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The title complex, [Ag(NO3)(C10H8N2)(C18H15P)], contains a bidentate bipyrid­yl ligand, a monodentate triphenyl­phosphine mol­ecule and a nitrate anion coordinated to silver. The geometry of the resulting AgN2PO coordination could be described as grossly distorted tetra­hedral or as irregular.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S160053680502057X/hb6231sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S160053680502057X/hb6231Isup2.hkl
Contains datablock I

CCDC reference: 282362

Key indicators

  • Single-crystal X-ray study
  • T = 173 K
  • Mean [sigma](C-C)= 0.003 Å
  • R factor = 0.032
  • wR factor = 0.095
  • Data-to-parameter ratio = 22.7

checkCIF/PLATON results

No syntax errors found


No errors found in this datablock

Computing details top

Data collection: COLLECT (Nonius, 1998); cell refinement: DENZO (Otwinowski & Minor, 1997); data reduction: DENZO; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: PLATON98 (Spek, 1998); software used to prepare material for publication: SHELXL97.

(2,2'-Bipyridyl-κ2N,N')nitrato(triphenylphosphine-κP)silver(I) top
Crystal data top
[Ag(NO3)(C10H8N2)(C18H15P)]Z = 2
Mr = 588.33F(000) = 596
Triclinic, P1Dx = 1.548 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71069 Å
a = 8.070 (5) ÅCell parameters from 9415 reflections
b = 9.644 (5) Åθ = 1.0–30.0°
c = 18.125 (5) ŵ = 0.90 mm1
α = 100.28 (5)°T = 173 K
β = 96.20 (5)°Prism, colorless
γ = 112.12 (5)°0.10 × 0.08 × 0.06 mm
V = 1261.9 (11) Å3
Data collection top
Nonius KappaCCD
diffractometer
6228 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tubeRint = 0.037
Graphite monochromatorθmax = 30.1°, θmin = 1.2°
φ scansh = 1111
19212 measured reflectionsk = 1313
7388 independent reflectionsl = 2525
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.032Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.095H-atom parameters constrained
S = 1.06 w = 1/[σ2(Fo2) + (0.0472P)2 + 0.1974P]
where P = (Fo2 + 2Fc2)/3
7388 reflections(Δ/σ)max = 0.001
325 parametersΔρmax = 0.41 e Å3
0 restraintsΔρmin = 0.99 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ag0.575178 (19)0.366316 (18)0.322157 (7)0.03187 (6)
P0.38876 (6)0.30496 (6)0.20211 (2)0.02320 (10)
O10.7585 (2)0.19941 (18)0.32939 (9)0.0372 (3)
O20.4807 (2)0.0615 (2)0.33481 (13)0.0619 (6)
