Hexaaqua­cobalt(II) 5,5′-(propane-1,3-diyldithio)bis­(1H-tetra­zole-1-acetate)

Liang, W.-L.; Yu, Q.; Zhang, X.-Q.; Qin, J.-K.; Liang, H.

doi:10.1107/S1600536809028463

metal-organic compounds

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 65| Part 8| August 2009| Page m1006

doi:10.1107/S1600536809028463

Open

access

Hexaaquacobalt(II) 5,5′-(propane-1,3-diyldithio)bis(1H-tetrazole-1-acetate)

Wan-Ling Liang,^a ^* Qing Yu,^a Xiu-Qing Zhang,^a Jiang-Ke Qin ^a and Hong Liang ^a

^aCollege of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin, Guangxi 541004, People's Republic of China
^*Correspondence e-mail: gxnuchem312@yahoo.com.cn

(Received 16 July 2009; accepted 18 July 2009; online 29 July 2009)

The asymmetric unit of the title complex, [Co(H₂O)₆](C₉H₁₀N₈O₄S₂), contains one-half of a [Co(H₂O)₆]²⁺ cation and one-half of a 5,5′-(propane-1,3-diyldithio)bis(1H-tetrazole-1-acetate) (battp²⁻) anion. The Co^II center is coordinated by six H₂O molecules in a distorted octahedral coordination environment. In the crystal structure, intra- and intermolecular O—H⋯O and O—H⋯N hydrogen bonds link the cations and anions into a three-dimensional network. π–π contacts between the tetrazole rings [centroid–centroid distance = 3.346 (1) Å] may further stabilize the structure.

Related literature

For related structures, see: Du et al. (2004 ); Jiang & Li (2004 ); Liu et al. (2004 ).

Experimental

Crystal data

[Co(H₂O)₆](C₉H₁₀N₈O₄S₂)
M_r = 525.42
Monoclinic, C 2/c
a = 19.420 (2) Å
b = 7.9069 (11) Å
c = 13.7356 (17) Å
β = 112.957 (2)°
V = 1942.1 (4) Å³
Z = 4
Mo Kα radiation
μ = 1.17 mm⁻¹
T = 298 K
0.38 × 0.35 × 0.20 mm

Data collection

Bruker SMART CCD area-detector diffractometer
Absorption correction: multi-scan (SADABS; Bruker, 1997 ) T_min = 0.665, T_max = 0.800
4714 measured reflections
1716 independent reflections
1518 reflections with I > 2σ(I)
R_int = 0.024

Refinement

R[F² > 2σ(F²)] = 0.025
wR(F²) = 0.068
S = 1.02
1716 reflections
142 parameters
H atoms treated by a mixture of independent and constrained refinement
Δρ_max = 0.24 e Å⁻³
Δρ_min = −0.36 e Å⁻³

Table 1
Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O3—H3A⋯O1	0.85	1.93	2.767 (2)	166
O4—H4A⋯O2ⁱ	0.85	1.90	2.742 (2)	172
O4—H4B⋯N3ⁱⁱ	0.85	2.19	2.970 (2)	152
O5—H5A⋯O1ⁱ	0.85	1.86	2.7069 (19)	173
O5—H5B⋯N4ⁱⁱⁱ	0.85	1.99	2.833 (2)	173
Symmetry codes: (i) $[-x+{\script{1\over 2}}, y+{\script{1\over 2}}, -z+{\script{1\over 2}}]$ ; (ii) $[-x+1, y, -z+{\script{1\over 2}}]$ ; (iii) $[x-{\script{1\over 2}}, -y+{\script{1\over 2}}, z-{\script{1\over 2}}]$ .

Data collection: SMART (Bruker, 1997); cell refinement: SAINT (Bruker, 1997); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL and PLATON (Spek, 2009 ).

Supporting information

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536809028463/hk2740sup1.cif

Structure factors: contains datablock I. DOI: 10.1107/S1600536809028463/hk2740Isup2.hkl

checkCIF report

Comment top

Coordination compounds of the type [Co(H₂O)₆](C₁₀H₈O₆), [Co(H₂O)₆](L)₂ (L = isonicotinate N-oxide, C₆H₄NO₃) and [Co(H₂O)₆].2H₂O.2L.2ClO₄ (L = 1,1'-(propane -1,3-diyl)dipyridinium-4-carboxylate) have been previously prepared and studied by several groups (Liu et al., 2004; Du et al., 2004; Jiang & Li, 2004). We report herein the crystal structure of the new title mononuclear cobalt complex, [Co(H₂O)₆].(battp) [where battp is 1,3-bis(1-acetic acid-1,2,3,4-tetrazole-5- thioether propane)].

