Buy article online - an online subscription or single-article purchase is required to access this article.
Download citation
Download citation
link to html
In the title complex, [Zn(C11H12N3O2)(C2H3O2)(C9H7N)]·0.5C9H7N, the ZnII atom is five-coordinate, bonded to one acetate O atom, one O atom and two N atoms from the tridentate hydrazone HL ligand (H2L is di­acetyl monoxime benzoyl­hydrazone), and one N atom from the quinoline mol­ecule. The uncoordinated quinoline mol­ecule is disordered and lies on a center of inversion. The presence of π–π stacking interactions between the coordinated quinoline ligands results in a chain structure along the a axis.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804009389/hb6035sup1.cif
Contains datablocks gloabl, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536804009389/hb6035Isup2.hkl
Contains datablock I

CCDC reference: 239078

Key indicators

  • Single-crystal X-ray study
  • T = 293 K
  • R factor = 0.051
  • wR factor = 0.135
  • Data-to-parameter ratio = 18.0

checkCIF/PLATON results

No syntax errors found



Alert level A PLAT241_ALERT_2_A Check High U(eq) as Compared to Neighbors .... C24 PLAT241_ALERT_2_A Check High U(eq) as Compared to Neighbors .... C32
Alert level B PLAT220_ALERT_2_B Large Non-Solvent C Ueq(max)/Ueq(min) ... 3.57 Ratio PLAT241_ALERT_2_B Check High U(eq) as Compared to Neighbors .... C31 PLAT242_ALERT_2_B Check Low U(eq) as Compared to Neighbors .... C38 PLAT414_ALERT_2_B Short Intra D-H..H-X H1 .. H9C .. 1.89 Ang.
Alert level C PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings Differ .... ? PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............ 0.50 Ratio PLAT165_ALERT_3_C Nr. of Status R Flagged Non-Hydrogen Atoms ..... 20 PLAT222_ALERT_3_C Large Non-Solvent H Ueq(max)/Ueq(min) ... 3.63 Ratio PLAT241_ALERT_2_C Check High U(eq) as Compared to Neighbors .... N7 PLAT241_ALERT_2_C Check High U(eq) as Compared to Neighbors .... C33 PLAT241_ALERT_2_C Check High U(eq) as Compared to Neighbors .... C37 PLAT242_ALERT_2_C Check Low U(eq) as Compared to Neighbors .... C25 PLAT242_ALERT_2_C Check Low U(eq) as Compared to Neighbors .... C27 PLAT242_ALERT_2_C Check Low U(eq) as Compared to Neighbors .... C29 PLAT242_ALERT_2_C Check Low U(eq) as Compared to Neighbors .... C34 PLAT301_ALERT_3_C Main Residue Disorder ......................... 14.00 Perc. PLAT414_ALERT_2_C Short Intra D-H..H-X H1 .. H7 .. 1.90 Ang. PLAT420_ALERT_2_C D-H Without Acceptor N1 - H1 ... ?
2 ALERT level A = In general: serious problem 4 ALERT level B = Potentially serious problem 15 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 3 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 15 ALERT type 2 Indicator that the structure model may be wrong or deficient 3 ALERT type 3 Indicator that the structure quality may be low 0 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: RAPID-AUTO (Rigaku Corporation, 1998); cell refinement: RAPID-AUTO; data reduction: CrystalStructure (Rigaku/MSC and Rigaku Corporation, 2002); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.

