trans-Dichloro­{P,P'-[3,3'-oxybis(m-phenyl­enemethyl­ene)]bis­(diphenyl­phosphine)}palladium(II)

The square-planar title complex, [PdCl₂(C₃₈H₃₂OP₂)], shows the P atoms to be trans coordinated, with a P-Pd-P angle of 176.50 (4)°. The phenyl rings in the phospho­rus ligand are inclined at an angle of 61.2 (1)° to each other.

Key indicators

• Single-crystal X-ray study
• T = 203 K
• Mean [sigma](C-C) = 0.006 Å
• R factor = 0.037
• wR factor = 0.074
• Data-to-parameter ratio = 16.1

checkCIF/PLATON results

No syntax errors found



Alert level C
PLAT480_ALERT_4_C Long H...A H-Bond Reported H1B    ..  CL2     ..       3.09 Ang.

   0 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   1 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   0 ALERT type 2 Indicator that the structure model may be wrong or deficient
   0 ALERT type 3 Indicator that the structure quality may be low
   1 ALERT type 4 Improvement, methodology, query or suggestion

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Computing details

Data collection: EXPOSE in IPDS Software (Stoe & Cie, 2000); cell refinement: CELL in IPDS Software; data reduction: INTEGRATE in IPDS Software; program(s) used to solve structure: SHELXS97 (Sheldrick, 1990); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-32 (Farrugia, 1997); software used to prepare material for publication: SHELXL97.

Dichloro{P,P'-[3,3'-oxybis(m- phenylenemethylene)]bis(diphenylphosphine)}palladium(II)

Crystal data

[PdCl2(C38H32OP2)]	F(000) = 3024
Mr = 743.88	Dx = 1.498 Mg m^−3
Orthorhombic, Pbca	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ac 2ab	Cell parameters from 8000 reflections
a = 11.4170 (5) Å	θ = 2.1–26.0°
b = 20.8796 (17) Å	µ = 0.85 mm^−1
c = 27.6747 (13) Å	T = 203 K
V = 6597.2 (7) Å^3	Plate, orange
Z = 8	0.28 × 0.16 × 0.08 mm

Data collection

Stoe IPDS diffractometer	3612 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube	Rint = 0.073
Graphite monochromator	θmax = 26.0°, θmin = 2.1°
Detector resolution: 0.81 pixels mm^-1	h = −13→14
φ scans	k = −25→20
24892 measured reflections	l = −34→33
6403 independent reflections

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.037	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.074	H-atom parameters constrained
S = 0.82	w = 1/[σ^2(Fo^2) + (0.0295P)^2] where P = (Fo^2 + 2Fc^2)/3
6403 reflections	(Δ/σ)max = 0.001
397 parameters	Δρmax = 0.64 e Å^−3
0 restraints	Δρmin = −0.80 e Å^−3

