μ-Chloro-μ-diphenyl­phosphido-μ-hydrido-bis­[(η⁶-hexa­methyl­benzene)ruthenium(II)] tetra­fluoro­borate

The new triple-bridged dinuclear cation [(η⁶-C₆Me₆)₂Ru₂(μ₂-Cl)(μ₂-H)(μ₂-PPh₂)]⁺ was formed in chloro­form from the precursor [(η⁶-C₆Me₆)₂Ru₂(μ₂-H)₂(μ₂-PPh₂)]⁺ and characterized as the tetra­fluoro­borate salt [(η⁶-C₁₂H₁₈)₂Ru₂(μ₂-Cl)(μ₂-H){μ₂-P(C₆H₅)₂}]BF₄. The single-crystal X-ray structure analysis confirms the formation of the meso form. Despite the presence of two stereogenic centres, the complex is not chiral.

Key indicators

• Single-crystal X-ray study
• T = 173 K
• Mean [sigma](C-C) = 0.007 Å
• R factor = 0.032
• wR factor = 0.097
• Data-to-parameter ratio = 15.7

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT230_ALERT_2_B Hirshfeld Test Diff for    C5     -   C6      ..      11.61 su

Alert level C
PLAT029_ALERT_3_C _diffrn_measured_fraction_theta_full Low .......       0.97
PLAT062_ALERT_4_C Rescale T(min) & T(max) by .....................       1.02
PLAT213_ALERT_2_C Atom C6      has ADP max/min Ratio .............       3.70 prolat
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.32 Ratio
PLAT222_ALERT_3_C Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       3.37 Ratio
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for         B1
PLAT333_ALERT_2_C Large Average Benzene C-C Dist.  C19    -C24           1.43 Ang.
PLAT412_ALERT_2_C Short Intra XH3 .. XHn     H33C   ..  H34B    ..       1.86 Ang.

   0 ALERT level A = In general: serious problem
   1 ALERT level B = Potentially serious problem
   8 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   5 ALERT type 2 Indicator that the structure model may be wrong or deficient
   2 ALERT type 3 Indicator that the structure quality may be low
   2 ALERT type 4 Improvement, methodology, query or suggestion

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Computing details

Data collection: EXPOSE in IPDS Software (Stoe & Cie, 2000); cell refinement: CELL in IPDS Software; data reduction: INTEGRATE in IPDS Software; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-32 (Farrugia, 1997); software used to prepare material for publication: SHELXL97 and Mercury (Bruno et al., 2002).

µ-Chloro-µ-diphenylphosphido-µ-hydrido- bis[(η⁶-hexamethylbenzene)ruthenium(II)] tetrafluoroborate

Crystal data

[Ru2ClH(C12H10P)(C10H15)2]BF4	F(000) = 1696
Mr = 835.11	Dx = 1.595 Mg m^−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 8000 reflections
a = 13.5299 (8) Å	θ = 2.0–25.9°
b = 12.8959 (12) Å	µ = 1.04 mm^−1
c = 20.6136 (13) Å	T = 173 K
β = 104.778 (7)°	Block, red
V = 3477.7 (5) Å^3	0.39 × 0.14 × 0.11 mm
Z = 4

Data collection

Stoe IPDS diffractometer	6613 independent reflections
Radiation source: fine-focus sealed tube	4899 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.049
Detector resolution: 0.81Å pixels mm^-1	θmax = 25.9°, θmin = 2.0°
phi oscillation scans	h = −16→16
Absorption correction: part of the refinement model (ΔF) (Walker & Stuart, 1983)	k = −15→15
Tmin = 0.593, Tmax = 0.877	l = −25→25
22538 measured reflections

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.033	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.097	H atoms treated by a mixture of independent and constrained refinement
S = 1.02	w = 1/[σ^2(Fo^2) + (0.0578P)^2] where P = (Fo^2 + 2Fc^2)/3
6613 reflections	(Δ/σ)max = 0.001
422 parameters	Δρmax = 2.05 e Å^−3
0 restraints	Δρmin = −1.32 e Å^−3

