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The title mononuclear RhIII complex, (bis{[2-(diethyl­phosphino-κP)­ethyl]­phenyl­phosphino}methane)­di­chlororho­dium(III) tetra­fluoro­borate perdeuteroacetone solvate, [RhCl2(C25H40P4)]BF4·C3D6O, is based on the racemic η4-coordinated tetraphosphine ligand (Et2PCH2CH2)(Ph)PCH2P(Ph)(CH2CH2PEt2). The Rh—Cl distances are 2.4164 (7) and 2.4282 (7) Å, and the Rh—P bond distances are in the range 2.2501 (7)–2.3649 (7) Å, with distorted octahedral coordination geometry for the Rh atom.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804015533/hb6060sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536804015533/hb6060Isup2.hkl
Contains datablock I

CCDC reference: 248706

Key indicators

  • Single-crystal X-ray study
  • T = 105 K
  • Mean [sigma](C-C) = 0.004 Å
  • R factor = 0.031
  • wR factor = 0.071
  • Data-to-parameter ratio = 23.4

checkCIF/PLATON results

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Alert level C PLAT031_ALERT_4_C Refined Extinction Parameter within Range ...... 3.00 Sigma PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Rh1 - Cl2 .. 8.60 su PLAT244_ALERT_4_C Low Solvent U(eq) as Compared to Neighbors .... C1S PLAT244_ALERT_4_C Low Solvent U(eq) as Compared to Neighbors .... B1
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 5 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 1 ALERT type 2 Indicator that the structure model may be wrong or deficient 0 ALERT type 3 Indicator that the structure quality may be low 3 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: COLLECT (Nonius, 2000); cell refinement: HKL SCALEPACK (Otwinowski & Minor, 1997); data reduction: HKL SCALEPACK and DENZO (Otwinowski & Minor 1997); program(s) used to solve structure: SIR97 (Altomare et al., 1999); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997); software used to prepare material for publication: SHELXL97.

(bis{[2-(diethylphosphino- κP)ethyl]phenylphosphino}methane)dichloro[]rhodium(III) tetrafluoroborate acetone solvate top
Crystal data top
[RhCl2(C25H40P4)]BF4·C3H6OF(000) = 1608
Mr = 783.15Dx = 1.502 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 7957 reflections
a = 10.595 (2) Åθ = 2.5–28.7°
b = 14.750 (3) ŵ = 0.88 mm1
c = 22.285 (5) ÅT = 105 K
β = 96.186 (9)°Tablet, pale yellow
V = 3462.3 (12) Å30.28 × 0.23 × 0.12 mm
Z = 4