Special details

Experimental. A crystal was mounted at 203 K on a Stoe Image Plate Diffraction System (Stoe & Cie, 2000) using Mo Kα graphite monochromated radiation. Image plate distance 70 mm, φ oscillation scans 0 - 200°, step Δφ = 0.8°, 10 minutes per frame.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
C1	0.3890 (3)	0.0435 (2)	0.58133 (13)	0.0261 (9)
H1A	0.3173	0.0673	0.5757	0.031*
H1B	0.4075	0.0206	0.5518	0.031*
C2	0.3666 (3)	−0.0050 (2)	0.62097 (13)	0.0223 (9)
C3	0.2757 (3)	0.0049 (2)	0.65342 (14)	0.0274 (10)
H3	0.2297	0.0415	0.6509	0.033*
C4	0.2527 (4)	−0.0394 (2)	0.68961 (14)	0.0326 (11)
H4	0.1913	−0.0325	0.7111	0.039*
C5	0.3208 (4)	−0.0937 (2)	0.69374 (13)	0.0309 (10)
H5	0.3052	−0.1238	0.7177	0.037*
C6	0.4131 (3)	−0.1029 (2)	0.66185 (14)	0.0261 (9)
C7	0.4349 (3)	−0.05946 (19)	0.62531 (13)	0.0249 (10)
H7	0.4956	−0.0668	0.6036	0.030*
C8	0.5959 (4)	−0.1597 (2)	0.67097 (14)	0.0257 (9)
C9	0.6494 (4)	−0.2189 (2)	0.66721 (14)	0.0306 (10)
H9	0.6048	−0.2555	0.6616	0.037*
C10	0.7695 (4)	−0.2232 (2)	0.67190 (15)	0.0346 (11)
H10	0.8062	−0.2629	0.6697	0.041*
C11	0.8354 (4)	−0.1684 (2)	0.67983 (14)	0.0310 (10)
H11	0.9163	−0.1719	0.6831	0.037*
C12	0.7832 (3)	−0.1089 (2)	0.68297 (13)	0.0258 (10)
C13	0.6607 (3)	−0.1044 (2)	0.67962 (12)	0.0237 (9)
H13	0.6235	−0.0650	0.6831	0.028*
C14	0.8558 (3)	−0.0491 (2)	0.68865 (13)	0.0273 (9)
H14A	0.9354	−0.0606	0.6973	0.033*
H14B	0.8237	−0.0229	0.7144	0.033*
C15	0.4459 (3)	0.1596 (2)	0.63502 (14)	0.0224 (9)
C16	0.4253 (3)	0.2231 (2)	0.62130 (14)	0.0254 (9)
H16	0.4430	0.2358	0.5899	0.031*
C17	0.3794 (4)	0.2672 (2)	0.65330 (15)	0.0308 (10)
H17	0.3652	0.3090	0.6433	0.037*
C18	0.3546 (3)	0.2488 (2)	0.70045 (15)	0.0318 (11)
H18	0.3252	0.2785	0.7223	0.038*
C19	0.3737 (4)	0.1863 (2)	0.71470 (15)	0.0302 (10)
H19	0.3553	0.1739	0.7461	0.036*
C20	0.4197 (3)	0.1419 (2)	0.68292 (13)	0.0268 (10)
H20	0.4334	0.1002	0.6932	0.032*
C21	0.5233 (4)	0.1435 (2)	0.53712 (14)	0.0266 (10)
C22	0.4307 (4)	0.1522 (2)	0.50554 (15)	0.0381 (12)
H22	0.3563	0.1381	0.5142	0.046*
C23	0.4475 (6)	0.1818 (3)	0.46104 (16)	0.0514 (15)
H23	0.3847	0.1874	0.4401	0.062*
C24	0.5558 (6)	0.2024 (2)	0.44827 (17)	0.0495 (15)
H24	0.5669	0.2212	0.4181	0.059*
C25	0.6493 (5)	0.1961 (2)	0.47900 (18)	0.0476 (14)
