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The CuII ion in the title compound, [Cu(C14H32N4)(H2O)](ClO4)2, is five-coordinate in a distorted square-pyramidal geometry with the four N atoms of the macrocyclic ligand equatorial and the O atom of the aqua group axial. The quadridentate ligand adopts its most stable conformation with the two six-membered rings in chair conformations and the two five-membered rings in gauche conformations. The complex has a 1SR,4SR,8SR,11SR configuration for the four chiral N-atom centers and a 5RS,12RS configuration for the two chiral C-atom centers.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks text, hr1024a

CCDC reference: 128128

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