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In the title salt, 1-(4-fluoro­benz­yl)pyridinium 7,7,8,8-tetra­cyano­quinodimethanide 7,7,8,8-tetra­cyano­quinodimethane, C13H13FN+·C8H4(CN)4·C8H4(CN)4, the asymmetric unit contains one cation, one anion and a neutral mol­ecule. Intra­molecular C—H...N and inter­molecular C—H...N and C—H...F hydrogen bonds and π—π stacking inter­actions seem to be effective in the stabilization of the crystal structure.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536807000967/hk2184sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536807000967/hk2184Isup2.hkl
Contains datablock I

CCDC reference: 636688

Key indicators

  • Single-crystal X-ray study
  • T = 294 K
  • Mean [sigma](C-C) = 0.003 Å
  • R factor = 0.044
  • wR factor = 0.087
  • Data-to-parameter ratio = 12.6

checkCIF/PLATON results

No syntax errors found



Alert level C PLAT026_ALERT_3_C Ratio Observed / Unique Reflections too Low .... 47 Perc. PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT066_ALERT_1_C Predicted and Reported Transmissions Identical . ? PLAT154_ALERT_1_C The su's on the Cell Angles are Equal (x 10000) 200 Deg. PLAT230_ALERT_2_C Hirshfeld Test Diff for C15 - C16 .. 5.01 su PLAT230_ALERT_2_C Hirshfeld Test Diff for C26 - C28 .. 6.04 su PLAT230_ALERT_2_C Hirshfeld Test Diff for C35 - C36 .. 6.93 su PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C7 PLAT371_ALERT_2_C Long C(sp2)-C(sp1) Bond C14 - C16 ... 1.43 Ang. PLAT371_ALERT_2_C Long C(sp2)-C(sp1) Bond C15 - C16 ... 1.42 Ang. PLAT371_ALERT_2_C Long C(sp2)-C(sp1) Bond C23 - C24 ... 1.42 Ang. PLAT371_ALERT_2_C Long C(sp2)-C(sp1) Bond C23 - C25 ... 1.43 Ang. PLAT371_ALERT_2_C Long C(sp2)-C(sp1) Bond C26 - C28 ... 1.43 Ang. PLAT371_ALERT_2_C Long C(sp2)-C(sp1) Bond C27 - C28 ... 1.42 Ang. PLAT371_ALERT_2_C Long C(sp2)-C(sp1) Bond C35 - C36 ... 1.42 Ang. PLAT371_ALERT_2_C Long C(sp2)-C(sp1) Bond C35 - C37 ... 1.42 Ang.
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 16 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 3 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 12 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 0 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check

Computing details top

Data collection: SMART (Bruker, 2000); cell refinement: SAINT (Bruker, 2000); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 2000); software used to prepare material for publication: SHELXTL.

