Bis(μ-phenyl­phosphido-κ2P:P)­bis{[1,2-(di­cyclo­hexyl­phosphino)­ethane-κ2P,P′]­platinum(I)} dichloride bis­(di­chloro­methane) hexane solvate

Jaska, C.A.; Lough, A.J.; Manners, I.

doi:10.1107/S1600536804025309

Bis(μ-phenylphosphido-κ²P:P)bis{[1,2-(dicyclohexylphosphino)ethane-κ²P,P′]platinum(I)} dichloride bis(dichloromethane) hexane solvate

In the title compound, [Pt₂(C₆H₆P)₂(C₂₆H₄₈P₂)₂]Cl₂·2CH₂Cl₂·C₆H₁₄, the cation crystallizes as a phosphido-bridged Pt^I dimer [Pt(dcype)(μ-PPhH)]₂Cl₂, with crystallographic 2/m symmetry [dcype is 1,2-bis(dicyclohexylphosphino)ethane]. The Pt₂P₂ core forms a planar distorted square capped by chelating bis-phosphine ligands, resulting in a distorted square-planar geometry for the Pt atoms. In the Pt₂P₂ core, the Pt—P bond length is 2.3403 (9) Å, with a narrow P—Pt—P angle of 76.87 (6)° and a wide Pt—P—Pt angle of 103.13 (6)°. The bite angle of the dcype ligand is 85.70 (6)°, with a Pt—P bond length of 2.2993 (11)°.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804025309/hb6109sup1.cif Contains datablocks global, I
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536804025309/hb6109Isup2.hkl Contains datablock I

CCDC reference: 255433

checkCIF report

Key indicators

Single-crystal X-ray study
T = 150 K
Mean (C-C) = 0.008 Å
Disorder in solvent or counterion
R factor = 0.036
wR factor = 0.087
Data-to-parameter ratio = 23.5

checkCIF/PLATON results

No syntax errors found



Alert level A
PLAT432_ALERT_2_A Short Inter X...Y Contact  C1SA   ..  Cl1A    ..       2.67 Ang.

Author Response: This is an artefact arising from two partially disordered sites which are not occupied simultaneously.

PLAT601_ALERT_2_A Structure Contains Solvent Accessible VOIDS of .     303.00 A   3

Author Response: This void is present because the contribution of one highly disordered molecule of hexane has been removed from the intensity data using the program SQUEEZE in PLATON (Spek, 2004). See Experimental section for further details.


Alert level B
CHEMW03_ALERT_2_B WARNING: The ratio of given/expected molecular weight as
            calculated from the _atom_site* data lies outside
            the range 0.95 <> 1.05
           From the CIF: _cell_formula_units_Z                    2
           From the CIF: _chemical_formula_weight          1780.43
           TEST: Calculate formula weight from _atom_site_*
           atom     mass    num     sum
           C        12.01   66.00  792.73
           H         1.01  112.00  112.90
           Cl       35.45    6.00  212.72
           P        30.97    6.00  185.84
           Pt      195.08    2.00  390.16
           H         1.01    0.00    0.00
           Calculated formula weight             1694.34
PLAT043_ALERT_1_B Check Reported Molecular Weight ................    1780.43
PLAT044_ALERT_1_B Calculated and Reported Dx Differ ..............          ?

Alert level C
PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings    Differ ....          ?
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT068_ALERT_1_C Reported F000 Differs from Calcd (or Missing)...          ?
PLAT076_ALERT_1_C Occupancy       0.50 less than 1.0 for Sp.pos  .        C1S
PLAT076_ALERT_1_C Occupancy       0.50 less than 1.0 for Sp.pos  .        H1#
PLAT076_ALERT_1_C Occupancy       0.50 less than 1.0 for Sp.pos  .        H2#
PLAT076_ALERT_1_C Occupancy       0.50 less than 1.0 for Sp.pos  .        C1#
PLAT076_ALERT_1_C Occupancy       0.50 less than 1.0 for Sp.pos  .        H3#
PLAT076_ALERT_1_C Occupancy       0.50 less than 1.0 for Sp.pos  .        H4#
PLAT243_ALERT_4_C High Solvent U(eq) as Compared to Neighbors  for        Cl2
PLAT243_ALERT_4_C High Solvent U(eq) as Compared to Neighbors  for       C1SA
PLAT244_ALERT_4_C Low  Solvent U(eq) as Compared to Neighbors  for        C1S
PLAT302_ALERT_4_C Anion/Solvent Disorder .........................      33.00 Perc.
PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........          5