H25	0.7227	0.2115	0.4702	0.057*
C26	0.6329 (4)	0.1664 (2)	0.52356 (16)	0.0371 (11)
H26	0.6960	0.1617	0.5445	0.045*
C27	0.9229 (3)	−0.05852 (19)	0.58918 (13)	0.0228 (9)
C28	0.8546 (4)	−0.1068 (2)	0.56920 (14)	0.0285 (10)
H28	0.7752	−0.1089	0.5766	0.034*
C29	0.9028 (4)	−0.1518 (2)	0.53854 (15)	0.0355 (11)
H29	0.8564	−0.1841	0.5257	0.043*
C30	1.0205 (4)	−0.1485 (2)	0.52707 (15)	0.0388 (12)
H30	1.0532	−0.1785	0.5062	0.047*
C31	1.0887 (4)	−0.1012 (2)	0.54622 (16)	0.0398 (12)
H31	1.1678	−0.0992	0.5382	0.048*
C32	1.0415 (4)	−0.0562 (2)	0.57758 (14)	0.0330 (11)
H32	1.0890	−0.0245	0.5908	0.040*
C33	0.9620 (3)	0.06065 (19)	0.63969 (14)	0.0251 (9)
C34	0.9997 (3)	0.0825 (2)	0.68446 (13)	0.0238 (9)
H34	0.9742	0.0621	0.7125	0.029*
C35	1.0748 (3)	0.1343 (2)	0.68775 (15)	0.0284 (10)
H35	1.0994	0.1486	0.7179	0.034*
C36	1.1132 (4)	0.1648 (2)	0.64679 (15)	0.0301 (10)
H36	1.1638	0.1995	0.6492	0.036*
C37	1.0761 (4)	0.1435 (2)	0.60172 (15)	0.0316 (11)
H37	1.1029	0.1638	0.5739	0.038*
C38	1.0004 (4)	0.0928 (2)	0.59784 (14)	0.0278 (10)
H38	0.9744	0.0797	0.5676	0.033*
O1	0.4748 (2)	−0.16025 (15)	0.66673 (11)	0.0336 (7)
P1	0.50731 (9)	0.10066 (5)	0.59370 (3)	0.0214 (2)
P2	0.85659 (8)	−0.00311 (5)	0.63181 (3)	0.0216 (2)
Cl1	0.68596 (10)	0.08552 (6)	0.69191 (3)	0.0349 (3)
Cl2	0.67431 (10)	0.00658 (5)	0.53700 (3)	0.0342 (2)
Pd1	0.67902 (3)	0.046387 (15)	0.614145 (10)	0.02061 (8)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
C1	0.027 (2)	0.028 (2)	0.023 (2)	0.002 (2)	−0.0039 (16)	0.0005 (19)
C2	0.0226 (19)	0.027 (2)	0.0170 (19)	−0.0024 (17)	−0.0043 (16)	−0.0049 (17)
C3	0.0180 (19)	0.038 (3)	0.026 (2)	0.003 (2)	−0.0019 (16)	−0.0060 (19)
C4	0.025 (2)	0.047 (3)	0.025 (2)	−0.003 (2)	0.0083 (17)	−0.004 (2)
C5	0.029 (2)	0.041 (3)	0.023 (2)	−0.010 (2)	0.002 (2)	−0.0013 (18)
C6	0.026 (2)	0.023 (2)	0.029 (2)	−0.0007 (19)	−0.0039 (18)	−0.0022 (19)
C7	0.025 (2)	0.027 (3)	0.023 (2)	−0.0021 (17)	0.0024 (16)	−0.0010 (17)
C8	0.028 (2)	0.028 (3)	0.021 (2)	0.001 (2)	0.0000 (17)	0.0029 (18)
C9	0.040 (3)	0.026 (3)	0.026 (2)	−0.001 (2)	0.0007 (18)	0.0028 (19)
C10	0.046 (3)	0.024 (3)	0.034 (2)	0.006 (2)	0.008 (2)	0.0005 (19)
C11	0.033 (3)	0.031 (3)	0.029 (2)	0.012 (2)	0.001 (2)	0.0048 (18)
C12	0.030 (2)	0.032 (3)	0.0154 (19)	0.0015 (19)	0.0005 (16)	0.0039 (18)