Bis{(acetato-κO)(diacetyl monoxime benzoylhydrazonato-κ3O,O',N)- (quinoline-κN)zinc(II)} quinoline solvate top
Crystal data top
[Zn(C11H12N3O2)(C2H3O2)(C9H7N)]·0.5C9H7NZ = 2
Mr = 536.39F(000) = 556
Triclinic, P1Dx = 1.431 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 7.383 (2) ÅCell parameters from 4813 reflections
b = 12.286 (3) Åθ = 3.3–27.4°
c = 13.910 (3) ŵ = 1.03 mm1
α = 85.97 (3)°T = 293 K
β = 83.51 (3)°Prism, yellow
γ = 84.07 (3)°0.35 × 0.27 × 0.18 mm
V = 1244.8 (5) Å3
Data collection top
Rigaku R-AXIS RAPID
diffractometer
5674 independent reflections
Radiation source: fine-focus sealed tube4301 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.025
Detector resolution: 10 pixels mm-1θmax = 27.5°, θmin = 3.0°
ω scansh = 98
Absorption correction: multi-scan
(ABSCOR; Higashi, 1995)
k = 1515
Tmin = 0.715, Tmax = 0.837l = 1818
12128 measured reflections
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.051Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.135H-atom parameters constrained
S = 1.04 w = 1/[σ2(Fo2) + (0.0719P)2 + 0.4688P]
where P = (Fo2 + 2Fc2)/3
5674 reflections(Δ/σ)max = 0.001
315 parametersΔρmax = 0.63 e Å3
0 restraintsΔρmin = 0.38 e Å3
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Zn10.69689 (5)0.03691 (3)0.23214 (2)0.0518 (1)
N10.6615 (4)0.2562 (2)0.1340 (2)0.0581 (6)
N20.7851 (3)0.1659 (2)0.1443 (2)0.0544 (6)
N30.9740 (4)0.0155 (2)0.1615 (2)0.0572 (6)
N40.7370 (3)0.0078 (2)0.3756 (2)0.0517 (5)
N60.505 (1)0.5028 (8)0.6353 (6)0.073 (3)*0.25
N70.685 (1)0.535 (1)0.5754 (7)0.098 (5)*0.25
O10.4731 (3)0.1540 (2)0.2383 (2)0.0578 (5)
O21.0727 (3)0.1162 (2)0.1768 (2)0.0660 (6)
O30.5730 (3)0.0849 (2)0.1968 (2)0.0641 (5)
O40.7867 (4)0.2240 (2)0.2093 (2)0.0760 (7)
C10.5052 (4)0.2399 (2)0.1859 (2)0.0507 (6)
C20.3585 (4)0.3309 (2)0.1802 (2)0.0554 (7)
C30.1887 (5)0.3213 (3)0.2318 (2)0.0632 (8)
C40.0499 (6)0.4048 (3)0.2262 (3)0.077 (1)
C50.0811 (6)0.4991 (3)0.1701 (3)0.086 (1)
C60.2483 (6)0.5090 (3)0.1187 (4)0.091 (1)
C70.3855 (5)0.4258 (3)0.1233 (3)0.076 (1)
C80.9426 (4)0.1620 (3)0.0953 (2)0.0550 (7)
C91.0051 (5)0.2510 (3)0.0257 (2)0.0722 (9)
C101.0569 (4)0.0579 (3)0.1103 (2)0.0551 (7)
C111.2493 (4)0.0401 (3)0.0648 (3)0.0729 (9)
C120.7167 (5)0.0917 (3)0.4142 (2)0.0642 (8)
C130.7181 (5)0.1202 (3)0.5132 (3)0.074 (1)
C140.7393 (5)0.0439 (3)0.5736 (2)0.0693 (9)
