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metal-organic compounds
In the title compound, [SnCl2(C19H22N2O)]·CHCl3, the deprotonated N-(2-aminocyclohexyl)salicylaldimine Schiff base chelates in an O,N,N′-tridentate manner to the Sn atom. The octahedral tin coordination environment is completed by a phenyl ring and two chloride ions; the bonded C atom of the phenyl ring along with the three chelating atoms comprise an approximate square plane. The molecules of the complex are linked by N—HO and N—HCl hydrogen bonds to form a helical chain running along the b axis; the solvent molecules occupy the space between the chains but are not hydrogen bonded to them.
Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804025036/hb6204sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536804025036/hb6204Isup2.hkl |
CCDC reference: 255419
Key indicators
- Single-crystal X-ray study
- T = 223 K
- Mean (C-C) = 0.007 Å
- R factor = 0.041
- wR factor = 0.114
- Data-to-parameter ratio = 21.4
checkCIF/PLATON results
No syntax errors found
Alert level A PLAT241_ALERT_2_A Check High U(eq) as Compared to Neighbors for C17
Author Response: This atom probably shows unresolved disorder over adjacent sites. |
Alert level B PLAT220_ALERT_2_B Large Non-Solvent C Ueq(max)/Ueq(min) ... 3.83 Ratio PLAT242_ALERT_2_B Check Low U(eq) as Compared to Neighbors for C15 PLAT242_ALERT_2_B Check Low U(eq) as Compared to Neighbors for C18
Alert level C PLAT222_ALERT_3_C Large Non-Solvent H Ueq(max)/Ueq(min) ... 3.43 Ratio PLAT230_ALERT_2_C Hirshfeld Test Diff for C16 - C17 .. 5.31 su PLAT241_ALERT_2_C Check High U(eq) as Compared to Neighbors for C19
Author Response: This atom probably shows unresolved disorder over adjacent sites. |
PLAT242_ALERT_2_C Check Low U(eq) as Compared to Neighbors for N2 PLAT244_ALERT_4_C Low Solvent U(eq) as Compared to Neighbors for C20 PLAT360_ALERT_2_C Short C(sp3)-C(sp3) Bond C16 - C17 ... 1.39 Ang. PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........ 2
1 ALERT level A = In general: serious problem 3 ALERT level B = Potentially serious problem 7 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 8 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 2 ALERT type 4 Improvement, methodology, query or suggestion
Computing details top
Data collection: SMART (Bruker, 2001); cell refinement: SAINT (Bruker, 2001); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.