C13	0.029 (2)	0.021 (2)	0.0209 (19)	0.0030 (19)	0.0016 (17)	0.0032 (16)
C14	0.024 (2)	0.033 (2)	0.025 (2)	0.006 (2)	−0.0027 (15)	−0.001 (2)
C15	0.0164 (19)	0.026 (2)	0.025 (2)	−0.0022 (17)	−0.0028 (16)	0.0003 (18)
C16	0.026 (2)	0.027 (2)	0.023 (2)	−0.0034 (18)	0.0025 (17)	−0.0022 (19)
C17	0.029 (2)	0.026 (3)	0.037 (3)	0.000 (2)	−0.001 (2)	0.0009 (19)
C18	0.026 (2)	0.035 (3)	0.034 (2)	0.006 (2)	−0.0029 (18)	−0.011 (2)
C19	0.028 (2)	0.041 (3)	0.022 (2)	0.000 (2)	−0.0004 (18)	−0.007 (2)
C20	0.025 (2)	0.033 (3)	0.023 (2)	0.0019 (19)	−0.0047 (17)	−0.0009 (19)
C21	0.033 (2)	0.025 (2)	0.022 (2)	0.004 (2)	0.0037 (18)	−0.0007 (18)
C22	0.051 (3)	0.035 (3)	0.028 (2)	−0.006 (2)	−0.010 (2)	0.009 (2)
C23	0.090 (4)	0.038 (3)	0.026 (3)	−0.008 (3)	−0.018 (3)	0.011 (2)
C24	0.097 (5)	0.028 (3)	0.023 (2)	−0.003 (3)	0.009 (3)	0.001 (2)
C25	0.064 (4)	0.027 (3)	0.051 (3)	0.006 (2)	0.033 (3)	0.007 (2)
C26	0.037 (3)	0.036 (3)	0.038 (3)	0.003 (2)	0.010 (2)	0.004 (2)
C27	0.024 (2)	0.022 (3)	0.022 (2)	0.0012 (18)	0.0020 (16)	0.0017 (17)
C28	0.035 (2)	0.026 (2)	0.024 (2)	0.000 (2)	−0.0009 (18)	0.0009 (18)
C29	0.049 (3)	0.028 (3)	0.030 (2)	0.002 (2)	−0.008 (2)	−0.005 (2)
C30	0.054 (3)	0.037 (3)	0.026 (2)	0.013 (3)	0.000 (2)	−0.002 (2)
C31	0.035 (3)	0.042 (3)	0.042 (3)	0.014 (2)	0.007 (2)	−0.006 (2)
C32	0.030 (2)	0.034 (3)	0.035 (2)	0.004 (2)	−0.0032 (18)	−0.008 (2)
C33	0.0182 (19)	0.026 (3)	0.031 (2)	0.0057 (17)	−0.0006 (17)	0.0016 (19)
C34	0.025 (2)	0.032 (3)	0.0143 (19)	0.0026 (19)	−0.0022 (16)	−0.0022 (17)
C35	0.024 (2)	0.033 (3)	0.028 (2)	0.004 (2)	−0.0049 (18)	−0.008 (2)
C36	0.029 (2)	0.024 (2)	0.037 (2)	0.0005 (19)	−0.004 (2)	−0.001 (2)
C37	0.035 (3)	0.030 (3)	0.030 (3)	0.002 (2)	0.0010 (18)	0.0064 (19)
C38	0.033 (2)	0.027 (2)	0.023 (2)	−0.002 (2)	−0.0054 (18)	0.0038 (18)
O1	0.0281 (17)	0.0240 (18)	0.0486 (18)	−0.0031 (14)	−0.0016 (14)	0.0065 (14)
P1	0.0219 (5)	0.0240 (6)	0.0184 (5)	0.0014 (5)	−0.0008 (4)	0.0019 (4)
P2	0.0216 (5)	0.0233 (6)	0.0201 (5)	0.0025 (4)	−0.0010 (4)	−0.0015 (4)
Cl1	0.0315 (5)	0.0493 (7)	0.0240 (5)	0.0127 (6)	−0.0055 (5)	−0.0156 (5)
Cl2	0.0431 (6)	0.0392 (6)	0.0202 (5)	0.0120 (6)	−0.0053 (5)	−0.0078 (4)
Pd1	0.02104 (13)	0.02376 (15)	0.01704 (13)	0.00179 (16)	−0.00113 (14)	−0.00246 (14)