Special details

Experimental. A crystal was mounted at 173 K on a Stoe Image Plate Diffraction System (Stoe & Cie, 2000) using Mo Kα graphite monochromated radiation. Image plate distance 70 mm, φ oscillation scans 0 - 200°, step Δφ = 1.2°, 1 minutes per frame.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
C1	0.0466 (3)	0.7229 (3)	−0.0231 (2)	0.0204 (9)
C2	−0.0231 (3)	0.6483 (3)	−0.0124 (2)	0.0251 (10)
H2	−0.0060	0.6066	0.0256	0.030*
C3	−0.1166 (4)	0.6364 (3)	−0.0577 (2)	0.0307 (11)
H3	−0.1615	0.5859	−0.0502	0.037*
C4	−0.1448 (4)	0.6985 (3)	−0.1143 (2)	0.0311 (11)
H4	−0.2076	0.6897	−0.1452	0.037*
C5	−0.0772 (4)	0.7740 (4)	−0.1239 (2)	0.0374 (12)
H5	−0.0954	0.8169	−0.1613	0.045*
C6	0.0164 (3)	0.7864 (4)	−0.0791 (2)	0.0265 (10)
H6	0.0603	0.8381	−0.0863	0.032*
C7	0.2379 (3)	0.6180 (3)	0.0094 (2)	0.0209 (9)
C8	0.1954 (4)	0.5570 (3)	−0.0476 (2)	0.0298 (11)
H8	0.1315	0.5736	−0.0750	0.036*
C9	0.2480 (4)	0.4729 (4)	−0.0632 (3)	0.0382 (13)
H9	0.2188	0.4329	−0.1007	0.046*
C10	0.3429 (5)	0.4473 (4)	−0.0240 (3)	0.0429 (14)
H10	0.3779	0.3907	−0.0351	0.051*
C11	0.3864 (4)	0.5062 (4)	0.0322 (3)	0.0403 (13)
H11	0.4505	0.4887	0.0591	0.048*
C12	0.3346 (4)	0.5915 (3)	0.0486 (2)	0.0295 (11)
H12	0.3647	0.6313	0.0861	0.035*
C13	0.2515 (4)	0.6495 (3)	0.2075 (2)	0.0265 (10)
C14	0.1450 (4)	0.6632 (4)	0.1989 (2)	0.0311 (11)
C15	0.1057 (4)	0.7593 (4)	0.2127 (2)	0.0312 (11)
C16	0.1747 (4)	0.8423 (4)	0.2397 (2)	0.0315 (11)
C17	0.2808 (4)	0.8313 (3)	0.2494 (2)	0.0288 (11)
C18	0.3187 (4)	0.7345 (4)	0.2296 (2)	0.0273 (10)
C19	0.2616 (3)	1.0427 (3)	−0.0139 (2)	0.0228 (9)
C20	0.2590 (3)	0.9640 (3)	−0.0630 (2)	0.0233 (9)
C21	0.3298 (4)	0.8795 (3)	−0.0471 (2)	0.0244 (10)
C22	0.4095 (3)	0.8801 (3)	0.0142 (2)	0.0252 (10)
C23	0.4154 (3)	0.9643 (3)	0.0606 (2)	0.0221 (9)
C24	0.3414 (3)	1.0457 (3)	0.0468 (2)	0.0212 (9)
C25	0.2937 (5)	0.5428 (4)	0.1983 (3)	0.0491 (15)
H25A	0.3657	0.5480	0.2018	0.074*
H25B	0.2595	0.5161	0.1549	0.074*
H25C	0.2826	0.4968	0.2324	0.074*
C26	0.0753 (6)	0.5699 (5)	0.1762 (3)	0.064 (2)
H26A	0.0809	0.5232	0.2132	0.096*
H26B	0.0953	0.5348	0.1405	0.096*
H26C	0.0058	0.5930	0.1606	0.096*
C27	−0.0085 (4)	0.7740 (6)	0.2011 (3)	0.068 (2)
H27A	−0.0429	0.7442	0.1587	0.101*
H27B	−0.0238	0.8466	0.2010	0.101*
H27C	−0.0311	0.7403	0.2363	0.101*
C28	0.1292 (6)	0.9434 (5)	0.2545 (3)	0.063 (2)
H28A	0.1824	0.9942	0.2677	0.095*
H28B	0.0963	0.9335	0.2901	0.095*
H28C	0.0799	0.9669	0.2150	0.095*
C29	0.3516 (5)	0.9190 (5)	0.2789 (3)	0.0533 (16)
H29A	0.3335	0.9796	0.2515	0.080*
H29B	0.4208	0.8996	0.2806	0.080*
H29C	0.3458	0.9335	0.3235	0.080*
C30	0.4326 (4)	0.7236 (5)	0.2375 (3)	0.0451 (14)
H30A	0.4648	0.6998	0.2820	0.068*
H30B	0.4606	0.7896	0.2301	0.068*
H30C	0.4445	0.6744	0.2053	0.068*
C31	0.1813 (4)	1.1261 (4)	−0.0267 (3)	0.0358 (12)
H31A	0.2021	1.1819	−0.0511	0.054*
H31B	0.1729	1.1516	0.0153	0.054*
H31C	0.1177	1.0980	−0.0526	0.054*
C32	0.1843 (4)	0.9739 (4)	−0.1316 (2)	0.0396 (13)
H32A	0.1165	0.9842	−0.1263	0.059*
H32B	0.1860	0.9117	−0.1569	0.059*
H32C	0.2032	1.0320	−0.1549	0.059*
C33	0.3239 (5)	0.7919 (4)	−0.0964 (3)	0.0404 (13)
H33A	0.3613	0.8103	−0.1286	0.061*
H33B	0.2537	0.7792	−0.1192	0.061*
H33C	0.3530	0.7304	−0.0729	0.061*
C34	0.4904 (4)	0.7977 (4)	0.0285 (3)	0.0419 (13)
H34A	0.5551	0.8276	0.0278	0.063*
H34B	0.4731	0.7444	−0.0050	0.063*
H34C	0.4949	0.7682	0.0720	0.063*
C35	0.4987 (4)	0.9648 (4)	0.1248 (2)	0.0372 (12)
H35A	0.5582	0.9983	0.1173	0.056*
H35B	0.5153	0.8948	0.1393	0.056*
H35C	0.4758	1.0017	0.1587	0.056*
C36	0.3462 (5)	1.1340 (4)	0.0958 (3)	0.0424 (13)
H36A	0.4155	1.1434	0.1215	0.064*
H36B	0.3039	1.1180	0.1255	0.064*
H36C	0.3222	1.1965	0.0716	0.064*