1-(4-fluorobenzyl)pyridinium 7,7,8,8-tetracyanoquinodimethanide 7,7,8,8-tetracyanoquinodimethane top
Crystal data top
C13H13FN+·C12H4N4·C12H4N4Z = 2
Mr = 610.63F(000) = 630
Triclinic, P1Dx = 1.325 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 9.5476 (13) ÅCell parameters from 1378 reflections
b = 10.8917 (14) Åθ = 2.6–25.7°
c = 15.346 (2) ŵ = 0.09 mm1
α = 101.203 (2)°T = 294 K
β = 94.189 (2)°Block, dark green
γ = 100.215 (2)°0.20 × 0.16 × 0.12 mm
V = 1531.1 (3) Å3
Data collection top
Bruker SMART APEX CCD area-detector
diffractometer
5336 independent reflections
Radiation source: sealed tube2529 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.043
φ and ω scansθmax = 25.0°, θmin = 2.1°
Absorption correction: multi-scan
(SADABS; Bruker, 2000)
h = 1111
Tmin = 0.983, Tmax = 0.990k = 912
7803 measured reflectionsl = 1818
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.044Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.087H-atom parameters constrained
S = 1.01 w = 1/[σ2(Fo2) + (0.01P)2]
where P = (Fo2 + 2Fc2)/3
5336 reflections(Δ/σ)max < 0.001
425 parametersΔρmax = 0.17 e Å3
0 restraintsΔρmin = 0.24 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
F10.25409 (16)0.44607 (16)0.11758 (11)0.0928 (6)
N10.8145 (2)0.2174 (2)0.03154 (11)0.0459 (5)
N20.8331 (2)0.2859 (2)0.25040 (13)0.0668 (7)
N30.5938 (2)0.5315 (2)0.40316 (13)0.0692 (7)
N41.2725 (3)0.1953 (3)0.72285 (15)0.0889 (9)
N51.0286 (2)0.4229 (2)0.88049 (13)0.0626 (7)
N60.4525 (2)0.0476 (2)0.13401 (14)0.0736 (8)
N70.2346 (3)0.3067 (2)0.29747 (14)0.0817 (8)
N80.9181 (3)0.0341 (2)0.59835 (14)0.0761 (8)
N90.6803 (3)0.2067 (2)0.75973 (14)0.0784 (8)
C10.3715 (3)0.4045 (3)0.0867 (2)0.0608 (8)
C20.3615 (3)0.3449 (3)0.0006 (2)0.0675 (9)
H20.27610.33050.03760.081*
C30.4816 (3)0.3062 (3)0.03300 (17)0.0589 (8)
H30.47710.26410.09230.071*
C40.6084 (3)0.3300 (2)0.02257 (17)0.0484 (7)
C50.6123 (3)0.3895 (3)0.11090 (16)0.0559 (8)
H50.69710.40440.14860.067*
C60.4927 (3)0.4275 (3)0.14447 (17)0.0599 (8)
H60.49510.46710.20410.072*
C70.7419 (3)0.3000 (3)0.01631 (15)0.0641 (8)
H7A0.71700.25740.07860.077*
H7B0.80840.37930.01410.077*
C80.9560 (3)0.2512 (3)0.05677 (14)0.0513 (7)
H81.00700.32770.04730.062*
C91.0254 (3)0.1732 (3)0.09638 (15)0.0524 (7)
H91.12360.19680.11310.063*
C100.9522 (3)0.0610 (3)0.11171 (15)0.0491 (7)
C110.8071 (3)0.0301 (3)0.08543 (16)0.0563 (7)