Geometric parameters (Å, º)

C1—C2	1.515 (6)	C20—H20	0.9300
C1—P1	1.835 (4)	C21—C22	1.384 (6)
C1—H1A	0.9700	C21—C26	1.391 (6)
C1—H1B	0.9700	C21—P1	1.812 (4)
C2—C7	1.383 (6)	C22—C23	1.391 (6)
C2—C3	1.389 (5)	C22—H22	0.9300
C3—C4	1.389 (6)	C23—C24	1.356 (8)
C3—H3	0.9300	C23—H23	0.9300
C4—C5	1.379 (6)	C24—C25	1.371 (8)
C4—H4	0.9300	C24—H24	0.9300
C5—C6	1.387 (6)	C25—C26	1.394 (6)
C5—H5	0.9300	C25—H25	0.9300
C6—C7	1.381 (6)	C26—H26	0.9300
C6—O1	1.396 (5)	C27—C28	1.390 (6)
C7—H7	0.9300	C27—C32	1.393 (6)
C8—C9	1.383 (6)	C27—P2	1.817 (4)
C8—O1	1.388 (5)	C28—C29	1.380 (6)
C8—C13	1.393 (6)	C28—H28	0.9300
C9—C10	1.380 (6)	C29—C30	1.382 (7)
C9—H9	0.9300	C29—H29	0.9300
C10—C11	1.387 (6)	C30—C31	1.363 (7)
C10—H10	0.9300	C30—H30	0.9300
C11—C12	1.382 (6)	C31—C32	1.389 (6)
C11—H11	0.9300	C31—H31	0.9300
C12—C13	1.405 (6)	C32—H32	0.9300
C12—C14	1.506 (6)	C33—C34	1.389 (5)
C13—H13	0.9300	C33—C38	1.409 (5)
C14—P2	1.843 (4)	C33—P2	1.808 (4)
C14—H14A	0.9700	C34—C35	1.384 (6)
C14—H14B	0.9700	C34—H34	0.9300
C15—C16	1.399 (6)	C35—C36	1.372 (6)
C15—C20	1.408 (5)	C35—H35	0.9300
C15—P1	1.819 (4)	C36—C37	1.390 (6)
C16—C17	1.381 (6)	C36—H36	0.9300
C16—H16	0.9300	C37—C38	1.370 (6)
C17—C18	1.389 (6)	C37—H37	0.9300
C17—H17	0.9300	C38—H38	0.9300
C18—C19	1.381 (6)	P1—Pd1	2.3341 (11)
C18—H18	0.9300	P2—Pd1	2.3275 (10)
C19—C20	1.381 (6)	Cl1—Pd1	2.3034 (9)
C19—H19	0.9300	Cl2—Pd1	2.2916 (9)
C2—C1—P1	115.1 (3)	C21—C22—H22	119.6
C2—C1—H1A	108.5	C23—C22—H22	119.6
P1—C1—H1A	108.5	C24—C23—C22	119.9 (5)
C2—C1—H1B	108.5	C24—C23—H23	120.1
P1—C1—H1B	108.5	C22—C23—H23	120.1
H1A—C1—H1B	107.5	C23—C24—C25	121.2 (4)
C7—C2—C3	119.2 (4)	C23—C24—H24	119.4
C7—C2—C1	121.1 (3)	C25—C24—H24	119.4
C3—C2—C1	119.6 (4)	C24—C25—C26	119.2 (5)
C4—C3—C2	120.5 (4)	C24—C25—H25	120.4
C4—C3—H3	119.7	C26—C25—H25	120.4
C2—C3—H3	119.7	C21—C26—C25	120.8 (5)
C5—C4—C3	120.1 (4)	C21—C26—H26	119.6
C5—C4—H4	120.0	C25—C26—H26	119.6
C3—C4—H4	120.0	C28—C27—C32	118.7 (4)
C4—C5—C6	119.3 (4)	C28—C27—P2	119.1 (3)
C4—C5—H5	120.3	C32—C27—P2	122.2 (3)
C6—C5—H5	120.3	C29—C28—C27	120.9 (4)
C7—C6—C5	120.8 (4)	C29—C28—H28	119.5
C7—C6—O1	122.9 (4)	C27—C28—H28	119.5
C5—C6—O1	116.1 (4)	C28—C29—C30	119.7 (5)
C6—C7—C2	120.1 (4)	C28—C29—H29	120.2
C6—C7—H7	120.0	C30—C29—H29	120.2