C150.7638 (4)0.0623 (3)0.5369 (2)0.0579 (7)
C160.7625 (4)0.0872 (2)0.4362 (2)0.0505 (6)
C170.7846 (5)0.1937 (3)0.3980 (2)0.0631 (8)
C180.8052 (6)0.2730 (3)0.4588 (3)0.080 (1)
C190.8056 (6)0.2490 (4)0.5582 (3)0.088 (1)
C200.7861 (5)0.1475 (4)0.5966 (2)0.078 (1)
C210.6353 (5)0.1834 (3)0.1875 (2)0.0654 (8)
C220.5108 (6)0.2548 (3)0.1484 (4)0.096 (1)
C230.358 (1)0.4488 (9)0.6787 (6)0.091 (6)*0.25
C240.241 (1)0.4073 (9)0.6216 (8)0.123 (9)*0.25
C250.272 (1)0.4198 (8)0.5212 (8)0.059 (3)*0.25
C260.419 (1)0.4738 (7)0.4778 (6)0.062 (4)*0.25
C270.536 (1)0.5154 (7)0.5348 (6)0.050 (4)*0.25
C280.683 (1)0.5694 (7)0.4914 (6)0.069 (4)*0.25
C290.714 (1)0.5819 (8)0.3910 (7)0.055 (3)*0.25
C300.597 (1)0.5404 (8)0.3340 (6)0.082 (5)*0.25
C310.450 (1)0.4864 (8)0.3774 (6)0.102 (7)*0.25
C320.814 (1)0.584 (1)0.5104 (9)0.15 (1)*0.25
C330.791 (1)0.5954 (9)0.4122 (8)0.099 (7)*0.25
C340.640 (1)0.5573 (8)0.3790 (7)0.051 (3)*0.25
C350.511 (1)0.5082 (7)0.4440 (6)0.070 (4)*0.25
C360.534 (1)0.4972 (7)0.5422 (6)0.058 (5)*0.25
C370.405 (1)0.4481 (8)0.6072 (6)0.088 (5)*0.25
C380.254 (1)0.4100 (7)0.5740 (6)0.042 (2)*0.25
C390.232 (1)0.4210 (7)0.4758 (7)0.059 (3)*0.25
C400.360 (1)0.4701 (7)0.4108 (6)0.078 (5)*0.25
H10.68270.31450.09770.070*
H30.16810.25800.27050.076*
H40.06450.39730.26020.092*
H50.01160.55620.16720.103*
H60.26870.57260.08030.109*
H70.49850.43320.08770.091*
H9A1.00820.22870.03920.108*
H9B1.12560.26600.03740.108*
H9C0.92210.31590.03400.108*
H11A1.31620.01510.10270.109*
H11B1.30580.10740.06190.109*
H11C1.24990.01650.00040.109*
H120.70060.14590.37340.077*
H130.70430.19190.53690.088*
H140.73760.06160.63980.083*
H170.78530.21050.33170.076*
H180.81910.34410.43350.096*
H190.81970.30430.59840.106*
H200.78700.13280.66300.093*
H22A0.47110.22100.08900.144*
H22B0.40610.26370.19480.144*
H22C0.57550.32520.13630.144*
H230.33710.44040.74590.109*0.25
H240.14250.37110.65070.147*0.25
H250.19370.39200.48310.071*0.25
H280.76080.59720.52960.083*0.25
H290.81200.61810.36190.066*0.25
H300.61740.54880.26680.098*0.25
H310.37160.45860.33920.123*0.25
H320.91460.60990.53260.185*0.25
H330.87730.62830.36870.119*0.25
H340.62510.56470.31330.061*0.25
H370.42000.44070.67290.105*0.25
H380.16780.37710.61750.051*0.25
H390.13040.39550.45360.070*0.25
H400.34520.47740.34510.094*0.25
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Zn10.0625 (2)0.0491 (2)0.0419 (2)0.0066 (1)0.0017 (1)0.0056 (1)
