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The title compound, [Co(C7H5O2)2(C5H6N2)2], contains CoII cations bonded to two bidentate benzoate ligands and two 2-amino­pyridine ligands, resulting in highly distorted cis-CoN2O4 octa­hedra. The crystal structure is stabilized by N—H...O hydrogen bonds.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806011925/hb2030sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536806011925/hb2030Isup2.hkl
Contains datablock I

CCDC reference: 608593

Key indicators

  • Single-crystal X-ray study
  • T = 293 K
  • Mean [sigma](C-C) = 0.003 Å
  • R factor = 0.031
  • wR factor = 0.086
  • Data-to-parameter ratio = 17.2

checkCIF/PLATON results

No syntax errors found



Alert level B PLAT232_ALERT_2_B Hirshfeld Test Diff (M-X) Co1 - O1 .. 16.28 su PLAT232_ALERT_2_B Hirshfeld Test Diff (M-X) Co1 - O2 .. 15.44 su PLAT232_ALERT_2_B Hirshfeld Test Diff (M-X) Co1 - O3 .. 19.40 su PLAT232_ALERT_2_B Hirshfeld Test Diff (M-X) Co1 - O4 .. 12.84 su
Alert level C PLAT199_ALERT_1_C Check the Reported _cell_measurement_temperature 293 K PLAT200_ALERT_1_C Check the Reported _diffrn_ambient_temperature . 293 K PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 2.63 Ratio PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Co1 - N1 .. 6.68 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Co1 - N3 .. 7.82 su PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C4 PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C18 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for C15
0 ALERT level A = In general: serious problem 4 ALERT level B = Potentially serious problem 8 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 10 ALERT type 2 Indicator that the structure model may be wrong or deficient 0 ALERT type 3 Indicator that the structure quality may be low 0 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Bruker, 2001); cell refinement: SAINT (Bruker, 2001); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 2001); software used to prepare material for publication: SHELXL97.

Bis(2-aminopyridine)dibenzoatocobalt(II) top
Crystal data top
[Co(C7H5O2)2(C5H6N2)2]F(000) = 2024
Mr = 489.39Dx = 1.373 Mg m3
Monoclinic, C2/cMo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2ycCell parameters from 2530 reflections