F1	0.6116 (2)	0.6672 (3)	0.16360 (16)	0.0538 (8)
F2	0.6649 (4)	0.8021 (4)	0.2332 (3)	0.128 (2)
F3	0.7742 (4)	0.6721 (3)	0.2268 (3)	0.130 (2)
F4	0.7215 (5)	0.7797 (6)	0.1459 (3)	0.152 (3)
B1	0.6934 (5)	0.7265 (4)	0.1971 (3)	0.0329 (13)
P1	0.17560 (9)	0.73290 (7)	0.03134 (5)	0.0175 (2)
Cl1	0.11116 (8)	0.93211 (7)	0.07889 (5)	0.0228 (2)
Ru1	0.20186 (3)	0.78688 (2)	0.142178 (15)	0.01637 (10)
H1H	0.284 (4)	0.846 (4)	0.115 (3)	0.047 (15)*
Ru2	0.25897 (3)	0.89129 (2)	0.036807 (15)	0.01564 (10)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
C1	0.025 (3)	0.018 (2)	0.019 (2)	−0.0001 (17)	0.0064 (19)	−0.0021 (15)
C2	0.022 (3)	0.024 (2)	0.025 (2)	−0.0026 (18)	−0.001 (2)	0.0022 (17)
C3	0.026 (3)	0.027 (2)	0.037 (3)	−0.009 (2)	0.004 (2)	−0.0030 (19)
C4	0.033 (3)	0.030 (2)	0.028 (2)	0.001 (2)	0.004 (2)	−0.0104 (19)
C5	0.052 (4)	0.032 (3)	0.029 (2)	0.001 (2)	0.010 (3)	0.008 (2)
C6	0.011 (2)	0.037 (2)	0.023 (2)	−0.0061 (19)	−0.011 (2)	0.0089 (18)
C7	0.025 (3)	0.018 (2)	0.022 (2)	0.0014 (17)	0.010 (2)	0.0036 (16)
C8	0.042 (3)	0.023 (2)	0.026 (2)	0.002 (2)	0.012 (2)	−0.0023 (18)
C9	0.054 (4)	0.029 (2)	0.036 (3)	0.000 (2)	0.020 (3)	−0.006 (2)
C10	0.052 (4)	0.031 (3)	0.054 (3)	0.014 (2)	0.029 (3)	−0.001 (2)
C11	0.038 (3)	0.040 (3)	0.045 (3)	0.018 (2)	0.013 (3)	0.008 (2)
C12	0.032 (3)	0.031 (2)	0.026 (2)	0.005 (2)	0.010 (2)	0.0027 (18)
C13	0.045 (3)	0.019 (2)	0.015 (2)	0.002 (2)	0.007 (2)	0.0051 (16)
C14	0.035 (3)	0.038 (3)	0.019 (2)	−0.013 (2)	0.002 (2)	0.0094 (18)
C15	0.021 (3)	0.056 (3)	0.018 (2)	0.005 (2)	0.008 (2)	0.014 (2)
C16	0.045 (3)	0.037 (3)	0.016 (2)	0.014 (2)	0.016 (2)	0.0085 (18)
C17	0.046 (3)	0.025 (2)	0.015 (2)	−0.006 (2)	0.008 (2)	0.0013 (17)
C18	0.025 (3)	0.041 (3)	0.015 (2)	0.007 (2)	0.005 (2)	0.0116 (18)
C19	0.026 (3)	0.019 (2)	0.026 (2)	−0.0019 (17)	0.012 (2)	0.0063 (16)
C20	0.028 (3)	0.026 (2)	0.0164 (19)	−0.0058 (18)	0.0067 (19)	0.0049 (16)
C21	0.031 (3)	0.025 (2)	0.022 (2)	−0.0044 (19)	0.015 (2)	−0.0001 (17)
C22	0.025 (3)	0.026 (2)	0.029 (2)	0.0026 (19)	0.017 (2)	0.0077 (18)
C23	0.015 (2)	0.029 (2)	0.022 (2)	−0.0081 (18)	0.0032 (19)	0.0058 (17)
C24	0.017 (2)	0.024 (2)	0.021 (2)	−0.0090 (17)	0.0025 (19)	−0.0003 (16)
C25	0.087 (5)	0.024 (2)	0.038 (3)	0.011 (3)	0.020 (3)	0.008 (2)
C26	0.081 (5)	0.061 (4)	0.044 (3)	−0.042 (4)	0.004 (3)	0.013 (3)
C27	0.026 (4)	0.127 (6)	0.053 (4)	0.016 (4)	0.016 (3)	0.028 (4)
C28	0.101 (6)	0.055 (4)	0.043 (3)	0.034 (4)	0.036 (4)	0.004 (3)
C29	0.071 (5)	0.049 (3)	0.033 (3)	−0.023 (3)	0.000 (3)	−0.006 (2)
C30	0.015 (3)	0.081 (4)	0.038 (3)	0.011 (3)	0.003 (2)	0.016 (3)
C31	0.038 (3)	0.030 (3)	0.039 (3)	0.007 (2)	0.009 (3)	0.012 (2)
C32	0.051 (4)	0.046 (3)	0.018 (2)	−0.012 (3)	0.000 (2)	0.009 (2)
C33	0.060 (4)	0.034 (3)	0.034 (3)	−0.001 (2)	0.024 (3)	−0.007 (2)
C34	0.029 (3)	0.038 (3)	0.064 (4)	0.010 (2)	0.022 (3)	0.014 (2)
C35	0.018 (3)	0.055 (3)	0.032 (2)	−0.007 (2)	−0.005 (2)	0.010 (2)
C36	0.052 (4)	0.036 (3)	0.038 (3)	−0.006 (2)	0.008 (3)	−0.015 (2)
F1	0.037 (2)	0.061 (2)	0.0563 (19)	−0.0018 (16)	−0.0012 (17)	−0.0089 (16)
F2	0.082 (4)	0.113 (4)	0.165 (5)	0.022 (3)	−0.012 (4)	−0.092 (4)
F3	0.079 (4)	0.063 (3)	0.187 (5)	0.022 (3)	−0.079 (4)	−0.025 (3)
F4	0.107 (5)	0.201 (7)	0.143 (5)	−0.066 (4)	0.023 (4)	0.065 (5)
B1	0.025 (3)	0.032 (3)	0.038 (3)	0.009 (2)	0.000 (3)	0.002 (2)
P1	0.0193 (6)	0.0174 (5)	0.0156 (5)	−0.0001 (4)	0.0039 (5)	0.0004 (4)
Cl1	0.0237 (6)	0.0226 (5)	0.0241 (5)	0.0062 (4)	0.0097 (5)	0.0048 (4)
Ru1	0.0183 (2)	0.01754 (16)	0.01363 (16)	0.00044 (13)	0.00481 (14)	0.00178 (12)
Ru2	0.0173 (2)	0.01609 (16)	0.01369 (16)	−0.00019 (13)	0.00426 (14)	0.00121 (12)

