catena-Poly[[[μ-pyridine-2-carbaldehyde azine-κ⁴N,N′:N′′,N′′′-bis­[(triphenyl­phosphine-κP)copper(I)]]-μ-1,2-bis­(4-pyrid­yl)ethene-κ²N:N′] bis­(tetra­fluoro­borate)]

In the title complex, {[Cu₂(C₁₂H₁₀N₂)(C₁₂H₁₀N₄)(C₁₈H₁₅P)₂](BF₄)₂}_n, the cations form a linear chain, and are bridged by 1,2-bis­(4-pyrid­yl)ethene and pyridine-2-carbaldehyde azine. Each Cu^I atom is coordinated by one P atom of a PPh₃ ligand, two N atoms of a pyridine-2-carbaldehyde azine bridging ligand and one N atom of a bridging 1,2-bis­(4-pyrid­yl)ethene ligand. There is a crystallographic centre of symmetry at the mid-point of the N—N bond.

Key indicators

• Single-crystal X-ray study
• T = 292 K
• Mean [sigma](C-C) = 0.014 Å
• Disorder in solvent or counterion
• R factor = 0.066
• wR factor = 0.216
• Data-to-parameter ratio = 12.2

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT368_ALERT_2_B Short  C(sp2)-C(sp2) Bond  C12    -   C12_b  ...       1.09 Ang.

Alert level C
PLAT029_ALERT_3_C _diffrn_measured_fraction_theta_full Low .......       0.97
PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings    Differ ....          ?
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............       2.00 Ratio
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.20 Ratio
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for         C9
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C19
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for         B1
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for        B1'
PLAT302_ALERT_4_C Anion/Solvent Disorder .........................      50.00 Perc.
PLAT331_ALERT_2_C Small Average Phenyl C-C Dist.   C13    -C18           1.37 Ang.
PLAT341_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...         14
PLAT601_ALERT_2_C Structure Contains Solvent Accessible VOIDS of .      69.00 A   3  

   0 ALERT level A = In general: serious problem
   1 ALERT level B = Potentially serious problem
  13 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   3 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   6 ALERT type 2 Indicator that the structure model may be wrong or deficient
   2 ALERT type 3 Indicator that the structure quality may be low
   3 ALERT type 4 Improvement, methodology, query or suggestion

---

Computing details

Data collection: SMART (Bruker, 1997); cell refinement: SAINT (Bruker, 1997); data reduction: SHELXL97 (Sheldrick, 1997); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97; molecular graphics: XP (Sheldrick, 1998); software used to prepare material for publication: XP.

catena-Poly[[[µ-pyridine-2-carbaldehyde azine-k⁴N,N':N'',N'''-bis[(triphenylphosphine-κP)copper(I)]]-µ- 1,2-bis(4-pyridyl)ethene-κ²N:N'] bis(tetrafluoroborate)]

Crystal data

[Cu2(C12H10N2)(C12H10N4)(C18H15P)2](BF4)2	Z = 1
Mr = 1217.70	F(000) = 622
Triclinic, P1	Dx = 1.386 Mg m^−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 10.196 (5) Å	Cell parameters from 777 reflections
b = 10.710 (6) Å	θ = 3.2–23.8°
c = 13.590 (7) Å	µ = 0.85 mm^−1
α = 82.447 (12)°	T = 292 K
β = 84.181 (12)°	Block, yellow
γ = 84.620 (13)°	0.20 × 0.18 × 0.16 mm
V = 1458.8 (14) Å^3

Data collection

Bruker SMART CCD area-detector diffractometer	4985 independent reflections
Radiation source: fine-focus sealed tube	2554 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.068
φ and ω scans	θmax = 25.0°, θmin = 2.3°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −11→12
Tmin = 0.845, Tmax = 0.876	k = −12→12
7124 measured reflections	l = −11→16