O30.6934 (2)0.01806 (18)0.36166 (9)0.0433 (4)
N10.8388 (2)0.5928 (2)0.37563 (9)0.0281 (3)
N20.6189 (2)0.40494 (18)0.45317 (8)0.0243 (3)
N30.6443 (2)0.0799 (2)0.34250 (10)0.0334 (4)
C10.9393 (3)0.6889 (3)0.33715 (12)0.0379 (5)
H10.91120.65900.28290.046*
C21.0809 (3)0.8283 (3)0.37149 (14)0.0446 (6)
H21.15040.89200.34190.053*
C31.1185 (3)0.8727 (3)0.44996 (15)0.0464 (6)
H31.21430.96880.47560.056*
C41.0164 (3)0.7769 (3)0.49105 (12)0.0356 (5)
H41.03990.80710.54530.043*
C50.8785 (2)0.6355 (2)0.45264 (10)0.0238 (4)
C60.7702 (2)0.5240 (2)0.49403 (10)0.0221 (3)
C70.8254 (3)0.5413 (2)0.57215 (10)0.0287 (4)
H70.93340.62570.60030.034*
C80.7203 (3)0.4337 (3)0.60773 (11)0.0344 (5)
H80.75560.44330.66070.041*
C90.5641 (3)0.3126 (3)0.56609 (12)0.0359 (5)
H90.48940.23810.58970.043*
C100.5191 (3)0.3025 (2)0.48914 (12)0.0310 (4)
H100.41180.21860.46020.037*
C110.3144 (2)0.4558 (2)0.18627 (10)0.0246 (4)
C120.4339 (3)0.6080 (2)0.21758 (11)0.0305 (4)
H120.55310.63090.24370.037*
C130.3806 (3)0.7266 (2)0.21106 (12)0.0364 (5)
H130.46440.83040.23180.044*
C140.2076 (3)0.6954 (3)0.17481 (13)0.0369 (5)
H140.17070.77720.17170.044*
C150.0877 (3)0.5448 (3)0.14291 (16)0.0462 (6)
H150.03170.52280.11730.055*
C160.1412 (3)0.4252 (3)0.14813 (14)0.0395 (5)
H160.05860.32170.12540.047*
C170.5079 (2)0.2778 (2)0.12428 (10)0.0235 (4)
C180.5020 (3)0.3396 (3)0.06094 (11)0.0302 (4)
H180.43560.40200.05720.036*
C190.5926 (3)0.3107 (3)0.00302 (12)0.0347 (5)
H190.59070.35550.03950.042*
C200.6855 (3)0.2167 (3)0.00720 (12)0.0350 (5)
H200.74550.19540.03290.042*
C210.6909 (3)0.1537 (3)0.06971 (13)0.0340 (4)
H210.75340.08810.07220.041*
C220.6054 (3)0.1858 (2)0.12880 (11)0.0296 (4)
H220.61310.14520.17250.036*
C230.1797 (2)0.1293 (2)0.17673 (10)0.0239 (4)
C240.1205 (3)0.0298 (2)0.10453 (10)0.0257 (4)
H240.19050.05210.06590.031*
C250.0409 (3)0.1027 (2)0.08846 (11)0.0317 (4)
H250.07990.17070.03920.038*
C260.1443 (3)0.1351 (3)0.14416 (13)0.0361 (5)
H260.25450.22520.13300.043*
C270.0874 (3)0.0366 (3)0.21622 (13)0.0374 (5)
H270.15860.05890.25440.045*
C280.0736 (3)0.0944 (3)0.23243 (11)0.0328 (4)
H280.11250.16140.28200.039*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag0.02972 (9)0.03951 (11)0.02079 (8)0.01237 (7)0.00340 (6)0.00221 (6)
P0.0220 (2)0.0263 (2)0.0189 (2)0.00948 (19)0.00048 (16)0.00238 (18)
O10.0333 (8)0.0346 (8)0.0417 (8)0.0102 (7)0.0066 (6)0.0125 (7)
O20.0311 (9)0.0373 (10)0.1011 (16)0.0065 (7)0.0144 (9)0.0072 (10)