N10.072 (2)0.052 (1)0.049 (1)0.011 (1)0.008 (1)0.015 (1)
N20.063 (2)0.058 (1)0.041 (1)0.010 (1)0.006 (1)0.008 (1)
N30.061 (1)0.063 (2)0.047 (1)0.004 (1)0.004 (1)0.002 (1)
N40.056 (1)0.050 (1)0.045 (1)0.003 (1)0.001 (1)0.006 (1)
O10.065 (1)0.050 (1)0.055 (1)0.0051 (9)0.000 (1)0.0135 (9)
O20.064 (1)0.066 (1)0.067 (1)0.001 (1)0.005 (1)0.005 (1)
O30.068 (1)0.052 (1)0.073 (1)0.011 (1)0.006 (1)0.001 (1)
O40.072 (2)0.058 (1)0.094 (2)0.006 (1)0.009 (1)0.000 (1)
C10.066 (2)0.047 (2)0.040 (1)0.011 (1)0.011 (1)0.004 (1)
C20.072 (2)0.048 (2)0.049 (2)0.010 (1)0.017 (1)0.005 (1)
C30.077 (2)0.052 (2)0.058 (2)0.002 (2)0.006 (2)0.008 (1)
C40.079 (2)0.068 (2)0.079 (2)0.005 (2)0.007 (2)0.004 (2)
C50.096 (3)0.059 (2)0.101 (3)0.009 (2)0.030 (2)0.016 (2)
C60.091 (3)0.063 (2)0.117 (3)0.011 (2)0.027 (3)0.039 (2)
C70.077 (2)0.062 (2)0.087 (2)0.013 (2)0.017 (2)0.025 (2)
C80.062 (2)0.069 (2)0.036 (1)0.018 (1)0.008 (1)0.003 (1)
C90.079 (2)0.083 (2)0.055 (2)0.026 (2)0.003 (2)0.013 (2)
C100.056 (2)0.074 (2)0.038 (1)0.016 (2)0.007 (1)0.002 (1)
C110.056 (2)0.101 (3)0.061 (2)0.015 (2)0.003 (2)0.006 (2)
C120.072 (2)0.055 (2)0.059 (2)0.002 (2)0.003 (2)0.013 (1)
C130.079 (2)0.066 (2)0.067 (2)0.002 (2)0.003 (2)0.029 (2)
C140.067 (2)0.086 (2)0.046 (2)0.010 (2)0.001 (1)0.022 (2)
C150.052 (2)0.074 (2)0.041 (1)0.015 (1)0.001 (1)0.004 (1)
C160.050 (2)0.055 (2)0.042 (1)0.010 (1)0.000 (1)0.006 (1)
C170.083 (2)0.056 (2)0.049 (2)0.004 (2)0.011 (2)0.004 (1)
C180.111 (3)0.056 (2)0.073 (2)0.005 (2)0.024 (2)0.003 (2)
C190.116 (3)0.082 (3)0.067 (2)0.012 (2)0.023 (2)0.023 (2)
C200.084 (2)0.097 (3)0.047 (2)0.018 (2)0.009 (2)0.007 (2)
C210.070 (2)0.057 (2)0.066 (2)0.014 (2)0.012 (2)0.004 (2)
C220.093 (3)0.066 (2)0.132 (4)0.024 (2)0.007 (3)0.024 (2)
Geometric parameters (Å, º) top
Zn1—N22.047 (2)C15—C161.414 (4)
Zn1—N32.220 (3)C15—C201.414 (5)
Zn1—N42.052 (2)C16—C171.396 (4)
Zn1—O12.074 (2)C17—C181.365 (5)
Zn1—O31.950 (2)C17—H170.9300
N1—N21.373 (4)C18—C191.394 (5)
N2—C81.278 (4)C18—H180.9300
N3—C101.272 (4)C19—C201.337 (6)
O1—C11.267 (3)C19—H190.9300
O2—N31.386 (3)C20—H200.9300
N1—H10.8600C21—C221.502 (5)
N1—C11.320 (4)C22—H22A0.9600
N4—C121.316 (4)C22—H22B0.9600
N4—C161.373 (4)C22—H22C0.9600
N6—C231.3900C23—C241.3900
N6—C271.3900C23—H230.9300
N7—C321.3900C24—C251.3900