The asymmetric unit of the title complex contains one-half of the [Co(H₂O)₆]²⁺ cation and one-half of the [battp]^2- anion (Fig. 1). The Co center is coordinated by six H₂O molecules in a distorted octahedral coordination environment. The average Co-O bond distance is 2.0973 (14) Å.

In the crystal structure, intra- and intermolecular O-H···O and O-H···N hydrogen bonds (Table 1) link the [Co(H₂O)₆]²⁺ cations and [battp]^2- anions into a three-dimensional network (Fig. 2), in which they may be effective in the stabilization of the structure. The π–π contact between the tetrazole rings, Cg1—Cg1ⁱ [symmetry code: (i) -x, 2 - y, -z, where Cg1 is centroid of the ring A (N1-N4/C1)] may further stabilize the structure, with centroid-centroid distance of 3.346 (1) Å.

Related literature top

For related structures, see: Du et al. (2004); Jiang & Li (2004); Liu et al. (2004).

Experimental top

For the preparation of the title compound, H₂battp (0.1440 g, 0.4 mmol) was dissolved in water (5 ml), and the solution of CoClO₄.6H₂O (0.1832 g, 0.5 mmol) in distilled water (5 ml) was added. The mixture was stirred at 353 K for 3 h, and then cooled and filtered. The filtrate was allowed to slowly evaporate at room temperature. Two weeks later, pink block crystals were obtained.

Computing details top

Data collection: SMART (Bruker, 1997); cell refinement: SAINT (Bruker, 1997); data reduction: SAINT (Bruker, 1997); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008) and PLATON (Spek, 2009).

Figures top

	Fig. 1. The molecular structure of the title molecule with the atom-numbering scheme. Displacement ellipsoids are drawn at the 30% probability level [symmetry codes: (A) 1/2 - x, 1/2 - y, -z; (B) 1 - x, y, 3/2 -z]. Hydrogen atoms have been omitted for clarity.
	Fig. 2. A partial packing diagram. Hydrogen bonds are shown as dashed lines.

Hexaaquacobalt(II) 5,5'-(propane-1,3-diyldithio)bis(1H-tetrazole-1-acetate) top

Crystal data top

[Co(H₂O)₆](C₉H₁₀N₈O₄S₂)	F(000) = 1084
M_r = 525.42	D_x = 1.797 Mg m⁻³
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yc	Cell parameters from 3230 reflections
a = 19.420 (2) Å	θ = 2.8–28.0°
b = 7.9069 (11) Å	µ = 1.17 mm⁻¹
c = 13.7356 (17) Å	T = 298 K
β = 112.957 (2)°	Block, pink
V = 1942.1 (4) Å³	0.38 × 0.35 × 0.20 mm
Z = 4

Data collection top

Bruker SMART CCD area-detector diffractometer	1716 independent reflections
Radiation source: fine-focus sealed tube	1518 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.024
ϕ and ω scans	θ_max = 25.0°, θ_min = 2.3°
Absorption correction: multi-scan (SADABS; Bruker, 1997)	h = −22→22
T_min = 0.665, T_max = 0.800	k = −5→9
4714 measured reflections	l = −16→16

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.025	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.068	H atoms treated by a mixture of independent and constrained refinement
S = 1.02	w = 1/[σ²(F_o²) + (0.0317P)² + 3P] where P = (F_o² + 2F_c²)/3
1716 reflections	(Δ/σ)_max < 0.001
142 parameters	Δρ_max = 0.24 e Å⁻³
0 restraints	Δρ_min = −0.36 e Å⁻³

Crystal data top

[Co(H₂O)₆](C₉H₁₀N₈O₄S₂)	V = 1942.1 (4) Å³
M_r = 525.42	Z = 4
Monoclinic, C2/c	Mo Kα radiation
a = 19.420 (2) Å	µ = 1.17 mm⁻¹
b = 7.9069 (11) Å	T = 298 K
c = 13.7356 (17) Å	0.38 × 0.35 × 0.20 mm
β = 112.957 (2)°

Data collection top

Bruker SMART CCD area-detector diffractometer	1716 independent reflections
Absorption correction: multi-scan (SADABS; Bruker, 1997)	1518 reflections with I > 2σ(I)
T_min = 0.665, T_max = 0.800	R_int = 0.024
4714 measured reflections