a = 25.097 (5) Åθ = 2.6–25.8°
b = 10.991 (2) ŵ = 0.76 mm1
c = 17.499 (3) ÅT = 293 K
β = 101.28 (3)°Block, red
V = 4733.7 (15) Å30.28 × 0.23 × 0.16 mm
Z = 8
Data collection top
Bruker APEX area-detector
diffractometer
5137 independent reflections
Radiation source: fine-focus sealed tube4599 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.018
φ and ω scansθmax = 27.0°, θmin = 2.0°
Absorption correction: multi-scan
(SADABS; Bruker, 2001)
h = 1432
Tmin = 0.815, Tmax = 0.888k = 1313
19355 measured reflectionsl = 2220
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.031Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.086H-atom parameters constrained
S = 1.04 w = 1/[σ2(Fo2) + (0.0529P)2 + 1.2499P]
where P = (Fo2 + 2Fc2)/3
5137 reflections(Δ/σ)max = 0.018
298 parametersΔρmax = 0.37 e Å3
0 restraintsΔρmin = 0.28 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Co10.120156 (7)0.138620 (15)0.006827 (10)0.04299 (8)
O10.13394 (4)0.29252 (9)0.06811 (6)0.0561 (3)
O20.09142 (5)0.13190 (9)0.09894 (7)0.0577 (3)
O30.19061 (4)0.03701 (9)0.05233 (6)0.0534 (2)
O40.11890 (4)0.04925 (9)0.01728 (6)0.0544 (3)
N10.04674 (5)0.19529 (12)0.07201 (8)0.0599 (3)
N20.00974 (6)0.00258 (15)0.09110 (10)0.0790 (5)
H2A0.01770.04710.11220.080*
H2B0.04070.02880.06340.080*
N30.15783 (5)0.17189 (11)0.09914 (7)0.0505 (3)
N40.20350 (6)0.34496 (12)0.04591 (9)0.0613 (3)
H4B0.22750.40530.04770.080*
H4C0.18520.34170.00650.080*
C10.11145 (6)0.23606 (13)0.11651 (9)0.0504 (3)
C20.10890 (6)0.29030 (13)0.19355 (9)0.0534 (3)
C30.08232 (9)0.22927 (19)0.24448 (11)0.0782 (5)
H3A0.06540.15230.22950.080*
C40.08049 (12)0.2794 (2)0.31640 (13)0.1007 (8)
H4A0.06220.23720.35190.080*
C50.10474 (12)0.3891 (2)0.33727 (13)0.0917 (7)
H5A0.10260.42450.38680.080*
C60.13155 (10)0.44929 (18)0.28814 (12)0.0851 (6)
H6A0.14900.52560.30370.080*
C70.13420 (8)0.39972 (16)0.21647 (11)0.0694 (5)
H7A0.15330.44170.18190.080*
C80.16454 (6)0.05823 (12)0.02820 (8)0.0463 (3)
C90.18655 (6)0.18102 (13)0.05272 (8)0.0473 (3)
C100.15254 (7)0.28116 (14)0.03886 (9)0.0577 (4)
H10A0.11520.27100.01400.080*
C110.17267 (9)0.39638 (16)0.06087 (11)0.0717 (5)
H11A0.14910.46580.05130.080*
C120.22605 (9)0.41086 (16)0.09597 (10)0.0723 (5)
H12A0.23980.49050.11140.080*
C130.26009 (8)0.31135 (17)0.10975 (9)0.0657 (4)
H13A0.29760.32210.13400.080*