C2—C7—H7	120.0	C31—C30—C29	120.2 (4)
C9—C8—O1	115.2 (4)	C31—C30—H30	119.9
C9—C8—C13	121.3 (4)	C29—C30—H30	119.9
O1—C8—C13	123.4 (4)	C30—C31—C32	120.7 (4)
C10—C9—C8	119.3 (4)	C30—C31—H31	119.6
C10—C9—H9	120.3	C32—C31—H31	119.6
C8—C9—H9	120.3	C31—C32—C27	119.8 (4)
C9—C10—C11	120.1 (4)	C31—C32—H32	120.1
C9—C10—H10	120.0	C27—C32—H32	120.1
C11—C10—H10	120.0	C34—C33—C38	118.7 (4)
C12—C11—C10	121.2 (4)	C34—C33—P2	123.8 (3)
C12—C11—H11	119.4	C38—C33—P2	117.3 (3)
C10—C11—H11	119.4	C35—C34—C33	120.5 (4)
C11—C12—C13	119.1 (4)	C35—C34—H34	119.7
C11—C12—C14	121.0 (4)	C33—C34—H34	119.7
C13—C12—C14	119.9 (4)	C36—C35—C34	120.4 (4)
C8—C13—C12	119.0 (4)	C36—C35—H35	119.8
C8—C13—H13	120.5	C34—C35—H35	119.8
C12—C13—H13	120.5	C35—C36—C37	119.7 (4)
C12—C14—P2	110.2 (3)	C35—C36—H36	120.1
C12—C14—H14A	109.6	C37—C36—H36	120.1
P2—C14—H14A	109.6	C38—C37—C36	120.6 (4)
C12—C14—H14B	109.6	C38—C37—H37	119.7
P2—C14—H14B	109.6	C36—C37—H37	119.7
H14A—C14—H14B	108.1	C37—C38—C33	120.0 (4)
C16—C15—C20	117.9 (4)	C37—C38—H38	120.0
C16—C15—P1	122.3 (3)	C33—C38—H38	120.0
C20—C15—P1	119.8 (3)	C8—O1—C6	120.3 (3)
C17—C16—C15	121.5 (4)	C21—P1—C15	104.38 (19)
C17—C16—H16	119.3	C21—P1—C1	103.52 (18)
C15—C16—H16	119.3	C15—P1—C1	105.87 (19)
C16—C17—C18	119.7 (4)	C21—P1—Pd1	111.39 (14)
C16—C17—H17	120.1	C15—P1—Pd1	119.94 (13)
C18—C17—H17	120.1	C1—P1—Pd1	110.35 (14)
C19—C18—C17	119.8 (4)	C33—P2—C27	105.66 (18)
C19—C18—H18	120.1	C33—P2—C14	106.51 (18)
C17—C18—H18	120.1	C27—P2—C14	102.96 (19)
C18—C19—C20	120.8 (4)	C33—P2—Pd1	106.14 (13)
C18—C19—H19	119.6	C27—P2—Pd1	120.61 (13)
C20—C19—H19	119.6	C14—P2—Pd1	113.97 (13)
C19—C20—C15	120.4 (4)	Cl2—Pd1—Cl1	179.21 (4)
C19—C20—H20	119.8	Cl2—Pd1—P2	93.15 (4)
C15—C20—H20	119.8	Cl1—Pd1—P2	86.06 (4)
C22—C21—C26	118.1 (4)	Cl2—Pd1—P1	86.02 (4)
C22—C21—P1	122.3 (3)	Cl1—Pd1—P1	94.77 (4)
C26—C21—P1	119.5 (3)	P2—Pd1—P1	176.50 (4)
C21—C22—C23	120.8 (5)
P1—C1—C2—C7	−81.4 (4)	C34—C35—C36—C37	0.1 (6)
P1—C1—C2—C3	99.0 (4)	C35—C36—C37—C38	0.8 (6)
C7—C2—C3—C4	−0.5 (6)	C36—C37—C38—C33	−1.8 (6)
C1—C2—C3—C4	179.1 (4)	C34—C33—C38—C37	1.8 (6)
C2—C3—C4—C5	0.4 (6)	P2—C33—C38—C37	177.0 (3)
C3—C4—C5—C6	0.8 (6)	C9—C8—O1—C6	−169.3 (3)
C4—C5—C6—C7	−1.9 (6)	C13—C8—O1—C6	12.3 (6)
C4—C5—C6—O1	−177.1 (4)	C7—C6—O1—C8	56.8 (5)