N7—C361.3900C24—H240.9300
O3—C211.260 (4)C25—C261.3900
O4—C211.237 (4)C25—H250.9300
C1—C21.479 (4)C26—C271.3900
C2—C31.384 (5)C26—C311.3900
C2—C71.382 (4)C27—C281.3900
C3—C41.377 (5)C28—C291.3900
C3—H30.9300C28—H280.9300
C4—C51.376 (5)C29—C301.3900
C4—H40.9300C29—H290.9300
C5—C61.368 (6)C30—C311.3900
C5—H50.9300C30—H300.9300
C6—C71.366 (5)C31—H310.9300
C6—H60.9300C32—C331.3900
C7—H70.9300C32—H320.9300
C8—C91.483 (4)C33—C341.3900
C8—C101.473 (5)C33—H330.9300
C9—H9A0.9600C34—C351.3900
C9—H9B0.9600C34—H340.9300
C9—H9C0.9600C35—C361.3900
C10—C111.489 (4)C35—C401.3900
C11—H11A0.9600C36—C371.3900
C11—H11B0.9600C37—C381.3900
C11—H11C0.9600C37—H370.9300
C12—C131.398 (5)C38—C391.3900
C12—H120.9300C38—H380.9300
C13—C141.335 (5)C39—C401.3900
C13—H130.9300C39—H390.9300
C14—C151.390 (5)C40—H400.9300
C14—H140.9300
N2—Zn1—N372.1 (1)C17—C16—C15119.8 (3)
N2—Zn1—N4125.3 (1)C17—C18—C19121.0 (4)
N2—Zn1—O175.73 (9)C17—C18—H18119.5
N4—Zn1—O1102.17 (9)C18—C17—C16119.4 (3)
N4—Zn1—N3100.87 (9)C18—C17—H17120.3
O1—Zn1—N3147.34 (9)C18—C19—H19119.6
O3—Zn1—N2127.9 (1)C19—C18—H18119.5
O3—Zn1—N397.5 (1)C19—C20—C15120.5 (3)
O3—Zn1—N4106.7 (1)C19—C20—H20119.7
O3—Zn1—O197.68 (9)C20—C19—C18120.8 (4)
N1—N2—Zn1116.85 (19)C20—C19—H19119.6
N1—C1—C2115.4 (2)C21—O3—Zn1128.8 (2)
N2—N1—H1125.2C21—C22—H22A109.5
N2—C8—C9124.0 (3)C21—C22—H22B109.5
N2—C8—C10114.0 (3)C21—C22—H22C109.5
N3—C10—C8114.0 (3)C23—N6—C27120.0
N3—C10—C11123.8 (3)C23—C24—C25120.0
N4—C12—C13123.5 (3)C23—C24—H24120.0
N4—C16—C15120.6 (3)C24—C23—N6120.0
N4—C16—C17119.6 (2)C24—C23—H23120.0
N4—C12—H12118.2C24—C25—H25120.0
N6—C23—H23120.0C25—C24—H24120.0
N7—C32—C33120.0C25—C26—C31120.0
N7—C32—H32120.0C26—C25—C24120.0
O1—C1—N1125.4 (3)C26—C25—H25120.0
O1—C1—C2119.2 (3)C26—C27—N6120.0
O2—N3—Zn1126.1 (2)C26—C31—H31120.0
O4—C21—O3125.0 (3)C27—C26—C25120.0
O4—C21—C22119.3 (3)C27—C26—C31120.0
C1—N1—N2110.0 (2)C27—C28—H28120.0
C1—N1—H1125.2C28—C27—N6120.0
C1—O1—Zn1112.1 (2)C28—C27—C26120.0
C2—C3—H3119.7C28—C29—C30120.0
C2—C7—H7119.6C28—C29—H29120.0
C3—C2—C1119.8 (3)C29—C28—C27120.0
C3—C4—H4120.1C29—C28—H28120.0
C4—C3—C2120.5 (3)C29—C30—H30120.0
C4—C3—H3119.7C30—C29—H29120.0
C4—C5—H5120.0C30—C31—C26120.0
C5—C4—C3119.8 (4)C30—C31—H31120.0
C5—C4—H4120.1C31—C30—C29120.0
C5—C6—H6119.9C31—C30—H30120.0
C6—C5—C4120.0 (4)C32—N7—C36120.0
C6—C5—H5120.0C32—C33—H33120.0
C6—C7—C2120.8 (4)C33—C32—H32120.0