C140.24039 (7)0.19599 (14)0.08847 (8)0.0542 (3)
H14A0.26390.12660.09850.080*
C150.00461 (7)0.12360 (17)0.10169 (10)0.0611 (4)
C160.04365 (8)0.1722 (2)0.14477 (14)0.0914 (7)
H16A0.07370.11990.16540.080*
C170.04753 (10)0.2928 (3)0.15827 (18)0.1170 (10)
H17A0.08100.32720.18570.080*
C180.00407 (11)0.3670 (2)0.1290 (2)0.1218 (11)
H18A0.00540.45240.14090.080*
C190.04140 (9)0.3152 (2)0.08692 (16)0.0941 (7)
H19A0.07140.36740.06610.080*
C200.19484 (6)0.25963 (13)0.10237 (9)0.0515 (3)
C210.22300 (8)0.26391 (18)0.16389 (10)0.0688 (4)
H21A0.25040.32480.16430.080*
C220.21138 (9)0.1813 (2)0.22269 (11)0.0773 (5)
H22A0.23050.18400.26510.080*
C230.17156 (8)0.09328 (19)0.22153 (10)0.0718 (5)
H23A0.16220.03520.26300.080*
C240.14656 (7)0.09186 (16)0.15927 (9)0.0610 (4)
H24A0.11920.03140.15740.080*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Co10.04012 (12)0.03381 (11)0.05397 (13)0.00831 (6)0.00654 (8)0.00088 (6)
O10.0613 (6)0.0447 (5)0.0643 (6)0.0128 (5)0.0170 (5)0.0020 (4)
O20.0571 (6)0.0461 (6)0.0723 (7)0.0161 (4)0.0189 (5)0.0068 (4)
O30.0511 (6)0.0433 (5)0.0645 (6)0.0094 (4)0.0080 (5)0.0027 (4)
O40.0530 (6)0.0414 (5)0.0643 (6)0.0063 (4)0.0006 (5)0.0003 (4)
N10.0469 (7)0.0557 (7)0.0745 (8)0.0039 (6)0.0053 (6)0.0069 (6)
N20.0530 (8)0.0710 (10)0.1049 (12)0.0208 (7)0.0051 (8)0.0021 (9)
N30.0474 (6)0.0475 (6)0.0548 (7)0.0028 (5)0.0056 (5)0.0039 (5)
N40.0604 (8)0.0510 (7)0.0749 (9)0.0171 (6)0.0190 (7)0.0005 (6)
C10.0440 (7)0.0427 (7)0.0641 (8)0.0052 (6)0.0093 (6)0.0001 (6)
C20.0525 (8)0.0473 (7)0.0589 (8)0.0010 (6)0.0071 (6)0.0006 (6)
C30.0933 (14)0.0710 (11)0.0754 (11)0.0190 (10)0.0292 (10)0.0052 (9)
C40.136 (2)0.1015 (17)0.0746 (13)0.0152 (16)0.0442 (14)0.0017 (12)
C50.130 (2)0.0828 (13)0.0612 (11)0.0148 (14)0.0165 (12)0.0098 (10)
C60.1178 (17)0.0573 (10)0.0724 (11)0.0024 (10)0.0002 (12)0.0119 (9)
C70.0869 (13)0.0520 (8)0.0667 (10)0.0105 (9)0.0085 (9)0.0022 (7)
C80.0491 (7)0.0425 (7)0.0484 (7)0.0065 (6)0.0120 (6)0.0005 (5)
C90.0571 (8)0.0442 (7)0.0424 (6)0.0011 (6)0.0142 (6)0.0008 (5)
C100.0659 (9)0.0450 (8)0.0621 (9)0.0046 (7)0.0125 (7)0.0027 (6)
C110.0956 (14)0.0435 (8)0.0775 (11)0.0029 (9)0.0203 (10)0.0061 (8)
C120.1000 (14)0.0529 (9)0.0654 (10)0.0193 (9)0.0201 (10)0.0114 (8)
C130.0683 (10)0.0736 (11)0.0554 (9)0.0180 (9)0.0129 (7)0.0084 (8)
