Tetra­pyridinium di-μ-oxo-bis­[trifluoro­tellurate(IV)] bis­[penta­fluoro­tellurate(IV)]

Klapötke, T.M.; Krumm, B.; Mayer, P.; Schwab, I.

doi:10.1107/S1600536805025304

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Tetrapyridinium di-μ-oxo-bis[trifluorotellurate(IV)] bis[pentafluorotellurate(IV)]

T. M. Klapötke, B. Krumm, P. Mayer and I. Schwab

The title compound, 2C₅H₆N⁺·TeF₅⁻·0.5Te₂F₆O₂²⁻, contains two anions, [TeF₅]⁻ and [Te₂O₂F₆]²⁻. The [Te₂O₂F₆]²⁻ anions are involved in H

F/O bonding with the pyridinium cations. Crystallographically imposed inversion leads to molecular C_s symmetry for the [Te₂O₂F₆]²⁻ anions. Extended chains of inversion-related pyridinium cations are built up by π–π interactions.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536805025304/hk6029sup1.cif Contains datablocks I, global
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536805025304/hk6029Isup2.hkl Contains datablock I

CCDC reference: 215494

checkCIF report

Key indicators

Single-crystal X-ray study
T = 200 K
Mean (C-C) = 0.006 Å
R factor = 0.029
wR factor = 0.064
Data-to-parameter ratio = 17.2

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT432_ALERT_2_B Short Inter X...Y Contact  Te2    ..  F8      ..       3.15 Ang.

Alert level C
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        Te2
PLAT764_ALERT_4_C Overcomplete CIF Bond List Detected (Rep/Expd) .       1.43 Ratio
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      40.18 Deg.
              O    -TE1  -TE1     1.555   1.555   3.666
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      35.33 Deg.
              O    -TE1  -TE1     3.666   1.555   3.666
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      40.58 Deg.
              O    -TE1  -N1      1.555   1.555   1.555
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      44.80 Deg.
              O    -TE1  -F3      1.555   1.555   3.555
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      43.96 Deg.
              F3   -TE1  -F3      1.555   1.555   3.555
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      27.15 Deg.
              O    -TE1  -F1      1.555   1.555   3.556
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      42.03 Deg.
              N1   -TE1  -F1      1.555   1.555   3.556
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      17.65 Deg.
              F3   -TE1  -F1      3.555   1.555   3.556
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      31.68 Deg.
              O    -TE1  -F2      1.555   1.555   3.556
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      16.62 Deg.
              F3   -TE1  -F2      3.555   1.555   3.556
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......       9.37 Deg.
              F1   -TE1  -F2      3.556   1.555   3.556
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      44.09 Deg.
              F4   -TE2  -F8      1.555   1.555   4.566
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      40.91 Deg.
              F4   -TE2  -F7      1.555   1.555   4.566
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......       5.07 Deg.
              F8   -TE2  -F7      4.566   1.555   4.566
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      44.23 Deg.
              F5   -TE2  -F6      1.555   1.555   4.566
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......       4.88 Deg.
              F8   -TE2  -F6      4.566   1.555   4.566
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......       7.76 Deg.
              F7   -TE2  -F6      4.566   1.555   4.566
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      27.45 Deg.
              F5   -TE2  -N1      1.555   1.555   3.556
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      24.02 Deg.
              F8   -TE2  -N1      4.566   1.555   3.556
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      27.20 Deg.
              F7   -TE2  -N1      4.566   1.555   3.556
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      19.58 Deg.
              F6   -TE2  -N1      4.566   1.555   3.556
PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ......      27.30 Deg.
              TE1  -N1   -H1      1.555   1.555   1.555

   0 ALERT level A = In general: serious problem
   1 ALERT level B = Potentially serious problem
  25 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
  24 ALERT type 2 Indicator that the structure model may be wrong or deficient
   0 ALERT type 3 Indicator that the structure quality may be low
   1 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: COLLECT (Nonius, 2000); cell refinement: SCALEPACK (Otwinowski & Minor, 1997); data reduction: SCALEPACK and DENZO (Otwinowski & Minor, 1997); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: DIAMOND (Brandenburg, 1996); software used to prepare material for publication: SHELXL97.

Tetrapyridinium di-µ-oxo-bis[trifluorotellurate(IV)] bis[pentafluorotellurate(IV)] top

Crystal data top

2C₅H₆N⁺·TeF₅⁻·0.5Te₂O₂F₆²⁻	F(000) = 1080
M_r = 583.42	D_x = 2.473 Mg m⁻³
Monoclinic, P2₁/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 35743 reflections
a = 10.1509 (2) Å	θ = 3.1–27.5°
b = 20.0739 (3) Å	µ = 3.81 mm⁻¹
c = 7.9950 (1) Å	T = 200 K
β = 105.8894 (8)°	Block, colorless
V = 1566.88 (4) Å³	0.30 × 0.20 × 0.07 mm
Z = 4

Data collection top

Nonius KappaCCD diffractometer	3586 independent reflections
Radiation source: fine-focus sealed tube	2948 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.073
Detector resolution: 9 pixels mm^-1	θ_max = 27.5°, θ_min = 3.3°
area detection scans	h = −13→13
Absorption correction: numerical (XRED32 and XSHAPE; Stoe & Cie, 1997)	k = −26→26
T_min = 0.350, T_max = 0.690	l = −10→10
36947 measured reflections

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.029	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.064	H-atom parameters constrained
S = 1.08	w = 1/[σ²(F_o²) + (0.0306P)² + 0.4788P] where P = (F_o² + 2F_c²)/3
3586 reflections	(Δ/σ)_max = 0.001
208 parameters	Δρ_max = 1.00 e Å⁻³
0 restraints	Δρ_min = −1.10 e Å⁻³

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Refinement of hydrogen atoms: H atoms calculated in geometrically idealized position with U(H) = 1.2 U(C/N)

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Te1	0.52043 (2)	0.509365 (11)	0.31119 (3)	0.02514 (8)
Te2	0.89376 (2)	0.702005 (11)	0.47140 (3)	0.02895 (8)
F1	0.6577 (2)	0.43510 (10)	0.3707 (3)	0.0354 (5)
F2	0.3562 (2)	0.56873 (10)	0.2558 (3)	0.0355 (5)
F3	0.4220 (2)	0.45665 (10)	0.1086 (3)	0.0375 (5)
O	0.4192 (2)	0.45604 (11)	0.4285 (3)	0.0270 (5)
F4	1.0332 (2)	0.63253 (11)	0.5249 (3)	0.0469 (6)
F5	0.7513 (2)	0.63330 (12)	0.3969 (3)	0.0507 (6)
F6	0.7666 (2)	0.76924 (11)	0.3420 (3)	0.0482 (6)
F7	1.0394 (2)	0.76409 (12)	0.4696 (4)	0.0528 (6)
F8	0.9087 (3)	0.68431 (12)	0.2477 (3)	0.0504 (6)
N1	0.1423 (3)	0.45709 (15)	0.2678 (4)	0.0310 (7)
H1	0.2312	0.4543	0.3155	0.037*
C1	0.0730 (4)	0.50523 (18)	0.3203 (5)	0.0317 (8)
H1A	0.1191	0.5355	0.4082	0.038*
C2	−0.0666 (4)	0.51103 (19)	0.2461 (5)	0.0337 (8)
H2A	−0.1173	0.5456	0.2809	0.040*
C3	−0.1308 (4)	0.46554 (19)	0.1205 (5)	0.0342 (8)
H3	−0.2269	0.4683	0.0696	0.041*
C4	−0.0567 (4)	0.41668 (19)	0.0694 (5)	0.0353 (9)
H4	−0.1004	0.3857	−0.0179	0.042*
C5	0.0832 (4)	0.41281 (17)	0.1462 (5)	0.0327 (8)
H5	0.1362	0.3790	0.1126	0.039*
N2	0.3838 (3)	0.68576 (17)	0.4616 (5)	0.0440 (9)
H2	0.3732	0.6425	0.4701	0.053*
C6	0.5002 (4)	0.7138 (2)	0.5550 (6)	0.0411 (10)
H6	0.5698	0.6871	0.6284	0.049*
C7	0.5182 (4)	0.7803 (2)	0.5446 (6)	0.0416 (9)
H7	0.6007	0.8008	0.6099	0.050*
C8	0.4152 (4)	0.8180 (2)	0.4377 (6)	0.0420 (10)
H8	0.4261	0.8648	0.4299	0.050*
C9	0.2967 (4)	0.7876 (2)	0.3424 (6)	0.0428 (10)
H9	0.2254	0.8131	0.2683	0.051*
C10	0.2831 (4)	0.7208 (2)	0.3556 (6)	0.0442 (10)
H10	0.2024	0.6991	0.2899	0.053*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Te1	0.02339 (13)	0.02542 (13)	0.02513 (13)	−0.00086 (8)	0.00415 (9)	0.00096 (9)
Te2	0.02926 (14)	0.02737 (14)	0.02997 (14)	−0.00188 (9)	0.00767 (10)	0.00142 (9)
F1	0.0294 (11)	0.0372 (12)	0.0388 (13)	0.0067 (9)	0.0082 (9)	0.0009 (10)
F2	0.0368 (12)	0.0297 (11)	0.0351 (12)	0.0059 (9)	0.0014 (9)	0.0017 (9)
F3	0.0418 (12)	0.0361 (12)	0.0308 (12)	−0.0007 (10)	0.0036 (9)	−0.0064 (9)
O	0.0259 (12)	0.0262 (12)	0.0279 (13)	−0.0032 (10)	0.0056 (10)	0.0007 (10)
F4	0.0458 (14)	0.0352 (12)	0.0555 (15)	0.0097 (10)	0.0068 (11)	0.0047 (11)
F5	0.0437 (14)	0.0376 (12)	0.0650 (17)	−0.0138 (11)	0.0052 (12)	0.0022 (12)
F6	0.0364 (13)	0.0383 (13)	0.0604 (16)	0.0031 (10)	−0.0030 (11)	0.0044 (11)
F7	0.0387 (13)	0.0386 (13)	0.0849 (19)	−0.0085 (10)	0.0233 (13)	−0.0009 (13)
F8	0.0794 (18)	0.0438 (13)	0.0316 (13)	0.0053 (13)	0.0210 (12)	0.0041 (10)
N1	0.0231 (14)	0.0366 (17)	0.0321 (17)	−0.0032 (13)	0.0055 (12)	0.0084 (14)
C1	0.0293 (19)	0.037 (2)	0.027 (2)	−0.0079 (16)	0.0044 (15)	−0.0003 (15)
C2	0.034 (2)	0.035 (2)	0.033 (2)	0.0030 (16)	0.0106 (16)	0.0023 (16)
C3	0.0245 (18)	0.044 (2)	0.031 (2)	−0.0009 (16)	0.0010 (15)	0.0086 (17)
C4	0.035 (2)	0.033 (2)	0.033 (2)	−0.0092 (16)	0.0007 (16)	0.0011 (16)
C5	0.042 (2)	0.0245 (18)	0.031 (2)	0.0013 (16)	0.0091 (16)	0.0024 (15)
N2	0.048 (2)	0.0273 (17)	0.058 (2)	−0.0023 (15)	0.0153 (18)	−0.0059 (16)
C6	0.040 (2)	0.042 (2)	0.041 (2)	0.0083 (18)	0.0087 (18)	0.0070 (19)
C7	0.034 (2)	0.046 (2)	0.043 (2)	−0.0090 (18)	0.0084 (17)	−0.0036 (19)
C8	0.047 (2)	0.033 (2)	0.048 (3)	−0.0020 (18)	0.015 (2)	0.0068 (18)
C9	0.036 (2)	0.050 (3)	0.041 (2)	0.0114 (19)	0.0066 (18)	0.0054 (19)
C10	0.031 (2)	0.050 (3)	0.050 (3)	−0.0057 (19)	0.0080 (18)	−0.015 (2)

Geometric parameters (Å, º) top

Te1—O	1.900 (2)	N1—H1	0.8800
Te1—F3	1.964 (2)	C1—C2	1.383 (5)
Te1—F2	1.998 (2)	C1—H1A	0.9500
Te1—F1	2.007 (2)	C2—C3	1.382 (5)
Te1—Oⁱ	2.119 (2)	C2—H2A	0.9500
Te1—Te1ⁱ	3.1803 (4)	C3—C4	1.366 (6)
Te1—N1	3.902 (3)	C3—H3	0.9500
Te1—F3ⁱⁱ	21.476 (2)	C4—C5	1.386 (5)
Te1—F1ⁱⁱⁱ	22.926 (2)	C4—H4	0.9500
Te1—F2ⁱⁱⁱ	24.008 (2)	C5—H5	0.9500
Te2—F8	1.870 (2)	N2—C10	1.336 (5)
Te2—F7	1.937 (2)	N2—C6	1.337 (5)
Te2—F4	1.949 (2)	N2—H2	0.8800
Te2—F6	1.956 (2)	C6—C7	1.354 (6)
Te2—F5	1.969 (2)	C6—H6	0.9500
Te2—F8^iv	17.924 (2)	C7—C8	1.381 (6)
Te2—F7^iv	19.772 (2)	C7—H7	0.9500
Te2—F6^iv	19.816 (2)	C8—C9	1.378 (6)
Te2—N1ⁱⁱⁱ	25.852 (3)	C8—H8	0.9500
O—Te1ⁱ	2.119 (2)	C9—C10	1.354 (6)
N1—C1	1.329 (5)	C9—H9	0.9500
N1—C5	1.333 (5)	C10—H10	0.9500
N1—Te2ⁱⁱⁱ	25.852 (3)

O—Te1—F3	83.21 (10)	F6—Te2—F7^iv	141.76 (7)
O—Te1—F2	85.08 (9)	F5—Te2—F7^iv	51.83 (7)
F3—Te1—F2	86.18 (8)	F8^iv—Te2—F7^iv	5.067 (11)
O—Te1—F1	84.17 (9)	F8—Te2—F6^iv	88.96 (7)
F3—Te1—F1	87.64 (9)	F7—Te2—F6^iv	135.67 (7)
F2—Te1—F1	168.16 (8)	F4—Te2—F6^iv	48.42 (7)
O—Te1—Oⁱ	75.51 (10)	F6—Te2—F6^iv	134.22 (7)
F3—Te1—Oⁱ	158.70 (9)	F5—Te2—F6^iv	44.23 (7)
F2—Te1—Oⁱ	91.22 (9)	F8^iv—Te2—F6^iv	4.877 (11)
F1—Te1—Oⁱ	90.88 (9)	F7^iv—Te2—F6^iv	7.757 (10)
O—Te1—Te1ⁱ	40.18 (7)	F8—Te2—N1ⁱⁱⁱ	92.72 (8)
F3—Te1—Te1ⁱ	123.38 (7)	F7—Te2—N1ⁱⁱⁱ	155.23 (7)
F2—Te1—Te1ⁱ	87.88 (6)	F4—Te2—N1ⁱⁱⁱ	68.00 (7)
F1—Te1—Te1ⁱ	87.11 (6)	F6—Te2—N1ⁱⁱⁱ	116.08 (7)
Oⁱ—Te1—Te1ⁱ	35.33 (6)	F5—Te2—N1ⁱⁱⁱ	27.45 (7)
O—Te1—N1	40.58 (8)	F8^iv—Te2—N1ⁱⁱⁱ	24.016 (11)
F3—Te1—N1	61.03 (8)	F7^iv—Te2—N1ⁱⁱⁱ	27.202 (10)
F2—Te1—N1	53.12 (8)	F6^iv—Te2—N1ⁱⁱⁱ	19.579 (9)
F1—Te1—N1	115.05 (7)	Te1—O—Te1ⁱ	104.49 (10)
Oⁱ—Te1—N1	100.85 (8)	C1—N1—C5	122.9 (3)
Te1ⁱ—Te1—N1	70.84 (5)	C1—N1—Te1	111.7 (2)
O—Te1—F3ⁱⁱ	44.80 (7)	C5—N1—Te1	118.7 (2)
F3—Te1—F3ⁱⁱ	43.96 (7)	C1—N1—Te2ⁱⁱⁱ	111.5 (2)
F2—Te1—F3ⁱⁱ	101.25 (6)	C5—N1—Te2ⁱⁱⁱ	49.2 (2)
F1—Te1—F3ⁱⁱ	67.47 (6)	Te1—N1—Te2ⁱⁱⁱ	130.31 (5)
Oⁱ—Te1—F3ⁱⁱ	116.49 (6)	C1—N1—H1	118.5
Te1ⁱ—Te1—F3ⁱⁱ	82.724 (10)	C5—N1—H1	118.5
N1—Te1—F3ⁱⁱ	50.06 (5)	Te1—N1—H1	27.3
O—Te1—F1ⁱⁱⁱ	27.15 (7)	Te2ⁱⁱⁱ—N1—H1	107.5
F3—Te1—F1ⁱⁱⁱ	58.85 (7)	N1—C1—C2	119.7 (3)
F2—Te1—F1ⁱⁱⁱ	95.10 (6)	N1—C1—H1A	120.2
F1—Te1—F1ⁱⁱⁱ	73.06 (6)	C2—C1—H1A	120.2
Oⁱ—Te1—F1ⁱⁱⁱ	100.45 (6)	C3—C2—C1	118.7 (4)
Te1ⁱ—Te1—F1ⁱⁱⁱ	65.755 (9)	C3—C2—H2A	120.7
N1—Te1—F1ⁱⁱⁱ	42.03 (4)	C1—C2—H2A	120.7
F3ⁱⁱ—Te1—F1ⁱⁱⁱ	17.648 (8)	C4—C3—C2	120.2 (3)
O—Te1—F2ⁱⁱⁱ	31.68 (7)	C4—C3—H3	119.9
F3—Te1—F2ⁱⁱⁱ	60.53 (6)	C2—C3—H3	119.9
F2—Te1—F2ⁱⁱⁱ	104.47 (6)	C3—C4—C5	119.3 (3)
F1—Te1—F2ⁱⁱⁱ	63.69 (6)	C3—C4—H4	120.3
Oⁱ—Te1—F2ⁱⁱⁱ	99.94 (6)	C5—C4—H4	120.3
Te1ⁱ—Te1—F2ⁱⁱⁱ	66.844 (9)	N1—C5—C4	119.2 (3)
N1—Te1—F2ⁱⁱⁱ	51.39 (4)	N1—C5—H5	120.4
F3ⁱⁱ—Te1—F2ⁱⁱⁱ	16.621 (8)	C4—C5—H5	120.4
F1ⁱⁱⁱ—Te1—F2ⁱⁱⁱ	9.372 (7)	C10—N2—C6	122.6 (4)
F8—Te2—F7	81.57 (11)	C10—N2—H2	118.7
F8—Te2—F4	80.22 (11)	C6—N2—H2	118.7
F7—Te2—F4	87.25 (10)	N2—C6—C7	119.6 (4)
F8—Te2—F6	80.77 (11)	N2—C6—H6	120.2
F7—Te2—F6	86.94 (10)	C7—C6—H6	120.2
F4—Te2—F6	160.75 (11)	C6—C7—C8	119.1 (4)
F8—Te2—F5	79.79 (11)	C6—C7—H7	120.4
F7—Te2—F5	161.35 (12)	C8—C7—H7	120.4
F4—Te2—F5	89.67 (10)	C9—C8—C7	119.8 (4)
F6—Te2—F5	89.99 (10)	C9—C8—H8	120.1
F8—Te2—F8^iv	85.94 (7)	C7—C8—H8	120.1
F7—Te2—F8^iv	131.22 (7)	C10—C9—C8	119.2 (4)
F4—Te2—F8^iv	44.09 (7)	C10—C9—H9	120.4
F6—Te2—F8^iv	137.07 (7)	C8—C9—H9	120.4
F5—Te2—F8^iv	47.36 (7)	N2—C10—C9	119.6 (4)
F8—Te2—F7^iv	89.16 (7)	N2—C10—H10	120.2
F7—Te2—F7^iv	128.14 (8)	C9—C10—H10	120.2
F4—Te2—F7^iv	40.91 (7)