Alert level G
FORMU01_ALERT_2_G  There is a discrepancy between the atom counts in the
            _chemical_formula_sum and the formula from the _atom_site* data.
            Atom count from _chemical_formula_sum:C72 H126 Cl6 P6 Pt2
            Atom count from the _atom_site data:  C66 H112 Cl6 P6 Pt2
CELLZ01_ALERT_1_G Difference between formula and atom_site contents detected.
CELLZ01_ALERT_1_G ALERT: Large difference may be due to a
            symmetry error - see SYMMG tests
           From the CIF: _cell_formula_units_Z    2
           From the CIF: _chemical_formula_sum  C72 H126 Cl6 P6 Pt2
           TEST: Compare cell contents of formula and atom_site data

           atom    Z*formula  cif sites diff
           C        144.00    132.00   12.00
           H        252.00    224.00   28.00
           Cl        12.00     12.00    0.00
           P         12.00     12.00    0.00
           Pt         4.00      4.00    0.00

   2 ALERT level A = In general: serious problem
   3 ALERT level B = Potentially serious problem
  14 ALERT level C = Check and explain
   3 ALERT level G = General alerts; check

  13 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   4 ALERT type 2 Indicator that the structure model may be wrong or deficient
   0 ALERT type 3 Indicator that the structure quality may be low
   5 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: COLLECT (Nonius, 1997-2003); cell refinement: DENZO–SMN (Otwinowski & Minor, 1997); data reduction: DENZO–SMN; program(s) used to solve structure: SHELXTL (Sheldrick, 2001); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Bis(µ-phenylphosphido-κ²P:P)bis{[1,2-(dicyclohexylphosphino)ethane- κ²P,P']platinum(I)} dichloride bis(dichloromethane) hexane solvate top

Crystal data top

[Pt₂(C₆H₆P)₂(C₂₆H₄₈P₂)₂]Cl₂·2CH₂Cl₂·C₆H₁₄	F(000) = 1812
M_r = 1780.43	D_x = 1.461 Mg m⁻³
Monoclinic, C2/m	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2y	Cell parameters from 14701 reflections
a = 25.2590 (9) Å	θ = 2.6–27.5°
b = 13.9810 (5) Å	µ = 3.81 mm⁻¹
c = 12.3080 (5) Å	T = 150 K
β = 111.348 (2)°	Block, colourless
V = 4048.3 (3) Å³	0.12 × 0.10 × 0.10 mm
Z = 2

Data collection top

Nonius KapppaCCD diffractometer	4810 independent reflections
Radiation source: fine-focus sealed tube	4223 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.061
Detector resolution: 9 pixels mm^-1	θ_max = 27.5°, θ_min = 2.7°
φ scans and ω scans with κ offsets	h = −32→30
Absorption correction: multi-scan (SORTAV; Blessing, 1995)	k = −16→18
T_min = 0.636, T_max = 0.683	l = −15→15
14701 measured reflections

Refinement top

Refinement on F²	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F² > 2σ(F²)] = 0.036	H atoms treated by a mixture of independent and constrained refinement
wR(F²) = 0.087	w = 1/[σ²(F_o²) + (0.0435P)²] where P = (F_o² + 2F_c²)/3
S = 1.09	(Δ/σ)_max = 0.002
4810 reflections	Δρ_max = 2.26 e Å⁻³
205 parameters	Δρ_min = −1.38 e Å⁻³
1 restraint	Extinction correction: SHELXTL, Fc^*=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4
Primary atom site location: structure-invariant direct methods	Extinction coefficient: 0.00110 (10)