Crystal data top
[SnCl2(C19H22N2O)]·CHCl3 | F(000) = 1200 |
Mr = 603.34 | Dx = 1.640 Mg m−3 |
Monoclinic, P21/n | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -P 2yn | Cell parameters from 967 reflections |
a = 11.877 (1) Å | θ = 2.4–28.3° |
b = 11.559 (1) Å | µ = 1.61 mm−1 |
c = 18.766 (2) Å | T = 223 K |
β = 108.449 (2)° | Block, colorless |
V = 2443.9 (4) Å3 | 0.40 × 0.36 × 0.24 mm |
Z = 4 |
Data collection top
Bruker SMART CCD diffractometer | 5614 independent reflections |
Radiation source: medium-focus sealed tube | 4850 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.027 |
φ and ω scans | θmax = 27.5°, θmin = 1.8° |
Absorption correction: multi-scan (SADABS; Bruker, 2001) | h = −15→15 |
Tmin = 0.545, Tmax = 0.678 | k = −14→15 |
16789 measured reflections | l = −24→16 |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.041 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.114 | H-atom parameters constrained |
S = 1.01 | w = 1/[σ2(Fo2) + (0.0648P)2 + 3.2538P] where P = (Fo2 + 2Fc2)/3 |
5614 reflections | (Δ/σ)max = 0.001 |
262 parameters | Δρmax = 1.31 e Å−3 |
0 restraints | Δρmin = −0.72 e Å−3 |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
x | y | z | Uiso*/Ueq | ||
Sn1 | 0.34057 (2) | 0.46627 (2) | 0.28778 (1) | 0.0312 (1) | |
Cl1 | 0.52697 (9) | 0.55029 (9) | 0.37183 (5) | 0.0476 (2) | |
Cl2 | 0.14078 (8) | 0.38936 (8) | 0.21909 (5) | 0.0434 (2) | |
Cl3 | 0.6614 (4) | 0.8219 (3) | 0.2025 (2) | 0.193 (2) | |
Cl4 | 0.7778 (2) | 0.6333 (3) | 0.2861 (2) | 0.146 (1) | |
Cl5 | 0.7091 (3) | 0.8252 (3) | 0.3605 (2) | 0.171 (1) | |
O1 | 0.4111 (2) | 0.3030 (2) | 0.3018 (1) | 0.0407 (6) | |
N1 | 0.2982 (3) | 0.4312 (3) | 0.3910 (2) | 0.0396 (7) | |
N2 | 0.2503 (3) | 0.6286 (2) | 0.3063 (2) | 0.0384 (6) | |
C1 | 0.3811 (3) | 0.5165 (3) | 0.1895 (2) | 0.035 (1) | |
C2 | 0.2955 (4) | 0.5717 (3) | 0.1303 (2) | 0.043 (1) | |
C3 | 0.3232 (4) | 0.6056 (4) | 0.0668 (2) | 0.052 (1) | |
C4 | 0.4343 (5) | 0.5855 (4) | 0.0621 (2) | 0.058 (1) | |
C5 | 0.5195 (4) | 0.5310 (4) | 0.1198 (3) | 0.058 (1) | |
C6 | 0.4931 (4) | 0.4962 (4) | 0.1837 (2) | 0.046 (1) | |
C7 | 0.4664 (3) | 0.2514 (3) | 0.3673 (2) | 0.037 (1) | |
C8 | 0.5506 (4) | 0.1667 (3) | 0.3686 (3) | 0.051 (1) | |
C9 | 0.6063 (4) | 0.1060 (4) | 0.4341 (3) | 0.064 (1) | |
C10 | 0.5796 (4) | 0.1268 (4) | 0.4993 (3) | 0.058 (1) | |
C11 | 0.4970 (4) | 0.2094 (3) | 0.4992 (2) | 0.045 (1) | |
C12 | 0.4400 (3) | 0.2739 (3) | 0.4343 (2) | 0.036 (1) | |
C13 | 0.3532 (4) | 0.3575 (3) | 0.4405 (2) | 0.040 (1) | |
C14 | 0.2082 (6) | 0.5127 (4) | 0.4029 (3) | 0.069 (2) | |
C15 | 0.1846 (4) | 0.5052 (4) | 0.4760 (2) | 0.047 (1) | |
C16 | 0.0996 (6) | 0.6013 (5) | 0.4832 (4) | 0.089 (2) | |
C17 | 0.1178 (9) | 0.7110 (6) | 0.4582 (4) | 0.132 (4) | |
C18 | 0.1436 (5) | 0.7188 (4) | 0.3861 (3) | 0.062 (1) | |
C19 | 0.2289 (6) | 0.6259 (4) | 0.3777 (3) | 0.079 (2) | |
C20 | 0.6741 (5) | 0.7421 (6) | 0.2808 (3) | 0.083 (2) | |
H2n1 | 0.2966 | 0.6908 | 0.3048 | 0.046* | |
H2n2 | 0.1801 | 0.6367 | 0.2689 | 0.046* | |
H2 | 0.2193 | 0.5857 | 0.1335 | 0.051* | |
H3 | 0.2656 | 0.6424 | 0.0269 | 0.062* | |
H4 | 0.4527 | 0.6092 | 0.0191 | 0.070* | |
H5 | 0.5954 | 0.5172 | 0.1159 | 0.070* | |
H6 | 0.5511 | 0.4590 | 0.2231 | 0.056* | |
H8 | 0.5698 | 0.1506 | 0.3247 | 0.061* | |
H9 | 0.6633 | 0.0497 | 0.4340 | 0.076* | |
H10 | 0.6177 | 0.0848 | 0.5432 | 0.069* | |
H11 | 0.4781 | 0.2233 | 0.5434 | 0.054* | |
H13 | 0.3352 | 0.3576 | 0.4858 | 0.048* | |
H14 | 0.1327 | 0.4879 | 0.3656 | 0.083* | |
H15a | 0.2596 | 0.5119 | 0.5172 | 0.056* | |
H15b | 0.1498 | 0.4296 | 0.4801 | 0.056* | |
H16a | 0.0185 | 0.5772 | 0.4553 | 0.107* | |
H16b | 0.1046 | 0.6074 | 0.5362 | 0.107* | |
H17a | 0.1839 | 0.7470 | 0.4972 | 0.158* | |
H17b | 0.0468 | 0.7575 | 0.4537 | 0.158* | |
H18a | 0.1776 | 0.7950 | 0.3826 | 0.074* | |
H18b | 0.0691 | 0.7121 | 0.3446 | 0.074* | |
H19 | 0.3060 | 0.6491 | 0.4140 | 0.095* | |
H20 | 0.5965 | 0.7048 | 0.2745 | 0.100* |
Atomic displacement parameters (Å2) top
U11 | U22 | U33 | U12 | U13 | U23 | |
Sn1 | 0.0356 (1) | 0.0313 (1) | 0.0264 (1) | 0.00193 (8) | 0.0096 (1) | 0.00093 (8) |
Cl1 | 0.0408 (5) | 0.0611 (6) | 0.0373 (5) | −0.0073 (4) | 0.0072 (4) | −0.0089 (4) |
Cl2 | 0.0403 (4) | 0.0433 (5) | 0.0431 (5) | −0.0039 (4) | 0.0081 (4) | −0.0050 (4) |
Cl3 | 0.324 (5) | 0.148 (2) | 0.120 (2) | −0.064 (3) | 0.092 (3) | 0.017 (2) |
Cl4 | 0.097 (1) | 0.188 (3) | 0.166 (2) | −0.012 (2) | 0.060 (2) | −0.029 (2) |
Cl5 | 0.214 (3) | 0.196 (3) | 0.140 (2) | −0.128 (2) | 0.107 (2) | −0.107 (2) |
O1 | 0.051 (2) | 0.040 (1) | 0.029 (1) | 0.013 (1) | 0.010 (1) | −0.001 (1) |
N1 | 0.055 (2) | 0.033 (1) | 0.037 (2) | 0.008 (1) | 0.022 (2) | 0.006 (1) |
N2 | 0.046 (2) | 0.032 (1) | 0.039 (2) | 0.004 (1) | 0.017 (1) | 0.006 (1) |
C1 | 0.042 (2) | 0.032 (2) | 0.030 (2) | −0.001 (1) | 0.012 (2) | −0.002 (1) |
C2 | 0.051 (2) | 0.042 (2) | 0.037 (2) | 0.006 (2) | 0.016 (2) | 0.003 (2) |
C3 | 0.070 (3) | 0.052 (2) | 0.036 (2) | 0.009 (2) | 0.020 (2) | 0.009 (2) |
C4 | 0.084 (3) | 0.058 (3) | 0.045 (2) | −0.008 (2) | 0.039 (2) | 0.003 (2) |
C5 | 0.052 (3) | 0.078 (3) | 0.053 (3) | −0.004 (2) | 0.029 (2) | −0.008 (2) |
C6 | 0.044 (2) | 0.058 (2) | 0.038 (2) | 0.000 (2) | 0.015 (2) | −0.003 (2) |
C7 | 0.040 (2) | 0.029 (2) | 0.036 (2) | −0.001 (1) | 0.005 (1) | −0.002 (1) |
C8 | 0.056 (2) | 0.044 (2) | 0.049 (2) | 0.013 (2) | 0.014 (2) | −0.002 (2) |
C9 | 0.063 (3) | 0.051 (2) | 0.069 (3) | 0.025 (2) | 0.009 (2) | 0.007 (2) |
C10 | 0.068 (3) | 0.044 (2) | 0.049 (2) | 0.010 (2) | 0.002 (2) | 0.012 (2) |
C11 | 0.055 (2) | 0.036 (2) | 0.036 (2) | −0.002 (2) | 0.004 (2) | 0.004 (2) |
C12 | 0.042 (2) | 0.028 (2) | 0.032 (2) | −0.003 (1) | 0.004 (1) | 0.000 (1) |
C13 | 0.059 (2) | 0.032 (2) | 0.032 (2) | −0.001 (2) | 0.018 (2) | 0.002 (1) |
C14 | 0.101 (4) | 0.054 (3) | 0.078 (4) | 0.032 (3) | 0.064 (3) | 0.025 (2) |
C15 | 0.053 (2) | 0.051 (2) | 0.042 (2) | 0.006 (2) | 0.024 (2) | 0.007 (2) |
C16 | 0.124 (5) | 0.068 (3) | 0.116 (5) | 0.019 (3) | 0.096 (4) | 0.008 (3) |
C17 | 0.218 (9) | 0.105 (5) | 0.124 (6) | 0.097 (6) | 0.127 (7) | 0.047 (5) |
C18 | 0.089 (3) | 0.043 (2) | 0.067 (3) | 0.028 (2) | 0.044 (3) | 0.010 (2) |
C19 | 0.132 (5) | 0.059 (3) | 0.072 (3) | 0.050 (3) | 0.070 (3) | 0.027 (2) |
C20 | 0.081 (4) | 0.098 (4) | 0.081 (4) | −0.031 (3) | 0.040 (3) | −0.022 (3) |
Geometric parameters (Å, º) top
Sn1—Cl1 | 2.474 (1) | C15—C16 | 1.536 (7) |
Sn1—Cl2 | 2.479 (1) | C16—C17 | 1.392 (9) |
Sn1—O1 | 2.048 (2) | C17—C18 | 1.482 (7) |
Sn1—C1 | 2.129 (4) | C18—C19 | 1.519 (6) |
Sn1—N1 | 2.188 (3) | N2—H2n1 | 0.91 |
Sn1—N2 | 2.243 (3) | N2—H2n2 | 0.91 |
Cl3—C20 | 1.701 (7) | C2—H2 | 0.94 |
Cl4—C20 | 1.741 (7) | C3—H3 | 0.94 |
Cl5—C20 | 1.715 (6) | C4—H4 | 0.94 |
O1—C7 | 1.337 (4) | C5—H5 | 0.94 |
N1—C13 | 1.278 (5) | C6—H6 | 0.94 |
N1—C14 | 1.494 (5) | C8—H8 | 0.94 |
N2—C19 | 1.440 (5) | C9—H9 | 0.94 |
C1—C6 | 1.388 (5) | C10—H10 | 0.94 |
C1—C2 | 1.400 (5) | C11—H11 | 0.94 |
C2—C3 | 1.390 (5) | C13—H13 | 0.94 |
C3—C4 | 1.370 (7) | C14—H14 | 0.99 |
C4—C5 | 1.379 (7) | C15—H15a | 0.98 |
C5—C6 | 1.392 (6) | C15—H15b | 0.98 |
C7—C8 | 1.394 (5) | C16—H16a | 0.98 |
C7—C12 | 1.413 (5) | C16—H16b | 0.98 |
C8—C9 | 1.388 (6) | C17—H17a | 0.98 |
C9—C10 | 1.378 (7) | C17—H17b | 0.98 |
C10—C11 | 1.368 (6) | C18—H18a | 0.98 |
C11—C12 | 1.406 (5) | C18—H18b | 0.98 |
C12—C13 | 1.444 (5) | C19—H19 | 0.99 |
C14—C19 | 1.438 (7) | C20—H20 | 0.99 |
C14—C15 | 1.487 (6) | ||
Cl1—Sn1—Cl2 | 171.21 (3) | Cl5—C20—Cl4 | 112.5 (4) |
Cl1—Sn1—O1 | 91.9 (1) | C19—N2—H2n1 | 109.4 |
Cl1—Sn1—C1 | 92.5 (1) | Sn1—N2—H2n1 | 109.4 |
Cl1—Sn1—N1 | 85.3 (1) | C19—N2—H2n2 | 109.4 |
Cl1—Sn1—N2 | 87.0 (1) | Sn1—N2—H2n2 | 109.4 |
Cl2—Sn1—O1 | 91.2 (1) | H2n1—N2—H2n2 | 108.0 |
Cl2—Sn1—N1 | 86.8 (1) | C3—C2—H2 | 120.0 |
Cl2—Sn1—N2 | 87.4 (1) | C1—C2—H2 | 120.0 |
Cl2—Sn1—C1 | 95.1 (1) | C4—C3—H3 | 119.9 |
O1—Sn1—N1 | 85.1 (1) | C2—C3—H3 | 119.9 |
O1—Sn1—N2 | 161.4 (1) | C3—C4—H4 | 119.7 |
O1—Sn1—C1 | 99.7 (1) | C5—C4—H4 | 119.7 |
N1—Sn1—N2 | 76.3 (1) | C4—C5—H5 | 120.0 |
N1—Sn1—C1 | 174.8 (1) | C6—C5—H5 | 120.0 |
N2—Sn1—C1 | 99.0 (1) | C1—C6—H6 | 120.0 |
C7—O1—Sn1 | 126.2 (2) | C5—C6—H6 | 120.0 |
C13—N1—C14 | 122.5 (3) | C9—C8—H8 | 119.7 |
C13—N1—Sn1 | 124.0 (3) | C7—C8—H8 | 119.7 |
C14—N1—Sn1 | 113.0 (2) | C10—C9—H9 | 119.4 |
C19—N2—Sn1 | 111.1 (2) | C8—C9—H9 | 119.4 |
C6—C1—C2 | 119.3 (4) | C10—C11—H11 | 119.3 |
C6—C1—Sn1 | 120.4 (3) | C12—C11—H11 | 119.3 |
C2—C1—Sn1 | 120.3 (3) | N1—C13—H13 | 116.5 |
C3—C2—C1 | 119.9 (4) | C12—C13—H13 | 116.5 |
C4—C3—C2 | 120.1 (4) | C19—C14—H14 | 104.0 |
C3—C4—C5 | 120.6 (4) | C15—C14—H14 | 104.0 |
C4—C5—C6 | 120.0 (4) | N1—C14—H14 | 104.0 |
C1—C6—C5 | 120.1 (4) | C14—C15—H15a | 109.4 |
O1—C7—C8 | 118.1 (3) | C16—C15—H15a | 109.4 |
O1—C7—C12 | 123.6 (3) | C14—C15—H15b | 109.4 |
C8—C7—C12 | 118.3 (3) | C16—C15—H15b | 109.4 |
C9—C8—C7 | 120.6 (4) | H15a—C15—H15b | 108.0 |
C10—C9—C8 | 121.3 (4) | C17—C16—H16a | 108.1 |
C11—C10—C9 | 119.1 (4) | C15—C16—H16a | 108.1 |
C11—C10—H10 | 120.5 | C17—C16—H16b | 108.1 |
C9—C10—H10 | 120.5 | C15—C16—H16b | 108.1 |
C10—C11—C12 | 121.3 (4) | H16a—C16—H16b | 107.3 |
C11—C12—C7 | 119.4 (3) | C16—C17—H17a | 107.9 |
C11—C12—C13 | 116.4 (3) | C18—C17—H17a | 107.9 |
C7—C12—C13 | 124.1 (3) | C16—C17—H17b | 107.9 |
N1—C13—C12 | 126.9 (3) | C18—C17—H17b | 107.9 |
C19—C14—C15 | 117.3 (5) | H17a—C17—H17b | 107.2 |
C19—C14—N1 | 108.6 (4) | C17—C18—H18a | 109.0 |
C15—C14—N1 | 117.0 (4) | C19—C18—H18a | 109.0 |
C14—C15—C16 | 111.1 (4) | C17—C18—H18b | 109.0 |
C17—C16—C15 | 116.9 (5) | C19—C18—H18b | 109.0 |
C16—C17—C18 | 117.5 (6) | H18a—C18—H18b | 107.8 |
C17—C18—C19 | 112.9 (4) | C14—C19—H19 | 103.8 |
C14—C19—N2 | 115.2 (4) | N2—C19—H19 | 103.8 |
C14—C19—C18 | 114.8 (5) | C18—C19—H19 | 103.8 |
N2—C19—C18 | 113.6 (4) | Cl3—C20—H20 | 107.9 |
Cl3—C20—Cl5 | 112.3 (4) | Cl5—C20—H20 | 107.9 |
Cl3—C20—Cl4 | 108.0 (4) | Cl4—C20—H20 | 107.9 |
C1—Sn1—O1—C7 | 143.5 (3) | Sn1—O1—C7—C8 | −152.9 (3) |
N1—Sn1—O1—C7 | −34.5 (3) | Sn1—O1—C7—C12 | 30.5 (5) |
N2—Sn1—O1—C7 | −35.5 (5) | O1—C7—C8—C9 | −176.6 (4) |
Cl1—Sn1—O1—C7 | 50.6 (3) | C12—C7—C8—C9 | 0.2 (6) |
Cl2—Sn1—O1—C7 | −121.1 (3) | C7—C8—C9—C10 | 0.5 (7) |
O1—Sn1—N1—C13 | 23.9 (3) | C8—C9—C10—C11 | −0.3 (7) |
N2—Sn1—N1—C13 | −156.4 (3) | C9—C10—C11—C12 | −0.6 (6) |
Cl1—Sn1—N1—C13 | −68.4 (3) | C10—C11—C12—C7 | 1.3 (5) |
Cl2—Sn1—N1—C13 | 115.4 (3) | C10—C11—C12—C13 | 179.1 (4) |
O1—Sn1—N1—C14 | −163.4 (4) | O1—C7—C12—C11 | 175.5 (3) |
N2—Sn1—N1—C14 | 16.3 (4) | C8—C7—C12—C11 | −1.1 (5) |
Cl1—Sn1—N1—C14 | 104.3 (4) | O1—C7—C12—C13 | −2.1 (5) |
Cl2—Sn1—N1—C14 | −71.8 (4) | C8—C7—C12—C13 | −178.7 (4) |
O1—Sn1—N2—C19 | 8.1 (6) | C14—N1—C13—C12 | 178.9 (4) |
C1—Sn1—N2—C19 | −170.9 (4) | Sn1—N1—C13—C12 | −9.0 (6) |
N1—Sn1—N2—C19 | 7.0 (4) | C11—C12—C13—N1 | 173.9 (4) |
Cl1—Sn1—N2—C19 | −78.9 (4) | C7—C12—C13—N1 | −8.4 (6) |
Cl2—Sn1—N2—C19 | 94.3 (4) | C13—N1—C14—C19 | 135.8 (5) |
O1—Sn1—C1—C6 | −45.7 (3) | Sn1—N1—C14—C19 | −37.1 (6) |
N2—Sn1—C1—C6 | 134.0 (3) | C13—N1—C14—C15 | 0.2 (8) |
Cl1—Sn1—C1—C6 | 46.6 (3) | Sn1—N1—C14—C15 | −172.7 (4) |
Cl2—Sn1—C1—C6 | −137.8 (3) | C19—C14—C15—C16 | 42.9 (8) |
O1—Sn1—C1—C2 | 135.0 (3) | N1—C14—C15—C16 | 174.6 (5) |
N2—Sn1—C1—C2 | −45.3 (3) | C14—C15—C16—C17 | −41.7 (9) |
Cl1—Sn1—C1—C2 | −132.7 (3) | C15—C16—C17—C18 | 43.2 (12) |
Cl2—Sn1—C1—C2 | 42.9 (3) | C16—C17—C18—C19 | −41.8 (11) |
C6—C1—C2—C3 | −0.2 (6) | C15—C14—C19—N2 | −179.5 (5) |
Sn1—C1—C2—C3 | 179.1 (3) | N1—C14—C19—N2 | 45.1 (7) |
C1—C2—C3—C4 | −0.2 (6) | C15—C14—C19—C18 | −44.7 (8) |
C2—C3—C4—C5 | 0.5 (7) | N1—C14—C19—C18 | 179.9 (5) |
C3—C4—C5—C6 | −0.3 (7) | Sn1—N2—C19—C14 | −31.2 (7) |
C2—C1—C6—C5 | 0.3 (6) | Sn1—N2—C19—C18 | −166.5 (4) |
Sn1—C1—C6—C5 | −179.0 (3) | C17—C18—C19—C14 | 41.6 (9) |
C4—C5—C6—C1 | 0.0 (7) | C17—C18—C19—N2 | 177.0 (6) |
Hydrogen-bond geometry (Å, º) top
D—H···A | D—H | H···A | D···A | D—H···A |
N2—H2n1···Cl2i | 0.91 | 2.50 | 3.372 (3) | 162 |
N2—H2n2···O1i | 0.91 | 2.39 | 3.065 (4) | 131 |
Symmetry code: (i) −x+1/2, y+1/2, −z+1/2. |
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