Data collection top
Nonius KappaCCD (with an Oxford Cryosystems Cryostream cooler)
diffractometer
8837 independent reflections
Radiation source: fine-focus sealed tube7230 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.027
ω scans with κ offsetsθmax = 28.7°, θmin = 2.7°
Absorption correction: multi-scan
(HKL SCALEPACK; Otwinowski & Minor, 1997)
h = 1414
Tmin = 0.806, Tmax = 0.900k = 1914
29400 measured reflectionsl = 3030
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.031H-atom parameters constrained
wR(F2) = 0.071 w = 1/[σ2(Fo2) + (0.0196P)2 + 3.8331P]
where P = (Fo2 + 2Fc2)/3
S = 1.01(Δ/σ)max = 0.001
8837 reflectionsΔρmax = 0.55 e Å3
377 parametersΔρmin = 0.85 e Å3
0 restraintsExtinction correction: SHELXL97, Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
Primary atom site location: structure-invariant direct methodsExtinction coefficient: 0.0003 (1)
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Rh10.240170 (16)0.276057 (10)0.328026 (7)0.01309 (5)
Cl10.23936 (6)0.42713 (3)0.28604 (3)0.02114 (12)
Cl20.37178 (6)0.31683 (4)0.42006 (3)0.02430 (13)
P10.05890 (6)0.30764 (4)0.37706 (3)0.01593 (12)
P20.09665 (5)0.21664 (4)0.25654 (2)0.01393 (11)
P30.24355 (6)0.12520 (4)0.34310 (3)0.01533 (12)
P40.42017 (5)0.24879 (4)0.27644 (3)0.01605 (12)
C10.0752 (2)0.24567 (15)0.33734 (10)0.0206 (5)
H1A0.07430.18200.35150.025*
H1B0.15610.27380.34610.025*
C20.0656 (2)0.24792 (15)0.26921 (10)0.0197 (5)
H2A0.08570.30940.25320.024*
H2B0.12690.20470.24830.024*
C30.1180 (2)0.09891 (14)0.28204 (10)0.0162 (4)
H3A0.14760.05870.25080.019*
H3B0.04090.07340.29710.019*
C40.3914 (2)0.07802 (15)0.32167 (10)0.0203 (5)
H4A0.45950.08560.35530.024*
H4B0.38050.01240.31340.024*
C50.4291 (2)0.12591 (15)0.26539 (10)0.0190 (5)
H5A0.37110.10770.22960.023*
H5B0.51660.10850.25840.023*
C60.0082 (2)0.42587 (15)0.37108 (11)0.0232 (5)
H6A0.00410.44500.32830.028*
H6B0.07830.43090.38370.028*
C70.0971 (3)0.49007 (17)0.40978 (12)0.0330 (6)
H7A0.09010.47840.45260.049*
H7B0.07310.55300.40020.049*
H7C0.18480.47980.40130.049*
C80.0593 (2)0.27648 (17)0.45602 (10)0.0257 (5)
H8A0.07610.21060.46010.031*
H8B0.13000.30860.47980.031*
C90.0640 (3)0.29797 (18)0.48304 (12)0.0316 (6)
H9A0.08060.36330.48020.047*
H9B0.05590.27940.52550.047*
H9C0.13440.26500.46070.047*
C100.1082 (2)0.22870 (14)0.17672 (10)0.0169 (4)
C110.1516 (2)0.15987 (16)0.14130 (10)0.0210 (5)
H110.17160.10190.15820.025*