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.066	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.216	H-atom parameters constrained
S = 0.96	w = 1/[σ^2(Fo^2) + (0.1091P)^2] where P = (Fo^2 + 2Fc^2)/3
4985 reflections	(Δ/σ)max < 0.001
407 parameters	Δρmax = 0.80 e Å^−3
206 restraints	Δρmin = −1.17 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Cu1	0.52519 (8)	0.84937 (9)	0.85846 (6)	0.0372 (3)
P1	0.34264 (17)	0.86788 (18)	0.78490 (13)	0.0367 (5)
N1	0.5938 (5)	0.7028 (5)	0.9581 (4)	0.0354 (14)
N2	0.5223 (5)	0.9395 (5)	0.9885 (4)	0.0322 (13)
N3	0.6849 (6)	0.8860 (6)	0.7613 (4)	0.0413 (15)
C1	0.6446 (8)	0.5893 (7)	0.9415 (6)	0.049 (2)
H1	0.6398	0.5653	0.8788	0.059*
C2	0.7044 (8)	0.5036 (8)	1.0113 (6)	0.058 (2)
H2	0.7399	0.4246	0.9960	0.070*
C3	0.7097 (9)	0.5392 (8)	1.1038 (7)	0.065 (2)
H3	0.7502	0.4844	1.1527	0.078*
C4	0.6559 (8)	0.6536 (8)	1.1234 (5)	0.051 (2)
H4	0.6556	0.6772	1.1869	0.062*
C5	0.6017 (6)	0.7353 (6)	1.0496 (5)	0.0350 (16)
C6	0.5527 (7)	0.8623 (7)	1.0631 (5)	0.0386 (17)
H6	0.5433	0.8879	1.1264	0.046*
C7	0.7304 (8)	0.8026 (10)	0.6986 (6)	0.065 (3)
H7	0.6953	0.7244	0.7074	0.078*
C8	0.8246 (9)	0.8260 (13)	0.6230 (7)	0.080 (3)
H8	0.8532	0.7635	0.5824	0.096*
C9	0.8780 (8)	0.9375 (13)	0.6051 (6)	0.070 (3)
C10	0.8373 (8)	1.0201 (10)	0.6709 (8)	0.071 (3)
H10	0.8749	1.0969	0.6647	0.085*
C11	0.7398 (8)	0.9921 (9)	0.7479 (6)	0.055 (2)
H11	0.7130	1.0517	0.7914	0.066*
C12	0.9754 (9)	0.9592 (14)	0.5192 (9)	0.109 (5)
H12	1.0018	0.8859	0.4901	0.131*
C13	0.3002 (7)	1.0248 (7)	0.7241 (5)	0.0386 (17)
C14	0.3915 (9)	1.0801 (9)	0.6550 (7)	0.064 (2)
H14	0.4723	1.0356	0.6399	0.076*
C15	0.3657 (12)	1.2007 (10)	0.6073 (8)	0.083 (3)
H15	0.4299	1.2382	0.5625	0.099*
C16	0.2458 (13)	1.2645 (10)	0.6261 (9)	0.085 (3)
H16	0.2263	1.3442	0.5922	0.102*
C17	0.1561 (11)	1.2118 (9)	0.6936 (9)	0.076 (3)
H17	0.0749	1.2561	0.7076	0.091*
C18	0.1826 (8)	1.0935 (8)	0.7425 (6)	0.054 (2)
H18	0.1188	1.0589	0.7894	0.065*
C19	0.1964 (7)	0.8291 (7)	0.8641 (6)	0.0443 (18)
C20	0.1880 (8)	0.8522 (9)	0.9622 (6)	0.064 (2)
H20	0.2581	0.8858	0.9855	0.077*
C21	0.0787 (11)	0.8267 (12)	1.0253 (8)	0.093 (4)
H21	0.0760	0.8416	1.0914	0.112*