O30.0537 (10)0.0322 (8)0.0382 (8)0.0109 (8)0.0034 (7)0.0119 (7)
N10.0242 (8)0.0350 (9)0.0249 (7)0.0100 (7)0.0038 (6)0.0118 (7)
N20.0243 (8)0.0236 (8)0.0228 (7)0.0077 (6)0.0037 (6)0.0051 (6)
N30.0336 (9)0.0286 (9)0.0290 (8)0.0078 (7)0.0038 (7)0.0028 (7)
C10.0304 (11)0.0518 (14)0.0310 (10)0.0112 (10)0.0061 (8)0.0206 (10)
C20.0325 (11)0.0482 (14)0.0510 (13)0.0063 (10)0.0077 (10)0.0297 (12)
C30.0351 (12)0.0337 (12)0.0572 (14)0.0009 (10)0.0000 (10)0.0175 (11)
C40.0341 (11)0.0280 (10)0.0348 (10)0.0048 (9)0.0002 (8)0.0051 (9)
C50.0219 (8)0.0253 (9)0.0250 (8)0.0098 (7)0.0037 (6)0.0080 (7)
C60.0216 (8)0.0239 (9)0.0215 (8)0.0102 (7)0.0040 (6)0.0046 (7)
C70.0287 (10)0.0359 (11)0.0209 (8)0.0138 (8)0.0028 (7)0.0044 (8)
C80.0424 (12)0.0459 (13)0.0230 (8)0.0230 (10)0.0112 (8)0.0139 (9)
C90.0432 (12)0.0390 (12)0.0349 (10)0.0189 (10)0.0192 (9)0.0199 (10)
C100.0298 (10)0.0286 (10)0.0333 (10)0.0090 (8)0.0085 (8)0.0094 (8)
C110.0253 (9)0.0268 (9)0.0213 (8)0.0112 (7)0.0043 (6)0.0030 (7)
C120.0291 (10)0.0293 (10)0.0269 (9)0.0084 (8)0.0003 (7)0.0026 (8)
C130.0468 (13)0.0257 (10)0.0319 (10)0.0122 (9)0.0046 (9)0.0023 (8)
C140.0479 (13)0.0344 (11)0.0391 (11)0.0250 (10)0.0144 (9)0.0124 (9)
C150.0309 (12)0.0427 (13)0.0668 (16)0.0202 (10)0.0019 (11)0.0121 (12)
C160.0290 (10)0.0284 (11)0.0543 (13)0.0103 (9)0.0056 (9)0.0040 (10)
C170.0182 (8)0.0243 (9)0.0240 (8)0.0059 (7)0.0019 (6)0.0034 (7)
C180.0314 (10)0.0353 (11)0.0289 (9)0.0184 (9)0.0060 (8)0.0084 (8)
C190.0392 (11)0.0412 (12)0.0291 (9)0.0189 (10)0.0114 (8)0.0125 (9)
C200.0303 (10)0.0390 (12)0.0360 (10)0.0141 (9)0.0127 (8)0.0054 (9)
C210.0287 (10)0.0347 (11)0.0425 (11)0.0171 (9)0.0085 (8)0.0082 (9)
C220.0252 (9)0.0315 (10)0.0334 (10)0.0121 (8)0.0047 (7)0.0101 (8)
C230.0240 (9)0.0257 (9)0.0237 (8)0.0113 (7)0.0034 (7)0.0077 (7)
C240.0257 (9)0.0284 (10)0.0230 (8)0.0114 (8)0.0032 (7)0.0058 (7)
C250.0301 (10)0.0293 (10)0.0304 (9)0.0090 (8)0.0014 (8)0.0050 (8)
C260.0243 (10)0.0331 (11)0.0495 (12)0.0080 (8)0.0033 (8)0.0163 (10)
C270.0321 (11)0.0441 (13)0.0417 (11)0.0150 (10)0.0155 (9)0.0202 (10)
C280.0352 (11)0.0384 (12)0.0260 (9)0.0150 (9)0.0100 (8)0.0078 (8)
Geometric parameters (Å, º) top
Ag—N12.353 (3)C11—C161.388 (3)
Ag—N22.3036 (17)C12—C131.384 (3)
Ag—P2.3475 (15)C12—H120.9500
Ag—O12.573 (2)C13—C141.374 (3)
P—C111.824 (2)C13—H130.9500
P—C231.825 (2)C14—C151.379 (4)
P—C171.826 (2)C14—H140.9500