H110.75400.04520.09530.068*
C120.7403 (3)0.1081 (3)0.04523 (15)0.0543 (7)
H120.64240.08520.02710.065*
C131.0269 (3)0.0223 (3)0.15860 (17)0.0750 (9)
H13A1.02550.00340.22200.112*
H13B1.12430.01390.14510.112*
H13C0.97870.10960.13880.112*
C140.8132 (2)0.3324 (2)0.32015 (16)0.0431 (7)
C150.6788 (3)0.4696 (2)0.40626 (14)0.0450 (7)
C160.7854 (2)0.3934 (2)0.40635 (14)0.0389 (6)
C170.8574 (2)0.3776 (2)0.48440 (14)0.0348 (6)
C180.9645 (2)0.3014 (2)0.48149 (14)0.0395 (6)
H180.98630.26100.42640.047*
C191.0350 (2)0.2866 (2)0.55694 (14)0.0400 (6)
H191.10490.23680.55280.048*
C201.0046 (2)0.3459 (2)0.64319 (14)0.0376 (6)
C210.8979 (2)0.4228 (2)0.64632 (14)0.0398 (6)
H210.87640.46330.70150.048*
C220.8273 (2)0.4379 (2)0.57044 (14)0.0393 (6)
H220.75810.48840.57440.047*
C231.0773 (2)0.3288 (2)0.72101 (14)0.0422 (6)
C241.1859 (3)0.2545 (3)0.72027 (15)0.0547 (8)
C251.0468 (2)0.3826 (2)0.80847 (17)0.0461 (7)
C260.4435 (3)0.1018 (3)0.20434 (17)0.0492 (7)
C270.3203 (3)0.2456 (3)0.29492 (15)0.0531 (7)
C280.4257 (2)0.1678 (2)0.29137 (15)0.0430 (6)
C290.5025 (2)0.1537 (2)0.36817 (14)0.0380 (6)
C300.6072 (2)0.0752 (2)0.36351 (14)0.0402 (6)
H300.62560.03320.30800.048*
C310.6806 (2)0.0607 (2)0.43845 (14)0.0410 (6)
H310.74980.01010.43360.049*
C320.6534 (2)0.1219 (2)0.52484 (14)0.0381 (6)
C330.5485 (2)0.2007 (2)0.52952 (14)0.0407 (6)
H330.52920.24190.58500.049*
C340.4770 (2)0.2164 (2)0.45445 (14)0.0409 (6)
H340.40990.26900.45910.049*
C350.7268 (2)0.1048 (2)0.60223 (15)0.0416 (6)
C360.8330 (3)0.0277 (3)0.59921 (15)0.0506 (7)
C370.7001 (3)0.1621 (2)0.68933 (17)0.0493 (7)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
F10.0578 (11)0.0936 (14)0.1417 (15)0.0331 (11)0.0258 (10)0.0382 (12)
N10.0436 (13)0.0603 (17)0.0343 (12)0.0118 (13)0.0065 (10)0.0095 (11)
N20.0783 (17)0.084 (2)0.0391 (13)0.0292 (15)0.0048 (13)0.0052 (13)
N30.0797 (18)0.0694 (19)0.0644 (16)0.0377 (16)0.0008 (13)0.0103 (14)
N40.095 (2)0.099 (2)0.0817 (18)0.0591 (19)0.0048 (15)0.0096 (16)
N50.0649 (15)0.0800 (19)0.0418 (13)0.0187 (14)0.0045 (12)0.0062 (14)
N60.0766 (17)0.091 (2)0.0432 (14)0.0076 (16)0.0083 (13)0.0018 (14)
N70.091 (2)0.091 (2)0.0646 (16)0.0497 (18)0.0100 (14)0.0005 (15)
N80.093 (2)0.079 (2)0.0673 (16)0.0458 (17)0.0029 (14)0.0171 (14)
N90.0972 (19)0.091 (2)0.0392 (14)0.0106 (17)0.0089 (14)0.0027 (15)
C10.0451 (18)0.053 (2)0.094 (2)0.0157 (17)0.0132 (18)0.0313 (19)