C22	−0.0225 (12)	0.7816 (13)	0.9945 (12)	0.112 (5)
H22	−0.0985	0.7704	1.0376	0.134*
C23	−0.0178 (10)	0.7498 (13)	0.8966 (12)	0.108 (4)
H23	−0.0865	0.7108	0.8763	0.129*
C24	0.0904 (9)	0.7776 (10)	0.8323 (8)	0.080 (3)
H24	0.0930	0.7619	0.7664	0.096*
C25	0.3464 (7)	0.7690 (7)	0.6862 (5)	0.0413 (18)
C26	0.4149 (7)	0.6545 (7)	0.6944 (6)	0.050 (2)
H26	0.4638	0.6312	0.7490	0.060*
C27	0.4155 (9)	0.5698 (8)	0.6250 (7)	0.064 (2)
H27	0.4622	0.4909	0.6338	0.076*
C28	0.3456 (10)	0.6055 (10)	0.5433 (7)	0.072 (3)
H28	0.3441	0.5507	0.4958	0.086*
C29	0.2790 (10)	0.7213 (10)	0.5325 (6)	0.081 (3)
H29	0.2327	0.7457	0.4767	0.097*
C30	0.2784 (9)	0.8024 (9)	0.6015 (7)	0.070 (3)
H30	0.2319	0.8814	0.5920	0.084*
B1	0.7049 (12)	0.3420 (12)	0.7463 (10)	0.108 (8)	0.545 (13)
F1	0.8254 (10)	0.3000 (11)	0.7041 (11)	0.102 (4)	0.545 (13)
F2	0.6102 (11)	0.2875 (12)	0.7066 (10)	0.132 (6)	0.545 (13)
F3	0.6970 (15)	0.3059 (14)	0.8471 (9)	0.170 (7)	0.545 (13)
F4	0.6818 (12)	0.4687 (10)	0.7288 (11)	0.108 (5)	0.545 (13)
B1'	0.7851 (17)	0.3972 (17)	0.7316 (14)	0.133 (11)	0.455 (13)
F1'	0.704 (2)	0.496 (2)	0.6937 (19)	0.200 (12)	0.455 (13)
F2'	0.8590 (18)	0.4389 (18)	0.7966 (13)	0.167 (9)	0.455 (13)
F3'	0.8651 (17)	0.3538 (17)	0.6549 (13)	0.126 (6)	0.455 (13)
F4'	0.716 (3)	0.301 (2)	0.780 (2)	0.295 (14)	0.455 (13)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Cu1	0.0393 (5)	0.0581 (6)	0.0144 (4)	−0.0011 (4)	−0.0023 (3)	−0.0073 (4)
P1	0.0368 (10)	0.0506 (12)	0.0230 (10)	−0.0008 (9)	−0.0035 (8)	−0.0066 (9)
N1	0.041 (3)	0.044 (4)	0.022 (3)	0.002 (3)	−0.001 (2)	−0.012 (3)
N2	0.037 (3)	0.039 (3)	0.020 (3)	−0.001 (3)	0.000 (2)	−0.005 (3)
N3	0.041 (3)	0.061 (4)	0.020 (3)	−0.006 (3)	0.000 (3)	−0.003 (3)
C1	0.061 (5)	0.051 (5)	0.034 (4)	0.001 (4)	−0.001 (4)	−0.009 (4)
C2	0.073 (6)	0.051 (5)	0.050 (6)	0.006 (4)	−0.005 (5)	−0.012 (4)
C3	0.083 (6)	0.057 (6)	0.047 (5)	0.008 (5)	−0.011 (5)	0.016 (4)
C4	0.073 (5)	0.061 (6)	0.020 (4)	0.002 (4)	−0.014 (4)	0.000 (4)
C5	0.035 (4)	0.040 (4)	0.029 (4)	0.004 (3)	0.002 (3)	−0.010 (3)
C6	0.045 (4)	0.050 (5)	0.020 (4)	−0.003 (4)	0.001 (3)	−0.007 (3)
C7	0.050 (5)	0.100 (7)	0.049 (5)	−0.022 (5)	0.010 (4)	−0.025 (5)
C8	0.058 (6)	0.144 (10)	0.035 (5)	−0.013 (6)	0.022 (4)	−0.020 (6)