Geometric parameters (Å, º)

C1—C6	1.389 (6)	C22—Ru2	2.207 (4)
C1—C2	1.403 (6)	C23—C24	1.428 (6)
C1—P1	1.823 (5)	C23—C35	1.503 (6)
C2—C3	1.375 (7)	C23—Ru2	2.253 (4)
C2—H2	0.9300	C24—C36	1.513 (6)
C3—C4	1.387 (7)	C24—Ru2	2.266 (4)
C3—H3	0.9300	C25—H25A	0.9600
C4—C5	1.383 (7)	C25—H25B	0.9600
C4—H4	0.9300	C25—H25C	0.9600
C5—C6	1.373 (7)	C26—H26A	0.9600
C5—H5	0.9300	C26—H26B	0.9600
C6—H6	0.9300	C26—H26C	0.9600
C7—C12	1.394 (7)	C27—H27A	0.9600
C7—C8	1.409 (6)	C27—H27B	0.9600
C7—P1	1.819 (4)	C27—H27C	0.9600
C8—C9	1.379 (6)	C28—H28A	0.9600
C8—H8	0.9300	C28—H28B	0.9600
C9—C10	1.371 (8)	C28—H28C	0.9600
C9—H9	0.9300	C29—H29A	0.9600
C10—C11	1.385 (8)	C29—H29B	0.9600
C10—H10	0.9300	C29—H29C	0.9600
C11—C12	1.392 (6)	C30—H30A	0.9600
C11—H11	0.9300	C30—H30B	0.9600
C12—H12	0.9300	C30—H30C	0.9600
C13—C14	1.417 (7)	C31—H31A	0.9600
C13—C18	1.424 (7)	C31—H31B	0.9600
C13—C25	1.520 (6)	C31—H31C	0.9600
C13—Ru1	2.223 (4)	C32—H32A	0.9600
C14—C15	1.407 (7)	C32—H32B	0.9600
C14—C26	1.527 (7)	C32—H32C	0.9600
C14—Ru1	2.227 (4)	C33—H33A	0.9600
C15—C16	1.435 (7)	C33—H33B	0.9600
C15—C27	1.513 (7)	C33—H33C	0.9600
C15—Ru1	2.214 (4)	C34—H34A	0.9600
C16—C17	1.405 (7)	C34—H34B	0.9600
C16—C28	1.506 (7)	C34—H34C	0.9600
C16—Ru1	2.250 (4)	C35—H35A	0.9600
C17—C18	1.447 (6)	C35—H35B	0.9600
C17—C29	1.507 (7)	C35—H35C	0.9600
C17—Ru1	2.270 (4)	C36—H36A	0.9600
C18—C30	1.514 (7)	C36—H36B	0.9600
C18—Ru1	2.180 (4)	C36—H36C	0.9600
C19—C20	1.427 (6)	F1—B1	1.377 (7)
C19—C24	1.429 (6)	F2—B1	1.341 (7)
C19—C31	1.503 (6)	F3—B1	1.313 (7)
C19—Ru2	2.219 (4)	F4—B1	1.391 (7)
C20—C21	1.432 (6)	P1—Ru2	2.3221 (10)
C20—C32	1.520 (6)	P1—Ru1	2.3274 (10)
C20—Ru2	2.260 (4)	Cl1—Ru1	2.4287 (10)
C21—C22	1.437 (7)	Cl1—Ru2	2.4319 (10)
C21—C33	1.508 (6)	Ru1—Ru2	2.8256 (4)
C21—Ru2	2.187 (4)	Ru1—H1H	1.57 (5)
C22—C23	1.436 (6)	Ru2—H1H	1.67 (5)
C22—C34	1.501 (6)
C6—C1—C2	117.9 (4)	H30A—C30—H30C	109.5
C6—C1—P1	120.1 (3)	H30B—C30—H30C	109.5
C2—C1—P1	121.9 (3)	C19—C31—H31A	109.5
C3—C2—C1	120.6 (4)	C19—C31—H31B	109.5
C3—C2—H2	119.7	H31A—C31—H31B	109.5
C1—C2—H2	119.7	C19—C31—H31C	109.5
C2—C3—C4	121.0 (4)	H31A—C31—H31C	109.5
C2—C3—H3	119.5	H31B—C31—H31C	109.5
C4—C3—H3	119.5	C20—C32—H32A	109.5
C5—C4—C3	118.5 (5)	C20—C32—H32B	109.5
C5—C4—H4	120.8	H32A—C32—H32B	109.5
C3—C4—H4	120.8	C20—C32—H32C	109.5
C6—C5—C4	121.0 (4)	H32A—C32—H32C	109.5
C6—C5—H5	119.5	H32B—C32—H32C	109.5
C4—C5—H5	119.5	C21—C33—H33A	109.5
C5—C6—C1	121.0 (4)	C21—C33—H33B	109.5
C5—C6—H6	119.5	H33A—C33—H33B	109.5
C1—C6—H6	119.5	C21—C33—H33C	109.5
C12—C7—C8	118.1 (4)	H33A—C33—H33C	109.5
C12—C7—P1	118.7 (3)	H33B—C33—H33C	109.5
C8—C7—P1	123.1 (4)	C22—C34—H34A	109.5
C9—C8—C7	120.5 (5)	C22—C34—H34B	109.5
C9—C8—H8	119.7	H34A—C34—H34B	109.5
C7—C8—H8	119.7	C22—C34—H34C	109.5
C10—C9—C8	120.9 (5)	H34A—C34—H34C	109.5
C10—C9—H9	119.6	H34B—C34—H34C	109.5
C8—C9—H9	119.6	C23—C35—H35A	109.5
C9—C10—C11	119.7 (4)	C23—C35—H35B	109.5
C9—C10—H10	120.2	H35A—C35—H35B	109.5
C11—C10—H10	120.2	C23—C35—H35C	109.5
C10—C11—C12	120.3 (5)	H35A—C35—H35C	109.5
C10—C11—H11	119.9	H35B—C35—H35C	109.5
C12—C11—H11	119.9	C24—C36—H36A	109.5
C11—C12—C7	120.6 (5)	C24—C36—H36B	109.5
C11—C12—H12	119.7	H36A—C36—H36B	109.5
C7—C12—H12	119.7	C24—C36—H36C	109.5
C14—C13—C18	119.3 (4)	H36A—C36—H36C	109.5
C14—C13—C25	120.0 (4)	H36B—C36—H36C	109.5
C18—C13—C25	120.5 (5)	F3—B1—F2	117.0 (6)
C14—C13—Ru1	71.6 (2)	F3—B1—F1	113.9 (5)
C18—C13—Ru1	69.5 (2)	F2—B1—F1	112.0 (5)
C25—C13—Ru1	135.3 (3)	F3—B1—F4	105.1 (6)
C15—C14—C13	120.7 (4)	F2—B1—F4	103.6 (6)
C15—C14—C26	121.4 (5)	F1—B1—F4	103.5 (5)
C13—C14—C26	117.9 (5)	C7—P1—C1	102.76 (19)
C15—C14—Ru1	71.0 (2)	C7—P1—Ru2	118.61 (14)
C13—C14—Ru1	71.3 (2)	C1—P1—Ru2	117.98 (13)
C26—C14—Ru1	132.3 (3)	C7—P1—Ru1	121.58 (14)
C14—C15—C16	119.5 (4)	C1—P1—Ru1	120.52 (13)
C14—C15—C27	120.1 (5)	Ru2—P1—Ru1	74.85 (3)
C16—C15—C27	120.4 (5)	Ru1—Cl1—Ru2	71.09 (3)
C14—C15—Ru1	72.1 (2)	C18—Ru1—C15	80.27 (16)
C16—C15—Ru1	72.6 (2)	C18—Ru1—C13	37.73 (18)
C27—C15—Ru1	128.5 (3)	C15—Ru1—C13	67.14 (17)
C17—C16—C15	121.3 (4)	C18—Ru1—C14	67.61 (17)
C17—C16—C28	120.9 (5)	C15—Ru1—C14	36.93 (18)
C15—C16—C28	117.7 (5)	C13—Ru1—C14	37.14 (18)
C17—C16—Ru1	72.7 (2)	C18—Ru1—C16	66.99 (17)
C15—C16—Ru1	69.9 (2)	C15—Ru1—C16	37.50 (19)