O1—N31.256 (2)C15—C161.390 (3)
O2—N31.252 (3)C15—H150.9500
O3—N31.241 (2)C16—H160.9500
N1—C11.338 (3)C17—C181.389 (3)
N1—C51.349 (2)C17—C221.396 (3)
N2—C101.339 (3)C18—C191.389 (3)
N2—C61.343 (3)C18—H180.9500
C1—C21.375 (4)C19—C201.383 (3)
C1—H10.9500C19—H190.9500
C2—C31.375 (4)C20—C211.382 (3)
C2—H20.9500C20—H200.9500
C3—C41.375 (3)C21—C221.386 (3)
C3—H30.9500C21—H210.9500
C4—C51.391 (3)C22—H220.9500
C4—H40.9500C23—C241.390 (3)
C5—C61.485 (3)C23—C281.398 (3)
C6—C71.398 (2)C24—C251.395 (3)
C7—C81.381 (3)C24—H240.9500
C7—H70.9500C25—C261.382 (3)
C8—C91.376 (4)C25—H250.9500
C8—H80.9500C26—C271.385 (3)
C9—C101.379 (3)C26—H260.9500
C9—H90.9500C27—C281.386 (3)
C10—H100.9500C27—H270.9500
C11—C121.388 (3)C28—H280.9500
N2—Ag—N171.67 (8)C12—C11—P118.08 (15)
N1—Ag—P126.47 (7)C16—C11—P123.11 (16)
N2—Ag—P151.77 (5)C13—C12—C11120.47 (19)
N1—Ag—O191.20 (8)C13—C12—H12119.8
N2—Ag—O184.89 (7)C11—C12—H12119.8
P—Ag—O1113.22 (6)C14—C13—C12120.5 (2)
C11—P—C23104.40 (10)C14—C13—H13119.7
C11—P—C17104.74 (9)C12—C13—H13119.7
C23—P—C17102.83 (10)C13—C14—C15119.7 (2)
C11—P—Ag113.44 (8)C13—C14—H14120.2
C23—P—Ag118.26 (8)C15—C14—H14120.2
C17—P—Ag111.78 (7)C14—C15—C16120.1 (2)
N3—O1—Ag102.07 (13)C14—C15—H15119.9
C1—N1—C5118.01 (18)C16—C15—H15119.9
C1—N1—Ag126.01 (14)C11—C16—C15120.5 (2)
C5—N1—Ag115.60 (14)C11—C16—H16119.8
C10—N2—C6118.47 (16)C15—C16—H16119.8
C10—N2—Ag123.37 (14)C18—C17—C22119.15 (18)
C6—N2—Ag117.24 (13)C18—C17—P123.67 (15)
O3—N3—O2121.2 (2)C22—C17—P117.15 (15)
O3—N3—O1120.28 (18)C19—C18—C17120.35 (19)
O2—N3—O1118.6 (2)C19—C18—H18119.8
N1—C1—C2123.8 (2)C17—C18—H18119.8
N1—C1—H1118.1C20—C19—C18120.1 (2)
C2—C1—H1118.1C20—C19—H19120.0
C3—C2—C1117.9 (2)C18—C19—H19120.0
C3—C2—H2121.0C21—C20—C19119.99 (19)
C1—C2—H2121.0C21—C20—H20120.0
C2—C3—C4119.5 (2)C19—C20—H20120.0
C2—C3—H3120.2C20—C21—C22120.2 (2)
C4—C3—H3120.2C20—C21—H21119.9
C3—C4—C5119.5 (2)C22—C21—H21119.9
C3—C4—H4120.3C21—C22—C17120.17 (19)
C5—C4—H4120.3C21—C22—H22119.9
N1—C5—C4121.15 (19)C17—C22—H22119.9
N1—C5—C6116.96 (17)C24—C23—C28118.71 (18)
C4—C5—C6121.89 (17)C24—C23—P123.02 (15)
N2—C6—C7121.49 (18)C28—C23—P118.27 (15)
N2—C6—C5117.31 (16)C23—C24—C25120.39 (18)
C7—C6—C5121.20 (17)C23—C24—H24119.8
C8—C7—C6118.82 (19)C25—C24—H24119.8
C8—C7—H7120.6C26—C25—C24120.12 (19)
C6—C7—H7120.6C26—C25—H25119.9
C9—C8—C7119.74 (18)C24—C25—H25119.9
C9—C8—H8120.1C25—C26—C27120.1 (2)