C20.0435 (18)0.071 (2)0.088 (2)0.0060 (17)0.0129 (17)0.030 (2)
C30.0590 (18)0.062 (2)0.0534 (17)0.0055 (17)0.0087 (15)0.0171 (15)
C40.0428 (16)0.061 (2)0.0477 (16)0.0142 (15)0.0018 (13)0.0234 (15)
C50.0453 (16)0.080 (2)0.0469 (17)0.0146 (16)0.0000 (13)0.0241 (16)
C60.0554 (18)0.073 (2)0.0561 (17)0.0168 (17)0.0130 (15)0.0188 (16)
C70.0608 (18)0.097 (2)0.0448 (16)0.0247 (18)0.0057 (14)0.0329 (17)
C80.0437 (16)0.061 (2)0.0463 (16)0.0017 (16)0.0091 (13)0.0105 (15)
C90.0414 (16)0.066 (2)0.0489 (16)0.0104 (16)0.0026 (13)0.0126 (16)
C100.0547 (18)0.052 (2)0.0402 (15)0.0132 (16)0.0106 (13)0.0045 (14)
C110.0584 (19)0.0432 (19)0.0642 (19)0.0035 (16)0.0129 (15)0.0077 (15)
C120.0428 (16)0.060 (2)0.0500 (17)0.0003 (17)0.0005 (13)0.0027 (15)
C130.086 (2)0.078 (2)0.073 (2)0.035 (2)0.0122 (16)0.0263 (18)
C140.0490 (16)0.0470 (18)0.0351 (15)0.0127 (14)0.0012 (13)0.0112 (14)
C150.0573 (18)0.0430 (18)0.0340 (14)0.0113 (15)0.0022 (13)0.0062 (13)
C160.0461 (15)0.0385 (16)0.0327 (14)0.0122 (13)0.0051 (12)0.0053 (12)
C170.0410 (14)0.0316 (15)0.0305 (13)0.0073 (13)0.0038 (11)0.0036 (12)
C180.0472 (15)0.0386 (16)0.0333 (14)0.0142 (13)0.0064 (12)0.0029 (12)
C190.0419 (15)0.0412 (17)0.0377 (14)0.0143 (13)0.0062 (12)0.0041 (13)
C200.0397 (14)0.0372 (16)0.0359 (14)0.0076 (13)0.0032 (12)0.0082 (12)
C210.0462 (15)0.0410 (17)0.0315 (14)0.0116 (14)0.0057 (12)0.0026 (12)
C220.0447 (15)0.0384 (16)0.0376 (14)0.0163 (13)0.0062 (12)0.0063 (13)
C230.0462 (15)0.0454 (17)0.0368 (15)0.0148 (14)0.0028 (12)0.0080 (13)
C240.063 (2)0.061 (2)0.0423 (16)0.0220 (17)0.0000 (14)0.0086 (15)
C250.0459 (16)0.0520 (19)0.0413 (16)0.0136 (14)0.0037 (14)0.0119 (15)
C260.0466 (16)0.056 (2)0.0442 (17)0.0099 (15)0.0011 (14)0.0123 (15)
C270.0611 (19)0.059 (2)0.0380 (15)0.0175 (17)0.0032 (14)0.0057 (14)
C280.0479 (16)0.0468 (18)0.0346 (15)0.0124 (14)0.0036 (12)0.0069 (13)
C290.0413 (15)0.0378 (16)0.0339 (14)0.0074 (13)0.0061 (12)0.0051 (12)
C300.0493 (15)0.0400 (16)0.0311 (14)0.0122 (14)0.0069 (12)0.0027 (12)
C310.0462 (15)0.0382 (17)0.0391 (14)0.0132 (13)0.0076 (12)0.0039 (13)
C320.0433 (15)0.0344 (16)0.0356 (14)0.0044 (13)0.0045 (12)0.0080 (12)
C330.0478 (15)0.0398 (17)0.0341 (14)0.0110 (14)0.0080 (12)0.0031 (12)
C340.0440 (15)0.0401 (17)0.0390 (15)0.0129 (13)0.0069 (12)0.0043 (13)
C350.0476 (16)0.0401 (17)0.0374 (15)0.0102 (14)0.0050 (12)0.0078 (13)
C360.0647 (19)0.050 (2)0.0375 (15)0.0104 (16)0.0001 (14)0.0129 (14)