C28—C16—Ru1	128.6 (3)	C13—Ru1—C16	78.76 (15)
C16—C17—C18	118.0 (4)	C14—Ru1—C16	66.51 (17)
C16—C17—C29	120.2 (5)	C18—Ru1—C17	37.89 (17)
C18—C17—C29	121.7 (5)	C15—Ru1—C17	67.03 (17)
C16—C17—Ru1	71.1 (3)	C13—Ru1—C17	67.47 (16)
C18—C17—Ru1	67.7 (2)	C14—Ru1—C17	79.00 (16)
C29—C17—Ru1	132.5 (3)	C16—Ru1—C17	36.22 (18)
C13—C18—C17	120.7 (4)	C18—Ru1—P1	128.02 (12)
C13—C18—C30	120.8 (4)	C15—Ru1—P1	128.97 (14)
C17—C18—C30	118.3 (5)	C13—Ru1—P1	107.63 (11)
C13—C18—Ru1	72.8 (3)	C14—Ru1—P1	108.32 (12)
C17—C18—Ru1	74.4 (3)	C16—Ru1—P1	162.38 (14)
C30—C18—Ru1	128.4 (3)	C17—Ru1—P1	161.40 (13)
C20—C19—C24	121.0 (4)	C18—Ru1—Cl1	147.52 (13)
C20—C19—C31	119.9 (4)	C15—Ru1—Cl1	100.11 (13)
C24—C19—C31	119.0 (4)	C13—Ru1—Cl1	166.68 (13)
C20—C19—Ru2	73.0 (2)	C14—Ru1—Cl1	129.73 (14)
C24—C19—Ru2	73.2 (2)	C16—Ru1—Cl1	93.42 (12)
C31—C19—Ru2	127.9 (3)	C17—Ru1—Cl1	112.11 (12)
C19—C20—C21	119.1 (4)	P1—Ru1—Cl1	76.92 (4)
C19—C20—C32	119.3 (4)	C18—Ru1—Ru2	120.02 (11)
C21—C20—C32	121.6 (4)	C15—Ru1—Ru2	154.61 (13)
C19—C20—Ru2	69.9 (2)	C13—Ru1—Ru2	138.23 (12)
C21—C20—Ru2	68.4 (2)	C14—Ru1—Ru2	160.64 (12)
C32—C20—Ru2	136.7 (3)	C16—Ru1—Ru2	132.41 (12)
C20—C21—C22	120.3 (4)	C17—Ru1—Ru2	118.40 (11)
C20—C21—C33	119.9 (4)	P1—Ru1—Ru2	52.49 (3)
C22—C21—C33	119.7 (4)	Cl1—Ru1—Ru2	54.51 (2)
C20—C21—Ru2	74.0 (2)	C18—Ru1—H1H	91 (2)
C22—C21—Ru2	71.7 (2)	C15—Ru1—H1H	154.7 (19)
C33—C21—Ru2	128.8 (3)	C13—Ru1—H1H	118 (2)
C23—C22—C21	119.5 (4)	C14—Ru1—H1H	155 (2)
C23—C22—C34	119.4 (4)	C16—Ru1—H1H	117.2 (19)
C21—C22—C34	121.0 (4)	C17—Ru1—H1H	91 (2)
C23—C22—Ru2	73.0 (2)	P1—Ru1—H1H	74.9 (19)
C21—C22—Ru2	70.2 (2)	Cl1—Ru1—H1H	75 (2)
C34—C22—Ru2	132.1 (3)	Ru2—Ru1—H1H	30 (2)
C24—C23—C22	120.4 (4)	C21—Ru2—C22	38.18 (17)
C24—C23—C35	120.2 (4)	C21—Ru2—C19	68.01 (15)
C22—C23—C35	119.4 (4)	C22—Ru2—C19	80.28 (15)
C24—C23—Ru2	72.1 (2)	C21—Ru2—C23	67.95 (16)
C22—C23—Ru2	69.5 (2)	C22—Ru2—C23	37.55 (16)
C35—C23—Ru2	130.2 (3)	C19—Ru2—C23	66.91 (16)
C23—C24—C19	119.3 (4)	C21—Ru2—C20	37.53 (16)
C23—C24—C36	120.7 (4)	C22—Ru2—C20	67.68 (16)
C19—C24—C36	120.0 (4)	C19—Ru2—C20	37.13 (15)
C23—C24—Ru2	71.1 (2)	C23—Ru2—C20	78.84 (15)
C19—C24—Ru2	69.7 (2)	C21—Ru2—C24	80.08 (15)
C36—C24—Ru2	131.1 (3)	C22—Ru2—C24	67.47 (15)
C13—C25—H25A	109.5	C19—Ru2—C24	37.14 (16)
C13—C25—H25B	109.5	C23—Ru2—C24	36.84 (15)
H25A—C25—H25B	109.5	C20—Ru2—C24	66.64 (15)
C13—C25—H25C	109.5	C21—Ru2—P1	101.89 (11)
H25A—C25—H25C	109.5	C22—Ru2—P1	113.30 (11)
H25B—C25—H25C	109.5	C19—Ru2—P1	144.78 (12)
C14—C26—H26A	109.5	C23—Ru2—P1	142.74 (11)
C14—C26—H26B	109.5	C20—Ru2—P1	115.70 (11)
H26A—C26—H26B	109.5	C24—Ru2—P1	177.66 (10)
C14—C26—H26C	109.5	C21—Ru2—Cl1	149.73 (13)
H26A—C26—H26C	109.5	C22—Ru2—Cl1	167.59 (12)
H26B—C26—H26C	109.5	C19—Ru2—Cl1	95.22 (11)
C15—C27—H27A	109.5	C23—Ru2—Cl1	130.08 (11)
C15—C27—H27B	109.5	C20—Ru2—Cl1	115.21 (12)
H27A—C27—H27B	109.5	C24—Ru2—Cl1	102.01 (11)
C15—C27—H27C	109.5	P1—Ru2—Cl1	76.95 (4)
H27A—C27—H27C	109.5	C21—Ru2—Ru1	146.73 (11)
H27B—C27—H27C	109.5	C22—Ru2—Ru1	125.41 (11)
C16—C28—H28A	109.5	C19—Ru2—Ru1	145.26 (10)
C16—C28—H28B	109.5	C23—Ru2—Ru1	117.23 (10)
H28A—C28—H28B	109.5	C20—Ru2—Ru1	163.88 (12)
C16—C28—H28C	109.5	C24—Ru2—Ru1	125.03 (10)
H28A—C28—H28C	109.5	P1—Ru2—Ru1	52.66 (3)
H28B—C28—H28C	109.5	Cl1—Ru2—Ru1	54.40 (2)
C17—C29—H29A	109.5	C21—Ru2—H1H	135.8 (18)
C17—C29—H29B	109.5	C22—Ru2—H1H	102.0 (18)
H29A—C29—H29B	109.5	C19—Ru2—H1H	137.8 (18)
C17—C29—H29C	109.5	C23—Ru2—H1H	89.2 (19)
H29A—C29—H29C	109.5	C20—Ru2—H1H	168.0 (19)
H29B—C29—H29C	109.5	C24—Ru2—H1H	104.2 (18)
C18—C30—H30A	109.5	P1—Ru2—H1H	73.5 (18)
C18—C30—H30B	109.5	Cl1—Ru2—H1H	73.5 (18)
H30A—C30—H30B	109.5	Ru1—Ru2—H1H	28.2 (19)
C18—C30—H30C	109.5
C6—C1—C2—C3	2.5 (6)	C29—C17—Ru1—Cl1	−50.6 (6)
P1—C1—C2—C3	−174.1 (3)	C16—C17—Ru1—Ru2	124.0 (2)
C1—C2—C3—C4	−0.9 (7)	C18—C17—Ru1—Ru2	−103.4 (2)
C2—C3—C4—C5	−0.8 (7)	C29—C17—Ru1—Ru2	9.9 (6)
C3—C4—C5—C6	1.0 (7)	C7—P1—Ru1—C18	13.0 (2)
C4—C5—C6—C1	0.7 (7)	C1—P1—Ru1—C18	144.6 (2)
C2—C1—C6—C5	−2.4 (6)	Ru2—P1—Ru1—C18	−101.56 (16)
P1—C1—C6—C5	174.3 (4)	C7—P1—Ru1—C15	−97.9 (2)
C12—C7—C8—C9	0.9 (6)	C1—P1—Ru1—C15	33.7 (2)
P1—C7—C8—C9	177.5 (3)	Ru2—P1—Ru1—C15	147.55 (16)
C7—C8—C9—C10	−0.6 (7)	C7—P1—Ru1—C13	−23.4 (2)
C8—C9—C10—C11	0.4 (7)	C1—P1—Ru1—C13	108.2 (2)
C9—C10—C11—C12	−0.6 (7)	Ru2—P1—Ru1—C13	−137.95 (14)
C10—C11—C12—C7	0.9 (7)	C7—P1—Ru1—C14	−62.5 (2)
C8—C7—C12—C11	−1.1 (6)	C1—P1—Ru1—C14	69.1 (2)
P1—C7—C12—C11	−177.8 (3)	Ru2—P1—Ru1—C14	−177.06 (14)
C18—C13—C14—C15	−0.8 (6)	C7—P1—Ru1—C16	−132.3 (4)
C25—C13—C14—C15	174.6 (4)	C1—P1—Ru1—C16	−0.8 (4)
Ru1—C13—C14—C15	−53.1 (4)	Ru2—P1—Ru1—C16	113.1 (4)
C18—C13—C14—C26	−179.0 (4)	C7—P1—Ru1—C17	48.2 (4)
C25—C13—C14—C26	−3.7 (6)	C1—P1—Ru1—C17	179.8 (4)
Ru1—C13—C14—C26	128.6 (4)	Ru2—P1—Ru1—C17	−66.4 (3)
C18—C13—C14—Ru1	52.4 (3)	C7—P1—Ru1—Cl1	169.61 (16)
C25—C13—C14—Ru1	−132.3 (4)	C1—P1—Ru1—Cl1	−58.83 (15)
C13—C14—C15—C16	−3.8 (6)	Ru2—P1—Ru1—Cl1	55.04 (3)
C26—C14—C15—C16	174.4 (4)	C7—P1—Ru1—Ru2	114.57 (16)
Ru1—C14—C15—C16	−57.0 (3)	C1—P1—Ru1—Ru2	−113.86 (15)
C13—C14—C15—C27	177.9 (4)	Ru2—Cl1—Ru1—C18	91.4 (2)
C26—C14—C15—C27	−3.9 (6)	Ru2—Cl1—Ru1—C15	179.11 (14)
Ru1—C14—C15—C27	124.7 (4)	Ru2—Cl1—Ru1—C13	−164.6 (5)
C13—C14—C15—Ru1	53.2 (4)	Ru2—Cl1—Ru1—C14	−156.07 (16)
C26—C14—C15—Ru1	−128.6 (4)	Ru2—Cl1—Ru1—C16	141.93 (14)
C14—C15—C16—C17	3.2 (6)	Ru2—Cl1—Ru1—C17	109.93 (13)
C27—C15—C16—C17	−178.5 (4)	Ru2—Cl1—Ru1—P1	−52.98 (3)
Ru1—C15—C16—C17	−53.5 (4)	C20—C21—Ru2—C22	−130.3 (4)
C14—C15—C16—C28	−179.3 (4)	C33—C21—Ru2—C22	113.8 (5)
C27—C15—C16—C28	−1.0 (6)	C20—C21—Ru2—C19	−27.7 (3)
Ru1—C15—C16—C28	124.0 (4)	C22—C21—Ru2—C19	102.7 (3)
C14—C15—C16—Ru1	56.7 (3)	C33—C21—Ru2—C19	−143.5 (5)
C27—C15—C16—Ru1	−125.0 (4)	C20—C21—Ru2—C23	−100.6 (3)
C15—C16—C17—C18	1.8 (6)	C22—C21—Ru2—C23	29.7 (2)
C28—C16—C17—C18	−175.6 (4)	C33—C21—Ru2—C23	143.5 (5)
Ru1—C16—C17—C18	−50.5 (3)	C22—C21—Ru2—C20	130.3 (4)
C15—C16—C17—C29	−178.9 (4)	C33—C21—Ru2—C20	−115.9 (6)
C28—C16—C17—C29	3.7 (6)	C20—C21—Ru2—C24	−64.3 (3)
Ru1—C16—C17—C29	128.8 (4)	C22—C21—Ru2—C24	66.0 (2)
C15—C16—C17—Ru1	52.3 (3)	C33—C21—Ru2—C24	179.8 (5)
C28—C16—C17—Ru1	−125.1 (4)	C20—C21—Ru2—P1	117.0 (2)
C14—C13—C18—C17	5.9 (6)	C22—C21—Ru2—P1	−112.7 (2)
C25—C13—C18—C17	−169.4 (4)	C33—C21—Ru2—P1	1.1 (5)
Ru1—C13—C18—C17	59.3 (3)	C20—C21—Ru2—Cl1	32.5 (4)
C14—C13—C18—C30	−178.3 (4)	C22—C21—Ru2—Cl1	162.8 (2)
C25—C13—C18—C30	6.4 (6)	C33—C21—Ru2—Cl1	−83.3 (5)
Ru1—C13—C18—C30	−124.9 (4)	C20—C21—Ru2—Ru1	153.0 (2)
C14—C13—C18—Ru1	−53.3 (3)	C22—C21—Ru2—Ru1	−76.7 (3)
C25—C13—C18—Ru1	131.3 (4)	C33—C21—Ru2—Ru1	37.1 (6)
C16—C17—C18—C13	−6.4 (6)	C23—C22—Ru2—C21	131.1 (3)
C29—C17—C18—C13	174.3 (4)	C34—C22—Ru2—C21	−114.3 (6)
Ru1—C17—C18—C13	−58.5 (3)	C23—C22—Ru2—C19	64.5 (2)
C16—C17—C18—C30	177.7 (4)	C21—C22—Ru2—C19	−66.6 (2)
C29—C17—C18—C30	−1.6 (6)	C34—C22—Ru2—C19	179.1 (5)
Ru1—C17—C18—C30	125.6 (4)	C21—C22—Ru2—C23	−131.1 (3)
C16—C17—C18—Ru1	52.1 (3)	C34—C22—Ru2—C23	114.5 (6)
C29—C17—C18—Ru1	−127.2 (4)	C23—C22—Ru2—C20	101.0 (3)
C24—C19—C20—C21	8.2 (6)	C21—C22—Ru2—C20	−30.1 (2)
C31—C19—C20—C21	−173.8 (4)	C34—C22—Ru2—C20	−144.5 (5)
Ru2—C19—C20—C21	−49.4 (3)	C23—C22—Ru2—C24	28.1 (2)
C24—C19—C20—C32	−169.4 (4)	C21—C22—Ru2—C24	−103.1 (3)
C31—C19—C20—C32	8.6 (6)	C34—C22—Ru2—C24	142.6 (5)
Ru2—C19—C20—C32	133.0 (4)	C23—C22—Ru2—P1	−149.5 (2)
C24—C19—C20—Ru2	57.5 (3)	C21—C22—Ru2—P1	79.3 (2)
C31—C19—C20—Ru2	−124.4 (4)	C34—C22—Ru2—P1	−35.0 (5)
C19—C20—C21—C22	−6.9 (6)	C23—C22—Ru2—Cl1	−5.1 (7)
C32—C20—C21—C22	170.6 (4)	C21—C22—Ru2—Cl1	−136.2 (5)
Ru2—C20—C21—C22	−56.9 (3)	C34—C22—Ru2—Cl1	109.5 (6)
C19—C20—C21—C33	176.0 (4)	C23—C22—Ru2—Ru1	−89.8 (2)
C32—C20—C21—C33	−6.5 (6)	C21—C22—Ru2—Ru1	139.1 (2)
Ru2—C20—C21—C33	126.0 (4)	C34—C22—Ru2—Ru1	24.7 (5)
C19—C20—C21—Ru2	50.0 (3)	C20—C19—Ru2—C21	27.9 (3)
C32—C20—C21—Ru2	−132.4 (4)	C24—C19—Ru2—C21	−103.0 (3)
C20—C21—C22—C23	2.2 (5)	C31—C19—Ru2—C21	142.9 (5)
C33—C21—C22—C23	179.3 (4)	C20—C19—Ru2—C22	65.7 (3)
Ru2—C21—C22—C23	−55.8 (3)	C24—C19—Ru2—C22	−65.3 (2)
C20—C21—C22—C34	−174.0 (4)	C31—C19—Ru2—C22	−179.3 (4)
C33—C21—C22—C34	3.1 (6)	C20—C19—Ru2—C23	102.4 (3)
Ru2—C21—C22—C34	128.0 (4)	C24—C19—Ru2—C23	−28.6 (2)
C20—C21—C22—Ru2	58.1 (3)	C31—C19—Ru2—C23	−142.6 (4)
C33—C21—C22—Ru2	−124.8 (4)	C24—C19—Ru2—C20	−131.0 (4)
C21—C22—C23—C24	1.3 (5)	C31—C19—Ru2—C20	115.0 (5)
C34—C22—C23—C24	177.6 (4)	C20—C19—Ru2—C24	131.0 (4)
Ru2—C22—C23—C24	−53.1 (3)	C31—C19—Ru2—C24	−114.0 (5)
C21—C22—C23—C35	179.9 (4)	C20—C19—Ru2—P1	−51.3 (3)