C6—C7—H7119.6C33—C34—C35120.0
C7—C2—C1121.6 (3)C33—C34—H34120.0
C7—C2—C3118.6 (3)C34—C33—C32120.0
C7—C6—C5120.3 (3)C34—C33—H33120.0
C7—C6—H6119.9C34—C35—C36120.0
C8—N2—Zn1122.8 (2)C34—C35—C40120.0
C8—N2—N1119.9 (2)C35—C34—H34120.0
C8—C9—H9A109.5C35—C36—N7120.0
C8—C9—H9B109.5C35—C40—H40120.0
C8—C9—H9C109.5C36—C35—C40120.0
C8—C10—C11122.1 (3)C36—C37—C38120.0
C10—N3—Zn1116.5 (2)C36—C37—H37120.0
C10—N3—O2117.0 (3)C37—C36—N7120.0
C10—C8—C9121.9 (3)C37—C36—C35120.0
C10—C11—H11A109.5C37—C38—H38120.0
C10—C11—H11B109.5C38—C37—H37120.0
C10—C11—H11C109.5C38—C39—C40120.0
C12—N4—Zn1117.1 (2)C38—C39—H39120.0
C12—N4—C16117.9 (3)C39—C38—C37120.0
C12—C13—H13120.2C39—C38—H38120.0
C13—C12—H12118.2C39—C40—C35120.0
C13—C14—C15119.5 (3)C39—C40—H40120.0
C13—C14—H14120.3C40—C39—H39120.0
C14—C13—C12119.6 (3)H9A—C9—H9B109.5
C14—C13—H13120.2H9A—C9—H9C109.5
C14—C15—C16118.9 (3)H9B—C9—H9C109.5
C14—C15—C20122.6 (3)H11A—C11—H11B109.5
C15—C14—H14120.3H11A—C11—H11C109.5
C15—C20—H20119.7H11B—C11—H11C109.5
C16—N4—Zn1124.6 (2)H22A—C22—H22B109.5
C16—C15—C20118.5 (3)H22A—C22—H22C109.5
C16—C17—H17120.3H22B—C22—H22C109.5
Zn1—N2—C8—C9175.4 (2)C1—N1—N2—Zn10.4 (3)
Zn1—N2—C8—C101.9 (3)C1—N1—N2—C8176.1 (3)
Zn1—N3—C10—C88.4 (3)C1—C2—C3—C4179.1 (3)
Zn1—N3—C10—C11174.4 (2)C1—C2—C7—C6179.8 (3)
Zn1—N4—C12—C13172.1 (3)C2—C3—C4—C51.0 (6)
Zn1—N4—C16—C15171.2 (2)C3—C2—C7—C60.6 (5)
Zn1—N4—C16—C177.8 (4)C3—C4—C5—C61.3 (6)
Zn1—O1—C1—N10.7 (4)C4—C5—C6—C70.6 (7)
Zn1—O1—C1—C2178.7 (2)C5—C6—C7—C20.4 (7)
Zn1—O3—C21—O47.8 (5)C7—C2—C3—C40.1 (5)
Zn1—O3—C21—C22173.3 (3)C9—C8—C10—N3170.4 (3)
N1—N2—C8—C90.5 (4)C9—C8—C10—C116.8 (4)
N1—N2—C8—C10177.1 (3)C12—N4—C16—C151.0 (4)
N1—C1—C2—C3179.7 (3)C12—N4—C16—C17180.0 (3)
N1—C1—C2—C70.1 (4)C12—C13—C14—C151.4 (5)
N2—Zn1—N3—O2177.8 (2)C13—C14—C15—C161.1 (5)
N2—Zn1—N3—C105.8 (2)C13—C14—C15—C20179.6 (3)
N2—Zn1—N4—C1625.6 (3)C14—C15—C16—N40.2 (4)
N2—Zn1—O1—C10.9 (2)C14—C15—C16—C17179.2 (3)
N2—Zn1—O3—C21106.8 (3)C14—C15—C20—C19178.7 (4)
N2—N1—C1—O10.4 (4)C15—C16—C17—C180.7 (5)
N2—N1—C1—C2179.2 (2)C16—N4—C12—C130.6 (5)
N2—C8—C10—N36.9 (4)C16—C15—C20—C190.1 (5)
N2—C8—C10—C11175.9 (3)C16—C17—C18—C190.4 (6)
N3—Zn1—N2—N1173.6 (2)C17—C18—C19—C200.1 (7)
N3—Zn1—N2—C81.7 (2)C18—C19—C20—C150.2 (7)
N3—Zn1—N4—C1286.5 (2)C20—C15—C16—N4178.4 (3)
N3—Zn1—N4—C16101.3 (2)C20—C15—C16—C170.6 (4)
N3—Zn1—O1—C19.3 (3)C23—N6—C27—C260.0
