cis-Di-tert-butyl­amido­tetra-μ-tert-butyl­imido-di-μ-oxo-tetra­tellurium diiodide acetonitrile solvate

The title compound, C₂₄H₅₆N₆O₂Te₄²⁺·2I⁻·C₂H₃N or H[(^tBuNH)Te(μ-N^tBu)₂Te(μ-O)]₂(I)₂·MeCN, provides the first example of the cis form of an imidotelluroxane dication. The basket-shaped structure is bis­pirocyclic, with a `backbone' Te...Te...Te...Te pseudo-torsion angle of −31.51 (3)°. The structure exhibits two ionic Te...I inter­actions [3.4103 (8) and 3.445 (1) Å] and two Te...I close contacts [3.863 (1) and 3.924 (1) Å] within the mol­ecule, and two Te...I close contacts [3.651 (1) and 3.703 (2) Å] between ions. The inter­molecular close contacts connect the cations into pairs which are linked by a weak Te...I contact [4.090 (1) Å] to form an infinite chain.

Key indicators

• Single-crystal X-ray study
• T = 173 K
• Mean [sigma](C-C) = 0.007 Å
• R factor = 0.025
• wR factor = 0.055
• Data-to-parameter ratio = 19.9

checkCIF/PLATON results

No syntax errors found



Alert level A
PLAT432_ALERT_2_A Short Inter X...Y Contact  I1     ..  Te1A    ..       3.41 Ang.

Author Response: As discussed in the text, this is a typical distance for an ionic Te...I interaction

PLAT432_ALERT_2_A Short Inter X...Y Contact  I2     ..  Te1B    ..       3.45 Ang.

Author Response: As discussed in the text, this is a typical distance for an ionic Te...I interaction

Alert level C
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.12 Ratio
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for       C10A
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for         C5
PLAT420_ALERT_2_C D-H Without Acceptor       N1A    -   H1A    ...          ?

Author Response: Hydrogen atom of N-H group is shielded by the molecule and does not show hydrogen bonding

PLAT420_ALERT_2_C D-H Without Acceptor       N1B    -   H1B    ...          ?

Author Response: Hydrogen atom of N-H group is shielded by the molecule and does not show hydrogen bonding

   2 ALERT level A = In general: serious problem
   0 ALERT level B = Potentially serious problem
   6 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   6 ALERT type 2 Indicator that the structure model may be wrong or deficient
   0 ALERT type 3 Indicator that the structure quality may be low
   1 ALERT type 4 Improvement, methodology, query or suggestion

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Computing details

Data collection: COLLECT (Nonius, 2000); cell refinement: SCALEPACK (Otwinowski & Minor 1997); data reduction: DENZO-SMN (Otwinowski & Minor 1997); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: DIAMOND (Brandenburg & Berndt, 1999); software used to prepare material for publication: WinGX (Version 1.64-05; Farrugia, 1999).

cis-Di-tert-butylamidotetra-µ-tert-butylimido-di-µ-oxo-tetratellurium diiodide acetonitrile solvate

Crystal data

C24H56N6O2Te4^2+·2I^−·C2H3N	Z = 2
Mr = 1266.00	F(000) = 1188
Triclinic, P1	Dx = 2.001 Mg m^−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 12.340 (3) Å	Cell parameters from 37429 reflections
b = 12.836 (3) Å	θ = 2.3–25.0°
c = 14.121 (3) Å	µ = 4.25 mm^−1
α = 81.70 (3)°	T = 173 K
β = 86.20 (3)°	Rod, yellow
γ = 71.78 (3)°	0.20 × 0.08 × 0.05 mm
V = 2101.8 (9) Å^3

Data collection

Nonius KappaCCD (FR540C) diffractometer	7399 independent reflections
Radiation source: Enraf–Nonius FR590D, fine-focus sealed tube	6465 reflections with I > 2σ(I)
Horizonally mounted graphite crystal monochromator	Rint = 0.061
CCD rotation images, thick slices scans	θmax = 25.0°, θmin = 2.3°
Absorption correction: multi-scan (SHELXTL; Bruker, 2001)	h = −14→14
Tmin = 0.484, Tmax = 0.816	k = −15→15
37429 measured reflections	l = −16→16

Refinement

Refinement on F^2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F^2 > 2σ(F^2)] = 0.026	H-atom parameters constrained
wR(F^2) = 0.055	w = 1/[σ^2(Fo^2) + (0.0109P)^2 + 2.0911P] where P = (Fo^2 + 2Fc^2)/3
S = 1.10	(Δ/σ)max = 0.002
7399 reflections	Δρmax = 0.96 e Å^−3
372 parameters	Δρmin = −1.40 e Å^−3
0 restraints	Extinction correction: SHELXL97, Fc^*=kFc[1+0.001xFc^2λ^3/sin(2θ)]^-1/4
Primary atom site location: structure-invariant direct methods	Extinction coefficient: 0.00098 (7)