C7—C8—H8120.1C25—C26—H26120.0
C8—C9—C10118.1 (2)C27—C26—H26120.0
C8—C9—H9120.9C26—C27—C28119.9 (2)
C10—C9—H9120.9C26—C27—H27120.1
N2—C10—C9123.4 (2)C28—C27—H27120.1
N2—C10—H10118.3C27—C28—C23120.8 (2)
C9—C10—H10118.3C27—C28—H28119.6
C12—C11—C16118.7 (2)C23—C28—H28119.6
N2—Ag—P—C1171.45 (12)C6—C7—C8—C90.2 (3)
N1—Ag—P—C1151.89 (9)C7—C8—C9—C100.7 (3)
O1—Ag—P—C11162.10 (7)C6—N2—C10—C90.3 (3)
N2—Ag—P—C2351.29 (12)Ag—N2—C10—C9168.46 (17)
N1—Ag—P—C23174.63 (8)C8—C9—C10—N20.4 (3)
O1—Ag—P—C2375.16 (9)C23—P—C11—C12164.74 (15)
N2—Ag—P—C17170.39 (11)C17—P—C11—C1287.52 (17)
N1—Ag—P—C1766.27 (10)Ag—P—C11—C1234.64 (17)
O1—Ag—P—C1743.94 (9)C23—P—C11—C1611.6 (2)
N2—Ag—O1—N374.82 (13)C17—P—C11—C1696.1 (2)
P—Ag—O1—N382.72 (13)Ag—P—C11—C16141.75 (17)
N1—Ag—O1—N3146.29 (12)C16—C11—C12—C130.3 (3)
N2—Ag—N1—C1175.72 (19)P—C11—C12—C13176.28 (15)
P—Ag—N1—C120.3 (2)C11—C12—C13—C141.3 (3)
O1—Ag—N1—C1100.07 (19)C12—C13—C14—C151.7 (3)
N2—Ag—N1—C52.97 (13)C13—C14—C15—C160.7 (4)
P—Ag—N1—C5152.43 (12)C12—C11—C16—C151.3 (3)
O1—Ag—N1—C587.18 (14)P—C11—C16—C15175.04 (19)
P—Ag—N2—C1052.0 (2)C14—C15—C16—C110.9 (4)
N1—Ag—N2—C10173.05 (17)C11—P—C17—C1811.88 (19)
O1—Ag—N2—C1080.07 (16)C23—P—C17—C1897.00 (18)
P—Ag—N2—C6139.14 (12)Ag—P—C17—C18135.12 (16)
N1—Ag—N2—C64.19 (13)C11—P—C17—C22169.98 (14)
O1—Ag—N2—C688.78 (14)C23—P—C17—C2281.14 (16)
Ag—O1—N3—O3168.55 (14)Ag—P—C17—C2246.74 (16)
Ag—O1—N3—O212.4 (2)C22—C17—C18—C190.3 (3)
C5—N1—C1—C20.2 (3)P—C17—C18—C19178.36 (16)
Ag—N1—C1—C2172.76 (19)C17—C18—C19—C201.7 (3)
N1—C1—C2—C31.4 (4)C18—C19—C20—C211.1 (3)
C1—C2—C3—C40.8 (4)C19—C20—C21—C220.8 (3)
C2—C3—C4—C51.0 (4)C20—C21—C22—C172.2 (3)
C1—N1—C5—C41.7 (3)C18—C17—C22—C211.7 (3)
Ag—N1—C5—C4171.64 (16)P—C17—C22—C21176.55 (16)
C1—N1—C5—C6177.45 (18)C11—P—C23—C2494.30 (17)
Ag—N1—C5—C69.2 (2)C17—P—C23—C2414.84 (18)
C3—C4—C5—N12.3 (3)Ag—P—C23—C24138.52 (14)
C3—C4—C5—C6176.8 (2)C11—P—C23—C2885.05 (17)
C10—N2—C6—C70.8 (3)C17—P—C23—C28165.81 (16)
Ag—N2—C6—C7168.66 (14)Ag—P—C23—C2842.14 (18)
C10—N2—C6—C5179.84 (17)C28—C23—C24—C250.5 (3)
Ag—N2—C6—C510.4 (2)P—C23—C24—C25179.81 (15)
N1—C5—C6—N213.2 (3)C23—C24—C25—C260.6 (3)
C4—C5—C6—N2167.59 (19)C24—C25—C26—C270.3 (3)
N1—C5—C6—C7165.84 (18)C25—C26—C27—C280.1 (3)
C4—C5—C6—C713.3 (3)C26—C27—C28—C230.3 (3)
N2—C6—C7—C80.5 (3)C24—C23—C28—C270.0 (3)
C5—C6—C7—C8179.59 (18)P—C23—C28—C27179.37 (17)
 

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