C370.0547 (17)0.0496 (19)0.0428 (16)0.0057 (15)0.0017 (14)0.0128 (15)
Geometric parameters (Å, º) top
F1—C11.364 (3)C13—H13B0.9600
N1—C121.336 (3)C13—H13C0.9600
N1—C81.343 (3)C14—C161.426 (3)
N1—C71.494 (3)C15—C161.423 (3)
N2—C141.136 (3)C16—C171.392 (3)
N3—C151.146 (3)C17—C181.426 (3)
N4—C241.138 (3)C17—C221.429 (3)
N5—C251.145 (3)C18—C191.348 (3)
N6—C261.142 (3)C18—H180.9300
N7—C271.140 (3)C19—C201.429 (3)
N8—C361.143 (3)C19—H190.9300
N9—C371.139 (3)C20—C231.398 (3)
C1—C21.359 (3)C20—C211.427 (3)
C1—C61.360 (3)C21—C221.355 (3)
C2—C31.383 (3)C21—H210.9300
C2—H20.9300C22—H220.9300
C3—C41.383 (3)C23—C241.423 (3)
C3—H30.9300C23—C251.429 (3)
C4—C51.379 (3)C26—C281.426 (3)
C4—C71.507 (3)C27—C281.424 (3)
C5—C61.382 (3)C28—C291.391 (3)
C5—H50.9300C29—C301.423 (3)
C6—H60.9300C29—C341.426 (3)
C7—H7A0.9700C30—C311.353 (3)
C7—H7B0.9700C30—H300.9300
C8—C91.368 (3)C31—C321.428 (3)
C8—H80.9300C31—H310.9300
C9—C101.368 (3)C32—C351.395 (3)
C9—H90.9300C32—C331.426 (3)
C10—C111.377 (3)C33—C341.351 (3)
C10—C131.502 (3)C33—H330.9300
C11—C121.359 (3)C34—H340.9300
C11—H110.9300C35—C371.422 (3)
C12—H120.9300C35—C361.424 (3)
C13—H13A0.9600
C12—N1—C8120.5 (2)C15—C16—C14115.21 (19)
C12—N1—C7120.1 (2)C16—C17—C18121.2 (2)
C8—N1—C7119.4 (2)C16—C17—C22121.3 (2)
C2—C1—C6123.7 (3)C18—C17—C22117.47 (18)
C2—C1—F1118.1 (3)C19—C18—C17121.4 (2)
C6—C1—F1118.2 (3)C19—C18—H18119.3
C1—C2—C3118.3 (3)C17—C18—H18119.3
C1—C2—H2120.8C18—C19—C20121.4 (2)
C3—C2—H2120.8C18—C19—H19119.3
C4—C3—C2120.1 (3)C20—C19—H19119.3
C4—C3—H3119.9C23—C20—C21121.7 (2)
C2—C3—H3119.9C23—C20—C19120.9 (2)
C5—C4—C3119.2 (2)C21—C20—C19117.37 (19)
C5—C4—C7121.3 (2)C22—C21—C20121.2 (2)
C3—C4—C7119.3 (2)C22—C21—H21119.4
C4—C5—C6121.3 (2)C20—C21—H21119.4
C4—C5—H5119.4C21—C22—C17121.2 (2)
C6—C5—H5119.4C21—C22—H22119.4
C1—C6—C5117.3 (3)C17—C22—H22119.4
C1—C6—H6121.4C20—C23—C24123.2 (2)
C5—C6—H6121.4C20—C23—C25122.7 (2)
N1—C7—C4113.20 (19)C24—C23—C25114.13 (19)
N1—C7—H7A108.9N4—C24—C23177.6 (3)
C4—C7—H7A108.9N5—C25—C23176.0 (2)
N1—C7—H7B108.9N6—C26—C28177.5 (3)
C4—C7—H7B108.9N7—C27—C28179.1 (3)
H7A—C7—H7B107.8C29—C28—C27122.0 (2)
N1—C8—C9120.0 (2)C29—C28—C26122.3 (2)
N1—C8—H8120.0C27—C28—C26115.6 (2)
C9—C8—H8120.0C28—C29—C30121.3 (2)
C10—C9—C8120.9 (2)C28—C29—C34120.8 (2)
C10—C9—H9119.6C30—C29—C34117.85 (19)
C8—C9—H9119.6C31—C30—C29121.2 (2)
C9—C10—C11117.4 (2)C31—C30—H30119.4