C140.0595 (9)0.0569 (8)0.0475 (7)0.0009 (7)0.0133 (6)0.0014 (6)
C150.0447 (8)0.0759 (11)0.0620 (9)0.0069 (7)0.0088 (7)0.0009 (7)
C160.0502 (10)0.1092 (17)0.1054 (16)0.0038 (11)0.0077 (10)0.0097 (13)
C170.0677 (14)0.127 (2)0.143 (2)0.0194 (15)0.0119 (14)0.0367 (19)
C180.0861 (17)0.0823 (16)0.183 (3)0.0143 (12)0.0069 (18)0.0439 (17)
C190.0704 (12)0.0635 (11)0.138 (2)0.0029 (10)0.0061 (13)0.0226 (12)
C200.0463 (7)0.0490 (7)0.0575 (8)0.0015 (6)0.0059 (6)0.0133 (6)
C210.0666 (10)0.0754 (11)0.0672 (10)0.0051 (9)0.0198 (8)0.0162 (9)
C220.0803 (13)0.0967 (14)0.0586 (10)0.0074 (11)0.0225 (9)0.0150 (10)
C230.0766 (12)0.0828 (12)0.0518 (9)0.0096 (10)0.0026 (8)0.0034 (8)
C240.0600 (9)0.0609 (9)0.0581 (9)0.0018 (7)0.0017 (7)0.0029 (7)
Geometric parameters (Å, º) top
Co1—N32.0579 (14)C6—H6A0.9600
Co1—N12.0644 (14)C7—H7A0.9600
Co1—O42.0726 (11)C8—C91.4893 (19)
Co1—O22.1150 (13)C9—C141.383 (2)
Co1—O12.1268 (11)C9—C101.385 (2)
Co1—O32.1746 (12)C10—C111.390 (2)
C1—O11.2680 (18)C10—H10A0.9601
C1—O21.2638 (16)C11—C121.369 (3)
C8—O31.2625 (16)C11—H11A0.9600
C8—O41.2643 (17)C12—C131.380 (3)
N1—C151.339 (2)C12—H12A0.9600
N1—C191.345 (2)C13—C141.385 (2)
N2—C151.346 (2)C13—H13A0.9600
N2—H2A0.9000C14—H14A0.9599
N2—H2B0.9000C15—C161.401 (3)
N3—C201.3476 (19)C16—C171.346 (4)
N3—C241.358 (2)C16—H16A0.9599
N4—C201.349 (2)C17—C181.378 (4)
N4—H4B0.9001C17—H17A0.9599
N4—H4C0.8999C18—C191.357 (3)
C1—C21.487 (2)C18—H18A0.9600
C2—C71.382 (2)C19—H19A0.9600
C2—C31.386 (2)C20—C211.399 (2)
C3—C41.383 (3)C21—C221.360 (3)
C3—H3A0.9599C21—H21A0.9601
C4—C51.368 (3)C22—C231.394 (3)
C4—H4A0.9599C22—H22A0.9600
C5—C61.362 (3)C23—C241.360 (3)
C5—H5A0.9601C23—H23A0.9600
C6—C71.381 (3)C24—H24A0.9600
N3—Co1—N190.58 (6)O3—C8—O4119.48 (13)
N3—Co1—O496.27 (5)O3—C8—C9121.08 (13)
N1—Co1—O4104.79 (5)O4—C8—C9119.44 (12)
N3—Co1—O2168.76 (4)O3—C8—Co162.17 (8)
N1—Co1—O294.24 (6)O4—C8—Co157.54 (7)
O4—Co1—O292.32 (4)C9—C8—Co1174.22 (10)
N3—Co1—O1107.36 (5)C14—C9—C10119.92 (14)
N1—Co1—O196.93 (5)C14—C9—C8120.84 (13)
O4—Co1—O1147.63 (4)C10—C9—C8119.24 (14)
O2—Co1—O161.99 (4)C9—C10—C11119.83 (17)
N3—Co1—O390.53 (5)C9—C10—H10A120.1
N1—Co1—O3166.57 (5)C11—C10—H10A120.1
O4—Co1—O361.79 (4)C12—C11—C10120.06 (18)
O2—Co1—O387.14 (5)C12—C11—H11A120.0
O1—Co1—O395.50 (5)C10—C11—H11A119.9
C1—O1—Co189.00 (8)C11—C12—C13120.28 (16)