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Te1A	0.28213 (2)	−0.051701 (19)	0.278011 (18)	0.02205 (8)
Te2A	0.09992 (2)	0.155294 (19)	0.176249 (17)	0.01799 (7)
Te2B	0.08656 (2)	0.403556 (19)	0.125317 (17)	0.01951 (8)
Te1B	0.17772 (2)	0.56572 (2)	0.220231 (18)	0.02204 (8)
I2	0.13430 (2)	0.67213 (2)	−0.017416 (19)	0.03067 (8)
I1	0.03397 (3)	0.88462 (2)	0.27605 (2)	0.03362 (9)
O1A	0.1768 (2)	0.2439 (2)	0.09410 (18)	0.0228 (6)
O1B	0.0414 (2)	0.3074 (2)	0.22621 (18)	0.0227 (6)
N1A	0.4301 (3)	−0.0241 (3)	0.2854 (3)	0.0387 (10)
H1A	0.4323	0.0433	0.2645	0.046*
N2A	0.2423 (3)	0.0209 (3)	0.1483 (2)	0.0232 (7)
N3A	0.1857 (3)	0.0992 (2)	0.3021 (2)	0.0200 (7)
N1B	0.2323 (3)	0.5000 (3)	0.3503 (2)	0.0326 (9)
H1B	0.2301	0.4320	0.3680	0.039*
N2B	0.0394 (3)	0.5206 (2)	0.2241 (2)	0.0234 (7)
N3B	0.2342 (3)	0.4203 (3)	0.1670 (2)	0.0252 (8)
C10A	0.5371 (4)	−0.1050 (4)	0.3223 (3)	0.0353 (11)
C11A	0.5214 (5)	−0.1426 (5)	0.4286 (4)	0.0568 (15)
H11A	0.4608	−0.1778	0.4370	0.068*
H11B	0.5003	−0.0784	0.4637	0.068*
H11C	0.5929	−0.1957	0.4532	0.068*
C12A	0.6292 (4)	−0.0508 (4)	0.3067 (4)	0.0574 (15)
H12A	0.6377	−0.0274	0.2382	0.069*
H12B	0.7013	−0.1033	0.3306	0.069*
H12C	0.6088	0.0140	0.3412	0.069*
C13A	0.5665 (4)	−0.2076 (4)	0.2707 (5)	0.0601 (16)
H13A	0.5051	−0.2414	0.2820	0.072*
H13B	0.6380	−0.2608	0.2952	0.072*
H13C	0.5754	−0.1861	0.2019	0.072*
C20A	0.2630 (4)	−0.0333 (3)	0.0594 (3)	0.0309 (10)
C21A	0.1513 (4)	−0.0074 (4)	0.0078 (3)	0.0397 (12)
H21A	0.0985	−0.0380	0.0488	0.048*
H21B	0.1660	−0.0404	−0.0520	0.048*
H21C	0.1176	0.0730	−0.0065	0.048*
C22A	0.3130 (5)	−0.1578 (4)	0.0839 (4)	0.0517 (15)
H22A	0.2583	−0.1867	0.1242	0.062*
H22B	0.3840	−0.1749	0.1185	0.062*
H22C	0.3289	−0.1923	0.0248	0.062*
C23A	0.3459 (6)	0.0136 (6)	−0.0031 (4)	0.0717 (19)
H23A	0.3123	0.0939	−0.0181	0.086*
H23B	0.3619	−0.0201	−0.0625	0.086*
H23C	0.4171	−0.0028	0.0311	0.086*
C30A	0.1394 (3)	0.1255 (3)	0.4004 (3)	0.0245 (9)
C31A	0.0104 (4)	0.1493 (3)	0.4088 (3)	0.0314 (10)
H31A	−0.0093	0.0843	0.3962	0.038*
H31B	−0.0266	0.2128	0.3620	0.038*
H31C	−0.0160	0.1660	0.4735	0.038*
C32A	0.1953 (4)	0.0261 (3)	0.4751 (3)	0.0361 (11)
H32A	0.1746	−0.0384	0.4629	0.043*
H32B	0.1683	0.0440	0.5394	0.043*
H32C	0.2784	0.0096	0.4705	0.043*
C33A	0.1717 (4)	0.2255 (4)	0.4197 (3)	0.0369 (11)
H33A	0.2548	0.2092	0.4141	0.044*
H33B	0.1459	0.2425	0.4844	0.044*
H33C	0.1353	0.2893	0.3730	0.044*
