powder X-ray diffraction, energy-dispersive X-ray spectroscopy and single-crystal X-ray diffraction. The compound crystallizes in the monoclinic P2/n space group. The most remarkable feature is that the centrosymmetric Zr-based polyoxotungstate tetra­mer consists of dilacunary Keggin-type germanotungstate and trilacunary Keggin-type phospho­tungstate units that are linked by Zr^IV ions.

Computing details

Data collection: FRAMBO (Bruker, 2009); cell refinement: FRAMBO (Bruker, 2009); data reduction: SAINT-Plus (Bruker, 2009); program(s) used to solve structure: SHELXTL (Sheldrick, 2008); program(s) used to refine structure: SHELXL2017 (Sheldrick, 2015); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Hexahydride tetrapotassium hexadecasodium (germanodecatungstato)(phosphononatungstato)tetrazirconate heptatriacontahydrate

Crystal data

H6K4Na16[Zr4(GeW10O38)2(PW9O34)2]·37H2O	F(000) = 9692
Mr = 11059.18	Dx = 4.361 Mg m^−3
Monoclinic, P2/n	Mo Kα radiation, λ = 0.71073 Å
a = 22.5605 (13) Å	Cell parameters from 11245 reflections
b = 11.4578 (6) Å	θ = 3.0–29.6°
c = 32.7134 (13) Å	µ = 26.70 mm^−1
β = 95.172 (4)°	T = 293 K
V = 8421.8 (7) Å^3	Block, colorless
Z = 2	0.28 × 0.14 × 0.10 mm

Data collection

Multiwire proportional diffractometer	14781 independent reflections
Radiation source: sealed tube	10800 reflections with I > 2σ(I)
Detector resolution: 10.4170 pixels mm^-1	Rint = 0.097
phi and ω scans	θmax = 25.0°, θmin = 3.1°
Absorption correction: multi-scan	h = −26→26
Tmin = 0.098, Tmax = 1.000	k = −13→13
43361 measured reflections	l = −34→38

Refinement

Refinement on F^2	234 restraints
Least-squares matrix: full	H-atom parameters not defined
R[F^2 > 2σ(F^2)] = 0.083	w = 1/[σ^2(Fo^2) + (0.0731P)^2 + 1085.8478P] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.205	(Δ/σ)max = 0.001
S = 1.04	Δρmax = 5.85 e Å^−3
14781 reflections	Δρmin = −3.10 e Å^−3
1113 parameters

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Zr1	0.84980 (12)	0.2193 (3)	0.37743 (9)	0.0203 (6)
Zr2	0.62152 (12)	0.2710 (3)	0.36543 (8)	0.0200 (6)
Ge1	0.73052 (13)	0.1282 (2)	0.43909 (8)	0.0136 (6)
P1	0.4797 (3)	0.3496 (6)	0.22056 (19)	0.0090 (13)
W1	0.73505 (5)	0.42917 (10)	0.41592 (4)	0.0210 (3)
W2	0.73582 (5)	0.04952 (11)	0.33472 (4)	0.0221 (3)
W3	0.83617 (6)	−0.07174 (11)	0.40446 (4)	0.0232 (3)
W4	0.62415 (5)	0.33572 (11)	0.46916 (4)	0.0229 (3)
W5	0.61564 (6)	−0.05001 (11)	0.39607 (4)	0.0254 (3)
W6	0.36534 (5)	0.51507 (11)	0.25876 (4)	0.0237 (3)
W7	0.84683 (6)	0.29329 (11)	0.49036 (4)	0.0235 (3)
W8	0.73693 (6)	0.19955 (12)	0.54606 (4)	0.0252 (3)
W9	0.47336 (5)	0.35327 (12)	0.32835 (4)	0.0240 (3)
W10	0.59982 (5)	0.48361 (11)	0.17628 (4)	0.0243 (3)
W11	0.47953 (6)	0.65856 (11)	0.21844 (4)	0.0277 (3)
W12	0.71478 (6)	−0.17416 (11)	0.46634 (4)	0.0255 (3)
W13	0.36541 (5)	0.18339 (11)	0.25875 (4)	0.0244 (3)
W14	0.49764 (6)	0.34614 (13)	0.11360 (4)	0.0276 (3)
W15	0.83680 (6)	0.00844 (11)	0.51540 (4)	0.0249 (3)
W16	0.61527 (6)	0.01843 (11)	0.49643 (4)	0.0248 (3)
W17	0.37683 (6)	0.50958 (12)	0.15575 (4)	0.0285 (3)
W18	0.58646 (5)	0.48787 (11)	0.28807 (4)	0.0240 (3)
W19	0.37769 (6)	0.17919 (12)	0.15753 (4)	0.0302 (3)
K1	0.4938 (4)	0.1580 (7)	0.4221 (3)	0.0417 (19)
K2	0.2470 (3)	0.3576 (7)	0.1889 (3)	0.0384 (18)
Na1	0.7228 (6)	0.7189 (11)	0.3509 (4)	0.035 (3)
Na2	0.4866 (6)	0.6988 (11)	0.3387 (4)	0.040 (3)
Na3	0.4849 (6)	0.0165 (12)	0.2262 (4)	0.039 (3)
Na4	0.6357 (5)	0.1915 (9)	0.2446 (3)	0.021 (3)
Na5	0.5131 (5)	0.4855 (10)	0.5609 (3)	0.020 (2)
Na6	0.5234 (6)	0.0941 (12)	0.0507 (4)	0.040 (3)
Na7	0.2164 (7)	0.1066 (16)	0.0828 (5)	0.065 (5)
Na8	0.7562 (8)	0.401 (2)	0.1938 (6)	0.079 (6)
O1	0.5382 (9)	0.5972 (17)	0.1872 (6)	0.020 (4)
O2	0.5334 (9)	0.4720 (19)	0.3320 (6)	0.026 (5)
O3	0.4391 (9)	0.2415 (17)	0.1266 (6)	0.022 (4)
O4	0.5996 (9)	0.1744 (17)	0.4797 (6)	0.024 (4)
O5	0.6752 (9)	0.4560 (17)	0.4566 (6)	0.024 (5)
O6	0.4228 (9)	0.4773 (18)	0.3010 (7)	0.029 (5)
O7	0.8034 (10)	0.297 (2)	0.5405 (6)	0.031 (5)
O8	0.8010 (9)	0.1412 (18)	0.3281 (6)	0.026 (5)
O9	0.7902 (9)	−0.0833 (17)	0.3531 (7)	0.029 (5)
O10	0.4209 (9)	0.2474 (17)	0.3021 (6)	0.025 (5)
O11	0.6855 (8)	0.1699 (16)	0.3415 (5)	0.017 (4)
O12	0.3429 (8)	0.3601 (19)	0.2536 (6)	0.025 (5)
O13	0.8833 (8)	0.0448 (16)	0.3864 (6)	0.018 (4)
O14	0.3550 (9)	0.354 (2)	0.1573 (6)	0.028 (5)
O15	0.6128 (9)	0.4719 (17)	0.2344 (6)	0.024 (4)
O16	0.4417 (10)	0.467 (2)	0.1265 (7)	0.041 (6)
O17	0.6876 (9)	0.2973 (17)	0.5147 (6)	0.024 (5)
O18	0.5224 (9)	0.3531 (19)	0.1858 (6)	0.026 (5)
O19	0.7703 (9)	−0.0989 (18)	0.5057 (6)	0.025 (5)
O20	0.7749 (9)	0.1507 (18)	0.4848 (6)	0.026 (5)
O21	0.4220 (10)	0.6505 (18)	0.1718 (6)	0.031 (5)
O22	0.8552 (9)	−0.0233 (17)	0.4604 (6)	0.022 (4)
O23	0.6799 (9)	0.0777 (19)	0.5323 (6)	0.031 (5)
O24	0.6708 (9)	0.4239 (16)	0.3775 (6)	0.020 (4)
O25	0.6836 (8)	0.0124 (15)	0.4485 (5)	0.015 (4)
O26	0.6381 (9)	0.346 (2)	0.1694 (6)	0.029 (5)
O27	0.6553 (9)	−0.1305 (16)	0.5023 (6)	0.020 (4)
O28	0.5274 (9)	0.5998 (19)	0.2635 (6)	0.026 (5)
O29	0.3995 (10)	0.0501 (19)	0.2594 (7)	0.036 (6)
O30	0.7764 (9)	0.0886 (16)	0.4003 (6)	0.020 (4)
O31	0.3302 (9)	0.175 (2)	0.2029 (6)	0.029 (5)
O32	0.5999 (9)	0.1057 (17)	0.3871 (6)	0.024 (4)
O33	0.4393 (9)	0.2470 (19)	0.2159 (6)	0.027 (5)
O34	0.4387 (9)	0.4622 (17)	0.2156 (6)	0.023 (5)
O35	0.7874 (10)	0.3946 (18)	0.4670 (6)	0.029 (5)
O36	0.7701 (9)	−0.1516 (18)	0.4269 (7)	0.028 (5)
O37	0.5822 (9)	0.337 (2)	0.4188 (7)	0.031 (5)
O38	0.7611 (10)	0.5677 (19)	0.4104 (7)	0.031 (5)
O39	0.8690 (9)	0.2447 (17)	0.4409 (6)	0.021 (4)
O40	0.5124 (9)	0.3523 (17)	0.2633 (6)	0.021 (4)