C120.1652 (2)0.17682 (18)0.08114 (11)0.0264 (5)
H120.19430.13000.05680.032*
C130.1370 (3)0.26139 (19)0.05619 (11)0.0306 (6)
H130.14730.27240.01500.037*
C140.0938 (3)0.32980 (17)0.09130 (11)0.0276 (5)
H140.07460.38780.07410.033*
C150.0785 (2)0.31410 (15)0.15130 (10)0.0217 (5)
H150.04800.36100.17520.026*
C160.2169 (2)0.06644 (15)0.41155 (10)0.0188 (5)
C170.1281 (2)0.00322 (15)0.41166 (11)0.0231 (5)
H170.07520.01780.37580.028*
C180.1172 (3)0.05121 (17)0.46453 (12)0.0304 (6)
H180.05730.09910.46450.036*
C190.1926 (3)0.02993 (18)0.51694 (12)0.0329 (6)
H190.18430.06290.55290.040*
C200.2807 (3)0.03973 (19)0.51705 (12)0.0349 (6)
H200.33260.05430.55320.042*
C210.2935 (3)0.08803 (17)0.46478 (11)0.0285 (6)
H210.35390.13560.46500.034*
C220.5723 (2)0.27816 (16)0.31822 (11)0.0230 (5)
H22A0.57430.25470.35990.028*
H22B0.64110.24790.29910.028*
C230.5980 (3)0.38048 (17)0.32073 (13)0.0310 (6)
H23A0.60870.40270.28010.047*
H23B0.67540.39250.34770.047*
H23C0.52620.41170.33590.047*
C240.4268 (2)0.30015 (16)0.20244 (10)0.0220 (5)
H24A0.34770.28490.17660.026*
H24B0.42950.36690.20720.026*
C250.5403 (3)0.27054 (18)0.17007 (12)0.0304 (6)
H25A0.61930.28740.19450.046*
H25B0.53650.30060.13070.046*
H25C0.53790.20470.16430.046*
B10.7420 (3)0.01968 (19)0.30275 (13)0.0247 (6)
F10.86574 (15)0.00685 (11)0.32240 (8)0.0402 (4)
F20.69748 (16)0.07493 (12)0.34659 (7)0.0410 (4)
F30.74176 (17)0.06957 (12)0.25002 (7)0.0437 (4)
F40.66369 (17)0.05409 (11)0.29292 (9)0.0515 (5)
O1S0.6663 (3)0.0553 (3)0.06315 (14)0.1278 (18)
C1S0.7760 (4)0.0822 (3)0.06820 (15)0.0664 (13)
C2S0.8077 (4)0.1746 (3)0.09012 (17)0.0735 (13)
H21S0.72930.20890.09280.110*
H22S0.85880.20510.06200.110*
H23S0.85610.17140.13010.110*
C3S0.8818 (5)0.0261 (2)0.04886 (16)0.0765 (15)
H31S0.85260.03640.04170.115*
H32S0.95340.02670.08060.115*
H33S0.90890.05120.01160.115*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Rh10.01270 (9)0.01110 (8)0.01553 (9)0.00076 (6)0.00181 (6)0.00109 (6)
Cl10.0249 (3)0.0124 (2)0.0270 (3)0.0013 (2)0.0071 (2)0.0022 (2)
Cl20.0220 (3)0.0294 (3)0.0209 (3)0.0046 (2)0.0001 (2)0.0058 (2)
P10.0152 (3)0.0148 (3)0.0183 (3)0.0001 (2)0.0042 (2)0.0022 (2)
P20.0135 (3)0.0120 (2)0.0162 (3)0.0000 (2)0.0011 (2)0.0009 (2)
P30.0151 (3)0.0119 (3)0.0189 (3)0.0005 (2)0.0015 (2)0.0005 (2)
P40.0130 (3)0.0158 (3)0.0196 (3)0.0010 (2)0.0029 (2)0.0016 (2)
C10.0154 (11)0.0196 (11)0.0277 (12)0.0020 (9)0.0066 (9)0.0050 (9)