C9	0.033 (5)	0.133 (9)	0.029 (5)	0.007 (6)	0.008 (4)	0.023 (6)
C10	0.046 (5)	0.083 (7)	0.074 (7)	−0.015 (5)	0.000 (5)	0.029 (6)
C11	0.055 (5)	0.064 (6)	0.044 (5)	−0.014 (5)	0.011 (4)	−0.003 (4)
C12	0.045 (7)	0.185 (16)	0.074 (9)	0.005 (7)	−0.004 (6)	0.062 (8)
C13	0.051 (4)	0.042 (4)	0.025 (4)	−0.014 (4)	−0.006 (3)	−0.003 (3)
C14	0.063 (5)	0.075 (6)	0.049 (5)	−0.013 (5)	−0.015 (4)	0.019 (5)
C15	0.098 (8)	0.086 (8)	0.061 (7)	−0.020 (7)	−0.022 (6)	0.021 (6)
C16	0.112 (9)	0.061 (7)	0.086 (8)	−0.016 (7)	−0.051 (7)	0.016 (6)
C17	0.075 (7)	0.057 (6)	0.096 (8)	0.012 (5)	−0.034 (6)	−0.009 (6)
C18	0.049 (5)	0.057 (5)	0.057 (5)	0.005 (4)	−0.013 (4)	−0.013 (4)
C19	0.039 (4)	0.050 (5)	0.041 (5)	−0.004 (4)	−0.003 (3)	0.002 (4)
C20	0.047 (5)	0.101 (7)	0.044 (5)	−0.011 (5)	0.010 (4)	−0.016 (5)
C21	0.063 (7)	0.150 (11)	0.063 (7)	−0.019 (7)	0.026 (6)	−0.018 (7)
C22	0.060 (7)	0.155 (12)	0.106 (11)	−0.015 (8)	0.027 (7)	0.015 (10)
C23	0.046 (6)	0.154 (12)	0.121 (11)	−0.042 (7)	−0.011 (7)	0.018 (9)
C24	0.056 (6)	0.123 (9)	0.065 (7)	−0.032 (6)	−0.019 (5)	0.001 (6)
C25	0.050 (4)	0.050 (5)	0.025 (4)	0.003 (4)	−0.013 (3)	−0.008 (3)
C26	0.056 (5)	0.058 (5)	0.037 (5)	−0.003 (4)	−0.016 (4)	−0.003 (4)
C27	0.076 (6)	0.053 (5)	0.064 (6)	−0.001 (5)	−0.006 (5)	−0.020 (5)
C28	0.097 (7)	0.082 (7)	0.044 (6)	−0.016 (6)	−0.012 (5)	−0.025 (5)
C29	0.117 (8)	0.091 (7)	0.043 (5)	0.028 (6)	−0.047 (5)	−0.034 (5)
C30	0.089 (7)	0.069 (6)	0.054 (6)	0.023 (5)	−0.035 (5)	−0.017 (5)
B1	0.110 (9)	0.108 (9)	0.106 (9)	−0.007 (5)	−0.009 (5)	−0.013 (5)
F1	0.098 (6)	0.099 (6)	0.109 (6)	0.001 (4)	0.007 (4)	−0.026 (4)
F2	0.133 (7)	0.138 (7)	0.128 (7)	−0.006 (4)	−0.022 (5)	−0.024 (5)
F3	0.174 (8)	0.176 (8)	0.161 (8)	−0.010 (5)	−0.023 (5)	−0.020 (5)
F4	0.117 (6)	0.105 (6)	0.101 (6)	0.011 (4)	−0.017 (4)	−0.022 (4)
B1'	0.134 (12)	0.134 (12)	0.133 (12)	−0.010 (5)	−0.012 (5)	−0.020 (5)
F1'	0.204 (13)	0.198 (13)	0.198 (13)	−0.012 (5)	−0.021 (5)	−0.028 (5)
F2'	0.166 (9)	0.176 (10)	0.161 (10)	−0.008 (5)	−0.022 (5)	−0.029 (5)
F3'	0.131 (8)	0.128 (8)	0.121 (8)	−0.003 (5)	−0.011 (5)	−0.023 (5)
F4'	0.295 (15)	0.296 (15)	0.294 (15)	−0.024 (5)	−0.024 (5)	−0.036 (5)

