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A well defined supramolecular structure, C6H8N2.C6H6O2.0.5H2O, is generated by molecular recognition between pyrocatechol and o-phenylenediamine in the presence of water. They spontaneously self assemble through a unique network of hydrogen bonds around a twofold axis.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, ha1221

fcf

Structure factor file (CIF format)
Contains datablock ha1221

CCDC reference: 130587

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