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We report the crystal structure of (phenyldiazenido-N)[phenylhydrazido(2-)-N][3-(trimethylsilyl)-2-pyridinethiolato-S,N]bis(triphenylphosphine-P)rhenium tetraphenylborate, [Re(C6H5N2)(C6H6N2)(C8H12NSSi)(C18H15P)2](C24H20B), prepared by the reaction of [ReCl(C6H6N2)2(C18H15P)2] with 3-(trimethylsilyl)-2-pyridinethiol in ethanol. The mixed diazenide/hydrazido(2-) complex represents a relatively rare class of complex.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks rehi, global

CCDC reference: 126433

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