C9—C10—C13121.0 (2)C29—C30—H30119.4
C11—C10—C13121.6 (3)C30—C31—C32120.9 (2)
C12—C11—C10120.9 (3)C30—C31—H31119.5
C12—C11—H11119.5C32—C31—H31119.5
C10—C11—H11119.5C35—C32—C33121.1 (2)
N1—C12—C11120.3 (2)C35—C32—C31121.0 (2)
N1—C12—H12119.8C33—C32—C31117.93 (19)
C11—C12—H12119.8C34—C33—C32120.9 (2)
C10—C13—H13A109.5C34—C33—H33119.5
C10—C13—H13B109.5C32—C33—H33119.5
H13A—C13—H13B109.5C33—C34—C29121.2 (2)
C10—C13—H13C109.5C33—C34—H34119.4
H13A—C13—H13C109.5C29—C34—H34119.4
H13B—C13—H13C109.5C32—C35—C37122.4 (2)
N2—C14—C16178.0 (3)C32—C35—C36122.1 (2)
N3—C15—C16177.5 (3)C37—C35—C36115.5 (2)
C17—C16—C15123.0 (2)N8—C36—C35178.8 (3)
C17—C16—C14121.7 (2)N9—C37—C35178.7 (3)
C6—C1—C2—C30.5 (4)C17—C18—C19—C200.5 (3)
F1—C1—C2—C3178.0 (2)C18—C19—C20—C23179.3 (2)
C1—C2—C3—C41.0 (4)C18—C19—C20—C210.8 (3)
C2—C3—C4—C51.7 (4)C23—C20—C21—C22179.5 (2)
C2—C3—C4—C7173.4 (2)C19—C20—C21—C220.6 (3)
C3—C4—C5—C61.0 (4)C20—C21—C22—C170.2 (3)
C7—C4—C5—C6174.0 (2)C16—C17—C22—C21179.7 (2)
C2—C1—C6—C51.2 (4)C18—C17—C22—C210.2 (3)
F1—C1—C6—C5177.3 (2)C21—C20—C23—C24178.9 (2)
C4—C5—C6—C10.4 (4)C19—C20—C23—C240.9 (4)
C12—N1—C7—C452.0 (3)C21—C20—C23—C252.3 (4)
C8—N1—C7—C4131.1 (2)C19—C20—C23—C25177.8 (2)
C5—C4—C7—N157.8 (3)C27—C28—C29—C30179.8 (2)
C3—C4—C7—N1127.1 (2)C26—C28—C29—C302.2 (4)
C12—N1—C8—C90.3 (3)C27—C28—C29—C340.7 (4)
C7—N1—C8—C9176.5 (2)C26—C28—C29—C34176.9 (2)
N1—C8—C9—C100.7 (4)C28—C29—C30—C31179.3 (2)
C8—C9—C10—C110.2 (4)C34—C29—C30—C310.1 (3)
C8—C9—C10—C13177.5 (2)C29—C30—C31—C321.2 (4)
C9—C10—C11—C120.5 (4)C30—C31—C32—C35178.6 (2)
C13—C10—C11—C12178.2 (2)C30—C31—C32—C331.2 (3)
C8—N1—C12—C110.4 (3)C35—C32—C33—C34179.6 (2)
C7—N1—C12—C11177.3 (2)C31—C32—C33—C340.3 (3)
C10—C11—C12—N10.9 (4)C32—C33—C34—C290.7 (3)
C15—C16—C17—C18179.4 (2)C28—C29—C34—C33178.3 (2)
C14—C16—C17—C181.3 (3)C30—C29—C34—C330.8 (3)
C15—C16—C17—C220.2 (4)C33—C32—C35—C371.3 (4)
C14—C16—C17—C22179.2 (2)C31—C32—C35—C37178.6 (2)
C16—C17—C18—C19179.5 (2)C33—C32—C35—C36179.3 (2)
C22—C17—C18—C190.0 (3)C31—C32—C35—C360.8 (4)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
C5—H5···N20.932.623.380 (3)139
C7—H7A···N9i0.972.423.366 (3)165
C8—H8···F1ii0.932.533.190 (3)128
C12—H12···N60.932.563.177 (4)124
C12—H12···N6iii0.932.623.189 (3)120
Symmetry codes: (i) x, y, z1; (ii) x+1, y, z; (iii) x+1, y, z.
 

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