C34—C22—C23—C35	−3.8 (6)	C24—C19—Ru2—P1	177.74 (18)
Ru2—C22—C23—C35	125.5 (3)	C31—C19—Ru2—P1	63.7 (5)
C21—C22—C23—Ru2	54.5 (3)	C20—C19—Ru2—Cl1	−126.0 (2)
C34—C22—C23—Ru2	−129.2 (4)	C24—C19—Ru2—Cl1	103.0 (2)
C22—C23—C24—C19	−0.2 (5)	C31—C19—Ru2—Cl1	−11.0 (4)
C35—C23—C24—C19	−178.8 (4)	C20—C19—Ru2—Ru1	−152.6 (2)
Ru2—C23—C24—C19	−52.1 (3)	C24—C19—Ru2—Ru1	76.4 (3)
C22—C23—C24—C36	179.2 (4)	C31—C19—Ru2—Ru1	−37.6 (5)
C35—C23—C24—C36	0.6 (6)	C24—C23—Ru2—C21	103.3 (3)
Ru2—C23—C24—C36	127.2 (4)	C22—C23—Ru2—C21	−30.1 (2)
C22—C23—C24—Ru2	51.9 (3)	C35—C23—Ru2—C21	−141.9 (5)
C35—C23—C24—Ru2	−126.7 (4)	C24—C23—Ru2—C22	133.5 (3)
C20—C19—C24—C23	−4.6 (5)	C35—C23—Ru2—C22	−111.7 (5)
C31—C19—C24—C23	177.3 (4)	C24—C23—Ru2—C19	28.8 (2)
Ru2—C19—C24—C23	52.8 (3)	C22—C23—Ru2—C19	−104.7 (3)
C20—C19—C24—C36	176.0 (4)	C35—C23—Ru2—C19	143.6 (5)
C31—C19—C24—C36	−2.1 (6)	C24—C23—Ru2—C20	65.7 (2)
Ru2—C19—C24—C36	−126.6 (4)	C22—C23—Ru2—C20	−67.8 (2)
C20—C19—C24—Ru2	−57.4 (3)	C35—C23—Ru2—C20	−179.5 (4)
C31—C19—C24—Ru2	124.5 (4)	C22—C23—Ru2—C24	−133.5 (3)
C12—C7—P1—C1	−170.5 (3)	C35—C23—Ru2—C24	114.8 (5)
C8—C7—P1—C1	12.9 (4)	C24—C23—Ru2—P1	−176.18 (17)
C12—C7—P1—Ru2	57.3 (3)	C22—C23—Ru2—P1	50.3 (3)
C8—C7—P1—Ru2	−119.2 (3)	C35—C23—Ru2—P1	−61.4 (5)
C12—C7—P1—Ru1	−31.9 (4)	C24—C23—Ru2—Cl1	−47.9 (3)
C8—C7—P1—Ru1	151.6 (3)	C22—C23—Ru2—Cl1	178.58 (19)
C6—C1—P1—C7	−105.1 (3)	C35—C23—Ru2—Cl1	66.8 (5)
C2—C1—P1—C7	71.4 (4)	C24—C23—Ru2—Ru1	−112.9 (2)
C6—C1—P1—Ru2	27.5 (4)	C22—C23—Ru2—Ru1	113.6 (2)
C2—C1—P1—Ru2	−156.0 (3)	C35—C23—Ru2—Ru1	1.8 (5)
C6—C1—P1—Ru1	115.7 (3)	C19—C20—Ru2—C21	−134.5 (4)
C2—C1—P1—Ru1	−67.8 (4)	C32—C20—Ru2—C21	113.7 (6)
C13—C18—Ru1—C15	65.0 (3)	C19—C20—Ru2—C22	−103.9 (3)
C17—C18—Ru1—C15	−64.9 (3)	C21—C20—Ru2—C22	30.6 (3)
C30—C18—Ru1—C15	−179.0 (5)	C32—C20—Ru2—C22	144.3 (5)
C17—C18—Ru1—C13	−129.9 (4)	C21—C20—Ru2—C19	134.5 (4)
C30—C18—Ru1—C13	116.0 (6)	C32—C20—Ru2—C19	−111.8 (6)
C13—C18—Ru1—C14	28.8 (2)	C19—C20—Ru2—C23	−66.3 (3)
C17—C18—Ru1—C14	−101.1 (3)	C21—C20—Ru2—C23	68.2 (3)
C30—C18—Ru1—C14	144.8 (5)	C32—C20—Ru2—C23	−178.1 (5)
C13—C18—Ru1—C16	101.7 (3)	C19—C20—Ru2—C24	−29.8 (3)
C17—C18—Ru1—C16	−28.2 (2)	C21—C20—Ru2—C24	104.7 (3)
C30—C18—Ru1—C16	−142.3 (5)	C32—C20—Ru2—C24	−141.6 (5)
C13—C18—Ru1—C17	129.9 (4)	C19—C20—Ru2—P1	150.0 (2)
C30—C18—Ru1—C17	−114.1 (6)	C21—C20—Ru2—P1	−75.5 (3)
C13—C18—Ru1—P1	−67.5 (3)	C32—C20—Ru2—P1	38.2 (5)
C17—C18—Ru1—P1	162.6 (2)	C19—C20—Ru2—Cl1	62.9 (3)
C30—C18—Ru1—P1	48.5 (5)	C21—C20—Ru2—Cl1	−162.6 (2)
C13—C18—Ru1—Cl1	158.6 (2)	C32—C20—Ru2—Cl1	−48.9 (5)
C17—C18—Ru1—Cl1	28.7 (4)	C19—C20—Ru2—Ru1	109.4 (4)
C30—C18—Ru1—Cl1	−85.4 (5)	C21—C20—Ru2—Ru1	−116.0 (4)
C13—C18—Ru1—Ru2	−131.4 (2)	C32—C20—Ru2—Ru1	−2.4 (8)
C17—C18—Ru1—Ru2	98.7 (2)	C23—C24—Ru2—C21	−66.3 (2)
C30—C18—Ru1—Ru2	−15.3 (5)	C19—C24—Ru2—C21	66.5 (2)
C14—C15—Ru1—C18	−65.5 (3)	C36—C24—Ru2—C21	179.0 (5)
C16—C15—Ru1—C18	64.7 (3)	C23—C24—Ru2—C22	−28.6 (2)
C27—C15—Ru1—C18	180.0 (6)	C19—C24—Ru2—C22	104.2 (3)
C14—C15—Ru1—C13	−28.5 (3)	C36—C24—Ru2—C22	−143.3 (5)
C16—C15—Ru1—C13	101.7 (3)	C23—C24—Ru2—C19	−132.8 (3)
C27—C15—Ru1—C13	−143.0 (6)	C36—C24—Ru2—C19	112.5 (5)
C16—C15—Ru1—C14	130.1 (4)	C19—C24—Ru2—C23	132.8 (3)
C27—C15—Ru1—C14	−114.5 (7)	C36—C24—Ru2—C23	−114.7 (5)
C14—C15—Ru1—C16	−130.1 (4)	C23—C24—Ru2—C20	−103.0 (3)
C27—C15—Ru1—C16	115.3 (7)	C19—C24—Ru2—C20	29.8 (2)
C14—C15—Ru1—C17	−102.6 (3)	C36—C24—Ru2—C20	142.3 (5)
C16—C15—Ru1—C17	27.5 (3)	C23—C24—Ru2—Cl1	144.5 (2)
C27—C15—Ru1—C17	142.8 (6)	C19—C24—Ru2—Cl1	−82.7 (2)
C14—C15—Ru1—P1	66.2 (3)	C36—C24—Ru2—Cl1	29.8 (5)
C16—C15—Ru1—P1	−163.7 (2)	C23—C24—Ru2—Ru1	89.8 (2)
C27—C15—Ru1—P1	−48.3 (6)	C19—C24—Ru2—Ru1	−137.44 (19)
C14—C15—Ru1—Cl1	147.5 (3)	C36—C24—Ru2—Ru1	−24.9 (5)
C16—C15—Ru1—Cl1	−82.4 (3)	C7—P1—Ru2—C21	38.0 (2)
C27—C15—Ru1—Cl1	33.0 (6)	C1—P1—Ru2—C21	−87.05 (19)
C14—C15—Ru1—Ru2	149.2 (3)	Ru1—P1—Ru2—C21	156.08 (13)
C16—C15—Ru1—Ru2	−80.7 (4)	C7—P1—Ru2—C22	−0.4 (2)
C27—C15—Ru1—Ru2	34.6 (8)	C1—P1—Ru2—C22	−125.42 (19)
C14—C13—Ru1—C18	132.5 (4)	Ru1—P1—Ru2—C22	117.71 (13)
C25—C13—Ru1—C18	−113.1 (6)	C7—P1—Ru2—C19	106.6 (2)
C14—C13—Ru1—C15	28.3 (3)	C1—P1—Ru2—C19	−18.5 (2)
C18—C13—Ru1—C15	−104.2 (3)	Ru1—P1—Ru2—C19	−135.35 (18)
C25—C13—Ru1—C15	142.7 (6)	C7—P1—Ru2—C23	−31.1 (2)