C10B	0.2762 (4)	0.5483 (3)	0.4217 (3)	0.0289 (10)
C11B	0.3529 (4)	0.4533 (4)	0.4875 (4)	0.0447 (13)
H11D	0.3082	0.4067	0.5195	0.054*
H11E	0.3845	0.4829	0.5355	0.054*
H11F	0.4152	0.4090	0.4497	0.054*
C12B	0.1777 (4)	0.6163 (4)	0.4804 (3)	0.0415 (12)
H12D	0.1345	0.5685	0.5129	0.050*
H12E	0.1273	0.6765	0.4379	0.050*
H12F	0.2082	0.6473	0.5282	0.050*
C13B	0.3435 (4)	0.6216 (4)	0.3713 (3)	0.0412 (12)
H13D	0.2931	0.6824	0.3293	0.049*
H13E	0.4059	0.5779	0.3331	0.049*
H13F	0.3751	0.6518	0.4189	0.049*
C20B	−0.0803 (3)	0.5918 (3)	0.2411 (3)	0.0233 (9)
C21B	−0.0861 (4)	0.6298 (3)	0.3393 (3)	0.0295 (10)
H21D	−0.0620	0.5651	0.3881	0.035*
H21E	−0.1646	0.6735	0.3536	0.035*
H21F	−0.0355	0.6753	0.3394	0.035*
C22B	−0.1175 (4)	0.6913 (3)	0.1641 (3)	0.0334 (10)
H22D	−0.1133	0.6657	0.1015	0.040*
H22E	−0.0669	0.7369	0.1636	0.040*
H22F	−0.1961	0.7352	0.1778	0.040*
C23B	−0.1586 (4)	0.5198 (3)	0.2425 (3)	0.0337 (11)
H23D	−0.1342	0.4561	0.2921	0.040*
H23E	−0.1545	0.4940	0.1799	0.040*
H23F	−0.2373	0.5634	0.2562	0.040*
C30B	0.3531 (4)	0.3743 (3)	0.1247 (3)	0.0300 (10)
C31B	0.4232 (4)	0.4496 (4)	0.1401 (4)	0.0450 (13)
H31D	0.3893	0.5232	0.1050	0.054*
H31E	0.5017	0.4183	0.1168	0.054*
H31F	0.4235	0.4553	0.2085	0.054*
C32B	0.4056 (4)	0.2596 (4)	0.1793 (4)	0.0387 (11)
H32D	0.4061	0.2652	0.2477	0.046*
H32E	0.4841	0.2282	0.1559	0.046*
H32F	0.3605	0.2115	0.1694	0.046*
C33B	0.3515 (4)	0.3676 (4)	0.0178 (3)	0.0366 (11)
H33D	0.3176	0.4419	−0.0163	0.044*
H33E	0.3062	0.3199	0.0072	0.044*
H33F	0.4298	0.3367	−0.0063	0.044*
C4	0.7574 (5)	0.1876 (6)	0.2503 (4)	0.0702 (18)
H4A	0.8216	0.1232	0.2728	0.084*
H4B	0.7864	0.2453	0.2151	0.084*
H4C	0.7107	0.1659	0.2080	0.084*
C5	0.6895 (5)	0.2291 (5)	0.3304 (5)	0.0625 (16)
N4	0.6361 (6)	0.2601 (6)	0.3922 (5)	0.111 (2)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Te1A	0.02189 (15)	0.01550 (13)	0.02704 (16)	−0.00353 (11)	−0.00383 (11)	−0.00077 (11)
Te2A	0.01948 (14)	0.01570 (13)	0.01856 (14)	−0.00509 (11)	−0.00188 (10)	−0.00151 (10)
Te2B	0.02357 (15)	0.01600 (13)	0.01845 (14)	−0.00604 (11)	−0.00232 (11)	0.00020 (10)
Te1B	0.02582 (15)	0.01937 (13)	0.02221 (15)	−0.00889 (12)	−0.00315 (11)	−0.00122 (11)
I2	0.03816 (18)	0.03006 (15)	0.02587 (16)	−0.01508 (13)	−0.00761 (12)	0.00314 (12)
I1	0.03795 (18)	0.03004 (15)	0.03790 (18)	−0.01899 (14)	−0.00096 (13)	−0.00130 (12)
O1A	0.0271 (15)	0.0183 (13)	0.0219 (15)	−0.0074 (12)	0.0037 (12)	0.0000 (11)
O1B	0.0287 (16)	0.0177 (13)	0.0216 (15)	−0.0068 (12)	0.0007 (12)	−0.0034 (11)
N1A	0.026 (2)	0.0260 (19)	0.060 (3)	−0.0068 (17)	−0.0151 (19)	0.0123 (18)
N2A	0.0233 (18)	0.0223 (17)	0.0231 (18)	−0.0045 (15)	−0.0009 (14)	−0.0051 (14)
N3A	0.0215 (18)	0.0181 (16)	0.0190 (17)	−0.0038 (14)	−0.0007 (14)	−0.0027 (13)
N1B	0.050 (2)	0.0256 (18)	0.028 (2)	−0.0210 (18)	−0.0097 (17)	0.0029 (15)
N2B	0.0219 (18)	0.0205 (16)	0.0278 (19)	−0.0059 (15)	−0.0022 (15)	−0.0036 (14)
N3B	0.0258 (19)	0.0224 (17)	0.0297 (19)	−0.0094 (15)	−0.0007 (15)	−0.0066 (15)
C10A	0.022 (2)	0.036 (2)	0.043 (3)	−0.004 (2)	−0.009 (2)	0.001 (2)
C11A	0.050 (3)	0.056 (3)	0.053 (3)	−0.003 (3)	−0.014 (3)	0.007 (3)
C12A	0.033 (3)	0.057 (3)	0.081 (4)	−0.015 (3)	−0.015 (3)	0.002 (3)
C13A	0.031 (3)	0.057 (3)	0.092 (5)	−0.002 (3)	−0.007 (3)	−0.028 (3)
C20A	0.033 (2)	0.034 (2)	0.027 (2)	−0.008 (2)	0.0007 (19)	−0.0125 (19)
C21A	0.045 (3)	0.039 (3)	0.033 (3)	−0.005 (2)	−0.009 (2)	−0.016 (2)
C22A	0.053 (3)	0.042 (3)	0.054 (3)	0.007 (3)	−0.015 (3)	−0.029 (3)
C23A	0.080 (4)	0.102 (5)	0.054 (4)	−0.051 (4)	0.041 (3)	−0.043 (3)
C30A	0.028 (2)	0.026 (2)	0.017 (2)	−0.0063 (19)	0.0014 (17)	−0.0020 (17)
C31A	0.035 (3)	0.031 (2)	0.025 (2)	−0.006 (2)	0.0057 (19)	−0.0036 (18)
C32A	0.043 (3)	0.035 (2)	0.024 (2)	−0.005 (2)	−0.003 (2)	−0.0002 (19)
C33A	0.051 (3)	0.035 (2)	0.028 (2)	−0.015 (2)	−0.005 (2)	−0.012 (2)
C10B	0.041 (3)	0.024 (2)	0.024 (2)	−0.013 (2)	−0.0085 (19)	0.0002 (18)
C11B	0.049 (3)	0.034 (3)	0.046 (3)	−0.006 (2)	−0.019 (2)	0.001 (2)
C12B	0.050 (3)	0.040 (3)	0.035 (3)	−0.013 (2)	−0.003 (2)	−0.007 (2)
C13B	0.056 (3)	0.037 (3)	0.039 (3)	−0.027 (2)	−0.008 (2)	−0.002 (2)
C20B	0.023 (2)	0.022 (2)	0.023 (2)	−0.0042 (18)	−0.0019 (17)	−0.0040 (17)
C21B	0.034 (3)	0.030 (2)	0.026 (2)	−0.012 (2)	0.0033 (19)	−0.0060 (18)
C22B	0.029 (2)	0.034 (2)	0.030 (2)	−0.002 (2)	0.0017 (19)	−0.0025 (19)
C23B	0.026 (2)	0.033 (2)	0.044 (3)	−0.009 (2)	0.003 (2)	−0.015 (2)
C30B	0.024 (2)	0.030 (2)	0.037 (3)	−0.009 (2)	0.0031 (19)	−0.0067 (19)
C31B	0.030 (3)	0.047 (3)	0.063 (3)	−0.018 (2)	0.011 (2)	−0.013 (3)
C32B	0.023 (2)	0.034 (2)	0.053 (3)	−0.002 (2)	−0.001 (2)	−0.003 (2)
C33B	0.035 (3)	0.037 (2)	0.039 (3)	−0.015 (2)	0.012 (2)	−0.009 (2)
C4	0.052 (4)	0.104 (5)	0.052 (4)	−0.027 (4)	0.006 (3)	−0.002 (3)
C5	0.057 (4)	0.086 (4)	0.056 (4)	−0.038 (4)	0.002 (3)	−0.013 (3)
N4	0.112 (6)	0.140 (6)	0.098 (5)	−0.053 (5)	0.037 (4)	−0.054 (5)

Geometric parameters (Å, º)

Te1A—N2A	1.951 (3)	C30A—C32A	1.540 (5)
Te1A—N1A	1.978 (4)	C31A—H31A	0.9800
Te1A—N3A	1.995 (3)	C31A—H31B	0.9800
Te1A—Te2A	3.1255 (14)	C31A—H31C	0.9800
Te2A—O1A	1.920 (3)	C32A—H32A	0.9800
Te2A—N3A	2.050 (3)	C32A—H32B	0.9800
Te2A—O1B	2.069 (2)	C32A—H32C	0.9800
Te2A—N2A	2.104 (3)	C33A—H33A	0.9800
Te2A—Te2B	3.1183 (8)	C33A—H33B	0.9800
Te2B—O1B	1.918 (3)	C33A—H33C	0.9800
Te2B—N3B	2.034 (3)	C10B—C13B	1.516 (6)
Te2B—O1A	2.098 (3)	C10B—C11B	1.520 (6)
Te2B—N2B	2.119 (3)	C10B—C12B	1.529 (6)
Te2B—Te1B	3.1407 (8)	C11B—H11D	0.9800
Te1B—N2B	1.963 (3)	C11B—H11E	0.9800
Te1B—N1B	1.975 (3)	C11B—H11F	0.9800
Te1B—N3B	2.013 (3)	C12B—H12D	0.9800
N1A—C10A	1.473 (5)	C12B—H12E	0.9800
N1A—H1A	0.8800	C12B—H12F	0.9800
N2A—C20A	1.492 (5)	C13B—H13D	0.9800
N3A—C30A	1.509 (5)	C13B—H13E	0.9800
N1B—C10B	1.470 (5)	C13B—H13F	0.9800
N1B—H1B	0.8800	C20B—C22B	1.523 (5)
N2B—C20B	1.499 (5)	C20B—C21B	1.525 (5)
N3B—C30B	1.518 (5)	C20B—C23B	1.529 (6)
C10A—C12A	1.498 (7)	C21B—H21D	0.9800
C10A—C11A	1.528 (7)	C21B—H21E	0.9800
C10A—C13A	1.528 (7)	C21B—H21F	0.9800
C11A—H11A	0.9800	C22B—H22D	0.9800
C11A—H11B	0.9800	C22B—H22E	0.9800
C11A—H11C	0.9800	C22B—H22F	0.9800
C12A—H12A	0.9800	C23B—H23D	0.9800
C12A—H12B	0.9800	C23B—H23E	0.9800
C12A—H12C	0.9800	C23B—H23F	0.9800
C13A—H13A	0.9800	C30B—C32B	1.525 (6)
C13A—H13B	0.9800	C30B—C33B	1.526 (6)
C13A—H13C	0.9800	C30B—C31B	1.528 (6)
C20A—C23A	1.516 (7)	C31B—H31D	0.9800
C20A—C22A	1.519 (6)	C31B—H31E	0.9800
C20A—C21A	1.521 (6)	C31B—H31F	0.9800
C21A—H21A	0.9800	C32B—H32D	0.9800
C21A—H21B	0.9800	C32B—H32E	0.9800
C21A—H21C	0.9800	C32B—H32F	0.9800
C22A—H22A	0.9800	C33B—H33D	0.9800
C22A—H22B	0.9800	C33B—H33E	0.9800
C22A—H22C	0.9800	C33B—H33F	0.9800
C23A—H23A	0.9800	C4—C5	1.426 (9)
C23A—H23B	0.9800	C4—H4A	0.9800
C23A—H23C	0.9800	C4—H4B	0.9800
C30A—C33A	1.522 (6)	C4—H4C	0.9800
C30A—C31A	1.524 (6)	C5—N4	1.102 (8)
N2A—Te1A—N1A	98.69 (15)	N3A—C30A—C32A	109.1 (3)
N2A—Te1A—N3A	78.31 (13)	C33A—C30A—C32A	109.2 (3)
N1A—Te1A—N3A	95.78 (14)	C31A—C30A—C32A	108.4 (3)
N1A—Te1A—Te2A	111.52 (10)	C30A—C31A—H31A	109.5
O1A—Te2A—N3A	108.84 (12)	C30A—C31A—H31B	109.5
O1A—Te2A—O1B	76.48 (11)	H31A—C31A—H31B	109.5
N3A—Te2A—O1B	86.14 (11)	C30A—C31A—H31C	109.5
O1A—Te2A—N2A	85.16 (12)	H31A—C31A—H31C	109.5
N3A—Te2A—N2A	73.70 (12)	H31B—C31A—H31C	109.5
O1B—Te2A—N2A	146.71 (12)	C30A—C32A—H32A	109.5
N3A—Te2A—Te2B	106.65 (9)	C30A—C32A—H32B	109.5
N2A—Te2A—Te2B	124.79 (9)	H32A—C32A—H32B	109.5
O1A—Te2A—Te1A	108.92 (8)	C30A—C32A—H32C	109.5
O1B—Te2A—Te1A	124.41 (7)	H32A—C32A—H32C	109.5
Te2B—Te2A—Te1A	133.25 (2)	H32B—C32A—H32C	109.5
O1B—Te2B—N3B	106.28 (12)	C30A—C33A—H33A	109.5
O1B—Te2B—O1A	75.83 (10)	C30A—C33A—H33B	109.5
N3B—Te2B—O1A	89.50 (12)	H33A—C33A—H33B	109.5
O1B—Te2B—N2B	84.69 (11)	C30A—C33A—H33C	109.5
N3B—Te2B—N2B	73.60 (13)	H33A—C33A—H33C	109.5
O1A—Te2B—N2B	149.56 (11)	H33B—C33A—H33C	109.5
N3B—Te2B—Te2A	107.65 (9)	N1B—C10B—C13B	109.4 (3)
N2B—Te2B—Te2A	124.25 (9)	N1B—C10B—C11B	107.4 (3)
O1B—Te2B—Te1B	107.75 (8)	C13B—C10B—C11B	110.4 (4)
O1A—Te2B—Te1B	128.06 (7)	N1B—C10B—C12B	110.3 (4)
Te2A—Te2B—Te1B	134.21 (2)	C13B—C10B—C12B	109.8 (4)
N2B—Te1B—N1B	98.88 (14)	C11B—C10B—C12B	109.5 (4)
N2B—Te1B—N3B	77.50 (13)	C10B—C11B—H11D	109.5
N1B—Te1B—N3B	93.82 (14)	C10B—C11B—H11E	109.5
N1B—Te1B—Te2B	110.68 (10)	H11D—C11B—H11E	109.5
Te2A—O1A—Te2B	101.71 (12)	C10B—C11B—H11F	109.5
Te2B—O1B—Te2A	102.83 (12)	H11D—C11B—H11F	109.5
C10A—N1A—Te1A	126.5 (3)	H11E—C11B—H11F	109.5
C10A—N1A—H1A	116.8	C10B—C12B—H12D	109.5
Te1A—N1A—H1A	116.8	C10B—C12B—H12E	109.5
C20A—N2A—Te1A	126.5 (3)	H12D—C12B—H12E	109.5
C20A—N2A—Te2A	125.5 (3)	C10B—C12B—H12F	109.5
Te1A—N2A—Te2A	100.78 (14)	H12D—C12B—H12F	109.5
C30A—N3A—Te1A	122.5 (2)	H12E—C12B—H12F	109.5
C30A—N3A—Te2A	126.3 (2)	C10B—C13B—H13D	109.5
Te1A—N3A—Te2A	101.19 (13)	C10B—C13B—H13E	109.5
C10B—N1B—Te1B	129.2 (3)	H13D—C13B—H13E	109.5
C10B—N1B—H1B	115.4	C10B—C13B—H13F	109.5
Te1B—N1B—H1B	115.4	H13D—C13B—H13F	109.5
C20B—N2B—Te1B	126.2 (2)	H13E—C13B—H13F	109.5
C20B—N2B—Te2B	124.5 (2)	N2B—C20B—C22B	112.2 (3)
Te1B—N2B—Te2B	100.54 (14)	N2B—C20B—C21B	107.9 (3)
C30B—N3B—Te1B	124.1 (2)	C22B—C20B—C21B	110.3 (3)
C30B—N3B—Te2B	127.3 (2)	N2B—C20B—C23B	107.5 (3)
Te1B—N3B—Te2B	101.78 (15)	C22B—C20B—C23B	109.9 (3)
N1A—C10A—C12A	108.1 (4)	C21B—C20B—C23B	108.9 (3)
N1A—C10A—C11A	109.6 (4)	C20B—C21B—H21D	109.5
C12A—C10A—C11A	110.9 (4)	C20B—C21B—H21E	109.5
N1A—C10A—C13A	109.9 (4)	H21D—C21B—H21E	109.5
C12A—C10A—C13A	111.1 (4)	C20B—C21B—H21F	109.5
C11A—C10A—C13A	107.3 (4)	H21D—C21B—H21F	109.5
C10A—C11A—H11A	109.5	H21E—C21B—H21F	109.5
C10A—C11A—H11B	109.5	C20B—C22B—H22D	109.5
H11A—C11A—H11B	109.5	C20B—C22B—H22E	109.5
C10A—C11A—H11C	109.5	H22D—C22B—H22E	109.5
H11A—C11A—H11C	109.5	C20B—C22B—H22F	109.5
H11B—C11A—H11C	109.5	H22D—C22B—H22F	109.5
C10A—C12A—H12A	109.5	H22E—C22B—H22F	109.5
C10A—C12A—H12B	109.5	C20B—C23B—H23D	109.5
H12A—C12A—H12B	109.5	C20B—C23B—H23E	109.5
C10A—C12A—H12C	109.5	H23D—C23B—H23E	109.5
H12A—C12A—H12C	109.5	C20B—C23B—H23F	109.5
H12B—C12A—H12C	109.5	H23D—C23B—H23F	109.5
C10A—C13A—H13A	109.5	H23E—C23B—H23F	109.5
C10A—C13A—H13B	109.5	N3B—C30B—C32B	106.9 (3)
H13A—C13A—H13B	109.5	N3B—C30B—C33B	112.3 (3)
C10A—C13A—H13C	109.5	C32B—C30B—C33B	110.4 (4)
H13A—C13A—H13C	109.5	N3B—C30B—C31B	108.5 (3)
H13B—C13A—H13C	109.5	C32B—C30B—C31B	109.6 (4)
N2A—C20A—C23A	106.8 (4)	C33B—C30B—C31B	109.0 (4)
N2A—C20A—C22A	110.2 (4)	C30B—C31B—H31D	109.5
C23A—C20A—C22A	110.6 (4)	C30B—C31B—H31E	109.5
N2A—C20A—C21A	109.9 (3)	H31D—C31B—H31E	109.5
C23A—C20A—C21A	110.2 (4)	C30B—C31B—H31F	109.5
C22A—C20A—C21A	109.1 (4)	H31D—C31B—H31F	109.5
C20A—C21A—H21A	109.5	H31E—C31B—H31F	109.5
C20A—C21A—H21B	109.5	C30B—C32B—H32D	109.5
H21A—C21A—H21B	109.5	C30B—C32B—H32E	109.5
C20A—C21A—H21C	109.5	H32D—C32B—H32E	109.5
H21A—C21A—H21C	109.5	C30B—C32B—H32F	109.5
H21B—C21A—H21C	109.5	H32D—C32B—H32F	109.5
C20A—C22A—H22A	109.5	H32E—C32B—H32F	109.5
C20A—C22A—H22B	109.5	C30B—C33B—H33D	109.5
H22A—C22A—H22B	109.5	C30B—C33B—H33E	109.5
C20A—C22A—H22C	109.5	H33D—C33B—H33E	109.5
H22A—C22A—H22C	109.5	C30B—C33B—H33F	109.5
H22B—C22A—H22C	109.5	H33D—C33B—H33F	109.5
C20A—C23A—H23A	109.5	H33E—C33B—H33F	109.5
C20A—C23A—H23B	109.5	C5—C4—H4A	109.5
H23A—C23A—H23B	109.5	C5—C4—H4B	109.5
C20A—C23A—H23C	109.5	H4A—C4—H4B	109.5
H23A—C23A—H23C	109.5	C5—C4—H4C	109.5
H23B—C23A—H23C	109.5	H4A—C4—H4C	109.5
N3A—C30A—C33A	107.6 (3)	H4B—C4—H4C	109.5
N3A—C30A—C31A	112.2 (3)	N4—C5—C4	179.0 (8)
C33A—C30A—C31A	110.3 (3)
N2A—Te1A—Te2A—O1A	−54.05 (17)	N3A—Te2A—N2A—Te1A	18.53 (13)
N1A—Te1A—Te2A—O1A	24.32 (15)	O1B—Te2A—N2A—Te1A	73.6 (2)
N3A—Te1A—Te2A—O1A	96.80 (16)	Te2B—Te2A—N2A—Te1A	117.76 (10)
N2A—Te1A—Te2A—N3A	−150.9 (2)	N2A—Te1A—N3A—C30A	166.6 (3)
N1A—Te1A—Te2A—N3A	−72.48 (19)	N1A—Te1A—N3A—C30A	−95.7 (3)
N2A—Te1A—Te2A—O1B	−140.35 (17)	Te2A—Te1A—N3A—C30A	147.4 (4)
N1A—Te1A—Te2A—O1B	−61.97 (16)	N2A—Te1A—N3A—Te2A	19.21 (13)
N3A—Te1A—Te2A—O1B	10.51 (17)	N1A—Te1A—N3A—Te2A	116.92 (15)
N1A—Te1A—Te2A—N2A	78.37 (19)	O1A—Te2A—N3A—C30A	117.3 (3)
N3A—Te1A—Te2A—N2A	150.9 (2)	O1B—Te2A—N3A—C30A	43.0 (3)
N2A—Te1A—Te2A—Te2B	−93.75 (15)	N2A—Te2A—N3A—C30A	−163.8 (3)
N1A—Te1A—Te2A—Te2B	−15.37 (13)	Te2B—Te2A—N3A—C30A	74.0 (3)
N3A—Te1A—Te2A—Te2B	57.11 (14)	Te1A—Te2A—N3A—C30A	−145.6 (4)
O1A—Te2A—Te2B—O1B	−158.72 (17)	O1A—Te2A—N3A—Te1A	−97.02 (14)
N3A—Te2A—Te2B—O1B	−58.93 (15)	O1B—Te2A—N3A—Te1A	−171.33 (14)
N2A—Te2A—Te2B—O1B	−140.37 (16)	N2A—Te2A—N3A—Te1A	−18.13 (13)
Te1A—Te2A—Te2B—O1B	−92.22 (12)	Te2B—Te2A—N3A—Te1A	−140.33 (9)
O1A—Te2A—Te2B—N3B	−64.15 (15)	N2B—Te1B—N1B—C10B	−135.3 (4)
N3A—Te2A—Te2B—N3B	35.65 (14)	N3B—Te1B—N1B—C10B	146.8 (4)
O1B—Te2A—Te2B—N3B	94.58 (16)	Te2B—Te1B—N1B—C10B	−176.6 (3)
N2A—Te2A—Te2B—N3B	−45.79 (14)	N1B—Te1B—N2B—C20B	100.5 (3)
Te1A—Te2A—Te2B—N3B	2.36 (10)	N3B—Te1B—N2B—C20B	−167.5 (3)
N3A—Te2A—Te2B—O1A	99.79 (15)	Te2B—Te1B—N2B—C20B	−148.3 (4)
O1B—Te2A—Te2B—O1A	158.72 (17)	N1B—Te1B—N2B—Te2B	−111.25 (15)
N2A—Te2A—Te2B—O1A	18.35 (16)	N3B—Te1B—N2B—Te2B	−19.28 (13)
Te1A—Te2A—Te2B—O1A	66.50 (12)	O1B—Te2B—N2B—C20B	−82.8 (3)
O1A—Te2A—Te2B—N2B	−145.99 (16)	N3B—Te2B—N2B—C20B	168.4 (3)
N3A—Te2A—Te2B—N2B	−46.20 (14)	O1A—Te2B—N2B—C20B	−132.8 (3)
O1B—Te2A—Te2B—N2B	12.73 (16)	Te2A—Te2B—N2B—C20B	−91.1 (3)
N2A—Te2A—Te2B—N2B	−127.64 (15)	Te1B—Te2B—N2B—C20B	149.0 (4)
Te1A—Te2A—Te2B—N2B	−79.49 (11)	O1B—Te2B—N2B—Te1B	128.15 (14)
O1A—Te2A—Te2B—Te1B	−98.01 (12)	N3B—Te2B—N2B—Te1B	19.43 (13)
N3A—Te2A—Te2B—Te1B	1.78 (9)	O1A—Te2B—N2B—Te1B	78.2 (2)
O1B—Te2A—Te2B—Te1B	60.71 (12)	Te2A—Te2B—N2B—Te1B	119.91 (10)
N2A—Te2A—Te2B—Te1B	−79.66 (11)	N2B—Te1B—N3B—C30B	173.1 (3)
Te1A—Te2A—Te2B—Te1B	−31.51 (3)	N1B—Te1B—N3B—C30B	−88.7 (3)
O1B—Te2B—Te1B—N2B	−55.31 (16)	Te2B—Te1B—N3B—C30B	152.8 (4)
N3B—Te2B—Te1B—N2B	−149.4 (2)	N2B—Te1B—N3B—Te2B	20.22 (14)
O1A—Te2B—Te1B—N2B	−140.96 (16)	N1B—Te1B—N3B—Te2B	118.48 (16)
Te2A—Te2B—Te1B—N2B	−91.64 (14)	O1B—Te2B—N3B—C30B	110.1 (3)
O1B—Te2B—Te1B—N1B	24.50 (15)	O1A—Te2B—N3B—C30B	35.0 (3)
N3B—Te2B—Te1B—N1B	−69.63 (19)	N2B—Te2B—N3B—C30B	−170.6 (3)
O1A—Te2B—Te1B—N1B	−61.15 (15)	Te2A—Te2B—N3B—C30B	67.9 (3)
N2B—Te2B—Te1B—N1B	79.81 (18)	Te1B—Te2B—N3B—C30B	−151.6 (4)
Te2A—Te2B—Te1B—N1B	−11.83 (12)	O1B—Te2B—N3B—Te1B	−98.26 (14)
O1B—Te2B—Te1B—N3B	94.13 (17)	O1A—Te2B—N3B—Te1B	−173.34 (13)
O1A—Te2B—Te1B—N3B	8.48 (17)	N2B—Te2B—N3B—Te1B	−19.01 (13)
N2B—Te2B—Te1B—N3B	149.4 (2)	Te2A—Te2B—N3B—Te1B	−140.47 (10)
Te2A—Te2B—Te1B—N3B	57.80 (15)	Te1A—N1A—C10A—C12A	175.4 (4)
N3A—Te2A—O1A—Te2B	−94.01 (13)	Te1A—N1A—C10A—C11A	−63.6 (5)
O1B—Te2A—O1A—Te2B	−12.94 (10)	Te1A—N1A—C10A—C13A	54.0 (5)
N2A—Te2A—O1A—Te2B	−164.96 (13)	Te1A—N2A—C20A—C23A	−116.0 (4)
Te1A—Te2A—O1A—Te2B	−135.08 (7)	Te2A—N2A—C20A—C23A	99.4 (4)
O1B—Te2B—O1A—Te2A	14.01 (11)	Te1A—N2A—C20A—C22A	4.2 (5)
N3B—Te2B—O1A—Te2A	120.95 (13)	Te2A—N2A—C20A—C22A	−140.4 (3)
N2B—Te2B—O1A—Te2A	65.8 (3)	Te1A—N2A—C20A—C21A	124.5 (3)
Te1B—Te2B—O1A—Te2A	115.65 (9)	Te2A—N2A—C20A—C21A	−20.1 (5)
N3B—Te2B—O1B—Te2A	−98.27 (13)	Te1A—N3A—C30A—C33A	128.0 (3)
O1A—Te2B—O1B—Te2A	−13.04 (10)	Te2A—N3A—C30A—C33A	−93.0 (4)
N2B—Te2B—O1B—Te2A	−169.46 (13)	Te1A—N3A—C30A—C31A	−110.5 (3)
Te1B—Te2B—O1B—Te2A	−138.98 (8)	Te2A—N3A—C30A—C31A	28.4 (4)
O1A—Te2A—O1B—Te2B	14.23 (11)	Te1A—N3A—C30A—C32A	9.6 (4)
N3A—Te2A—O1B—Te2B	124.66 (14)	Te2A—N3A—C30A—C32A	148.6 (3)
N2A—Te2A—O1B—Te2B	72.6 (2)	Te1B—N1B—C10B—C13B	−35.4 (5)
Te1A—Te2A—O1B—Te2B	118.09 (8)	Te1B—N1B—C10B—C11B	−155.2 (3)
N2A—Te1A—N1A—C10A	−134.5 (4)	Te1B—N1B—C10B—C12B	85.5 (4)
N3A—Te1A—N1A—C10A	146.5 (4)	Te1B—N2B—C20B—C22B	61.6 (4)
Te2A—Te1A—N1A—C10A	−175.4 (3)	Te2B—N2B—C20B—C22B	−79.5 (4)
N1A—Te1A—N2A—C20A	95.9 (3)	Te1B—N2B—C20B—C21B	−60.1 (4)
N3A—Te1A—N2A—C20A	−170.0 (3)	Te2B—N2B—C20B—C21B	158.7 (3)
Te2A—Te1A—N2A—C20A	−151.3 (4)	Te1B—N2B—C20B—C23B	−177.4 (3)
N1A—Te1A—N2A—Te2A	−112.81 (15)	Te2B—N2B—C20B—C23B	41.5 (4)
N3A—Te1A—N2A—Te2A	−18.66 (13)	Te1B—N3B—C30B—C32B	124.4 (3)
O1A—Te2A—N2A—C20A	−78.5 (3)	Te2B—N3B—C30B—C32B	−89.8 (4)
N3A—Te2A—N2A—C20A	170.3 (3)	Te1B—N3B—C30B—C33B	−114.3 (3)
O1B—Te2A—N2A—C20A	−134.7 (3)	Te2B—N3B—C30B—C33B	31.5 (5)
Te2B—Te2A—N2A—C20A	−90.5 (3)	Te1B—N3B—C30B—C31B	6.3 (5)
Te1A—Te2A—N2A—C20A	151.7 (4)	Te2B—N3B—C30B—C31B	152.1 (3)
O1A—Te2A—N2A—Te1A	129.77 (14)