C5—C6—C7—C2	1.8 (6)	C5—C6—O1—C8	−128.2 (4)
O1—C6—C7—C2	176.7 (4)	C22—C21—P1—C15	−81.7 (4)
C3—C2—C7—C6	−0.6 (6)	C26—C21—P1—C15	101.0 (4)
C1—C2—C7—C6	179.8 (4)	C22—C21—P1—C1	28.9 (4)
O1—C8—C9—C10	−178.8 (4)	C26—C21—P1—C1	−148.3 (4)
C13—C8—C9—C10	−0.3 (6)	C22—C21—P1—Pd1	147.5 (3)
C8—C9—C10—C11	−0.6 (6)	C26—C21—P1—Pd1	−29.8 (4)
C9—C10—C11—C12	−0.3 (6)	C16—C15—P1—C21	−2.5 (4)
C10—C11—C12—C13	2.1 (6)	C20—C15—P1—C21	178.8 (3)
C10—C11—C12—C14	−176.4 (4)	C16—C15—P1—C1	−111.4 (3)
C9—C8—C13—C12	2.1 (6)	C20—C15—P1—C1	69.9 (3)
O1—C8—C13—C12	−179.6 (3)	C16—C15—P1—Pd1	123.1 (3)
C11—C12—C13—C8	−3.0 (5)	C20—C15—P1—Pd1	−55.6 (3)
C14—C12—C13—C8	175.5 (3)	C2—C1—P1—C21	172.7 (3)
C11—C12—C14—P2	107.0 (4)	C2—C1—P1—C15	−77.8 (3)
C13—C12—C14—P2	−71.5 (4)	C2—C1—P1—Pd1	53.4 (3)
C20—C15—C16—C17	−0.8 (6)	C34—C33—P2—C27	−129.5 (3)
P1—C15—C16—C17	−179.6 (3)	C38—C33—P2—C27	55.6 (3)
C15—C16—C17—C18	1.1 (6)	C34—C33—P2—C14	−20.5 (4)
C16—C17—C18—C19	−1.4 (6)	C38—C33—P2—C14	164.6 (3)
C17—C18—C19—C20	1.4 (6)	C34—C33—P2—Pd1	101.3 (3)
C18—C19—C20—C15	−1.2 (6)	C38—C33—P2—Pd1	−73.6 (3)
C16—C15—C20—C19	0.8 (6)	C28—C27—P2—C33	−168.6 (3)
P1—C15—C20—C19	179.6 (3)	C32—C27—P2—C33	14.5 (4)
C26—C21—C22—C23	1.3 (7)	C28—C27—P2—C14	79.8 (3)
P1—C21—C22—C23	−176.0 (4)	C32—C27—P2—C14	−97.0 (4)
C21—C22—C23—C24	0.1 (8)	C28—C27—P2—Pd1	−48.5 (4)
C22—C23—C24—C25	−1.7 (8)	C32—C27—P2—Pd1	134.6 (3)
C23—C24—C25—C26	1.8 (8)	C12—C14—P2—C33	−171.9 (3)
C22—C21—C26—C25	−1.2 (7)	C12—C14—P2—C27	−61.0 (3)
P1—C21—C26—C25	176.2 (4)	C12—C14—P2—Pd1	71.4 (3)
C24—C25—C26—C21	−0.3 (7)	C33—P2—Pd1—Cl2	113.33 (14)
C32—C27—C28—C29	0.1 (6)	C27—P2—Pd1—Cl2	−6.52 (16)
P2—C27—C28—C29	−176.8 (3)	C14—P2—Pd1—Cl2	−129.77 (16)
C27—C28—C29—C30	−0.7 (6)	C33—P2—Pd1—Cl1	−66.78 (14)
C28—C29—C30—C31	0.4 (7)	C27—P2—Pd1—Cl1	173.37 (16)
C29—C30—C31—C32	0.3 (7)	C14—P2—Pd1—Cl1	50.12 (16)
C30—C31—C32—C27	−0.9 (7)	C21—P1—Pd1—Cl2	−49.90 (15)
C28—C27—C32—C31	0.6 (6)	C15—P1—Pd1—Cl2	−172.13 (16)
P2—C27—C32—C31	177.5 (3)	C1—P1—Pd1—Cl2	64.49 (13)
C38—C33—C34—C35	−0.9 (6)	C21—P1—Pd1—Cl1	130.16 (15)
P2—C33—C34—C35	−175.8 (3)	C15—P1—Pd1—Cl1	7.93 (16)
C33—C34—C35—C36	−0.1 (6)	C1—P1—Pd1—Cl1	−115.45 (13)

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
C1—H1B···Cl2	0.97	3.09	3.565 (4)	112