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X-ray analyses have established the structures of (3aα,7aα)-6-chloromethyl-8,8-dichloro-2,3-dihydro-5-methoxy-3a,7a-methano-1H-indene, C12H13Cl3O and (3aα,8aα)-6,9,9-trichloro-2,3,5,8-tetrahydro-1H,4H-3a,8a-methanoazulen-5-one, C11H11Cl3O, which have resulted from different modes of cyclopropane ring-cleavage within the framework of two closely related gem-dichloro[4.3.1]propellanes.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks 3, 4, default

hkl

Structure factor file (CIF format)
Contains datablock 3

hkl

Structure factor file (CIF format)
Contains datablock 4

CCDC references: 129709; 129710

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