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Pt1	0.0000	0.131118 (14)	0.5000	0.02304 (10)
P1	0.06391 (5)	0.25169 (7)	0.51287 (9)	0.0262 (2)
H1P	0.114 (3)	0.0000	0.535 (5)	0.035 (17)*
P2	0.06166 (6)	0.0000	0.55508 (12)	0.0243 (3)
C1	0.0327 (2)	0.3683 (3)	0.5233 (4)	0.0317 (10)
H1A	0.0469	0.3886	0.6061	0.038*
H1B	0.0457	0.4160	0.4791	0.038*
C2	0.07685 (19)	0.2521 (3)	0.3735 (4)	0.0310 (9)
H2A	0.0992	0.3108	0.3721	0.037*
C3	0.0203 (2)	0.2579 (3)	0.2720 (4)	0.0349 (10)
H3A	0.0001	0.3169	0.2788	0.042*
H3B	−0.0036	0.2025	0.2746	0.042*
C4	0.0294 (2)	0.2582 (4)	0.1558 (4)	0.0460 (12)
H4A	−0.0080	0.2587	0.0909	0.055*
H4B	0.0499	0.3172	0.1500	0.055*
C5	0.0629 (2)	0.1721 (4)	0.1437 (4)	0.0473 (12)
H5A	0.0695	0.1762	0.0693	0.057*
H5B	0.0408	0.1132	0.1418	0.057*
C6	0.1196 (2)	0.1669 (4)	0.2449 (4)	0.0458 (12)
H6A	0.1431	0.2230	0.2424	0.055*
H6B	0.1402	0.1085	0.2375	0.055*
C7	0.1109 (2)	0.1653 (4)	0.3618 (4)	0.0386 (10)
H7A	0.0905	0.1061	0.3674	0.046*
H7B	0.1483	0.1650	0.4265	0.046*
C8	0.13461 (18)	0.2549 (3)	0.6302 (4)	0.0332 (10)
H8A	0.1553	0.1957	0.6231	0.040*
C9	0.1312 (2)	0.2546 (3)	0.7519 (4)	0.0383 (11)
H9A	0.1111	0.1962	0.7617	0.046*
H9B	0.1092	0.3108	0.7604	0.046*
C10	0.1910 (2)	0.2574 (4)	0.8465 (5)	0.0544 (15)
H10A	0.1880	0.2592	0.9244	0.065*
H10B	0.2120	0.1986	0.8417	0.065*
C11	0.2235 (3)	0.3442 (4)	0.8314 (5)	0.0640 (18)
H11A	0.2040	0.4030	0.8416	0.077*
H11B	0.2622	0.3438	0.8918	0.077*
C12	0.2275 (2)	0.3447 (4)	0.7122 (6)	0.0613 (16)
H12A	0.2501	0.2889	0.7050	0.074*
H12B	0.2475	0.4034	0.7033	0.074*
C13	0.1690 (2)	0.3410 (4)	0.6151 (5)	0.0491 (13)
H13A	0.1736	0.3365	0.5387	0.059*
H13B	0.1481	0.4007	0.6158	0.059*
C14	0.0938 (2)	0.0000	0.7138 (5)	0.0278 (12)
C15	0.0598 (3)	0.0000	0.7821 (5)	0.0323 (13)
H15A	0.0196	0.0000	0.7446	0.039*
C16	0.0831 (3)	0.0000	0.9013 (6)	0.0447 (17)
H16A	0.0593	0.0000	0.9457	0.054*
C17	0.1423 (3)	0.0000	0.9578 (6)	0.0480 (18)
H17A	0.1586	0.0000	1.0406	0.058*
C18	0.1769 (3)	0.0000	0.8933 (6)	0.0467 (18)
H18A	0.2170	0.0000	0.9317	0.056*
C19	0.1528 (3)	0.0000	0.7708 (5)	0.0354 (14)
H19A	0.1768	0.0000	0.7266	0.043*
Cl1	0.0629 (2)	0.5000	0.2809 (4)	0.0558 (9)	0.60
Cl1a	0.0897 (3)	0.5000	0.3404 (5)	0.0470 (12)	0.40
Cl2	0.26019 (10)	0.10394 (19)	0.6145 (2)	0.1069 (7)
C1S	0.2690 (9)	0.0000	0.5444 (15)	0.068 (5)*	0.50
H1S1	0.3076	0.0000	0.5409	0.082*	0.50
H1S2	0.2411	0.0000	0.4633	0.082*	0.50
C1Sa	0.2986 (7)	0.0000	0.615 (3)	0.115 (9)*	0.50
H1S3	0.3095	0.0000	0.5455	0.138*	0.50
H1S4	0.3339	0.0000	0.6850	0.138*	0.50

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Pt1	0.02754 (14)	0.02024 (13)	0.01880 (13)	0.000	0.00542 (8)	0.000
P1	0.0307 (6)	0.0228 (5)	0.0219 (5)	−0.0028 (4)	0.0057 (4)	−0.0005 (4)
P2	0.0265 (7)	0.0197 (7)	0.0231 (7)	0.000	0.0046 (6)	0.000
C1	0.050 (3)	0.0189 (19)	0.027 (2)	−0.0099 (18)	0.0141 (19)	−0.0032 (17)
C2	0.039 (3)	0.028 (2)	0.027 (2)	−0.0020 (18)	0.0146 (19)	0.0028 (17)
C3	0.046 (3)	0.036 (2)	0.026 (2)	0.003 (2)	0.016 (2)	−0.0037 (19)
C4	0.064 (3)	0.048 (3)	0.028 (2)	0.009 (3)	0.020 (2)	0.002 (2)
C5	0.068 (3)	0.050 (3)	0.031 (2)	0.001 (3)	0.027 (2)	−0.006 (2)
C6	0.048 (3)	0.055 (3)	0.043 (3)	0.004 (3)	0.028 (2)	−0.004 (3)
C7	0.037 (2)	0.044 (3)	0.034 (2)	0.005 (2)	0.0118 (19)	0.000 (2)
C8	0.033 (2)	0.031 (2)	0.028 (2)	−0.0029 (18)	0.0020 (18)	−0.0035 (18)
C9	0.049 (3)	0.032 (2)	0.025 (2)	−0.001 (2)	0.003 (2)	−0.0010 (19)
C10	0.055 (3)	0.044 (3)	0.038 (3)	−0.009 (2)	−0.014 (2)	−0.002 (2)
C11	0.056 (4)	0.052 (3)	0.052 (3)	−0.017 (3)	−0.019 (3)	−0.002 (3)
C12	0.041 (3)	0.054 (3)	0.069 (4)	−0.017 (3)	−0.004 (3)	0.000 (3)
C13	0.044 (3)	0.052 (3)	0.044 (3)	−0.020 (2)	0.006 (2)	0.000 (2)
C14	0.034 (3)	0.019 (3)	0.024 (3)	0.000	0.003 (2)	0.000
C15	0.037 (3)	0.029 (3)	0.029 (3)	0.000	0.010 (3)	0.000
C16	0.066 (5)	0.036 (4)	0.034 (3)	0.000	0.021 (3)	0.000
C17	0.065 (5)	0.042 (4)	0.025 (3)	0.000	0.003 (3)	0.000
C18	0.046 (4)	0.039 (4)	0.037 (4)	0.000	−0.008 (3)	0.000
C19	0.034 (3)	0.032 (3)	0.032 (3)	0.000	0.002 (3)	0.000
Cl1	0.081 (3)	0.0361 (17)	0.057 (2)	0.000	0.033 (2)	0.000
Cl1a	0.075 (4)	0.030 (2)	0.047 (3)	0.000	0.036 (3)	0.000
Cl2	0.1023 (16)	0.1011 (14)	0.140 (2)	0.0295 (13)	0.0709 (15)	0.0097 (15)

Geometric parameters (Å, º) top

Pt1—P1ⁱ	2.2993 (11)	C9—C10	1.536 (6)
Pt1—P1	2.2993 (11)	C9—H9A	0.9900
Pt1—P2ⁱⁱ	2.3403 (9)	C9—H9B	0.9900
Pt1—P2	2.3403 (9)	C10—C11	1.514 (8)
P1—C1	1.836 (4)	C10—H10A	0.9900
P1—C8	1.843 (4)	C10—H10B	0.9900
P1—C2	1.859 (4)	C11—C12	1.506 (10)
H1P—P2	1.43 (6)	C11—H11A	0.9900
P2—C14	1.822 (6)	C11—H11B	0.9900
P2—Pt1ⁱⁱ	2.3403 (9)	C12—C13	1.525 (7)
C1—C1ⁱ	1.537 (9)	C12—H12A	0.9900
C1—H1A	0.9900	C12—H12B	0.9900
C1—H1B	0.9900	C13—H13A	0.9900
C2—C3	1.520 (6)	C13—H13B	0.9900
C2—C7	1.525 (6)	C14—C19	1.397 (8)
C2—H2A	1.0000	C14—C15	1.405 (8)
C3—C4	1.529 (6)	C15—C16	1.367 (9)
C3—H3A	0.9900	C15—H15A	0.9500
C3—H3B	0.9900	C16—C17	1.400 (10)
C4—C5	1.510 (7)	C16—H16A	0.9500
C4—H4A	0.9900	C17—C18	1.376 (11)
C4—H4B	0.9900	C17—H17A	0.9500
C5—C6	1.521 (7)	C18—C19	1.405 (9)
C5—H5A	0.9900	C18—H18A	0.9500
C5—H5B	0.9900	C19—H19A	0.9500
C6—C7	1.533 (6)	Cl2—C1S	1.746 (8)
C6—H6A	0.9900	Cl2—C1Sa	1.746 (8)
C6—H6B	0.9900	C1S—Cl2ⁱⁱⁱ	1.746 (8)
C7—H7A	0.9900	C1S—H1S1	0.9900
C7—H7B	0.9900	C1S—H1S2	0.9900
C8—C9	1.532 (6)	C1Sa—Cl2ⁱⁱⁱ	1.746 (8)
C8—C13	1.536 (6)	C1Sa—H1S3	0.9900
C8—H8A	1.0000	C1Sa—H1S4	0.9900

P1ⁱ—Pt1—P1	85.70 (6)	C9—C8—H8A	107.5
P1ⁱ—Pt1—P2ⁱⁱ	100.24 (4)	C13—C8—H8A	107.5
P1—Pt1—P2ⁱⁱ	166.11 (4)	P1—C8—H8A	107.5
P1ⁱ—Pt1—P2	166.11 (4)	C8—C9—C10	110.5 (4)
P1—Pt1—P2	100.24 (4)	C8—C9—H9A	109.5
P2ⁱ—Pt1—P2	76.87 (6)	C10—C9—H9A	109.5
C1—P1—C8	104.0 (2)	C8—C9—H9B	109.5
C1—P1—C2	106.6 (2)	C10—C9—H9B	109.5
C8—P1—C2	106.1 (2)	H9A—C9—H9B	108.1
C1—P1—Pt1	110.29 (14)	C11—C10—C9	110.8 (4)
C8—P1—Pt1	121.83 (15)	C11—C10—H10A	109.5
C2—P1—Pt1	107.08 (14)	C9—C10—H10A	109.5
H1P—P2—C14	96 (2)	C11—C10—H10B	109.5
H1P—P2—Pt1ⁱⁱ	120.6 (10)	C9—C10—H10B	109.5
C14—P2—Pt1ⁱⁱ	107.49 (12)	H10A—C10—H10B	108.1
H1P—P2—Pt1	120.6 (10)	C12—C11—C10	110.8 (5)
C14—P2—Pt1	107.49 (12)	C12—C11—H11A	109.5
Pt1ⁱⁱ—P2—Pt1	103.13 (6)	C10—C11—H11A	109.5
C1ⁱ—C1—P1	113.85 (17)	C12—C11—H11B	109.5
C1ⁱ—C1—H1A	108.8	C10—C11—H11B	109.5
P1—C1—H1A	108.8	H11A—C11—H11B	108.1
C1ⁱ—C1—H1B	108.8	C11—C12—C13	112.0 (5)
P1—C1—H1B	108.8	C11—C12—H12A	109.2
H1A—C1—H1B	107.7	C13—C12—H12A	109.2
C3—C2—C7	111.0 (4)	C11—C12—H12B	109.2
C3—C2—P1	109.3 (3)	C13—C12—H12B	109.2
C7—C2—P1	112.3 (3)	H12A—C12—H12B	107.9
C3—C2—H2A	108.1	C12—C13—C8	111.2 (4)
C7—C2—H2A	108.1	C12—C13—H13A	109.4
P1—C2—H2A	108.1	C8—C13—H13A	109.4
C2—C3—C4	110.7 (4)	C12—C13—H13B	109.4
C2—C3—H3A	109.5	C8—C13—H13B	109.4
C4—C3—H3A	109.5	H13A—C13—H13B	108.0
C2—C3—H3B	109.5	C19—C14—C15	118.2 (5)
C4—C3—H3B	109.5	C19—C14—P2	121.1 (5)
H3A—C3—H3B	108.1	C15—C14—P2	120.7 (4)
C5—C4—C3	111.7 (4)	C16—C15—C14	121.5 (6)
C5—C4—H4A	109.3	C16—C15—H15A	119.2
C3—C4—H4A	109.3	C14—C15—H15A	119.2
C5—C4—H4B	109.3	C15—C16—C17	119.9 (7)
C3—C4—H4B	109.3	C15—C16—H16A	120.0
H4A—C4—H4B	107.9	C17—C16—H16A	120.0
C4—C5—C6	110.6 (4)	C18—C17—C16	120.0 (6)
C4—C5—H5A	109.5	C18—C17—H17A	120.0
C6—C5—H5A	109.5	C16—C17—H17A	120.0
C4—C5—H5B	109.5	C17—C18—C19	120.1 (7)
C6—C5—H5B	109.5	C17—C18—H18A	120.0
H5A—C5—H5B	108.1	C19—C18—H18A	120.0
C5—C6—C7	110.8 (4)	C14—C19—C18	120.3 (6)
C5—C6—H6A	109.5	C14—C19—H19A	119.8
C7—C6—H6A	109.5	C18—C19—H19A	119.8
C5—C6—H6B	109.5	Cl2—C1S—Cl2ⁱⁱⁱ	112.7 (8)
C7—C6—H6B	109.5	Cl2—C1S—H1S1	109.0
H6A—C6—H6B	108.1	Cl2ⁱⁱⁱ—C1S—H1S1	109.0
C2—C7—C6	110.8 (4)	Cl2—C1S—H1S2	109.0
C2—C7—H7A	109.5	Cl2ⁱⁱⁱ—C1S—H1S2	109.0
C6—C7—H7A	109.5	H1S1—C1S—H1S2	107.8
C2—C7—H7B	109.5	Cl2ⁱⁱⁱ—C1Sa—Cl2	112.7 (8)
C6—C7—H7B	109.5	Cl2ⁱⁱⁱ—C1Sa—H1S3	109.0
H7A—C7—H7B	108.1	Cl2—C1Sa—H1S3	109.0
C9—C8—C13	110.9 (4)	Cl2ⁱⁱⁱ—C1Sa—H1S4	109.1
C9—C8—P1	112.5 (3)	Cl2—C1Sa—H1S4	109.1
C13—C8—P1	110.7 (3)	H1S3—C1Sa—H1S4	107.8

Symmetry codes: (i) −x, y, −z+1; (ii) −x, −y, −z+1; (iii) x, −y, z.

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Bis(μ-phenyl­phosphido-κ2P:P)­bis{[1,2-(di­cyclo­hexyl­phosphino)­ethane-κ2P,P′]­platinum(I)} dichloride bis­(di­chloro­methane) hexane solvate

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Bis(μ-phenylphosphido-κ²P:P)bis{[1,2-(dicyclohexylphosphino)ethane-κ²P,P′]platinum(I)} dichloride bis(dichloromethane) hexane solvate