C20.0159 (12)0.0189 (11)0.0237 (12)0.0024 (9)0.0006 (9)0.0033 (8)
C30.0173 (12)0.0119 (10)0.0196 (11)0.0013 (8)0.0027 (9)0.0013 (8)
C40.0176 (12)0.0168 (11)0.0264 (12)0.0038 (9)0.0015 (10)0.0003 (9)
C50.0135 (11)0.0188 (11)0.0248 (12)0.0007 (8)0.0027 (9)0.0034 (9)
C60.0237 (13)0.0176 (11)0.0297 (13)0.0038 (9)0.0097 (10)0.0026 (9)
C70.0403 (17)0.0206 (12)0.0397 (15)0.0061 (11)0.0121 (13)0.0105 (11)
C80.0275 (14)0.0310 (13)0.0199 (12)0.0008 (11)0.0083 (10)0.0008 (10)
C90.0349 (16)0.0368 (15)0.0258 (13)0.0021 (12)0.0165 (12)0.0001 (11)
C100.0154 (11)0.0181 (10)0.0169 (10)0.0041 (8)0.0006 (8)0.0000 (8)
C110.0186 (12)0.0226 (11)0.0220 (12)0.0016 (9)0.0019 (9)0.0007 (9)
C120.0228 (13)0.0355 (14)0.0213 (12)0.0021 (11)0.0037 (10)0.0033 (10)
C130.0282 (14)0.0423 (15)0.0220 (12)0.0006 (12)0.0054 (10)0.0060 (11)
C140.0286 (14)0.0256 (12)0.0283 (13)0.0017 (10)0.0021 (11)0.0080 (10)
C150.0228 (13)0.0199 (11)0.0219 (12)0.0034 (9)0.0003 (10)0.0001 (9)
C160.0204 (12)0.0169 (10)0.0192 (11)0.0032 (9)0.0033 (9)0.0021 (8)
C170.0267 (14)0.0200 (11)0.0229 (12)0.0014 (10)0.0038 (10)0.0008 (9)
C180.0352 (16)0.0262 (13)0.0308 (14)0.0078 (11)0.0081 (12)0.0061 (10)
C190.0392 (17)0.0367 (15)0.0234 (13)0.0009 (12)0.0057 (12)0.0118 (11)
C200.0387 (17)0.0418 (16)0.0223 (13)0.0036 (13)0.0049 (12)0.0050 (11)
C210.0300 (15)0.0276 (13)0.0264 (13)0.0055 (11)0.0036 (11)0.0055 (10)
C220.0126 (11)0.0271 (12)0.0290 (13)0.0026 (9)0.0005 (9)0.0063 (10)
C230.0227 (14)0.0312 (14)0.0394 (15)0.0094 (11)0.0044 (12)0.0087 (11)
C240.0187 (12)0.0247 (12)0.0233 (12)0.0014 (9)0.0061 (10)0.0026 (9)
C250.0310 (15)0.0336 (14)0.0293 (13)0.0003 (11)0.0158 (11)0.0016 (11)
B10.0176 (14)0.0256 (14)0.0307 (15)0.0004 (11)0.0011 (11)0.0011 (11)
F10.0190 (8)0.0469 (10)0.0538 (11)0.0071 (7)0.0000 (7)0.0038 (8)
F20.0368 (10)0.0519 (10)0.0331 (9)0.0149 (8)0.0021 (7)0.0083 (7)
F30.0456 (11)0.0484 (10)0.0375 (9)0.0014 (8)0.0070 (8)0.0120 (8)
F40.0389 (11)0.0364 (9)0.0782 (13)0.0200 (8)0.0014 (10)0.0046 (9)
O1S0.085 (2)0.210 (4)0.078 (2)0.105 (3)0.0414 (18)0.082 (2)
C1S0.059 (3)0.107 (3)0.0301 (17)0.049 (2)0.0126 (16)0.0305 (19)
C2S0.033 (2)0.133 (4)0.054 (2)0.005 (2)0.0025 (17)0.035 (2)
C3S0.146 (5)0.041 (2)0.038 (2)0.029 (2)0.009 (2)0.0116 (15)
Geometric parameters (Å, º) top
Rh1—P32.2501 (7)C11—H110.9500
Rh1—P22.2574 (7)C12—C131.385 (4)
Rh1—P12.3563 (7)C12—H120.9500