O41	0.7131 (10)	0.000 (2)	0.2853 (7)	0.033 (5)
O42	0.4130 (10)	0.653 (2)	0.2517 (7)	0.034 (5)
O43	0.5329 (10)	0.2444 (18)	0.3396 (6)	0.029 (5)
O44	0.6542 (9)	−0.192 (2)	0.4247 (6)	0.030 (5)
O45	0.6772 (10)	−0.0496 (19)	0.3626 (7)	0.032 (5)
O46	0.4131 (11)	0.045 (2)	0.1661 (7)	0.039 (6)
O47	0.7955 (9)	0.0728 (19)	0.5587 (6)	0.030 (5)
O48	0.8821 (10)	−0.1904 (19)	0.4010 (7)	0.033 (5)
O49	0.3052 (10)	0.156 (2)	0.2861 (8)	0.041 (6)
O50	0.7840 (9)	0.3439 (18)	0.3878 (6)	0.026 (5)
O51	0.6214 (10)	0.3481 (18)	0.3045 (6)	0.029 (5)
O52	0.5628 (10)	−0.003 (2)	0.5306 (7)	0.035 (6)
O53	0.8812 (11)	0.145 (2)	0.5155 (7)	0.037 (6)
O54	0.4471 (10)	0.3667 (19)	0.3756 (7)	0.032 (5)
O55	0.3325 (10)	0.5437 (19)	0.2026 (7)	0.032 (5)
O56	0.5575 (9)	0.4643 (19)	0.1227 (7)	0.031 (5)
O57	0.7207 (10)	0.2323 (19)	0.5948 (6)	0.031 (5)
O58	0.6894 (9)	0.2508 (18)	0.4272 (6)	0.025 (5)
O59	0.3099 (10)	0.574 (2)	0.2860 (8)	0.044 (6)
O60	0.9011 (11)	0.388 (2)	0.5061 (7)	0.042 (6)
O61	0.6555 (10)	0.578 (2)	0.1670 (7)	0.038 (6)
O62	0.3267 (11)	0.569 (2)	0.1180 (7)	0.042 (6)
O63	0.5553 (9)	0.240 (2)	0.1183 (6)	0.035 (6)
O64	0.8875 (10)	−0.079 (2)	0.5429 (7)	0.041 (6)
O65	0.4944 (11)	0.804 (2)	0.2223 (8)	0.044 (7)
O66	0.6360 (11)	0.591 (2)	0.3102 (7)	0.042 (6)
O67	0.5599 (11)	−0.119 (3)	0.3657 (8)	0.053 (7)
O68	0.7269 (11)	−0.314 (2)	0.4826 (7)	0.040 (6)
O69	0.5739 (9)	−0.040 (2)	0.4468 (7)	0.038 (6)
O70	0.5762 (12)	0.411 (2)	0.4975 (8)	0.050 (7)
O71	0.4845 (11)	0.354 (3)	0.0611 (7)	0.047 (7)
O72	0.3237 (12)	0.142 (3)	0.1198 (8)	0.066 (10)
O1W	0.507 (2)	0.230 (4)	0.5470 (14)	0.116 (14)
O2W	0.183 (3)	0.351 (5)	0.1078 (18)	0.16 (2)
O3W	0.411 (3)	0.056 (6)	0.368 (2)	0.20 (3)
O4W	0.5596 (16)	0.067 (3)	0.1904 (11)	0.085 (10)
O5W	0.607 (3)	0.381 (5)	0.613 (2)	0.18 (3)
O6W	0.4217 (11)	0.3834 (19)	0.5980 (8)	0.041 (6)
O7W	0.7534 (9)	0.5184 (18)	0.5390 (6)	0.028 (5)
O8W	0.9793 (11)	0.551 (2)	0.4812 (7)	0.039 (6)
O9W	0.8762 (13)	0.590 (3)	0.4374 (9)	0.058 (8)
O10W	0.228 (2)	−0.009 (4)	0.1590 (14)	0.119 (14)
O11W	0.487 (2)	−0.069 (5)	0.1120 (17)	0.144 (18)
O12W	0.4817 (16)	0.145 (4)	−0.0232 (13)	0.102 (14)
O13W	0.435 (2)	0.305 (4)	0.4756 (15)	0.123 (17)
O14W	0.404 (3)	0.881 (7)	0.318 (2)	0.22 (3)
O15W	0.5472 (13)	0.060 (3)	0.2850 (9)	0.067 (9)
O16W	0.3934 (11)	0.787 (2)	0.1020 (7)	0.043 (6)
O17W	0.750000	0.575 (8)	0.250000	0.17 (2)
O18W	0.2518 (10)	0.7397 (18)	0.3201 (6)	0.029 (5)
O19W	0.8439 (15)	0.683 (2)	0.5479 (9)	0.065 (9)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Zr1	0.0144 (14)	0.0259 (15)	0.0211 (14)	−0.0008 (12)	0.0038 (12)	0.0011 (12)
Zr2	0.0110 (13)	0.0281 (15)	0.0203 (14)	0.0015 (12)	−0.0011 (11)	0.0046 (12)
Ge1	0.0135 (14)	0.0127 (14)	0.0146 (14)	−0.0025 (12)	0.0018 (12)	0.0021 (11)
P1	0.008 (3)	0.010 (3)	0.010 (3)	0.004 (3)	0.007 (3)	0.002 (3)
W1	0.0216 (6)	0.0210 (6)	0.0211 (6)	−0.0007 (5)	0.0066 (5)	0.0018 (5)
W2	0.0179 (6)	0.0278 (7)	0.0205 (6)	−0.0001 (5)	0.0014 (5)	−0.0001 (5)
W3	0.0196 (6)	0.0234 (6)	0.0263 (6)	0.0014 (5)	0.0006 (5)	−0.0002 (5)
W4	0.0202 (6)	0.0287 (7)	0.0209 (6)	0.0018 (5)	0.0077 (5)	0.0031 (5)
W5	0.0196 (6)	0.0284 (7)	0.0275 (7)	−0.0064 (6)	−0.0022 (5)	0.0071 (5)
W6	0.0153 (6)	0.0274 (7)	0.0288 (7)	0.0048 (5)	0.0037 (5)	0.0002 (5)
W7	0.0210 (6)	0.0294 (7)	0.0199 (6)	−0.0054 (6)	0.0003 (5)	−0.0010 (5)
W8	0.0270 (7)	0.0306 (7)	0.0181 (6)	−0.0012 (6)	0.0027 (5)	0.0030 (5)
W9	0.0161 (6)	0.0355 (7)	0.0208 (6)	0.0009 (6)	0.0027 (5)	0.0044 (5)
W10	0.0187 (6)	0.0289 (7)	0.0258 (6)	0.0005 (5)	0.0051 (5)	0.0040 (5)
W11	0.0234 (7)	0.0223 (6)	0.0373 (7)	0.0035 (6)	0.0024 (6)	0.0060 (6)
W12	0.0252 (7)	0.0219 (6)	0.0287 (7)	−0.0035 (5)	−0.0013 (5)	0.0058 (5)
W13	0.0163 (6)	0.0259 (7)	0.0317 (7)	−0.0016 (5)	0.0054 (5)	0.0016 (5)
W14	0.0168 (6)	0.0459 (8)	0.0203 (6)	0.0032 (6)	0.0027 (5)	0.0008 (6)
W15	0.0217 (7)	0.0296 (7)	0.0226 (6)	−0.0003 (6)	−0.0025 (5)	0.0029 (5)
W16	0.0202 (6)	0.0291 (7)	0.0256 (6)	−0.0032 (5)	0.0050 (5)	0.0089 (5)
W17	0.0181 (7)	0.0399 (8)	0.0272 (7)	0.0072 (6)	0.0004 (5)	0.0062 (6)
W18	0.0181 (6)	0.0290 (7)	0.0243 (6)	−0.0017 (5)	−0.0015 (5)	0.0042 (5)
W19	0.0202 (7)	0.0387 (8)	0.0324 (7)	−0.0038 (6)	0.0052 (6)	−0.0102 (6)
K1	0.035 (4)	0.041 (4)	0.050 (5)	−0.007 (4)	0.008 (4)	0.022 (4)
K2	0.025 (4)	0.037 (4)	0.055 (5)	−0.001 (3)	0.012 (4)	−0.006 (4)
Na1	0.035 (3)	0.034 (3)	0.035 (3)	−0.0008 (10)	0.0020 (11)	0.0007 (10)
Na2	0.045 (9)	0.024 (7)	0.049 (8)	0.008 (6)	−0.013 (7)	−0.013 (6)
Na3	0.029 (7)	0.035 (7)	0.055 (9)	−0.014 (6)	0.008 (7)	−0.015 (7)
Na4	0.036 (7)	0.015 (5)	0.012 (5)	−0.003 (5)	0.003 (5)	0.000 (4)
Na5	0.021 (3)	0.021 (3)	0.020 (3)	0.0000 (10)	0.0020 (10)	−0.0005 (10)
Na6	0.040 (3)	0.039 (3)	0.040 (3)	0.0003 (10)	0.0026 (11)	−0.0007 (10)
Na7	0.043 (10)	0.071 (11)	0.071 (11)	0.020 (9)	−0.042 (9)	−0.018 (9)
Na8	0.043 (10)	0.132 (18)	0.061 (12)	−0.006 (11)	0.009 (9)	0.008 (12)
O1	0.020 (4)	0.020 (4)	0.020 (4)	0.0000 (10)	0.0017 (11)	0.0001 (10)
O2	0.022 (11)	0.042 (13)	0.014 (10)	0.006 (10)	0.004 (9)	0.010 (9)
O3	0.022 (11)	0.022 (11)	0.022 (10)	0.002 (9)	0.006 (9)	0.000 (9)
O4	0.023 (5)	0.024 (5)	0.024 (5)	−0.0001 (10)	0.0022 (11)	0.0000 (10)
O5	0.015 (11)	0.020 (11)	0.038 (12)	−0.005 (9)	0.004 (9)	0.002 (9)
O6	0.024 (12)	0.026 (11)	0.036 (12)	0.002 (10)	0.007 (10)	−0.016 (10)
O7	0.033 (13)	0.048 (14)	0.013 (10)	−0.019 (11)	0.000 (9)	−0.009 (10)
O8	0.026 (5)	0.026 (5)	0.026 (5)	−0.0001 (10)	0.0023 (11)	−0.0001 (10)
O9	0.020 (11)	0.015 (10)	0.049 (14)	0.008 (9)	−0.002 (10)	−0.007 (10)
O10	0.020 (11)	0.019 (10)	0.035 (12)	0.003 (9)	−0.005 (9)	0.012 (9)
O11	0.017 (4)	0.017 (4)	0.017 (4)	0.0002 (10)	0.0015 (11)	0.0002 (10)
O12	0.009 (10)	0.045 (13)	0.020 (10)	0.004 (10)	−0.003 (8)	0.010 (10)
O13	0.018 (4)	0.019 (4)	0.019 (4)	0.0000 (10)	0.0018 (11)	−0.0002 (10)
O14	0.016 (11)	0.049 (14)	0.019 (10)	0.015 (10)	−0.002 (9)	0.008 (10)
O15	0.024 (5)	0.024 (5)	0.024 (5)	−0.0003 (10)	0.0022 (11)	0.0001 (10)
O16	0.020 (12)	0.072 (18)	0.032 (13)	0.009 (12)	0.005 (10)	0.010 (12)
O17	0.030 (12)	0.019 (10)	0.023 (11)	−0.012 (9)	0.002 (9)	−0.003 (9)
O18	0.018 (11)	0.044 (13)	0.016 (10)	0.007 (10)	0.006 (9)	0.011 (9)
O19	0.023 (11)	0.025 (11)	0.028 (11)	−0.002 (9)	0.006 (9)	0.010 (9)
O20	0.022 (11)	0.031 (12)	0.022 (11)	−0.013 (10)	−0.009 (9)	0.008 (9)
O21	0.043 (14)	0.026 (11)	0.023 (11)	−0.007 (11)	−0.005 (10)	0.015 (9)
O22	0.022 (4)	0.022 (4)	0.022 (4)	0.0000 (10)	0.0018 (11)	−0.0001 (10)
O23	0.025 (12)	0.039 (13)	0.028 (11)	−0.012 (10)	−0.008 (9)	0.024 (10)
O24	0.020 (4)	0.020 (4)	0.020 (4)	0.0000 (10)	0.0017 (11)	0.0003 (10)
O25	0.015 (4)	0.015 (4)	0.015 (4)	−0.0004 (10)	0.0015 (11)	−0.0001 (10)
O26	0.019 (11)	0.057 (15)	0.008 (9)	0.007 (11)	−0.003 (8)	0.007 (10)
O27	0.020 (4)	0.020 (4)	0.020 (4)	−0.0001 (10)	0.0017 (11)	0.0003 (10)
O28	0.018 (11)	0.036 (12)	0.024 (11)	0.010 (10)	0.000 (9)	0.002 (9)
O29	0.032 (13)	0.030 (13)	0.049 (14)	0.010 (11)	0.017 (12)	0.005 (11)
O30	0.020 (4)	0.020 (4)	0.020 (4)	0.0001 (10)	0.0019 (11)	0.0001 (10)
O31	0.012 (10)	0.046 (14)	0.032 (12)	−0.016 (10)	0.009 (9)	−0.016 (10)
O32	0.024 (5)	0.024 (5)	0.024 (5)	0.0001 (10)	0.0021 (11)	0.0002 (10)
O33	0.014 (11)	0.041 (13)	0.027 (11)	0.017 (10)	0.003 (9)	0.011 (10)
O34	0.017 (11)	0.027 (11)	0.025 (11)	0.001 (9)	0.009 (9)	−0.003 (9)
O35	0.029 (5)	0.029 (5)	0.029 (5)	−0.0002 (10)	0.0024 (11)	0.0000 (10)
O36	0.016 (11)	0.028 (12)	0.038 (12)	−0.014 (9)	−0.007 (9)	0.015 (10)
O37	0.017 (11)	0.043 (13)	0.034 (12)	0.000 (10)	0.004 (9)	0.019 (11)
O38	0.029 (12)	0.035 (13)	0.031 (12)	−0.014 (10)	0.015 (10)	−0.001 (10)
O39	0.021 (4)	0.021 (4)	0.021 (4)	0.0000 (10)	0.0021 (11)	−0.0002 (10)
O40	0.021 (4)	0.020 (4)	0.021 (4)	0.0000 (10)	0.0020 (11)	0.0002 (10)
O41	0.023 (12)	0.043 (14)	0.032 (12)	0.002 (11)	−0.001 (10)	0.003 (11)
O42	0.023 (12)	0.034 (13)	0.045 (14)	0.012 (10)	0.007 (11)	−0.001 (11)
O43	0.029 (5)	0.029 (5)	0.029 (5)	0.0000 (10)	0.0026 (11)	−0.0001 (10)
O44	0.030 (13)	0.045 (14)	0.014 (10)	0.013 (11)	0.002 (9)	0.003 (9)
O45	0.031 (5)	0.032 (5)	0.032 (5)	−0.0002 (10)	0.0028 (11)	0.0001 (10)
O46	0.042 (15)	0.036 (13)	0.041 (14)	−0.002 (11)	0.013 (12)	−0.026 (11)
O47	0.019 (11)	0.038 (13)	0.031 (12)	−0.011 (10)	−0.004 (9)	0.005 (10)
O48	0.033 (5)	0.033 (5)	0.032 (5)	0.001 (2)	0.003 (2)	0.000 (2)
O49	0.019 (12)	0.038 (14)	0.068 (17)	−0.017 (11)	0.018 (12)	−0.007 (13)
O50	0.026 (5)	0.026 (5)	0.026 (5)	−0.0001 (10)	0.0024 (11)	−0.0002 (10)
O51	0.029 (5)	0.029 (5)	0.028 (5)	0.0001 (10)	0.0026 (11)	0.0002 (10)
O52	0.032 (13)	0.042 (14)	0.031 (12)	−0.008 (11)	0.010 (10)	0.025 (11)
O53	0.039 (14)	0.044 (14)	0.029 (12)	−0.004 (12)	0.005 (11)	0.002 (11)
O54	0.032 (5)	0.032 (5)	0.032 (5)	0.0001 (10)	0.0029 (11)	−0.0001 (10)
O55	0.032 (5)	0.032 (5)	0.032 (5)	0.0001 (10)	0.0030 (11)	−0.0001 (10)
O56	0.017 (11)	0.037 (13)	0.040 (13)	0.007 (10)	0.002 (10)	0.028 (11)
O57	0.037 (13)	0.033 (12)	0.023 (11)	−0.006 (11)	0.007 (10)	0.005 (10)
O58	0.021 (11)	0.028 (12)	0.027 (11)	0.000 (9)	0.006 (9)	0.008 (9)
O59	0.032 (14)	0.047 (15)	0.054 (16)	0.000 (12)	0.017 (12)	0.009 (13)
O60	0.037 (14)	0.043 (14)	0.043 (14)	−0.007 (12)	−0.008 (12)	0.007 (12)
O61	0.020 (12)	0.044 (14)	0.051 (15)	−0.020 (11)	0.001 (11)	−0.012 (12)
O62	0.037 (14)	0.055 (16)	0.032 (13)	0.016 (13)	0.001 (11)	0.016 (12)
O63	0.019 (12)	0.058 (15)	0.027 (12)	0.017 (11)	−0.005 (9)	−0.025 (11)
O64	0.027 (13)	0.055 (16)	0.039 (14)	0.001 (12)	0.000 (11)	−0.018 (12)
O65	0.033 (14)	0.032 (13)	0.068 (18)	0.015 (11)	0.012 (13)	0.023 (13)
O66	0.042 (6)	0.042 (6)	0.042 (6)	−0.0001 (10)	0.0036 (12)	0.0000 (10)
O67	0.035 (15)	0.064 (18)	0.057 (17)	−0.011 (14)	−0.008 (13)	0.006 (15)
O68	0.048 (15)	0.034 (13)	0.038 (13)	−0.024 (12)	−0.008 (12)	−0.002 (11)
O69	0.018 (12)	0.052 (15)	0.046 (14)	0.003 (11)	0.005 (11)	0.011 (12)
O70	0.051 (17)	0.059 (17)	0.043 (15)	0.011 (14)	0.014 (13)	−0.012 (13)
O71	0.033 (14)	0.077 (19)	0.032 (13)	0.000 (14)	0.007 (11)	0.008 (13)
O72	0.053 (18)	0.11 (3)	0.043 (16)	−0.046 (18)	0.032 (14)	−0.029 (16)
O1W	0.116 (14)	0.116 (14)	0.116 (14)	0.000 (2)	0.011 (2)	0.000 (2)
O2W	0.16 (2)	0.16 (2)	0.16 (2)	0.000 (2)	0.015 (3)	0.000 (2)
O3W	0.20 (3)	0.20 (3)	0.20 (3)	0.000 (2)	0.018 (3)	0.000 (2)
O4W	0.084 (10)	0.085 (10)	0.085 (10)	−0.0001 (10)	0.0077 (14)	0.0000 (10)
O5W	0.13 (5)	0.16 (5)	0.25 (7)	0.08 (4)	−0.01 (5)	−0.01 (5)
O6W	0.043 (15)	0.025 (12)	0.055 (16)	0.003 (11)	−0.001 (12)	−0.014 (11)
O7W	0.029 (5)	0.027 (5)	0.028 (5)	0.001 (2)	0.002 (2)	0.001 (2)
O8W	0.038 (6)	0.039 (6)	0.039 (6)	0.000 (2)	0.004 (2)	0.000 (2)
O9W	0.058 (8)	0.058 (8)	0.058 (8)	−0.001 (2)	0.005 (2)	0.001 (2)
O10W	0.119 (15)	0.119 (15)	0.119 (15)	0.000 (2)	0.011 (2)	0.000 (2)
O11W	0.144 (18)	0.144 (18)	0.144 (18)	0.000 (2)	0.013 (3)	0.000 (2)
O12W	0.07 (3)	0.12 (3)	0.11 (3)	−0.06 (2)	0.00 (2)	−0.04 (3)
O13W	0.15 (4)	0.09 (3)	0.14 (4)	−0.04 (3)	0.08 (3)	−0.02 (3)
O14W	0.22 (3)	0.22 (3)	0.22 (3)	0.000 (2)	0.020 (3)	0.000 (2)
O15W	0.042 (17)	0.09 (2)	0.07 (2)	0.010 (17)	−0.013 (15)	−0.009 (18)
O16W	0.042 (6)	0.043 (6)	0.042 (6)	−0.002 (2)	0.003 (2)	0.003 (2)
O17W	0.17 (2)	0.17 (2)	0.17 (2)	0.000	0.015 (2)	0.000
O18W	0.029 (5)	0.028 (5)	0.028 (5)	0.002 (2)	0.002 (2)	−0.001 (2)
O19W	0.10 (3)	0.041 (16)	0.055 (18)	0.014 (17)	0.011 (17)	−0.020 (14)

Geometric parameters (Å, º)

Zr1—O8	2.07 (2)	W13—K2^ii	3.760 (7)
Zr1—O39	2.102 (19)	W13—K2	3.905 (8)
Zr1—O50	2.11 (2)	W14—O71	1.72 (2)
Zr1—O26^i	2.14 (2)	W14—O63	1.78 (2)
Zr1—O63^i	2.15 (2)	W14—O3	1.860 (19)
Zr1—O13	2.148 (19)	W14—O56	1.92 (2)
Zr1—O30	2.402 (19)	W14—O16	1.94 (2)
Zr1—W2	3.421 (3)	W14—O18	2.379 (19)
Zr1—Na8^i	3.80 (2)	W14—Na6	3.622 (14)
Zr1—Na6^i	3.815 (14)	W15—O64	1.71 (3)
Zr2—O11	2.060 (18)	W15—O53	1.86 (2)
Zr2—O32	2.09 (2)	W15—O47	1.91 (2)
Zr2—O24	2.094 (19)	W15—O22	1.917 (19)
Zr2—O43	2.12 (2)	W15—O19	1.94 (2)
Zr2—O37	2.16 (2)	W15—O20	2.31 (2)
Zr2—O51	2.18 (2)	W16—O52	1.72 (2)
Zr2—O58	2.43 (2)	W16—O4	1.89 (2)
Zr2—W1	3.437 (3)	W16—O23	1.91 (2)
Zr2—K1	3.790 (8)	W16—O69	1.92 (2)
Zr2—Na8^i	3.814 (19)	W16—O27	1.932 (19)
Ge1—O58	1.71 (2)	W16—O25	2.296 (17)
Ge1—O25	1.743 (18)	W16—K1	3.845 (8)
Ge1—O20	1.743 (19)	W17—O62	1.73 (2)
Ge1—O30	1.767 (18)	W17—O14	1.85 (2)
P1—O33	1.49 (2)	W17—O16	1.88 (2)
P1—O40	1.52 (2)	W17—O55	1.94 (2)
P1—O18	1.555 (19)	W17—O21	1.96 (2)
P1—O34	1.59 (2)	W17—O34	2.36 (2)
W1—O38	1.71 (2)	W17—K2	3.654 (7)
W1—O50	1.79 (2)	W18—O66	1.74 (3)
W1—O24	1.83 (2)	W18—O51	1.84 (2)
W1—O35	2.00 (2)	W18—O15	1.912 (19)
W1—O5	2.00 (2)	W18—O2	1.961 (18)
W1—O58	2.33 (2)	W18—O28	1.97 (2)
W1—Na8^i	3.627 (18)	W18—O40	2.370 (19)
W2—O41	1.75 (2)	W18—Na8^i	3.684 (18)
W2—O11	1.812 (18)	W19—O72	1.71 (3)
W2—O8	1.84 (2)	W19—O46	1.75 (2)
W2—O9	2.01 (2)	W19—O31	1.908 (19)
W2—O45	2.02 (2)	W19—O3	1.926 (19)
W2—O30	2.299 (19)	W19—O14	2.06 (2)
W3—O48	1.72 (2)	W19—O33	2.39 (2)
W3—O13	1.838 (18)	W19—Na3	3.659 (15)
W3—O9	1.90 (2)	W19—K2	3.803 (7)
W3—O22	1.924 (19)	K1—O3W	2.72 (7)
W3—O36	1.949 (19)	K1—O52^iii	2.74 (2)
W3—O30	2.276 (19)	K1—O32	2.81 (2)
W4—O70	1.72 (2)	K1—O13W	2.85 (4)
W4—O37	1.82 (2)	K1—O37	2.87 (2)
W4—O5	1.865 (19)	K1—O4	2.91 (2)
W4—O4	1.97 (2)	K1—O69	2.97 (2)
W4—O17	2.02 (2)	K1—O54	2.97 (2)
W4—O58	2.32 (2)	K1—O43	3.08 (2)
W4—K1	3.787 (8)	K2—O14	2.73 (2)
W5—O67	1.72 (3)	K2—O49^ii	2.75 (2)
W5—O32	1.84 (2)	K2—O31	2.82 (2)
W5—O45	1.85 (2)	K2—O55	2.88 (2)
W5—O69	1.98 (2)	K2—O12	2.89 (2)
W5—O44	2.04 (2)	K2—O12^ii	2.89 (2)
W5—O25	2.309 (18)	K2—O2W	2.90 (6)
W5—K1	3.792 (8)	K2—O59^ii	2.95 (2)
W6—O59	1.74 (2)	Na1—O38	2.69 (3)
W6—O12	1.85 (2)	Na1—O66	2.70 (3)
W6—O6	1.86 (2)	Na1—O9^iv	2.73 (2)
W6—O42	1.94 (2)	Na1—O45^iv	2.88 (3)
W6—O55	1.95 (2)	Na1—O36^iv	3.01 (3)
W6—O34	2.350 (18)	Na1—Na8^i	3.97 (3)
W6—K2^ii	3.661 (7)	Na2—O67^iv	2.76 (3)
W6—K2	3.809 (8)	Na2—O2	2.82 (2)
W7—O60	1.68 (2)	Na2—O14W	2.85 (8)
W7—O39	1.824 (19)	Na2—O5W^v	2.90 (7)
W7—O35	1.88 (2)	Na2—O28	2.93 (2)
W7—O7	1.99 (2)	Na2—O6W^v	2.95 (3)
W7—O53	2.01 (2)	Na2—Na5^v	3.906 (18)
W7—O20	2.298 (19)	Na3—O4W	2.21 (4)
W8—O57	1.71 (2)	Na3—O29	2.33 (2)
W8—O17	1.83 (2)	Na3—O15W	2.33 (3)
W8—O7	1.89 (2)	Na3—O46	2.45 (3)
W8—O23	1.92 (2)	Na3—O65^vi	2.45 (3)
W8—O47	1.98 (2)	Na3—O33	2.84 (2)
W8—O20	2.32 (2)	Na3—Na4	3.949 (17)
W9—O54	1.71 (2)	Na4—O51	2.70 (2)
W9—O43	1.85 (2)	Na4—O4W	2.75 (4)
W9—O10	1.85 (2)	Na4—O15W	2.91 (3)
W9—O2	1.92 (2)	Na4—O8^i	2.94 (2)
W9—O6	1.98 (2)	Na4—Na8^i	3.86 (2)
W9—O40	2.374 (19)	Na4—Na8	4.09 (2)
W9—K1	3.790 (8)	Na5—O6W	2.75 (3)
W10—O61	1.70 (2)	Na5—O70	2.75 (3)
W10—O26	1.82 (2)	Na5—O54^v	2.77 (2)
W10—O15	1.90 (2)	Na5—O5W	2.87 (6)
W10—O56	1.93 (2)	Na5—O70^v	2.90 (3)
W10—O1	1.961 (19)	Na5—O1W	2.96 (5)
W10—O18	2.34 (2)	Na5—O13W^v	2.97 (4)
W10—Na8	3.648 (18)	Na5—Na5^v	3.99 (2)
W11—O65	1.70 (2)	Na6—O12W	2.58 (4)
W11—O28	1.87 (2)	Na6—O63	2.81 (2)
W11—O1	1.880 (19)	Na6—O13^i	2.86 (2)
W11—O21	1.91 (2)	Na6—O12W^vii	2.88 (4)
W11—O42	1.93 (2)	Na6—O11W	2.91 (6)
W11—O34	2.43 (2)	Na6—O39^i	2.97 (2)
W12—O68	1.71 (2)	Na6—Na6^vii	4.02 (3)
W12—O44	1.85 (2)	Na7—O72	2.64 (3)
W12—O36	1.89 (2)	Na7—O23^viii	2.76 (3)
W12—O19	1.92 (2)	Na7—O10W	2.81 (5)
W12—O27	1.930 (18)	Na7—O27^viii	2.87 (2)
W12—O25	2.309 (18)	Na7—O47^viii	2.88 (3)
W13—O29	1.71 (2)	Na7—O19^viii	2.90 (3)
W13—O49	1.72 (2)	Na8—O17W	2.73 (7)
W13—O31	1.93 (2)	Na8—O26	2.78 (3)
W13—O10	1.95 (2)	Na8—O50^i	2.82 (3)
W13—O12	2.09 (2)	Na8—O51^i	2.82 (3)
W13—O33	2.39 (2)	Na8—O24^i	2.99 (3)
W13—Na3	3.546 (13)	Na8—Na8^i	3.71 (4)
O8—Zr1—O39	151.2 (8)	O52^iii—K1—O43	152.6 (7)
O8—Zr1—O50	94.9 (8)	O32—K1—O43	52.4 (6)
O39—Zr1—O50	80.3 (8)	O13W—K1—O43	122.4 (10)
O8—Zr1—O26^i	80.1 (8)	O37—K1—O43	58.8 (6)
O39—Zr1—O26^i	125.7 (8)	O4—K1—O43	105.3 (6)
O50—Zr1—O26^i	78.1 (8)	O69—K1—O43	105.6 (6)
O8—Zr1—O63^i	123.7 (8)	O54—K1—O43	53.8 (6)
O39—Zr1—O63^i	78.8 (8)	O3W—K1—W4	163.5 (15)
O50—Zr1—O63^i	128.8 (9)	O52^iii—K1—W4	120.1 (6)
O26^i—Zr1—O63^i	77.3 (8)	O32—K1—W4	67.8 (4)
O8—Zr1—O13	82.0 (8)	O13W—K1—W4	79.6 (10)
O39—Zr1—O13	87.5 (7)	O37—K1—W4	27.6 (4)
O50—Zr1—O13	148.4 (7)	O4—K1—W4	30.8 (4)
O26^i—Zr1—O13	131.4 (8)	O69—K1—W4	82.5 (5)
O63^i—Zr1—O13	76.0 (8)	O54—K1—W4	90.1 (5)
O8—Zr1—O30	69.0 (7)	O43—K1—W4	84.9 (4)
O39—Zr1—O30	82.3 (7)	O3W—K1—W9	72.6 (15)
O50—Zr1—O30	81.7 (7)	O52^iii—K1—W9	144.0 (6)
O26^i—Zr1—O30	141.2 (7)	O32—K1—W9	80.9 (4)
O63^i—Zr1—O30	139.6 (7)	O13W—K1—W9	96.8 (10)
O13—Zr1—O30	67.8 (7)	O37—K1—W9	65.4 (4)
O8—Zr1—W2	27.1 (6)	O4—K1—W9	121.3 (4)
O39—Zr1—W2	124.2 (5)	O69—K1—W9	134.3 (5)
O50—Zr1—W2	86.4 (6)	O54—K1—W9	25.9 (4)
O26^i—Zr1—W2	103.4 (5)	O43—K1—W9	28.9 (4)
O63^i—Zr1—W2	143.0 (7)	W4—K1—W9	92.60 (16)
O13—Zr1—W2	76.6 (5)	O3W—K1—Zr2	109.8 (15)
O30—Zr1—W2	42.1 (5)	O52^iii—K1—Zr2	155.4 (6)
O8—Zr1—Na8^i	59.9 (7)	O32—K1—Zr2	32.9 (4)
O39—Zr1—Na8^i	126.2 (6)	O13W—K1—Zr2	121.1 (8)
O50—Zr1—Na8^i	46.8 (6)	O37—K1—Zr2	34.5 (5)
O26^i—Zr1—Na8^i	46.0 (6)	O4—K1—Zr2	71.3 (4)
O63^i—Zr1—Na8^i	123.2 (6)	O69—K1—Zr2	85.6 (5)
O13—Zr1—Na8^i	141.9 (6)	O54—K1—Zr2	74.1 (4)
O30—Zr1—Na8^i	96.8 (6)	O43—K1—Zr2	34.0 (4)
W2—Zr1—Na8^i	69.7 (3)	W4—K1—Zr2	54.48 (11)
O8—Zr1—Na6^i	129.3 (6)	W9—K1—Zr2	56.33 (11)