N3—Zn1—O3—C2133.6 (3)C23—N6—C27—C28180.0
N4—Zn1—N2—N195.6 (2)C23—C24—C25—C260.0
N4—Zn1—N2—C889.1 (2)C24—C25—C26—C270.0
N4—Zn1—N3—O254.0 (2)C24—C25—C26—C31180.0
N4—Zn1—N3—C10118.1 (2)C25—C26—C27—N60.0
N4—Zn1—O1—C1124.6 (2)C25—C26—C27—C28180.0
N4—Zn1—O3—C2170.1 (3)C25—C26—C31—C30180.0
N4—C12—C13—C140.6 (6)C26—C27—C28—C290.0
N4—C16—C17—C18178.3 (3)C27—N6—C23—C240.0
N6—C23—C24—C250.0C27—C26—C31—C300.0
N6—C27—C28—C29180.0C27—C28—C29—C300.0
N7—C32—C33—C340.0C28—C29—C30—C310.0
N7—C36—C37—C38180.0C29—C30—C31—C260.0
O1—Zn1—N2—N10.7 (2)C31—C26—C27—N6180.0
O1—Zn1—N2—C8176.0 (2)C31—C26—C27—C280.0
O1—Zn1—N3—O2171.8 (2)C32—N7—C36—C350.0
O1—Zn1—N3—C1016.2 (3)C32—N7—C36—C37180.0
O1—Zn1—N4—C12116.8 (2)C32—C33—C34—C350.0
O1—Zn1—N4—C1655.4 (2)C33—C34—C35—C360.0
O1—Zn1—O3—C21175.4 (3)C33—C34—C35—C40180.0
O1—C1—C2—C30.1 (4)C34—C35—C36—N70.0
O1—C1—C2—C7179.3 (3)C34—C35—C36—C37180.0
O2—N3—C10—C8178.8 (2)C34—C35—C40—C39180.0
O2—N3—C10—C111.7 (4)C35—C36—C37—C380.0
O3—Zn1—N2—N188.0 (2)C36—N7—C32—C330.0
O3—Zn1—N2—C887.3 (2)C36—C35—C40—C390.0
O3—Zn1—N3—O254.7 (2)C36—C37—C38—C390.0
O3—Zn1—N3—C10133.3 (2)C37—C38—C39—C400.0
O3—Zn1—N4—C1214.8 (2)C38—C39—C40—C350.0
O3—Zn1—N4—C16157.4 (2)C40—C35—C36—N7180.0
O3—Zn1—O1—C1126.4 (2)C40—C35—C36—C370.0
 

Subscribe to Acta Crystallographica Section E: Crystallographic Communications

The full text of this article is available to subscribers to the journal.

If you have already registered and are using a computer listed in your registration details, please email support@iucr.org for assistance.

Buy online

You may purchase this article in PDF and/or HTML formats. For purchasers in the European Community who do not have a VAT number, VAT will be added at the local rate. Payments to the IUCr are handled by WorldPay, who will accept payment by credit card in several currencies. To purchase the article, please complete the form below (fields marked * are required), and then click on `Continue'.
E-mail address* 
Repeat e-mail address* 
(for error checking) 

Format*   PDF (US $40)
   HTML (US $40)
   PDF+HTML (US $50)
In order for VAT to be shown for your country javascript needs to be enabled.

VAT number 
(non-UK EC countries only) 
Country* 
 

Terms and conditions of use
Contact us

Follow Acta Cryst. E
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds