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The title compounds are derivatives of dimethylenesuccinic anhydride and belong to the fulgide family of compounds. The fulgides were the first photochromic systems to be discovered. Fulgide (I) (C30H20O3) possesses a crystallographic twofold axis. The divinylsuccinic anhydride moiety is not planar in fulgides (II) (C27H22O3) and (III) (C27H20O6). In both (II) and (III), the C atom bonded to the fluorenyl moeity deviates significantly from the mean plane through the five-membered ring of the fluorenyl moiety.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks I, II, III, fulgid

sft

Structure factor file (SHELXL table format)
Supplementary material

sft

Structure factor file (SHELXL table format)
Supplementary material

sft

Structure factor file (SHELXL table format)
Supplementary material

CCDC references: 129951; 129952; 129953

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