C1—O2—Co189.64 (9)C11—C12—H12A119.9
C8—O3—Co186.95 (9)C13—C12—H12A119.8
C8—O4—Co191.49 (8)C12—C13—C14120.14 (17)
C15—N1—C19117.39 (16)C12—C13—H13A119.9
C15—N1—Co1126.04 (12)C14—C13—H13A119.9
C19—N1—Co1116.56 (12)C9—C14—C13119.76 (15)
C15—N2—H2A119.9C9—C14—H14A120.0
C15—N2—H2B120.1C13—C14—H14A120.2
H2A—N2—H2B120.0N1—C15—N2118.76 (15)
C20—N3—C24118.15 (14)N1—C15—C16121.20 (18)
C20—N3—Co1125.89 (11)N2—C15—C16120.02 (18)
C24—N3—Co1115.79 (11)C17—C16—C15119.7 (2)
C20—N4—H4B120.0C17—C16—H16A119.9
C20—N4—H4C120.0C15—C16—H16A120.4
H4B—N4—H4C120.0C16—C17—C18119.5 (2)
O2—C1—O1119.26 (14)C16—C17—H17A120.2
O2—C1—C2119.88 (14)C18—C17—H17A120.2
O1—C1—C2120.87 (13)C19—C18—C17118.3 (2)
O2—C1—Co159.40 (8)C19—C18—H18A121.2
O1—C1—Co159.94 (8)C17—C18—H18A120.4
C2—C1—Co1176.56 (11)N1—C19—C18123.9 (2)
C7—C2—C3119.08 (16)N1—C19—H19A118.1
C7—C2—C1120.87 (15)C18—C19—H19A118.0
C3—C2—C1120.02 (14)N3—C20—N4118.72 (14)
C4—C3—C2119.89 (19)N3—C20—C21120.81 (15)
C4—C3—H3A120.6N4—C20—C21120.45 (15)
C2—C3—H3A119.5C22—C21—C20119.58 (17)
C5—C4—C3120.1 (2)C22—C21—H21A120.5
C5—C4—H4A119.8C20—C21—H21A119.9
C3—C4—H4A120.1C21—C22—C23120.04 (18)
C6—C5—C4120.56 (19)C21—C22—H22A119.9
C6—C5—H5A119.6C23—C22—H22A120.1
C4—C5—H5A119.9C24—C23—C22117.65 (18)
C5—C6—C7119.93 (19)C24—C23—H23A121.0
C5—C6—H6A119.9C22—C23—H23A121.3
C7—C6—H6A120.1N3—C24—C23123.68 (17)
C6—C7—C2120.39 (18)N3—C24—H24A117.7
C6—C7—H7A120.1C23—C24—H24A118.7
C2—C7—H7A119.5
N3—Co1—O1—C1174.15 (9)O2—Co1—C1—O1176.67 (14)
N1—Co1—O1—C193.06 (9)O3—Co1—C1—O199.80 (9)
O4—Co1—O1—C139.17 (12)C8—Co1—C1—O1126.82 (9)
O2—Co1—O1—C11.94 (8)O2—C1—C2—C7174.92 (15)
O3—Co1—O1—C181.86 (9)O1—C1—C2—C74.5 (2)
C8—Co1—O1—C165.57 (10)O2—C1—C2—C33.1 (2)
N3—Co1—O2—C117.6 (3)O1—C1—C2—C3177.52 (16)
N1—Co1—O2—C197.55 (9)C7—C2—C3—C41.3 (3)
O4—Co1—O2—C1157.42 (9)C1—C2—C3—C4179.3 (2)
O1—Co1—O2—C11.95 (8)C2—C3—C4—C50.2 (4)
O3—Co1—O2—C195.83 (9)C3—C4—C5—C61.0 (4)
C8—Co1—O2—C1126.73 (9)C4—C5—C6—C70.3 (4)
N3—Co1—O3—C899.97 (9)C5—C6—C7—C21.2 (3)
N1—Co1—O3—C85.2 (2)C3—C2—C7—C62.0 (3)
O4—Co1—O3—C83.15 (8)C1—C2—C7—C6179.98 (17)
O2—Co1—O3—C891.03 (8)Co1—O3—C8—O45.23 (13)
O1—Co1—O3—C8152.53 (8)Co1—O3—C8—C9174.50 (12)
C1—Co1—O3—C8121.81 (9)Co1—O4—C8—O35.48 (14)
N3—Co1—O4—C890.37 (9)Co1—O4—C8—C9174.25 (11)
N1—Co1—O4—C8177.36 (9)N3—Co1—C8—O381.69 (9)
O2—Co1—O4—C882.36 (9)N1—Co1—C8—O3178.26 (8)