Rh1—P42.3649 (7)C13—C141.385 (4)
Rh1—Cl12.4164 (7)C13—H130.9500
Rh1—Cl22.4282 (7)C14—C151.384 (3)
P1—C81.818 (2)C14—H140.9500
P1—C61.825 (2)C15—H150.9500
P1—C11.835 (2)C16—C171.394 (3)
P2—C101.805 (2)C16—C211.400 (3)
P2—C21.831 (2)C17—C181.390 (3)
P2—C31.834 (2)C17—H170.9500
P3—C161.803 (2)C18—C191.378 (4)
P3—C41.824 (2)C18—H180.9500
P3—C31.839 (2)C19—C201.388 (4)
P4—C241.823 (2)C19—H190.9500
P4—C221.825 (2)C20—C211.384 (3)
P4—C51.833 (2)C20—H200.9500
C1—C21.533 (3)C21—H210.9500
C1—H1A0.9900C22—C231.534 (3)
C1—H1B0.9900C22—H22A0.9900
C2—H2A0.9900C22—H22B0.9900
C2—H2B0.9900C23—H23A0.9800
C3—H3A0.9900C23—H23B0.9800
C3—H3B0.9900C23—H23C0.9800
C4—C51.529 (3)C24—C251.532 (3)
C4—H4A0.9900C24—H24A0.9900
C4—H4B0.9900C24—H24B0.9900
C5—H5A0.9900C25—H25A0.9800
C5—H5B0.9900C25—H25B0.9800
C6—C71.534 (3)C25—H25C0.9800
C6—H6A0.9900B1—F41.372 (3)
C6—H6B0.9900B1—F31.386 (3)
C7—H7A0.9800B1—F11.392 (3)
C7—H7B0.9800B1—F21.393 (3)
C7—H7C0.9800O1S—C1S1.221 (4)
C8—C91.529 (3)C1S—C2S1.475 (6)
C8—H8A0.9900C1S—C3S1.494 (6)
C8—H8B0.9900C2S—H21S0.9800
C9—H9A0.9800C2S—H22S0.9800
C9—H9B0.9800C2S—H23S0.9800
C9—H9C0.9800C3S—H31S0.9800
C10—C111.394 (3)C3S—H32S0.9800
C10—C151.403 (3)C3S—H33S0.9800
C11—C121.387 (3)
P3—Rh1—P273.75 (2)C8—C9—H9A109.5
P3—Rh1—P197.29 (2)C8—C9—H9B109.5
P2—Rh1—P183.30 (3)H9A—C9—H9B109.5
P3—Rh1—P484.47 (2)C8—C9—H9C109.5
P2—Rh1—P496.21 (3)H9A—C9—H9C109.5
P1—Rh1—P4177.94 (2)H9B—C9—H9C109.5
P3—Rh1—Cl1165.72 (2)C11—C10—C15119.9 (2)
P2—Rh1—Cl196.36 (2)C11—C10—P2123.21 (17)
P1—Rh1—Cl191.61 (2)C15—C10—P2116.77 (17)
P4—Rh1—Cl186.45 (2)C12—C11—C10119.4 (2)
P3—Rh1—Cl296.91 (2)C12—C11—H11120.3
P2—Rh1—Cl2166.92 (2)C10—C11—H11120.3
P1—Rh1—Cl288.96 (3)C13—C12—C11120.7 (2)
P4—Rh1—Cl291.89 (3)C13—C12—H12119.7
Cl1—Rh1—Cl294.38 (2)C11—C12—H12119.7
C8—P1—C6106.39 (11)C14—C13—C12120.0 (2)
C8—P1—C1105.19 (11)C14—C13—H13120.0
C6—P1—C1103.54 (11)C12—C13—H13120.0
C8—P1—Rh1118.80 (8)C15—C14—C13120.3 (2)
C6—P1—Rh1113.78 (8)C15—C14—H14119.9
C1—P1—Rh1107.77 (7)C13—C14—H14119.9
C10—P2—C2106.94 (11)C14—C15—C10119.7 (2)
C10—P2—C3112.31 (10)C14—C15—H15120.1
C2—P2—C3106.08 (10)C10—C15—H15120.1
C10—P2—Rh1123.05 (7)C17—C16—C21119.7 (2)
C2—P2—Rh1111.45 (8)C17—C16—P3121.55 (18)
C3—P2—Rh195.62 (7)C21—C16—P3118.58 (18)
C16—P3—C4104.79 (11)C18—C17—C16119.7 (2)
C16—P3—C3110.97 (11)C18—C17—H17120.2
C4—P3—C3107.39 (11)C16—C17—H17120.2
C16—P3—Rh1126.89 (7)C19—C18—C17120.6 (2)
C4—P3—Rh1109.79 (8)C19—C18—H18119.7