F3—Te1—O—Te1ⁱ	−179.27 (11)	O—Te1—N1—Te2ⁱⁱⁱ	−46.32 (12)
F2—Te1—O—Te1ⁱ	−92.54 (10)	F3—Te1—N1—Te2ⁱⁱⁱ	69.69 (9)
F1—Te1—O—Te1ⁱ	92.43 (10)	F2—Te1—N1—Te2ⁱⁱⁱ	178.36 (11)
Oⁱ—Te1—O—Te1ⁱ	0.0	F1—Te1—N1—Te2ⁱⁱⁱ	−2.20 (10)
N1—Te1—O—Te1ⁱ	−126.92 (16)	Oⁱ—Te1—N1—Te2ⁱⁱⁱ	−98.33 (8)
F3ⁱⁱ—Te1—O—Te1ⁱ	156.08 (14)	Te1ⁱ—Te1—N1—Te2ⁱⁱⁱ	−79.42 (5)
F1ⁱⁱⁱ—Te1—O—Te1ⁱ	156.1 (2)	F3ⁱⁱ—Te1—N1—Te2ⁱⁱⁱ	17.246 (18)
F2ⁱⁱⁱ—Te1—O—Te1ⁱ	139.34 (17)	F1ⁱⁱⁱ—Te1—N1—Te2ⁱⁱⁱ	−4.713 (10)
O—Te1—N1—C1	102.4 (3)	F2ⁱⁱⁱ—Te1—N1—Te2ⁱⁱⁱ	−4.208 (13)
F3—Te1—N1—C1	−141.6 (3)	C5—N1—C1—C2	−0.6 (6)
F2—Te1—N1—C1	−32.9 (2)	Te1—N1—C1—C2	150.1 (3)
F1—Te1—N1—C1	146.5 (2)	Te2ⁱⁱⁱ—N1—C1—C2	−55.1 (4)
Oⁱ—Te1—N1—C1	50.4 (2)	N1—C1—C2—C3	1.0 (6)
Te1ⁱ—Te1—N1—C1	69.3 (2)	C1—C2—C3—C4	−1.1 (6)
F3ⁱⁱ—Te1—N1—C1	166.0 (3)	C2—C3—C4—C5	0.7 (6)
F1ⁱⁱⁱ—Te1—N1—C1	144.0 (3)	C1—N1—C5—C4	0.3 (5)
F2ⁱⁱⁱ—Te1—N1—C1	144.5 (3)	Te1—N1—C5—C4	−148.6 (3)
O—Te1—N1—C5	−105.5 (3)	Te2ⁱⁱⁱ—N1—C5—C4	91.3 (4)
F3—Te1—N1—C5	10.5 (2)	C3—C4—C5—N1	−0.3 (5)
F2—Te1—N1—C5	119.2 (3)	C10—N2—C6—C7	0.5 (7)
F1—Te1—N1—C5	−61.4 (3)	N2—C6—C7—C8	0.3 (7)
Oⁱ—Te1—N1—C5	−157.5 (2)	C6—C7—C8—C9	−0.6 (7)
Te1ⁱ—Te1—N1—C5	−138.6 (2)	C7—C8—C9—C10	0.1 (7)
F3ⁱⁱ—Te1—N1—C5	−41.9 (2)	C6—N2—C10—C9	−0.9 (7)
F1ⁱⁱⁱ—Te1—N1—C5	−63.9 (2)	C8—C9—C10—N2	0.6 (7)
F2ⁱⁱⁱ—Te1—N1—C5	−63.4 (2)

Symmetry codes: (i) −x+1, −y+1, −z+1; (ii) −x, −y, −z; (iii) −x, −y, −z+1; (iv) x, −y+1/2, z+1/2.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
N1—H1···O	0.88	1.88	2.752 (3)	175
N2—H2···F2	0.88	2.24	2.837 (4)	125
N2—H2···F1ⁱ	0.88	2.09	2.859 (4)	146

Symmetry code: (i) −x+1, −y+1, −z+1.

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