Geometric parameters (Å, º)

Cu1—N3	2.024 (6)	C15—C16	1.361 (14)
Cu1—N1	2.052 (6)	C15—H15	0.9300
Cu1—N2	2.118 (5)	C16—C17	1.336 (14)
Cu1—P1	2.182 (2)	C16—H16	0.9300
P1—C19	1.796 (8)	C17—C18	1.368 (12)
P1—C13	1.808 (8)	C17—H17	0.9300
P1—C25	1.810 (7)	C18—H18	0.9300
N1—C1	1.314 (9)	C19—C20	1.380 (11)
N1—C5	1.347 (8)	C19—C24	1.389 (11)
N2—C6	1.267 (8)	C20—C21	1.363 (12)
N2—N2^i	1.396 (10)	C20—H20	0.9300
N3—C11	1.296 (9)	C21—C22	1.306 (16)
N3—C7	1.336 (10)	C21—H21	0.9300
C1—C2	1.376 (11)	C22—C23	1.413 (18)
C1—H1	0.9300	C22—H22	0.9300
C2—C3	1.368 (12)	C23—C24	1.366 (14)
C2—H2	0.9300	C23—H23	0.9300
C3—C4	1.344 (11)	C24—H24	0.9300
C3—H3	0.9300	C25—C26	1.350 (10)
C4—C5	1.367 (10)	C25—C30	1.394 (10)
C4—H4	0.9300	C26—C27	1.391 (11)
C5—C6	1.433 (9)	C26—H26	0.9300
C6—H6	0.9300	C27—C28	1.373 (13)
C7—C8	1.348 (11)	C27—H27	0.9300
C7—H7	0.9300	C28—C29	1.354 (12)
C8—C9	1.342 (14)	C28—H28	0.9300
C8—H8	0.9300	C29—C30	1.358 (11)
C9—C10	1.349 (14)	C29—H29	0.9300
C9—C12	1.463 (12)	C30—H30	0.9300
C10—C11	1.392 (11)	B1—F4	1.350 (10)
C10—H10	0.9300	B1—F2	1.363 (10)
C11—H11	0.9300	B1—F1	1.364 (10)
C12—C12^ii	1.09 (2)	B1—F3	1.370 (10)
C12—H12	0.9300	B1'—F1'	1.356 (10)
C13—C18	1.366 (10)	B1'—F4'	1.358 (10)
C13—C14	1.370 (11)	B1'—F2'	1.360 (10)
C14—C15	1.382 (12)	B1'—F3'	1.361 (10)
C14—H14	0.9300
N3—Cu1—N1	104.0 (2)	C15—C14—H14	119.4
N3—Cu1—N2	112.4 (2)	C16—C15—C14	119.7 (10)
N1—Cu1—N2	78.7 (2)	C16—C15—H15	120.2
N3—Cu1—P1	112.28 (17)	C14—C15—H15	120.2
N1—Cu1—P1	128.12 (17)	C17—C16—C15	119.7 (10)
N2—Cu1—P1	117.03 (15)	C17—C16—H16	120.2
C19—P1—C13	104.3 (3)	C15—C16—H16	120.2
C19—P1—C25	103.9 (4)	C16—C17—C18	120.7 (10)
C13—P1—C25	103.5 (3)	C16—C17—H17	119.7
C19—P1—Cu1	115.6 (3)	C18—C17—H17	119.7
C13—P1—Cu1	114.3 (2)	C13—C18—C17	121.7 (9)
C25—P1—Cu1	113.9 (2)	C13—C18—H18	119.2
C1—N1—C5	116.8 (6)	C17—C18—H18	119.2
C1—N1—Cu1	129.0 (5)	C20—C19—C24	117.8 (8)
C5—N1—Cu1	113.7 (4)	C20—C19—P1	118.4 (6)
C6—N2—N2^i	114.0 (6)	C24—C19—P1	123.8 (7)
C6—N2—Cu1	112.0 (4)	C21—C20—C19	121.0 (9)
N2^i—N2—Cu1	133.4 (5)	C21—C20—H20	119.5