C3—P3—Rh195.71 (7)C17—C18—H18119.7
C24—P4—C22104.18 (11)C18—C19—C20119.9 (2)
C24—P4—C5106.38 (11)C18—C19—H19120.0
C22—P4—C5104.34 (11)C20—C19—H19120.0
C24—P4—Rh1118.73 (8)C21—C20—C19120.4 (3)
C22—P4—Rh1115.21 (8)C21—C20—H20119.8
C5—P4—Rh1106.82 (7)C19—C20—H20119.8
C2—C1—P1109.66 (15)C20—C21—C16119.7 (2)
C2—C1—H1A109.7C20—C21—H21120.1
P1—C1—H1A109.7C16—C21—H21120.1
C2—C1—H1B109.7C23—C22—P4113.30 (18)
P1—C1—H1B109.7C23—C22—H22A108.9
H1A—C1—H1B108.2P4—C22—H22A108.9
C1—C2—P2108.11 (16)C23—C22—H22B108.9
C1—C2—H2A110.1P4—C22—H22B108.9
P2—C2—H2A110.1H22A—C22—H22B107.7
C1—C2—H2B110.1C22—C23—H23A109.5
P2—C2—H2B110.1C22—C23—H23B109.5
H2A—C2—H2B108.4H23A—C23—H23B109.5
P2—C3—P394.86 (10)C22—C23—H23C109.5
P2—C3—H3A112.8H23A—C23—H23C109.5
P3—C3—H3A112.8H23B—C23—H23C109.5
P2—C3—H3B112.8C25—C24—P4114.60 (18)
P3—C3—H3B112.8C25—C24—H24A108.6
H3A—C3—H3B110.2P4—C24—H24A108.6
C5—C4—P3110.26 (15)C25—C24—H24B108.6
C5—C4—H4A109.6P4—C24—H24B108.6
P3—C4—H4A109.6H24A—C24—H24B107.6
C5—C4—H4B109.6C24—C25—H25A109.5
P3—C4—H4B109.6C24—C25—H25B109.5
H4A—C4—H4B108.1H25A—C25—H25B109.5
C4—C5—P4108.95 (15)C24—C25—H25C109.5
C4—C5—H5A109.9H25A—C25—H25C109.5
P4—C5—H5A109.9H25B—C25—H25C109.5
C4—C5—H5B109.9F4—B1—F3109.9 (2)
P4—C5—H5B109.9F4—B1—F1111.1 (2)
H5A—C5—H5B108.3F3—B1—F1109.4 (2)
C7—C6—P1113.00 (18)F4—B1—F2109.3 (2)
C7—C6—H6A109.0F3—B1—F2108.3 (2)
P1—C6—H6A109.0F1—B1—F2108.8 (2)
C7—C6—H6B109.0O1S—C1S—C2S120.7 (5)
P1—C6—H6B109.0O1S—C1S—C3S122.0 (5)
H6A—C6—H6B107.8C2S—C1S—C3S117.1 (3)
C6—C7—H7A109.5C1S—C2S—H21S109.5
C6—C7—H7B109.5C1S—C2S—H22S109.5
H7A—C7—H7B109.5H21S—C2S—H22S109.5
C6—C7—H7C109.5C1S—C2S—H23S109.5
H7A—C7—H7C109.5H21S—C2S—H23S109.5
H7B—C7—H7C109.5H22S—C2S—H23S109.5
C9—C8—P1114.55 (18)C1S—C3S—H31S109.5
C9—C8—H8A108.6C1S—C3S—H32S109.5
P1—C8—H8A108.6H31S—C3S—H32S109.5
C9—C8—H8B108.6C1S—C3S—H33S109.5
P1—C8—H8B108.6H31S—C3S—H33S109.5
H8A—C8—H8B107.6H32S—C3S—H33S109.5
P3—Rh1—P1—C858.51 (10)P1—C1—C2—P248.26 (18)
P2—Rh1—P1—C8131.11 (10)C10—P2—C2—C1175.54 (15)
Cl1—Rh1—P1—C8132.68 (10)C3—P2—C2—C164.41 (17)
Cl2—Rh1—P1—C838.32 (10)Rh1—P2—C2—C138.46 (16)
P3—Rh1—P1—C6175.03 (9)C10—P2—C3—P3127.09 (10)
P2—Rh1—P1—C6102.44 (9)C2—P2—C3—P3116.41 (11)
Cl1—Rh1—P1—C66.22 (9)Rh1—P2—C3—P32.15 (8)
Cl2—Rh1—P1—C688.13 (9)C16—P3—C3—P2135.35 (10)
P3—Rh1—P1—C160.84 (8)C4—P3—C3—P2110.66 (10)
P2—Rh1—P1—C111.76 (8)Rh1—P3—C3—P22.16 (8)
Cl1—Rh1—P1—C1107.97 (8)C16—P3—C4—C5177.08 (16)