C18—C13—Ru1—C14	−132.5 (4)	C1—P1—Ru2—C23	−156.1 (2)
C25—C13—Ru1—C14	114.4 (6)	Ru1—P1—Ru2—C23	87.00 (17)
C14—C13—Ru1—C16	65.8 (3)	C7—P1—Ru2—C20	75.1 (2)
C18—C13—Ru1—C16	−66.8 (3)	C1—P1—Ru2—C20	−49.99 (19)
C25—C13—Ru1—C16	−179.8 (6)	Ru1—P1—Ru2—C20	−166.86 (13)
C14—C13—Ru1—C17	101.9 (3)	C7—P1—Ru2—Cl1	−172.98 (16)
C18—C13—Ru1—C17	−30.7 (2)	C1—P1—Ru2—Cl1	61.95 (14)
C25—C13—Ru1—C17	−143.7 (6)	Ru1—P1—Ru2—Cl1	−54.92 (3)
C14—C13—Ru1—P1	−97.3 (2)	C7—P1—Ru2—Ru1	−118.06 (17)
C18—C13—Ru1—P1	130.2 (2)	C1—P1—Ru2—Ru1	116.87 (14)
C25—C13—Ru1—P1	17.1 (6)	Ru1—Cl1—Ru2—C21	144.4 (2)
C14—C13—Ru1—Cl1	10.9 (6)	Ru1—Cl1—Ru2—C22	−93.6 (5)
C18—C13—Ru1—Cl1	−121.7 (5)	Ru1—Cl1—Ru2—C19	−161.68 (12)
C25—C13—Ru1—Cl1	125.3 (5)	Ru1—Cl1—Ru2—C23	−97.64 (14)
C14—C13—Ru1—Ru2	−150.2 (2)	Ru1—Cl1—Ru2—C20	165.66 (12)
C18—C13—Ru1—Ru2	77.3 (3)	Ru1—Cl1—Ru2—C24	−124.71 (11)
C25—C13—Ru1—Ru2	−35.8 (6)	Ru1—Cl1—Ru2—P1	53.14 (3)
C15—C14—Ru1—C18	104.1 (3)	C18—Ru1—Ru2—C21	70.6 (3)
C13—C14—Ru1—C18	−29.2 (2)	C15—Ru1—Ru2—C21	−149.7 (4)
C26—C14—Ru1—C18	−140.3 (6)	C13—Ru1—Ru2—C21	27.0 (3)
C13—C14—Ru1—C15	−133.3 (4)	C14—Ru1—Ru2—C21	−37.9 (5)
C26—C14—Ru1—C15	115.6 (7)	C16—Ru1—Ru2—C21	155.8 (3)
C15—C14—Ru1—C13	133.3 (4)	C17—Ru1—Ru2—C21	114.3 (3)
C26—C14—Ru1—C13	−111.1 (7)	P1—Ru1—Ru2—C21	−46.3 (2)
C15—C14—Ru1—C16	30.5 (3)	Cl1—Ru1—Ru2—C21	−147.7 (2)
C13—C14—Ru1—C16	−102.8 (3)	C18—Ru1—Ru2—C22	23.1 (2)
C26—C14—Ru1—C16	146.1 (6)	C15—Ru1—Ru2—C22	162.7 (3)
C15—C14—Ru1—C17	66.2 (3)	C13—Ru1—Ru2—C22	−20.5 (2)
C13—C14—Ru1—C17	−67.1 (3)	C14—Ru1—Ru2—C22	−85.5 (4)
C26—C14—Ru1—C17	−178.2 (6)	C16—Ru1—Ru2—C22	108.3 (2)
C15—C14—Ru1—P1	−131.5 (3)	C17—Ru1—Ru2—C22	66.7 (2)
C13—C14—Ru1—P1	95.2 (2)	P1—Ru1—Ru2—C22	−93.90 (15)
C26—C14—Ru1—P1	−15.9 (6)	Cl1—Ru1—Ru2—C22	164.74 (15)
C15—C14—Ru1—Cl1	−43.5 (3)	C18—Ru1—Ru2—C19	−108.4 (3)
C13—C14—Ru1—Cl1	−176.76 (19)	C15—Ru1—Ru2—C19	31.3 (4)
C26—C14—Ru1—Cl1	72.1 (6)	C13—Ru1—Ru2—C19	−152.0 (3)
C15—C14—Ru1—Ru2	−138.5 (3)	C14—Ru1—Ru2—C19	143.1 (5)
C13—C14—Ru1—Ru2	88.2 (4)	C16—Ru1—Ru2—C19	−23.2 (3)
C26—C14—Ru1—Ru2	−22.9 (9)	C17—Ru1—Ru2—C19	−64.7 (3)
C17—C16—Ru1—C18	29.4 (3)	P1—Ru1—Ru2—C19	134.7 (2)
C15—C16—Ru1—C18	−104.6 (3)	Cl1—Ru1—Ru2—C19	33.3 (2)
C28—C16—Ru1—C18	145.5 (6)	C18—Ru1—Ru2—C23	−20.20 (19)
C17—C16—Ru1—C15	134.0 (4)	C15—Ru1—Ru2—C23	119.4 (3)
C28—C16—Ru1—C15	−109.9 (6)	C13—Ru1—Ru2—C23	−63.8 (2)
C17—C16—Ru1—C13	67.1 (3)	C14—Ru1—Ru2—C23	−128.7 (4)
C15—C16—Ru1—C13	−66.9 (3)	C16—Ru1—Ru2—C23	65.0 (2)
C28—C16—Ru1—C13	−176.9 (6)	C17—Ru1—Ru2—C23	23.43 (19)
C17—C16—Ru1—C14	103.9 (3)	P1—Ru1—Ru2—C23	−137.16 (13)
C15—C16—Ru1—C14	−30.1 (3)	Cl1—Ru1—Ru2—C23	121.48 (13)
C28—C16—Ru1—C14	−140.0 (6)	C18—Ru1—Ru2—C20	164.5 (4)
C15—C16—Ru1—C17	−134.0 (4)	C15—Ru1—Ru2—C20	−55.9 (5)
C28—C16—Ru1—C17	116.1 (6)	C13—Ru1—Ru2—C20	120.9 (4)
C17—C16—Ru1—P1	−179.7 (3)	C14—Ru1—Ru2—C20	56.0 (6)
C15—C16—Ru1—P1	46.3 (5)	C16—Ru1—Ru2—C20	−110.3 (4)
C28—C16—Ru1—P1	−63.7 (8)	C17—Ru1—Ru2—C20	−151.9 (4)
C17—C16—Ru1—Cl1	−123.8 (2)	P1—Ru1—Ru2—C20	47.5 (4)
C15—C16—Ru1—Cl1	102.2 (3)	Cl1—Ru1—Ru2—C20	−53.8 (4)
C28—C16—Ru1—Cl1	−7.8 (6)	C18—Ru1—Ru2—C24	−62.6 (2)
C17—C16—Ru1—Ru2	−81.0 (3)	C15—Ru1—Ru2—C24	77.0 (3)
C15—C16—Ru1—Ru2	145.0 (2)	C13—Ru1—Ru2—C24	−106.2 (2)
C28—C16—Ru1—Ru2	35.1 (6)	C14—Ru1—Ru2—C24	−171.1 (4)
C16—C17—Ru1—C18	−132.6 (4)	C16—Ru1—Ru2—C24	22.6 (2)
C29—C17—Ru1—C18	113.3 (6)	C17—Ru1—Ru2—C24	−19.0 (2)
C16—C17—Ru1—C15	−28.4 (3)	P1—Ru1—Ru2—C24	−179.56 (14)
C18—C17—Ru1—C15	104.2 (3)	Cl1—Ru1—Ru2—C24	79.09 (14)
C29—C17—Ru1—C15	−142.5 (6)	C18—Ru1—Ru2—P1	116.96 (15)
C16—C17—Ru1—C13	−102.1 (3)	C15—Ru1—Ru2—P1	−103.4 (3)
C18—C17—Ru1—C13	30.5 (3)	C13—Ru1—Ru2—P1	73.37 (18)
C29—C17—Ru1—C13	143.8 (6)	C14—Ru1—Ru2—P1	8.4 (4)
C16—C17—Ru1—C14	−65.1 (3)	C16—Ru1—Ru2—P1	−157.84 (18)
C18—C17—Ru1—C14	67.5 (3)	C17—Ru1—Ru2—P1	160.59 (14)
C29—C17—Ru1—C14	−179.2 (6)	Cl1—Ru1—Ru2—P1	−101.36 (5)
C18—C17—Ru1—C16	132.6 (4)	C18—Ru1—Ru2—Cl1	−141.69 (15)
C29—C17—Ru1—C16	−114.1 (6)	C15—Ru1—Ru2—Cl1	−2.0 (3)
C16—C17—Ru1—P1	179.7 (3)	C13—Ru1—Ru2—Cl1	174.72 (18)
C18—C17—Ru1—P1	−47.7 (5)	C14—Ru1—Ru2—Cl1	109.8 (4)
C29—C17—Ru1—P1	65.6 (7)	C16—Ru1—Ru2—Cl1	−56.49 (18)
C16—C17—Ru1—Cl1	63.5 (3)	C17—Ru1—Ru2—Cl1	−98.05 (14)
C18—C17—Ru1—Cl1	−163.9 (2)	P1—Ru1—Ru2—Cl1	101.36 (5)