Refinement top

R[F² > 2σ(F²)] = 0.025	0 restraints
wR(F²) = 0.068	H atoms treated by a mixture of independent and constrained refinement
S = 1.02	Δρ_max = 0.24 e Å⁻³
1716 reflections	Δρ_min = −0.36 e Å⁻³
142 parameters

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Co1	0.2500	0.2500	0.0000	0.01988 (13)
S1	0.43307 (3)	0.19008 (9)	0.57138 (5)	0.03941 (18)
O1	0.31180 (8)	0.09876 (18)	0.31741 (11)	0.0285 (3)
O2	0.23139 (9)	0.23926 (18)	0.36776 (14)	0.0344 (4)
O3	0.30995 (8)	0.07215 (18)	0.11553 (11)	0.0263 (3)
H3A	0.3132	0.0970	0.1774	0.032*
H3B	0.3001	−0.0328	0.1066	0.032*
O4	0.32343 (8)	0.43840 (19)	0.09350 (12)	0.0298 (3)
H4A	0.3105	0.5351	0.1074	0.036*
H4B	0.3708	0.4302	0.1214	0.036*
O5	0.18294 (8)	0.30070 (18)	0.08298 (11)	0.0262 (3)
H5A	0.1885	0.3941	0.1158	0.031*
H5B	0.1362	0.2841	0.0519	0.031*
N1	0.41422 (9)	0.3568 (2)	0.39209 (13)	0.0222 (4)
N2	0.45252 (10)	0.4106 (2)	0.33400 (14)	0.0284 (4)
N3	0.52125 (10)	0.3673 (2)	0.38552 (14)	0.0314 (4)
N4	0.52993 (10)	0.2844 (2)	0.47718 (14)	0.0287 (4)
C1	0.46251 (12)	0.2798 (3)	0.47931 (16)	0.0237 (4)
C2	0.28859 (12)	0.2281 (2)	0.34801 (15)	0.0225 (4)
C3	0.33493 (11)	0.3904 (3)	0.36361 (17)	0.0246 (4)
H3C	0.3160	0.4558	0.2988	0.030*
H3D	0.3290	0.4578	0.4188	0.030*
C4	0.52031 (11)	0.1138 (3)	0.67099 (16)	0.0282 (5)
H4C	0.5467	0.0439	0.6387	0.034*
H4D	0.5522	0.2081	0.7063	0.034*
C5	0.5000	0.0101 (4)	0.7500	0.0268 (6)
H5	0.5438 (12)	−0.061 (3)	0.7883 (18)	0.033 (6)*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Co1	0.0184 (2)	0.0201 (2)	0.0220 (2)	0.00018 (14)	0.00878 (16)	−0.00122 (15)
S1	0.0235 (3)	0.0601 (4)	0.0348 (3)	0.0030 (3)	0.0115 (3)	0.0230 (3)
O1	0.0354 (9)	0.0223 (8)	0.0279 (8)	0.0004 (6)	0.0124 (7)	0.0000 (6)
O2	0.0315 (9)	0.0284 (9)	0.0507 (10)	−0.0033 (7)	0.0239 (8)	0.0010 (7)
O3	0.0293 (8)	0.0234 (7)	0.0267 (8)	0.0031 (6)	0.0115 (6)	0.0008 (6)
O4	0.0196 (7)	0.0275 (8)	0.0386 (9)	−0.0016 (6)	0.0073 (6)	−0.0095 (7)
O5	0.0225 (7)	0.0268 (8)	0.0313 (8)	−0.0010 (6)	0.0126 (6)	−0.0066 (6)
N1	0.0205 (9)	0.0233 (9)	0.0236 (9)	−0.0013 (7)	0.0096 (7)	0.0014 (7)
N2	0.0279 (10)	0.0347 (10)	0.0260 (9)	−0.0019 (8)	0.0141 (8)	0.0019 (8)
N3	0.0265 (10)	0.0405 (11)	0.0302 (10)	−0.0008 (8)	0.0144 (8)	0.0018 (8)
N4	0.0228 (9)	0.0340 (10)	0.0300 (10)	−0.0008 (8)	0.0112 (8)	0.0010 (8)
C1	0.0231 (11)	0.0255 (11)	0.0225 (10)	−0.0012 (8)	0.0089 (9)	−0.0006 (8)
C2	0.0243 (11)	0.0232 (11)	0.0179 (10)	0.0008 (8)	0.0059 (8)	0.0040 (8)
C3	0.0204 (10)	0.0223 (10)	0.0304 (11)	0.0019 (8)	0.0090 (9)	0.0018 (9)
C4	0.0231 (11)	0.0357 (12)	0.0236 (10)	0.0023 (9)	0.0066 (9)	0.0007 (9)
C5	0.0282 (17)	0.0277 (16)	0.0211 (15)	0.000	0.0061 (13)	0.000