Cl2—Rh1—P1—C1157.67 (8)C3—P3—C4—C564.84 (18)
P3—Rh1—P2—C10119.44 (9)Rh1—P3—C4—C538.07 (17)
P1—Rh1—P2—C10140.92 (9)P3—C4—C5—P448.92 (19)
P4—Rh1—P2—C1037.06 (9)C24—P4—C5—C4166.13 (16)
Cl1—Rh1—P2—C1050.04 (9)C22—P4—C5—C484.08 (18)
Cl2—Rh1—P2—C10164.96 (11)Rh1—P4—C5—C438.38 (17)
P3—Rh1—P2—C2111.57 (8)C8—P1—C6—C760.4 (2)
P1—Rh1—P2—C211.93 (8)C1—P1—C6—C7171.04 (17)
P4—Rh1—P2—C2166.05 (8)Rh1—P1—C6—C772.27 (18)
Cl1—Rh1—P2—C278.95 (8)C6—P1—C8—C951.5 (2)
Cl2—Rh1—P2—C266.05 (13)C1—P1—C8—C958.0 (2)
P3—Rh1—P2—C31.83 (7)Rh1—P1—C8—C9178.65 (15)
P1—Rh1—P2—C397.81 (7)C2—P2—C10—C11127.2 (2)
P4—Rh1—P2—C384.21 (7)C3—P2—C10—C1111.2 (2)
Cl1—Rh1—P2—C3171.31 (7)Rh1—P2—C10—C11101.96 (19)
Cl2—Rh1—P2—C343.69 (12)C2—P2—C10—C1556.7 (2)
P2—Rh1—P3—C16123.47 (10)C3—P2—C10—C15172.72 (17)
P1—Rh1—P3—C1642.67 (10)Rh1—P2—C10—C1574.13 (19)
P4—Rh1—P3—C16138.40 (10)C15—C10—C11—C120.2 (3)
Cl1—Rh1—P3—C16170.83 (12)P2—C10—C11—C12175.81 (18)
Cl2—Rh1—P3—C1647.16 (10)C10—C11—C12—C130.4 (4)
P2—Rh1—P3—C4108.99 (9)C11—C12—C13—C140.5 (4)
P1—Rh1—P3—C4170.21 (8)C12—C13—C14—C150.1 (4)
P4—Rh1—P3—C410.86 (8)C13—C14—C15—C100.7 (4)
Cl1—Rh1—P3—C461.63 (13)C11—C10—C15—C140.7 (4)
Cl2—Rh1—P3—C480.38 (9)P2—C10—C15—C14175.52 (19)
P2—Rh1—P3—C31.82 (7)C4—P3—C16—C17103.0 (2)
P1—Rh1—P3—C378.98 (7)C3—P3—C16—C1712.7 (2)
P4—Rh1—P3—C399.95 (7)Rh1—P3—C16—C17127.55 (17)
Cl1—Rh1—P3—C349.17 (12)C4—P3—C16—C2172.9 (2)
Cl2—Rh1—P3—C3168.81 (7)C3—P3—C16—C21171.43 (18)
P3—Rh1—P4—C24132.60 (9)Rh1—P3—C16—C2156.5 (2)
P2—Rh1—P4—C2459.66 (9)C21—C16—C17—C180.6 (4)
Cl1—Rh1—P4—C2436.36 (9)P3—C16—C17—C18175.23 (19)
Cl2—Rh1—P4—C24130.64 (9)C16—C17—C18—C190.6 (4)
P3—Rh1—P4—C22102.87 (9)C17—C18—C19—C200.3 (4)
P2—Rh1—P4—C22175.81 (9)C18—C19—C20—C210.0 (4)
Cl1—Rh1—P4—C2288.17 (9)C19—C20—C21—C160.0 (4)
Cl2—Rh1—P4—C226.11 (9)C17—C16—C21—C200.3 (4)
P3—Rh1—P4—C512.49 (8)P3—C16—C21—C20175.7 (2)
P2—Rh1—P4—C560.45 (8)C24—P4—C22—C2356.1 (2)
Cl1—Rh1—P4—C5156.47 (8)C5—P4—C22—C23167.48 (17)
Cl2—Rh1—P4—C5109.26 (8)Rh1—P4—C22—C2375.74 (19)
C8—P1—C1—C2166.14 (16)C22—P4—C24—C2556.3 (2)
C6—P1—C1—C282.38 (17)C5—P4—C24—C2553.6 (2)
Rh1—P1—C1—C238.47 (17)Rh1—P4—C24—C25173.98 (15)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
C2—H2A···F4i0.992.373.349 (3)171
C3—H3B···F1ii0.992.323.302 (3)171
C17—H17···F1ii0.952.413.240 (3)146
Symmetry codes: (i) x+1/2, y+1/2, z+1/2; (ii) x1, y, z.
 

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