O1—Co1—O4—C846.84 (12)O4—Co1—C8—O3174.61 (14)
O3—Co1—O4—C83.14 (8)O2—Co1—C8—O387.65 (9)
C1—Co1—O4—C869.10 (10)O1—Co1—C8—O332.94 (10)
N3—Co1—N1—C15107.51 (15)C1—Co1—C8—O362.23 (9)
O4—Co1—N1—C1510.87 (16)N3—Co1—C8—O492.92 (9)
O2—Co1—N1—C1582.66 (15)N1—Co1—C8—O43.65 (12)
O1—Co1—N1—C15144.93 (15)O2—Co1—C8—O497.75 (9)
O3—Co1—N1—C1512.8 (3)O1—Co1—C8—O4152.45 (8)
C8—Co1—N1—C158.93 (18)O3—Co1—C8—O4174.61 (14)
C1—Co1—N1—C15113.61 (15)C1—Co1—C8—O4123.16 (9)
N3—Co1—N1—C1971.27 (17)O3—C8—C9—C1414.0 (2)
O4—Co1—N1—C19167.90 (17)O4—C8—C9—C14166.32 (13)
O2—Co1—N1—C1998.56 (17)O3—C8—C9—C10166.50 (14)
O1—Co1—N1—C1936.30 (17)O4—C8—C9—C1013.2 (2)
O3—Co1—N1—C19166.0 (2)C14—C9—C10—C110.1 (2)
C8—Co1—N1—C19169.85 (16)C8—C9—C10—C11179.48 (14)
C1—Co1—N1—C1967.61 (17)C9—C10—C11—C120.2 (3)
N1—Co1—N3—C20111.96 (12)C10—C11—C12—C130.1 (3)
O4—Co1—N3—C20143.09 (12)C11—C12—C13—C140.3 (3)
O2—Co1—N3—C203.5 (3)C10—C9—C14—C130.4 (2)
O1—Co1—N3—C2014.51 (13)C8—C9—C14—C13179.10 (13)
O3—Co1—N3—C2081.42 (12)C12—C13—C14—C90.6 (2)
C8—Co1—N3—C20111.95 (12)C19—N1—C15—N2176.7 (2)
C1—Co1—N3—C209.98 (15)Co1—N1—C15—N22.1 (2)
N1—Co1—N3—C2472.87 (12)C19—N1—C15—C161.7 (3)
O4—Co1—N3—C2432.08 (11)Co1—N1—C15—C16179.52 (16)
O2—Co1—N3—C24171.7 (2)N1—C15—C16—C171.5 (4)
O1—Co1—N3—C24170.31 (11)N2—C15—C16—C17176.8 (2)
O3—Co1—N3—C2493.75 (11)C15—C16—C17—C180.5 (5)
C8—Co1—N3—C2463.22 (12)C16—C17—C18—C190.3 (5)
C1—Co1—N3—C24174.84 (10)C15—N1—C19—C180.9 (4)
Co1—O2—C1—O13.31 (14)Co1—N1—C19—C18179.8 (3)
Co1—O2—C1—C2176.11 (12)C17—C18—C19—N10.1 (5)
Co1—O1—C1—O23.29 (14)C24—N3—C20—N4175.21 (14)
Co1—O1—C1—C2176.12 (12)Co1—N3—C20—N49.72 (19)
N3—Co1—C1—O2174.93 (8)C24—N3—C20—C213.5 (2)
N1—Co1—C1—O285.70 (9)Co1—N3—C20—C21171.60 (12)
O4—Co1—C1—O226.47 (10)N3—C20—C21—C222.6 (2)
O1—Co1—C1—O2176.67 (14)N4—C20—C21—C22176.11 (16)
O3—Co1—C1—O283.53 (9)C20—C21—C22—C230.1 (3)
C8—Co1—C1—O256.51 (10)C21—C22—C23—C241.7 (3)
N3—Co1—C1—O18.40 (12)C20—N3—C24—C231.8 (2)
N1—Co1—C1—O190.97 (9)Co1—N3—C24—C23173.73 (14)
O4—Co1—C1—O1156.86 (8)C22—C23—C24—N30.8 (3)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
N4—H4C···O10.902.082.9536 (19)164
N4—H4B···O3i0.902.172.9791 (17)150
N2—H2B···O40.901.982.849 (2)161
N2—H2A···O2ii0.902.122.9178 (18)147
Symmetry codes: (i) x+1/2, y+1/2, z; (ii) x, y, z.
 

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