Geometric parameters (Å, º) top

Co1—O3	2.1000 (14)	O5—H5B	0.8500
Co1—O3ⁱ	2.1000 (14)	N1—N2	1.354 (2)
Co1—O4ⁱ	2.1150 (14)	N1—C1	1.345 (3)
Co1—O4	2.1150 (14)	N1—C3	1.458 (3)
Co1—O5ⁱ	2.0770 (13)	N2—N3	1.290 (2)
Co1—O5	2.0770 (13)	N3—N4	1.370 (3)
S1—C1	1.730 (2)	N4—C1	1.321 (3)
S1—C4	1.816 (2)	C2—C3	1.533 (3)
O1—C2	1.254 (2)	C3—H3C	0.9700
O2—C2	1.245 (3)	C3—H3D	0.9700
O3—H3A	0.8500	C4—C5	1.529 (3)
O3—H3B	0.8500	C4—H4C	0.9700
O4—H4A	0.8499	C4—H4D	0.9700
O4—H4B	0.8499	C5—C4ⁱⁱ	1.529 (3)
O5—H5A	0.8500	C5—H5	0.98 (2)

O3—Co1—O3ⁱ	180.00 (12)	H4A—O4—H4B	109.2
O3—Co1—O4ⁱ	91.78 (6)	Co1—O5—H5A	118.7
O3ⁱ—Co1—O4ⁱ	88.22 (6)	Co1—O5—H5B	118.1
O3—Co1—O4	88.22 (6)	H5A—O5—H5B	106.9
O3ⁱ—Co1—O4	91.78 (6)	C1—S1—C4	102.11 (10)
O4ⁱ—Co1—O4	180.00 (14)	N4—C1—N1	108.69 (18)
O5ⁱ—Co1—O3	90.23 (6)	N4—C1—S1	129.81 (17)
O5—Co1—O3	89.77 (6)	N1—C1—S1	121.49 (16)
O5ⁱ—Co1—O3ⁱ	89.77 (6)	O2—C2—O1	126.76 (19)
O5—Co1—O3ⁱ	90.23 (6)	O2—C2—C3	115.80 (18)
O5ⁱ—Co1—O4ⁱ	87.10 (6)	O1—C2—C3	117.44 (18)
O5—Co1—O4ⁱ	92.90 (6)	N1—C3—C2	112.70 (16)
O5ⁱ—Co1—O4	92.90 (6)	N1—C3—H3C	109.1
O5—Co1—O4	87.10 (6)	C2—C3—H3C	109.1
O5ⁱ—Co1—O5	180.00 (10)	N1—C3—H3D	109.1
C1—N1—N2	108.35 (16)	C2—C3—H3D	109.1
C1—N1—C3	128.18 (17)	H3C—C3—H3D	107.8
N2—N1—C3	123.36 (16)	S1—C4—H4C	110.4
N3—N2—N1	106.36 (16)	S1—C4—H4D	110.4
N2—N3—N4	111.19 (16)	C5—C4—S1	106.84 (12)
C1—N4—N3	105.41 (17)	C5—C4—H4C	110.4
Co1—O3—H3A	113.8	C5—C4—H4D	110.4
Co1—O3—H3B	121.1	H4C—C4—H4D	108.6
H3A—O3—H3B	107.2	C4—C5—C4ⁱⁱ	115.2 (3)
Co1—O4—H4A	125.6	C4—C5—H5	106.0 (13)
Co1—O4—H4B	125.1	C4ⁱⁱ—C5—H5	109.5 (13)

C1—N1—N2—N3	−0.2 (2)	C3—N1—C1—S1	5.2 (3)
C3—N1—N2—N3	176.28 (18)	C4—S1—C1—N4	3.5 (2)
N1—N2—N3—N4	0.3 (2)	C4—S1—C1—N1	−178.16 (17)
N2—N3—N4—C1	−0.2 (2)	C1—N1—C3—C2	−63.3 (3)
N3—N4—C1—N1	0.1 (2)	N2—N1—C3—C2	120.9 (2)
N3—N4—C1—S1	178.55 (17)	O2—C2—C3—N1	150.83 (18)
N2—N1—C1—N4	0.1 (2)	O1—C2—C3—N1	−28.9 (3)
C3—N1—C1—N4	−176.20 (19)	C1—S1—C4—C5	−172.50 (15)
N2—N1—C1—S1	−178.54 (15)	S1—C4—C5—C4ⁱⁱ	−77.35 (11)