O39—Zr1—Na6^i	50.8 (6)	O14—K2—O49^ii	121.3 (7)
O50—Zr1—Na6^i	130.9 (6)	O14—K2—O31	56.4 (6)
O26^i—Zr1—Na6^i	123.9 (6)	O49^ii—K2—O31	68.0 (6)
O63^i—Zr1—Na6^i	46.7 (6)	O14—K2—O55	57.6 (7)
O13—Zr1—Na6^i	48.0 (6)	O49^ii—K2—O55	150.8 (8)
O30—Zr1—Na6^i	94.2 (5)	O31—K2—O55	95.6 (6)
W2—Zr1—Na6^i	122.2 (2)	O14—K2—O12	69.1 (6)
Na8^i—Zr1—Na6^i	168.0 (4)	O49^ii—K2—O12	95.9 (7)
O11—Zr2—O32	79.2 (7)	O31—K2—O12	56.3 (6)
O11—Zr2—O24	99.4 (7)	O55—K2—O12	55.4 (6)
O32—Zr2—O24	146.0 (8)	O14—K2—O12^ii	161.7 (7)
O11—Zr2—O43	115.8 (8)	O49^ii—K2—O12^ii	57.9 (6)
O32—Zr2—O43	76.4 (8)	O31—K2—O12^ii	113.4 (7)
O24—Zr2—O43	131.4 (8)	O55—K2—O12^ii	113.0 (6)
O11—Zr2—O37	148.7 (8)	O12—K2—O12^ii	92.6 (6)
O32—Zr2—O37	85.2 (8)	O14—K2—O2W	92.2 (13)
O24—Zr2—O37	78.8 (8)	O49^ii—K2—O2W	93.6 (13)
O43—Zr2—O37	86.1 (8)	O31—K2—O2W	113.4 (13)
O11—Zr2—O51	79.8 (8)	O55—K2—O2W	115.5 (13)
O32—Zr2—O51	134.0 (8)	O12—K2—O2W	161.3 (13)
O24—Zr2—O51	77.9 (8)	O12^ii—K2—O2W	106.1 (13)
O43—Zr2—O51	76.7 (8)	O14—K2—O59^ii	123.1 (7)
O37—Zr2—O51	129.1 (8)	O49^ii—K2—O59^ii	114.4 (7)
O11—Zr2—O58	81.5 (7)	O31—K2—O59^ii	151.6 (7)
O32—Zr2—O58	77.4 (7)	O55—K2—O59^ii	68.7 (7)
O24—Zr2—O58	68.8 (7)	O12—K2—O59^ii	95.9 (7)
O43—Zr2—O58	144.8 (7)	O12^ii—K2—O59^ii	57.3 (7)
O37—Zr2—O58	68.6 (7)	O2W—K2—O59^ii	94.9 (13)
O51—Zr2—O58	138.3 (7)	O14—K2—W17	29.5 (5)
O11—Zr2—W1	87.8 (5)	O49^ii—K2—W17	149.9 (5)
O32—Zr2—W1	120.0 (6)	O31—K2—W17	82.1 (4)
O24—Zr2—W1	26.8 (5)	O55—K2—W17	31.9 (4)
O43—Zr2—W1	154.4 (6)	O12—K2—W17	69.2 (4)
O37—Zr2—W1	76.7 (6)	O12^ii—K2—W17	144.8 (5)
O51—Zr2—W1	99.5 (6)	O2W—K2—W17	94.9 (12)
O58—Zr2—W1	42.7 (5)	O59^ii—K2—W17	93.6 (5)
O11—Zr2—K1	125.7 (5)	O14—K2—W6^ii	149.8 (6)
O32—Zr2—K1	46.8 (6)	O49^ii—K2—W6^ii	86.6 (5)
O24—Zr2—K1	127.4 (5)	O31—K2—W6^ii	140.2 (5)
O43—Zr2—K1	54.2 (6)	O55—K2—W6^ii	92.5 (5)
O37—Zr2—K1	48.7 (6)	O12—K2—W6^ii	99.0 (5)
O51—Zr2—K1	130.3 (6)	O12^ii—K2—W6^ii	30.0 (4)
O58—Zr2—K1	90.6 (5)	O2W—K2—W6^ii	97.7 (12)
W1—Zr2—K1	120.75 (16)	O59^ii—K2—W6^ii	27.9 (5)
O11—Zr2—Na8^i	57.5 (6)	W17—K2—W6^ii	120.7 (2)
O32—Zr2—Na8^i	136.6 (6)	O14—K2—W13^ii	145.6 (5)
O24—Zr2—Na8^i	51.2 (6)	O49^ii—K2—W13^ii	25.0 (4)
O43—Zr2—Na8^i	123.5 (6)	O31—K2—W13^ii	89.9 (4)
O37—Zr2—Na8^i	129.9 (7)	O55—K2—W13^ii	142.3 (5)
O51—Zr2—Na8^i	47.0 (6)	O12—K2—W13^ii	99.3 (4)
O58—Zr2—Na8^i	91.7 (5)	O12^ii—K2—W13^ii	33.5 (4)
W1—Zr2—Na8^i	59.8 (3)	O2W—K2—W13^ii	96.0 (12)
K1—Zr2—Na8^i	176.4 (4)	O59^ii—K2—W13^ii	89.5 (5)
O58—Ge1—O25	109.9 (9)	W17—K2—W13^ii	168.4 (3)
O58—Ge1—O20	109.4 (10)	W6^ii—K2—W13^ii	61.59 (12)
O25—Ge1—O20	105.8 (9)	O14—K2—W19	31.7 (5)
O58—Ge1—O30	112.9 (9)	O49^ii—K2—W19	89.6 (5)
O25—Ge1—O30	109.6 (9)	O31—K2—W19	28.9 (4)
O20—Ge1—O30	109.0 (10)	O55—K2—W19	85.2 (5)
O33—P1—O40	110.6 (11)	O12—K2—W19	69.9 (4)
O33—P1—O18	111.1 (12)	O12^ii—K2—W19	142.0 (5)
O40—P1—O18	113.0 (11)	O2W—K2—W19	94.1 (12)
O33—P1—O34	106.6 (11)	O59^ii—K2—W19	153.7 (5)
O40—P1—O34	107.9 (11)	W17—K2—W19	60.98 (11)
O18—P1—O34	107.3 (11)	W6^ii—K2—W19	167.8 (3)
O38—W1—O50	102.6 (10)	W13^ii—K2—W19	114.1 (2)
O38—W1—O24	102.5 (10)	O38—Na1—O66	100.3 (8)
O50—W1—O24	96.7 (9)	O38—Na1—O9^iv	112.0 (8)
O38—W1—O35	95.1 (10)	O66—Na1—O9^iv	147.4 (9)
O50—W1—O35	88.6 (9)	O38—Na1—O45^iv	126.3 (8)
O24—W1—O35	159.9 (8)	O66—Na1—O45^iv	108.3 (8)
O38—W1—O5	100.8 (9)	O9^iv—Na1—O45^iv	55.7 (6)
O50—W1—O5	155.4 (9)	O38—Na1—O36^iv	69.7 (7)
O24—W1—O5	85.5 (8)	O66—Na1—O36^iv	149.7 (8)
O35—W1—O5	81.8 (8)	O9^iv—Na1—O36^iv	54.0 (6)
O38—W1—O58	172.8 (9)	O45^iv—Na1—O36^iv	62.6 (7)
O50—W1—O58	84.5 (8)	O38—Na1—Na8^i	68.5 (6)
O24—W1—O58	75.3 (8)	O66—Na1—Na8^i	54.9 (6)
O35—W1—O58	86.0 (8)	O9^iv—Na1—Na8^i	133.4 (6)
O5—W1—O58	72.3 (7)	O45^iv—Na1—Na8^i	161.6 (7)
O38—W1—Zr2	133.5 (8)	O36^iv—Na1—Na8^i	135.4 (6)
O50—W1—Zr2	86.1 (7)	O67^iv—Na2—O2	120.3 (9)
O24—W1—Zr2	31.1 (6)	O67^iv—Na2—O14W	83.2 (17)
O35—W1—Zr2	131.0 (6)	O2—Na2—O14W	154.3 (17)
O5—W1—Zr2	83.3 (6)	O67^iv—Na2—O5W^v	120.8 (15)
O58—W1—Zr2	45.1 (5)	O2—Na2—O5W^v	92.8 (12)
O38—W1—Na8^i	85.9 (8)	O14W—Na2—O5W^v	82.2 (19)
O50—W1—Na8^i	49.6 (7)	O67^iv—Na2—O28	109.7 (9)
O24—W1—Na8^i	55.1 (6)	O2—Na2—O28	55.3 (6)
O35—W1—Na8^i	136.8 (7)	O14W—Na2—O28	109.5 (17)
O5—W1—Na8^i	140.5 (7)	O5W^v—Na2—O28	129.3 (14)
O58—W1—Na8^i	98.2 (6)	O67^iv—Na2—O6W^v	69.8 (8)
Zr2—W1—Na8^i	65.3 (3)	O2—Na2—O6W^v	61.1 (6)
O41—W2—O11	103.2 (9)	O14W—Na2—O6W^v	143.7 (17)
O41—W2—O8	104.4 (10)	O5W^v—Na2—O6W^v	91.1 (13)
O11—W2—O8	95.5 (9)	O28—Na2—O6W^v	102.3 (7)
O41—W2—O9	98.5 (10)	O67^iv—Na2—Na5^v	100.6 (7)
O11—W2—O9	155.6 (9)	O2—Na2—Na5^v	66.1 (5)
O8—W2—O9	89.7 (9)	O14W—Na2—Na5^v	123.3 (16)
O41—W2—O45	94.8 (10)	O5W^v—Na2—Na5^v	47.1 (12)
O11—W2—O45	86.0 (8)	O28—Na2—Na5^v	121.3 (6)
O8—W2—O45	159.8 (9)	O6W^v—Na2—Na5^v	44.6 (6)
O9—W2—O45	81.2 (9)	O4W—Na3—O29	154.9 (13)
O41—W2—O30	170.3 (9)	O4W—Na3—O15W	87.1 (13)
O11—W2—O30	86.5 (7)	O29—Na3—O15W	92.4 (11)
O8—W2—O30	75.1 (8)	O4W—Na3—O46	91.2 (12)
O9—W2—O30	71.8 (8)	O29—Na3—O46	80.7 (9)
O45—W2—O30	84.8 (8)	O15W—Na3—O46	159.8 (12)
O41—W2—Zr1	135.3 (7)	O4W—Na3—O65^vi	99.1 (12)
O11—W2—Zr1	88.5 (6)	O29—Na3—O65^vi	105.5 (9)
O8—W2—Zr1	30.9 (6)	O15W—Na3—O65^vi	101.8 (12)
O9—W2—Zr1	83.8 (6)	O46—Na3—O65^vi	98.3 (9)
O45—W2—Zr1	129.3 (6)	O4W—Na3—O33	88.9 (11)
O30—W2—Zr1	44.5 (5)	O29—Na3—O33	66.1 (8)
O48—W3—O13	100.6 (9)	O15W—Na3—O33	94.9 (10)
O48—W3—O9	99.9 (9)	O46—Na3—O33	65.0 (8)
O13—W3—O9	93.0 (9)	O65^vi—Na3—O33	161.8 (10)
O48—W3—O22	101.9 (9)	O4W—Na3—W13	130.9 (11)
O13—W3—O22	90.6 (8)	O29—Na3—W13	24.1 (6)
O9—W3—O22	156.9 (8)	O15W—Na3—W13	93.2 (8)
O48—W3—O36	98.0 (10)	O46—Na3—W13	72.8 (6)
O13—W3—O36	161.3 (9)	O65^vi—Na3—W13	128.6 (7)
O9—W3—O36	85.7 (9)	O33—Na3—W13	42.1 (4)
O22—W3—O36	83.7 (9)	O4W—Na3—W19	92.0 (11)
O48—W3—O30	172.7 (9)	O29—Na3—W19	70.9 (7)
O13—W3—O30	75.6 (7)	O15W—Na3—W19	135.6 (9)
O9—W3—O30	74.3 (7)	O46—Na3—W19	24.3 (5)
O22—W3—O30	84.5 (8)	O65^vi—Na3—W19	122.1 (8)
O36—W3—O30	86.1 (8)	O33—Na3—W19	40.7 (5)
O70—W4—O37	100.6 (11)	W13—Na3—W19	55.4 (2)
O70—W4—O5	100.4 (11)	O4W—Na3—Na4	42.4 (10)
O37—W4—O5	94.4 (9)	O29—Na3—Na4	125.6 (8)
O70—W4—O4	100.0 (11)	O15W—Na3—Na4	47.1 (9)
O37—W4—O4	91.9 (9)	O46—Na3—Na4	123.6 (7)
O5—W4—O4	157.1 (8)	O65^vi—Na3—Na4	115.8 (7)
O70—W4—O17	98.6 (11)	O33—Na3—Na4	81.0 (5)
O37—W4—O17	160.6 (9)	W13—Na3—Na4	110.4 (4)
O5—W4—O17	85.0 (8)	W19—Na3—Na4	110.3 (4)
O4—W4—O17	81.8 (8)	O51—Na4—O4W	134.8 (10)
O70—W4—O58	174.5 (11)	O51—Na4—O15W	83.3 (8)
O37—W4—O58	76.9 (8)	O4W—Na4—O15W	67.1 (10)
O5—W4—O58	75.1 (8)	O51—Na4—O8^i	144.8 (7)
O4—W4—O58	85.0 (8)	O4W—Na4—O8^i	72.4 (9)
O17—W4—O58	84.2 (8)	O15W—Na4—O8^i	131.9 (8)
O70—W4—K1	89.1 (9)	O51—Na4—Na8^i	47.0 (6)
O37—W4—K1	46.8 (7)	O4W—Na4—Na8^i	170.8 (9)
O5—W4—K1	141.2 (7)	O15W—Na4—Na8^i	120.8 (7)
O4—W4—K1	49.2 (6)	O8^i—Na4—Na8^i	102.4 (6)
O17—W4—K1	130.9 (5)	O51—Na4—Na3	106.9 (6)
O58—W4—K1	92.6 (5)	O4W—Na4—Na3	32.8 (8)
O67—W5—O32	103.4 (12)	O15W—Na4—Na3	35.9 (6)
O67—W5—O45	102.0 (12)	O8^i—Na4—Na3	104.6 (5)
O32—W5—O45	92.7 (9)	Na8^i—Na4—Na3	153.0 (4)
O67—W5—O69	97.6 (12)	O51—Na4—Na8	91.9 (6)
O32—W5—O69	88.7 (9)	O4W—Na4—Na8	116.2 (8)
O45—W5—O69	159.4 (10)	O15W—Na4—Na8	175.0 (8)
O67—W5—O44	99.1 (11)	O8^i—Na4—Na8	52.9 (5)
O32—W5—O44	156.9 (9)	Na8^i—Na4—Na8	55.6 (5)
O45—W5—O44	87.8 (9)	Na3—Na4—Na8	146.2 (4)
O69—W5—O44	83.0 (9)	O6W—Na5—O70	131.2 (9)
O67—W5—O25	166.4 (10)	O6W—Na5—O54^v	97.7 (7)
O32—W5—O25	85.7 (8)	O70—Na5—O54^v	127.0 (9)
O45—W5—O25	87.5 (8)	O6W—Na5—O5W	95.9 (16)
O69—W5—O25	72.2 (8)	O70—Na5—O5W	85.2 (15)
O44—W5—O25	71.3 (8)	O54^v—Na5—O5W	68.5 (14)
O67—W5—K1	84.9 (10)	O6W—Na5—O70^v	87.8 (8)
O32—W5—K1	44.9 (6)	O70—Na5—O70^v	90.4 (8)
O45—W5—K1	137.0 (7)	O54^v—Na5—O70^v	113.7 (8)
O69—W5—K1	50.8 (7)	O5W—Na5—O70^v	175.5 (15)
O44—W5—K1	133.5 (6)	O6W—Na5—O1W	67.6 (10)
O25—W5—K1	94.9 (5)	O70—Na5—O1W	66.3 (11)
O59—W6—O12	102.6 (10)	O54^v—Na5—O1W	136.7 (11)
O59—W6—O6	101.3 (11)	O5W—Na5—O1W	72.7 (16)
O12—W6—O6	90.6 (9)	O70^v—Na5—O1W	106.4 (11)
O59—W6—O42	100.2 (10)	O6W—Na5—O13W^v	149.5 (11)
O12—W6—O42	157.3 (8)	O70—Na5—O13W^v	72.5 (10)
O6—W6—O42	85.5 (9)	O54^v—Na5—O13W^v	72.2 (11)
O59—W6—O55	100.9 (11)	O5W—Na5—O13W^v	106.2 (18)
O12—W6—O55	89.9 (9)	O70^v—Na5—O13W^v	71.3 (12)
O6—W6—O55	157.2 (9)	O1W—Na5—O13W^v	138.7 (12)
O42—W6—O55	85.3 (10)	O6W—Na5—Na2^v	48.9 (6)
O59—W6—O34	170.9 (10)	O70—Na5—Na2^v	120.2 (7)
O12—W6—O34	84.2 (8)	O54^v—Na5—Na2^v	73.9 (5)
O6—W6—O34	84.5 (8)	O5W—Na5—Na2^v	47.6 (15)
O42—W6—O34	73.1 (8)	O70^v—Na5—Na2^v	136.3 (6)
O55—W6—O34	72.9 (8)	O1W—Na5—Na2^v	65.9 (9)
O59—W6—K2^ii	52.5 (8)	O13W^v—Na5—Na2^v	143.6 (11)
O12—W6—K2^ii	51.3 (6)	O6W—Na5—Na5^v	115.2 (7)
O6—W6—K2^ii	90.2 (7)	O70—Na5—Na5^v	46.7 (6)
O42—W6—K2^ii	150.9 (6)	O54^v—Na5—Na5^v	135.1 (7)
O55—W6—K2^ii	107.7 (7)	O5W—Na5—Na5^v	131.9 (14)
O34—W6—K2^ii	135.2 (5)	O70^v—Na5—Na5^v	43.7 (5)
O59—W6—K2	89.7 (9)	O1W—Na5—Na5^v	85.9 (9)
O12—W6—K2	47.1 (6)	O13W^v—Na5—Na5^v	63.8 (10)
O6—W6—K2	137.7 (6)	Na2^v—Na5—Na5^v	151.0 (5)
O42—W6—K2	132.9 (7)	O6W—Na5—K1^v	108.8 (6)
O55—W6—K2	47.7 (7)	O70—Na5—K1^v	116.0 (7)
O34—W6—K2	90.6 (5)	O54^v—Na5—K1^v	46.1 (5)
K2^ii—W6—K2	64.5 (2)	O5W—Na5—K1^v	111.5 (13)
O60—W7—O39	102.6 (11)	O70^v—Na5—K1^v	69.6 (6)
O60—W7—O35	101.5 (11)	O1W—Na5—K1^v	175.0 (10)
O39—W7—O35	94.0 (9)	O13W^v—Na5—K1^v	43.6 (8)
O60—W7—O7	97.7 (10)	Na2^v—Na5—K1^v	114.7 (3)
O39—W7—O7	159.1 (9)	Na5^v—Na5—K1^v	92.8 (4)
O35—W7—O7	86.4 (9)	O12W—Na6—O63	130.5 (11)
O60—W7—O53	100.1 (11)	O12W—Na6—O13^i	154.1 (11)
O39—W7—O53	88.9 (9)	O63—Na6—O13^i	55.5 (6)
O35—W7—O53	157.0 (9)	O12W—Na6—O12W^vii	85.4 (15)
O7—W7—O53	83.0 (9)	O63—Na6—O12W^vii	144.1 (11)
O60—W7—O20	166.4 (9)	O13^i—Na6—O12W^vii	92.5 (10)
O39—W7—O20	87.8 (8)	O12W—Na6—O11W	133.4 (14)
O35—W7—O20	86.3 (8)	O63—Na6—O11W	84.8 (13)
O7—W7—O20	71.4 (8)	O13^i—Na6—O11W	67.3 (12)
O53—W7—O20	71.1 (8)	O12W^vii—Na6—O11W	66.4 (14)
O57—W8—O17	102.6 (10)	O12W—Na6—O39^i	100.5 (9)
O57—W8—O7	101.5 (9)	O63—Na6—O39^i	55.5 (6)
O17—W8—O7	92.0 (9)	O13^i—Na6—O39^i	60.4 (6)
O57—W8—O23	100.5 (10)	O12W^vii—Na6—O39^i	126.2 (10)
O17—W8—O23	87.2 (9)	O11W—Na6—O39^i	126.0 (13)
O7—W8—O23	157.6 (9)	O12W—Na6—W14	106.9 (10)
O57—W8—O47	99.3 (10)	O63—Na6—W14	28.7 (5)
O17—W8—O47	158.0 (9)	O13^i—Na6—W14	83.9 (5)
O7—W8—O47	86.1 (9)	O12W^vii—Na6—W14	158.6 (9)
O23—W8—O47	86.4 (9)	O11W—Na6—W14	92.9 (11)
O57—W8—O20	170.5 (9)	O39^i—Na6—W14	69.9 (5)
O17—W8—O20	85.2 (8)	O12W—Na6—Zr1^i	133.0 (9)
O7—W8—O20	72.6 (8)	O63—Na6—Zr1^i	33.7 (4)
O23—W8—O20	85.1 (8)	O13^i—Na6—Zr1^i	33.9 (4)
O47—W8—O20	73.3 (8)	O12W^vii—Na6—Zr1^i	123.8 (9)
O54—W9—O43	100.7 (10)	O11W—Na6—Zr1^i	93.5 (11)
O54—W9—O10	102.6 (10)	O39^i—Na6—Zr1^i	33.2 (4)
O43—W9—O10	94.2 (9)	W14—Na6—Zr1^i	60.0 (2)
O54—W9—O2	100.4 (9)	O12W—Na6—Na6^vii	45.6 (9)
O43—W9—O2	88.3 (9)	O63—Na6—Na6^vii	176.0 (9)
O10—W9—O2	156.0 (8)	O13^i—Na6—Na6^vii	127.5 (7)
O54—W9—O6	96.4 (9)	O12W^vii—Na6—Na6^vii	39.8 (9)
O43—W9—O6	162.3 (9)	O11W—Na6—Na6^vii	98.9 (12)
O10—W9—O6	86.7 (8)	O39^i—Na6—Na6^vii	122.7 (7)
O2—W9—O6	83.9 (8)	W14—Na6—Na6^vii	148.6 (6)
O54—W9—O40	174.9 (9)	Zr1^i—Na6—Na6^vii	146.8 (6)
O43—W9—O40	81.5 (8)	O72—Na7—O23^viii	127.2 (10)
O10—W9—O40	81.7 (8)	O72—Na7—O10W	70.1 (12)
O2—W9—O40	75.1 (7)	O23^viii—Na7—O10W	99.8 (12)
O6—W9—O40	81.1 (7)	O72—Na7—O27^viii	138.6 (10)
O54—W9—K1	49.4 (7)	O23^viii—Na7—O27^viii	55.4 (7)
O43—W9—K1	53.6 (7)	O10W—Na7—O27^viii	148.7 (13)
O10—W9—K1	90.8 (6)	O72—Na7—O47^viii	70.7 (9)
O2—W9—K1	109.6 (6)	O23^viii—Na7—O47^viii	56.6 (7)
O6—W9—K1	144.1 (6)	O10W—Na7—O47^viii	84.2 (11)
O40—W9—K1	133.9 (5)	O27^viii—Na7—O47^viii	94.3 (8)
O61—W10—O26	99.2 (11)	O72—Na7—O19^viii	87.9 (8)
O61—W10—O15	100.0 (10)	O23^viii—Na7—O19^viii	65.3 (7)
O26—W10—O15	91.7 (8)	O10W—Na7—O19^viii	138.2 (12)
O61—W10—O56	102.9 (10)	O27^viii—Na7—O19^viii	53.9 (6)
O26—W10—O56	89.4 (9)	O47^viii—Na7—O19^viii	54.6 (7)
O15—W10—O56	156.6 (8)	O72—Na7—K2	58.6 (7)
O61—W10—O1	99.2 (10)	O23^viii—Na7—K2	164.7 (9)
O26—W10—O1	161.6 (9)	O10W—Na7—K2	67.8 (10)
O15—W10—O1	85.0 (8)	O27^viii—Na7—K2	132.2 (6)
O56—W10—O1	86.6 (8)	O47^viii—Na7—K2	127.6 (6)
O61—W10—O18	177.4 (9)	O19^viii—Na7—K2	129.9 (7)
O26—W10—O18	80.3 (8)	O17W—Na8—O26	104.7 (8)
O15—W10—O18	82.6 (8)	O17W—Na8—O50^i	141.0 (14)
O56—W10—O18	74.6 (8)	O26—Na8—O50^i	57.2 (7)
O1—W10—O18	81.4 (8)	O17W—Na8—O51^i	104.7 (8)
O61—W10—Na8	58.3 (9)	O26—Na8—O51^i	150.0 (11)
O26—W10—Na8	48.1 (8)	O50^i—Na8—O51^i	101.5 (8)
O15—W10—Na8	76.4 (7)	O17W—Na8—O24^i	121.8 (14)
O56—W10—Na8	120.3 (7)	O26—Na8—O24^i	112.1 (8)
O1—W10—Na8	146.6 (7)	O50^i—Na8—O24^i	55.4 (7)
O18—W10—Na8	122.4 (6)	O51^i—Na8—O24^i	55.0 (6)
O65—W11—O28	101.3 (11)	O17W—Na8—W1^i	127.7 (15)
O65—W11—O1	105.2 (10)	O26—Na8—W1^i	82.7 (6)
O28—W11—O1	84.8 (8)	O50^i—Na8—W1^i	28.9 (5)
O65—W11—O21	102.8 (11)	O51^i—Na8—W1^i	84.2 (6)
O28—W11—O21	155.8 (9)	O24^i—Na8—W1^i	30.2 (4)
O1—W11—O21	90.5 (9)	O17W—Na8—W10	78.9 (5)
O65—W11—O42	98.6 (10)	O26—Na8—W10	29.2 (5)
O28—W11—O42	88.1 (9)	O50^i—Na8—W10	71.8 (6)
O1—W11—O42	156.1 (9)	O51^i—Na8—W10	171.6 (8)
O21—W11—O42	86.6 (10)	O24^i—Na8—W10	116.6 (7)
O65—W11—O34	168.8 (9)	W1^i—Na8—W10	87.7 (4)
O28—W11—O34	83.5 (8)	O17W—Na8—W18^i	78.5 (5)
O1—W11—O34	85.2 (7)	O26—Na8—W18^i	172.3 (8)
O21—W11—O34	72.4 (8)	O50^i—Na8—W18^i	116.0 (7)
O42—W11—O34	71.3 (8)	O51^i—Na8—W18^i	29.3 (5)
O68—W12—O44	102.1 (10)	O24^i—Na8—W18^i	60.7 (5)
O68—W12—O36	104.2 (11)	W1^i—Na8—W18^i	89.9 (4)
O44—W12—O36	90.1 (9)	W10—Na8—W18^i	149.2 (7)
O68—W12—O19	97.8 (10)	O17W—Na8—Na8^i	47.1 (13)
O44—W12—O19	159.8 (9)	O26—Na8—Na8^i	97.4 (7)
O36—W12—O19	88.0 (9)	O50^i—Na8—Na8^i	153.1 (9)
O68—W12—O27	98.9 (10)	O51^i—Na8—Na8^i	98.1 (8)
O44—W12—O27	88.3 (8)	O24^i—Na8—Na8^i	150.4 (9)
O36—W12—O27	156.7 (9)	W1^i—Na8—Na8^i	174.7 (4)
O19—W12—O27	85.5 (8)	W10—Na8—Na8^i	89.9 (6)
O68—W12—O25	170.7 (10)	W18^i—Na8—Na8^i	89.9 (6)
O44—W12—O25	74.4 (8)	O17W—Na8—Zr1^i	138.2 (6)
O36—W12—O25	84.6 (8)	O26—Na8—Zr1^i	33.7 (5)
O19—W12—O25	85.4 (8)	O50^i—Na8—Zr1^i	33.1 (5)
O27—W12—O25	72.6 (7)	O51^i—Na8—Zr1^i	117.0 (8)
O29—W13—O49	102.1 (11)	O24^i—Na8—Zr1^i	86.0 (6)
O29—W13—O31	96.6 (11)	W1^i—Na8—Zr1^i	62.0 (3)
O49—W13—O31	101.9 (10)	W10—Na8—Zr1^i	60.0 (3)
O29—W13—O10	93.9 (10)	W18^i—Na8—Zr1^i	142.2 (6)
O49—W13—O10	100.1 (11)	Na8^i—Na8—Zr1^i	120.5 (6)
O31—W13—O10	153.1 (8)	O17W—Na8—Zr2^i	135.4 (7)
O29—W13—O12	166.4 (9)	O26—Na8—Zr2^i	118.9 (8)
O49—W13—O12	91.0 (10)	O50^i—Na8—Zr2^i	67.3 (6)
O31—W13—O12	84.0 (9)	O51^i—Na8—Zr2^i	34.4 (5)
O10—W13—O12	80.2 (8)	O24^i—Na8—Zr2^i	33.1 (4)
O29—W13—O33	86.7 (9)	W1^i—Na8—Zr2^i	54.9 (3)
O49—W13—O33	170.4 (10)	W10—Na8—Zr2^i	139.0 (6)
O31—W13—O33	73.1 (7)	W18^i—Na8—Zr2^i	57.1 (3)
O10—W13—O33	82.9 (8)	Na8^i—Na8—Zr2^i	128.7 (7)
O12—W13—O33	80.5 (7)	Zr1^i—Na8—Zr2^i	85.3 (4)
O29—W13—Na3	33.7 (7)	O17W—Na8—Na4^i	99.9 (11)
O49—W13—Na3	135.8 (8)	O26—Na8—Na4^i	123.5 (9)
O31—W13—Na3	87.0 (7)	O50^i—Na8—Na4^i	119.0 (8)
O10—W13—Na3	88.1 (6)	O51^i—Na8—Na4^i	44.4 (5)
O12—W13—Na3	133.1 (6)	O24^i—Na8—Na4^i	95.5 (6)
O33—W13—Na3	53.0 (5)	W1^i—Na8—Na4^i	119.0 (5)
O29—W13—K2^ii	142.2 (7)	W10—Na8—Na4^i	143.2 (6)
O49—W13—K2^ii	42.4 (8)	W18^i—Na8—Na4^i	61.9 (3)
O31—W13—K2^ii	102.7 (6)	Na8^i—Na8—Na4^i	65.4 (5)
O10—W13—K2^ii	83.3 (6)	Zr1^i—Na8—Na4^i	108.2 (6)
O12—W13—K2^ii	49.7 (5)	Zr2^i—Na8—Na4^i	64.6 (4)
O33—W13—K2^ii	129.9 (5)	W11—O1—W10	153.2 (11)
Na3—W13—K2^ii	170.2 (3)	W9—O2—W18	119.7 (11)
O29—W13—K2	138.4 (9)	W9—O2—Na2	113.1 (9)
O49—W13—K2	82.2 (9)	W18—O2—Na2	103.3 (9)
O31—W13—K2	43.0 (7)	W14—O3—W19	156.6 (11)
O10—W13—K2	126.5 (6)	W16—O4—W4	152.8 (12)
O12—W13—K2	46.3 (6)	W16—O4—K1	104.3 (8)
O33—W13—K2	88.7 (5)	W4—O4—K1	100.0 (8)
Na3—W13—K2	126.7 (3)	W4—O5—W1	119.9 (10)
K2^ii—W13—K2	62.7 (2)	W6—O6—W9	146.7 (11)
O71—W14—O63	100.5 (11)	W8—O7—W7	121.5 (10)
O71—W14—O3	101.5 (11)	W2—O8—Zr1	122.0 (10)
O63—W14—O3	93.9 (10)	W2—O8—Na4^i	131.4 (10)
O71—W14—O56	100.0 (11)	Zr1—O8—Na4^i	106.4 (8)
O63—W14—O56	88.2 (10)	W3—O9—W2	118.8 (10)
O3—W14—O56	157.6 (9)	W3—O9—Na1^vi	109.9 (10)
O71—W14—O16	97.0 (11)	W2—O9—Na1^vi	107.3 (9)
O63—W14—O16	162.2 (9)	W9—O10—W13	157.8 (11)
O3—W14—O16	85.5 (9)	W2—O11—Zr2	160.5 (10)
O56—W14—O16	85.7 (10)	W6—O12—W13	149.3 (11)
O71—W14—O18	173.9 (10)	W6—O12—K2	104.9 (8)
O63—W14—O18	80.3 (8)	W13—O12—K2	102.1 (8)
O3—W14—O18	84.4 (8)	W6—O12—K2^ii	98.8 (8)
O56—W14—O18	73.9 (8)	W13—O12—K2^ii	96.8 (7)
O16—W14—O18	82.0 (8)	K2—O12—K2^ii	87.4 (6)
O71—W14—Na6	59.8 (10)	W3—O13—Zr1	120.9 (9)
O63—W14—Na6	49.5 (7)	W3—O13—Na6^i	108.8 (8)
O3—W14—Na6	76.7 (6)	Zr1—O13—Na6^i	98.1 (7)
O56—W14—Na6	120.3 (7)	W17—O14—W19	150.1 (11)
O16—W14—Na6	146.2 (8)	W17—O14—K2	104.0 (9)
O18—W14—Na6	123.7 (6)	W19—O14—K2	104.1 (9)
O64—W15—O53	99.0 (11)	W10—O15—W18	151.4 (12)
O64—W15—O47	100.5 (10)	W17—O16—W14	147.5 (14)
O53—W15—O47	88.4 (9)	W8—O17—W4	154.6 (11)
O64—W15—O22	101.0 (10)	P1—O18—W10	129.3 (12)
O53—W15—O22	90.0 (9)	P1—O18—W14	128.3 (11)
O47—W15—O22	158.4 (9)	W10—O18—W14	90.0 (6)
O64—W15—O19	100.7 (10)	W12—O19—W15	147.3 (11)
O53—W15—O19	160.2 (9)	W12—O19—Na7^ix	105.7 (8)
O47—W15—O19	86.8 (9)	W15—O19—Na7^ix	104.8 (9)
O22—W15—O19	87.5 (8)	Ge1—O20—W7	121.3 (10)
O64—W15—O20	170.6 (9)	Ge1—O20—W15	123.0 (11)
O53—W15—O20	73.2 (9)	W7—O20—W15	94.2 (7)
O47—W15—O20	74.5 (8)	Ge1—O20—W8	123.3 (11)
O22—W15—O20	84.4 (8)	W7—O20—W8	94.2 (7)
O19—W15—O20	87.1 (8)	W15—O20—W8	93.0 (7)
O52—W16—O4	101.7 (10)	W11—O21—W17	123.6 (10)
O52—W16—O23	100.7 (10)	W15—O22—W3	154.0 (11)
O4—W16—O23	87.3 (9)	W16—O23—W8	149.2 (11)
O52—W16—O69	100.8 (10)	W16—O23—Na7^ix	105.4 (9)
O4—W16—O69	91.2 (9)	W8—O23—Na7^ix	104.9 (9)
O23—W16—O69	158.3 (9)	W1—O24—Zr2	122.1 (10)
O52—W16—O27	98.6 (9)	W1—O24—Na8^i	94.7 (8)
O4—W16—O27	159.4 (8)	Zr2—O24—Na8^i	95.7 (8)
O23—W16—O27	85.9 (9)	Ge1—O25—W16	123.6 (9)
O69—W16—O27	88.0 (9)	Ge1—O25—W12	125.0 (9)
O52—W16—O25	169.7 (9)	W16—O25—W12	93.7 (6)
O4—W16—O25	87.2 (7)	Ge1—O25—W5	118.5 (9)
O23—W16—O25	84.7 (8)	W16—O25—W5	94.3 (7)
O69—W16—O25	73.6 (8)	W12—O25—W5	93.9 (6)
O27—W16—O25	72.9 (7)	W10—O26—Zr1^i	139.9 (10)
O52—W16—K1	88.7 (7)	W10—O26—Na8	102.7 (11)
O4—W16—K1	47.2 (6)	Zr1^i—O26—Na8	100.3 (9)
O23—W16—K1	134.5 (7)	W12—O27—W16	120.8 (10)
O69—W16—K1	49.1 (7)	W12—O27—Na7^ix	106.3 (9)
O27—W16—K1	136.9 (6)	W16—O27—Na7^ix	100.9 (8)
O25—W16—K1	93.7 (5)	W11—O28—W18	151.2 (12)
O62—W17—O14	103.7 (11)	W11—O28—Na2	108.6 (8)
O62—W17—O16	103.1 (10)	W18—O28—Na2	99.4 (8)
O14—W17—O16	89.1 (10)	W13—O29—Na3	122.2 (12)
O62—W17—O55	97.7 (10)	Ge1—O30—W3	123.1 (9)
O14—W17—O55	90.9 (9)	Ge1—O30—W2	120.7 (10)
O16—W17—O55	158.6 (10)	W3—O30—W2	94.7 (7)
O62—W17—O21	99.2 (11)	Ge1—O30—Zr1	121.9 (9)
O14—W17—O21	157.1 (8)	W3—O30—Zr1	95.7 (7)
O16—W17—O21	86.6 (11)	W2—O30—Zr1	93.3 (7)
O55—W17—O21	85.1 (9)	W19—O31—W13	121.6 (10)
O62—W17—O34	167.9 (9)	W19—O31—K2	105.5 (10)
O14—W17—O34	84.0 (8)	W13—O31—K2	109.2 (9)
O16—W17—O34	86.2 (8)	W5—O32—Zr2	152.1 (11)
O55—W17—O34	72.6 (8)	W5—O32—K1	107.6 (8)
O21—W17—O34	73.3 (8)	Zr2—O32—K1	100.3 (8)
O62—W17—K2	84.7 (8)	P1—O33—W13	129.5 (12)
O14—W17—K2	46.5 (6)	P1—O33—W19	130.2 (11)
O16—W17—K2	135.0 (8)	W13—O33—W19	89.1 (7)
O55—W17—K2	51.6 (7)	P1—O33—Na3	120.7 (10)
O21—W17—K2	136.5 (7)	W13—O33—Na3	84.9 (7)
O34—W17—K2	94.3 (5)	W19—O33—Na3	88.3 (8)
O66—W18—O51	103.0 (11)	P1—O34—W6	125.7 (11)
O66—W18—O15	101.8 (10)	P1—O34—W17	124.5 (11)
O51—W18—O15	91.4 (9)	W6—O34—W17	92.4 (7)
O66—W18—O2	99.8 (10)	P1—O34—W11	122.3 (11)
O51—W18—O2	88.8 (9)	W6—O34—W11	91.3 (7)
O15—W18—O2	157.7 (9)	W17—O34—W11	90.7 (7)
O66—W18—O28	96.6 (10)	W7—O35—W1	143.9 (12)
O51—W18—O28	160.3 (9)	W12—O36—W3	153.5 (13)
O15—W18—O28	86.8 (8)	W12—O36—Na1^vi	106.9 (8)
O2—W18—O28	85.6 (8)	W3—O36—Na1^vi	98.4 (9)
O66—W18—O40	174.1 (9)	W4—O37—Zr2	120.7 (10)
O51—W18—O40	78.5 (8)	W4—O37—K1	105.6 (8)
O15—W18—O40	83.8 (8)	Zr2—O37—K1	96.8 (9)
O2—W18—O40	74.4 (8)	W1—O38—Na1	125.7 (11)
O28—W18—O40	81.8 (8)	W7—O39—Zr1	150.5 (11)
O66—W18—Na8^i	62.7 (9)	W7—O39—Na6^i	112.4 (9)
O51—W18—Na8^i	48.5 (8)	Zr1—O39—Na6^i	96.0 (7)
O15—W18—Na8^i	75.3 (7)	P1—O40—W18	126.6 (11)
O2—W18—Na8^i	120.0 (6)	P1—O40—W9	129.4 (11)
O28—W18—Na8^i	148.2 (7)	W18—O40—W9	89.9 (7)
O40—W18—Na8^i	121.1 (6)	W11—O42—W6	124.3 (11)
O72—W19—O46	100.5 (14)	W9—O43—Zr2	128.7 (11)
O72—W19—O31	98.1 (10)	W9—O43—K1	97.5 (8)
O46—W19—O31	97.7 (10)	Zr2—O43—K1	91.8 (7)
O72—W19—O3	102.3 (10)	W12—O44—W5	120.2 (12)
O46—W19—O3	94.1 (10)	W5—O45—W2	145.8 (12)
O31—W19—O3	154.1 (8)	W5—O45—Na1^vi	111.9 (10)
O72—W19—O14	94.5 (13)	W2—O45—Na1^vi	101.7 (8)
O46—W19—O14	164.8 (10)	W19—O46—Na3	120.3 (11)
O31—W19—O14	82.5 (9)	W15—O47—W8	119.2 (11)
O3—W19—O14	80.2 (8)	W15—O47—Na7^ix	106.5 (10)
O72—W19—O33	169.9 (10)	W8—O47—Na7^ix	99.4 (8)
O46—W19—O33	86.2 (9)	W13—O49—K2^ii	112.6 (10)
O31—W19—O33	73.3 (8)	W1—O50—Zr1	158.2 (12)
O3—W19—O33	84.6 (8)	W1—O50—Na8^i	101.5 (9)
O14—W19—O33	79.3 (8)	Zr1—O50—Na8^i	100.1 (8)
O72—W19—Na3	134.8 (12)	W18—O51—Zr2	125.7 (11)
O46—W19—Na3	35.3 (8)	W18—O51—Na4	116.2 (10)
O31—W19—Na3	84.1 (7)	Zr2—O51—Na4	113.9 (9)
O3—W19—Na3	92.5 (6)	W18—O51—Na8^i	102.2 (10)
O14—W19—Na3	130.2 (6)	Zr2—O51—Na8^i	98.5 (9)
O33—W19—Na3	50.9 (5)	Na4—O51—Na8^i	88.6 (8)
O72—W19—K2	79.0 (10)	W16—O52—K1^iii	147.6 (13)
O46—W19—K2	141.7 (8)	W15—O53—W7	121.5 (12)
O31—W19—K2	45.6 (7)	W9—O54—Na5^v	128.2 (11)
O3—W19—K2	123.7 (6)	W9—O54—K1	104.7 (9)
O14—W19—K2	44.1 (6)	Na5^v—O54—K1	91.8 (7)
O33—W19—K2	91.1 (5)	W17—O55—W6	122.1 (11)
Na3—W19—K2	126.4 (2)	W17—O55—K2	96.5 (8)
O3W—K1—O52^iii	76.2 (16)	W6—O55—K2	102.4 (9)
O3W—K1—O32	101.9 (16)	W14—O56—W10	120.4 (10)
O52^iii—K1—O32	123.3 (7)	Ge1—O58—W4	124.9 (10)
O3W—K1—O13W	108.7 (19)	Ge1—O58—W1	121.2 (10)
O52^iii—K1—O13W	76.6 (10)	W4—O58—W1	92.2 (7)
O32—K1—O13W	147.1 (11)	Ge1—O58—Zr2	123.7 (11)
O3W—K1—O37	136.3 (16)	W4—O58—Zr2	93.8 (7)
O52^iii—K1—O37	147.5 (7)	W1—O58—Zr2	92.2 (7)
O32—K1—O37	61.1 (6)	W6—O59—K2^ii	99.6 (10)
O13W—K1—O37	88.0 (10)	W14—O63—Zr1^i	143.2 (14)
O3W—K1—O4	157.7 (16)	W14—O63—Na6	101.8 (9)
O52^iii—K1—O4	94.1 (7)	Zr1^i—O63—Na6	99.7 (8)
O32—K1—O4	66.4 (6)	W11—O65—Na3^iv	163.7 (14)
O13W—K1—O4	88.0 (12)	W18—O66—Na1	170.2 (14)
O37—K1—O4	56.3 (6)	W5—O67—Na2^vi	156.5 (15)
O3W—K1—O69	102.5 (16)	W16—O69—W5	119.8 (11)
O52^iii—K1—O69	69.8 (7)	W16—O69—K1	101.7 (10)
O32—K1—O69	55.1 (6)	W5—O69—K1	98.0 (9)
O13W—K1—O69	126.3 (12)	W4—O70—Na5	162.8 (15)
O37—K1—O69	98.5 (7)	W4—O70—Na5^v	106.5 (11)
O4—K1—O69	55.2 (6)	Na5—O70—Na5^v	89.6 (8)
O3W—K1—O54	79.7 (16)	W19—O72—Na7	159.2 (14)
O52^iii—K1—O54	130.2 (7)	Na3—O4W—Na4	104.7 (14)
O32—K1—O54	103.8 (6)	Na5—O5W—Na2^v	85.2 (15)
O13W—K1—O54	71.0 (11)	Na5—O6W—Na2^v	86.5 (8)
O37—K1—O54	67.9 (6)	Na6—O12W—Na6^vii	94.6 (15)
O4—K1—O54	120.8 (6)	K1—O13W—Na5^v	90.4 (11)
O69—K1—O54	158.9 (7)	Na3—O15W—Na4	97.1 (11)
O3W—K1—O43	78.7 (16)	Na8—O17W—Na8^i	86 (3)

Symmetry codes: (i) −x+3/2, y, −z+1/2; (ii) −x+1/2, y, −z+1/2; (iii) −x+1, −y, −z+1; (iv) x, y+1, z; (v) −x+1, −y+1, −z+1; (vi) x, y−1, z; (vii) −x+1, −y, −z; (viii) x−1/2, −y, z−1/2; (ix) x+1/2, −y, z+1/2.