C11—N3—C7	116.0 (7)	C19—C20—H20	119.5
C11—N3—Cu1	124.4 (5)	C22—C21—C20	121.1 (11)
C7—N3—Cu1	119.2 (6)	C22—C21—H21	119.5
N1—C1—C2	124.2 (7)	C20—C21—H21	119.5
N1—C1—H1	117.9	C21—C22—C23	120.7 (10)
C2—C1—H1	117.9	C21—C22—H22	119.6
C3—C2—C1	117.5 (7)	C23—C22—H22	119.6
C3—C2—H2	121.2	C24—C23—C22	118.3 (11)
C1—C2—H2	121.2	C24—C23—H23	120.9
C4—C3—C2	119.6 (8)	C22—C23—H23	120.9
C4—C3—H3	120.2	C23—C24—C19	120.9 (10)
C2—C3—H3	120.2	C23—C24—H24	119.6
C3—C4—C5	119.6 (7)	C19—C24—H24	119.6
C3—C4—H4	120.2	C26—C25—C30	116.7 (7)
C5—C4—H4	120.2	C26—C25—P1	119.6 (5)
N1—C5—C4	122.2 (6)	C30—C25—P1	123.6 (6)
N1—C5—C6	115.3 (6)	C25—C26—C27	123.0 (7)
C4—C5—C6	122.5 (6)	C25—C26—H26	118.5
N2—C6—C5	119.7 (6)	C27—C26—H26	118.5
N2—C6—H6	120.2	C28—C27—C26	118.4 (8)
C5—C6—H6	120.2	C28—C27—H27	120.8
N3—C7—C8	123.3 (9)	C26—C27—H27	120.8
N3—C7—H7	118.3	C29—C28—C27	119.4 (8)
C8—C7—H7	118.3	C29—C28—H28	120.3
C9—C8—C7	121.4 (10)	C27—C28—H28	120.3
C9—C8—H8	119.3	C28—C29—C30	121.4 (8)
C7—C8—H8	119.3	C28—C29—H29	119.3
C8—C9—C10	115.6 (8)	C30—C29—H29	119.3
C8—C9—C12	118.8 (11)	C29—C30—C25	120.9 (8)
C10—C9—C12	125.5 (12)	C29—C30—H30	119.5
C9—C10—C11	120.9 (9)	C25—C30—H30	119.5
C9—C10—H10	119.5	F4—B1—F2	108.7 (10)
C11—C10—H10	119.5	F4—B1—F1	112.4 (10)
N3—C11—C10	122.5 (8)	F2—B1—F1	108.1 (10)
N3—C11—H11	118.8	F4—B1—F3	109.2 (10)
C10—C11—H11	118.8	F2—B1—F3	108.8 (10)
C12^ii—C12—C9	135 (2)	F1—B1—F3	109.6 (10)
C12^ii—C12—H12	112.3	F1'—B1'—F4'	112.0 (12)
C9—C12—H12	112.3	F1'—B1'—F2'	108.4 (11)
C18—C13—C14	117.1 (8)	F4'—B1'—F2'	109.1 (11)
C18—C13—P1	124.4 (6)	F1'—B1'—F3'	108.3 (11)
C14—C13—P1	118.5 (6)	F4'—B1'—F3'	109.0 (11)
C13—C14—C15	121.2 (9)	F2'—B1'—F3'	110.0 (11)
C13—C14—H14	119.4
N3—Cu1—P1—C19	176.9 (3)	C12—C9—C10—C11	177.3 (8)
N1—Cu1—P1—C19	46.0 (3)	C7—N3—C11—C10	2.1 (12)
N2—Cu1—P1—C19	−50.9 (3)	Cu1—N3—C11—C10	−170.7 (6)
N3—Cu1—P1—C13	−62.1 (3)	C9—C10—C11—N3	1.0 (14)
N1—Cu1—P1—C13	167.1 (3)	C8—C9—C12—C12^ii	170.4 (19)
N2—Cu1—P1—C13	70.1 (3)	C10—C9—C12—C12^ii	−11 (2)
N3—Cu1—P1—C25	56.6 (3)	C19—P1—C13—C18	2.6 (7)
N1—Cu1—P1—C25	−74.2 (3)	C25—P1—C13—C18	111.1 (7)
N2—Cu1—P1—C25	−171.2 (3)	Cu1—P1—C13—C18	−124.6 (6)
N3—Cu1—N1—C1	−60.3 (6)	C19—P1—C13—C14	−177.7 (6)
N2—Cu1—N1—C1	−170.9 (6)	C25—P1—C13—C14	−69.3 (6)
P1—Cu1—N1—C1	73.5 (6)	Cu1—P1—C13—C14	55.1 (6)
N3—Cu1—N1—C5	110.7 (5)	C18—C13—C14—C15	0.9 (12)
N2—Cu1—N1—C5	0.1 (4)	P1—C13—C14—C15	−178.9 (7)
P1—Cu1—N1—C5	−115.5 (4)	C13—C14—C15—C16	−2.5 (14)
N3—Cu1—N2—C6	−105.5 (5)	C14—C15—C16—C17	2.8 (15)
N1—Cu1—N2—C6	−4.8 (5)	C15—C16—C17—C18	−1.4 (15)
P1—Cu1—N2—C6	122.4 (4)	C14—C13—C18—C17	0.5 (11)
N3—Cu1—N2—N2^i	84.6 (7)	P1—C13—C18—C17	−179.8 (6)
N1—Cu1—N2—N2^i	−174.8 (8)	C16—C17—C18—C13	−0.3 (14)
P1—Cu1—N2—N2^i	−47.6 (8)	C13—P1—C19—C20	−94.4 (7)
N1—Cu1—N3—C11	−117.4 (6)	C25—P1—C19—C20	157.4 (7)
N2—Cu1—N3—C11	−34.0 (7)	Cu1—P1—C19—C20	31.9 (7)
P1—Cu1—N3—C11	100.5 (6)	C13—P1—C19—C24	85.2 (8)
N1—Cu1—N3—C7	70.1 (6)	C25—P1—C19—C24	−23.0 (8)
N2—Cu1—N3—C7	153.5 (6)	Cu1—P1—C19—C24	−148.5 (7)
P1—Cu1—N3—C7	−72.1 (6)	C24—C19—C20—C21	−0.7 (14)
C5—N1—C1—C2	−0.1 (11)	P1—C19—C20—C21	178.9 (8)
Cu1—N1—C1—C2	170.6 (6)	C19—C20—C21—C22	−1.2 (18)
N1—C1—C2—C3	0.7 (13)	C20—C21—C22—C23	4 (2)
C1—C2—C3—C4	0.8 (13)	C21—C22—C23—C24	−6 (2)
C2—C3—C4—C5	−2.8 (13)	C22—C23—C24—C19	3.7 (18)
C1—N1—C5—C4	−2.0 (10)	C20—C19—C24—C23	−0.7 (15)
Cu1—N1—C5—C4	−174.1 (6)	P1—C19—C24—C23	179.7 (8)
C1—N1—C5—C6	176.3 (6)	C19—P1—C25—C26	−92.7 (7)
Cu1—N1—C5—C6	4.2 (7)	C13—P1—C25—C26	158.5 (6)
C3—C4—C5—N1	3.5 (12)	Cu1—P1—C25—C26	33.9 (7)
C3—C4—C5—C6	−174.7 (7)	C19—P1—C25—C30	85.2 (8)
N2^i—N2—C6—C5	−179.2 (6)	C13—P1—C25—C30	−23.5 (8)
Cu1—N2—C6—C5	8.8 (8)	Cu1—P1—C25—C30	−148.2 (7)
N1—C5—C6—N2	−9.1 (10)	C30—C25—C26—C27	−2.4 (12)
C4—C5—C6—N2	169.2 (7)	P1—C25—C26—C27	175.7 (6)
C11—N3—C7—C8	−2.1 (13)	C25—C26—C27—C28	1.5 (13)
Cu1—N3—C7—C8	171.0 (7)	C26—C27—C28—C29	0.2 (15)
N3—C7—C8—C9	−1.0 (15)	C27—C28—C29—C30	−0.8 (17)
C7—C8—C9—C10	4.0 (14)	C28—C29—C30—C25	−0.2 (17)
C7—C8—C9—C12	−177.2 (9)	C26—C25—C30—C29	1.7 (14)
C8—C9—C10—C11	−3.9 (13)	P1—C25—C30—C29	−176.3 (8)

Symmetry codes: (i) −x+1, −y+2, −z+2; (ii) −x+2, −y+2, −z+1.