Symmetry codes: (i) −x+1/2, −y+1/2, −z; (ii) −x+1, y, −z+3/2.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O3—H3A···O1	0.85	1.93	2.767 (2)	166
O4—H4A···O2ⁱⁱⁱ	0.85	1.90	2.742 (2)	172
O4—H4B···N3^iv	0.85	2.19	2.970 (2)	152
O5—H5A···O1ⁱⁱⁱ	0.85	1.86	2.7069 (19)	173
O5—H5B···N4^v	0.85	1.99	2.833 (2)	173

Symmetry codes: (iii) −x+1/2, y+1/2, −z+1/2; (iv) −x+1, y, −z+1/2; (v) x−1/2, −y+1/2, z−1/2.

Experimental details

Crystal data
Chemical formula	[Co(H₂O)₆](C₉H₁₀N₈O₄S₂)
M_r	525.42
Crystal system, space group	Monoclinic, C2/c
Temperature (K)	298
a, b, c (Å)	19.420 (2), 7.9069 (11), 13.7356 (17)
β (°)	112.957 (2)
V (Å³)	1942.1 (4)
Z	4
Radiation type	Mo Kα
µ (mm⁻¹)	1.17
Crystal size (mm)	0.38 × 0.35 × 0.20

Data collection
Diffractometer	Bruker SMART CCD area-detector diffractometer
Absorption correction	Multi-scan (SADABS; Bruker, 1997)
T_min, T_max	0.665, 0.800
No. of measured, independent and observed [I > 2σ(I)] reflections	4714, 1716, 1518
R_int	0.024
(sin θ/λ)_max (Å⁻¹)	0.595

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.025, 0.068, 1.02
No. of reflections	1716
No. of parameters	142
H-atom treatment	H atoms treated by a mixture of independent and constrained refinement
Δρ_max, Δρ_min (e Å⁻³)	0.24, −0.36

Computer programs: SMART (Bruker, 1997), SAINT (Bruker, 1997), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), SHELXTL (Sheldrick, 2008) and PLATON (Spek, 2009).

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O3—H3A···O1	0.85	1.93	2.767 (2)	166.2
O4—H4A···O2ⁱ	0.85	1.90	2.742 (2)	172.0
O4—H4B···N3ⁱⁱ	0.85	2.19	2.970 (2)	151.9
O5—H5A···O1ⁱ	0.85	1.86	2.7069 (19)	173.0
O5—H5B···N4ⁱⁱⁱ	0.85	1.99	2.833 (2)	172.9

Symmetry codes: (i) −x+1/2, y+1/2, −z+1/2; (ii) −x+1, y, −z+1/2; (iii) x−1/2, −y+1/2, z−1/2.

Acknowledgements

We gratefully acknowledge the Innovation Project of Guangxi Graduate Education (grant No. 2008106020703M242) and the Science Foundation of Guangxi (grant Nos. 0639030, 0731052, 0832098).

References

Bruker (1997). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA. Google Scholar
Du, M., Zhao, X.-J. & Guo, J.-H. (2004). Acta Cryst. E60, m788–m790. Web of Science CSD CrossRef IUCr Journals Google Scholar
Jiang, N.-Y. & Li, S.-L. (2004). Chin. J. Struct. Chem. 25, 957–964. Google Scholar
Liu, J.-W., Huo, L.-H., Gao, S. & Ng, S. W. (2004). Acta Cryst. E60, m439–m440. Web of Science CSD CrossRef IUCr Journals Google Scholar
Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. Web of Science CrossRef CAS IUCr Journals Google Scholar
Spek, A. L. (2009). Acta Cryst. D65, 148–155. Web of Science CrossRef CAS IUCr Journals Google Scholar

This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 65| Part 8| August 2009| Page m1006

doi:10.1107/S1600536809028463

Open

access

Format		BIBTeX
		EndNote
		RefMan
		Refer
		Medline
		CIF
		SGML
		Plain Text

Format		BIBTeX
		EndNote
		RefMan
		Refer
		Medline
		CIF
		SGML
		Plain Text

Search IUCr Journals		doi		Advanced search
Author		volume	page

metal-organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

Hexa­aqua­cobalt(II) 5,5′-(propane-1,3-diyldi­thio)bis­­(1H-tetra­zole-1-acetate)

Related literature

Experimental

Crystal data

Data collection

Refinement

Supporting information

Acknowledgements

References

metal-organic compounds

Hexaaquacobalt(II) 5,5′-(propane-1,3-diyldithio)bis(1H-tetrazole-1-acetate)